• Title/Summary/Keyword: Base Potential

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Cempedak Durian (Artocarpus sp.) Peel as a Biosorbent for the Removal of Toxic Methyl Violet 2B from Aqueous Solution

  • Dahri, Muhammad Khairud;Chieng, Hei Ing;Lim, Linda B.L.;Priyantha, Namal;Mei, Chan Chin
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.576-583
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    • 2015
  • This paper aims to investigate the potential use of cempedak durian peel (CDP) from Negara Brunei Darussalam, which is low-cost, locally available, eco-friendly and highly efficient to remove methyl violet (MV) dye from aqueous solutions. The time required for equilibrium to be reached is 2.0 h with no adjustment of pH necessary. FTIR analysis was indicative of the involvement of -COOH and C=O functional groups in adsorption process. The Langmuir model provided the best fit with maximum adsorption capacity of $0.606mmol\;g^{-1}$. Thermodynamics data indicate that the adsorption is spontaneous, feasible and endothermic in nature. Best regeneration of CDP's adsorption ability is achieved by base solution, showing about 95% removal efficiency of MV even after 5 cycles, indicating that CDP can be regenerated and reused. This, together with its high adsorption capacity, makes CDP a potential adsorbent for the removal of MV in wastewater.

Stress Corrosion Cracking Behavior under Cavitation Erosion-Corrosion in Sea Water-Part (II) (해수환경중 캐비테이션 침식-부식 하에서의 응력부식균열 거동 (II))

  • 안석환;임우조
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.36 no.2
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    • pp.139-146
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    • 2000
  • Cavitation can occur in pipes when liquid is moving at high velocity, especially at pittings where the smooth bore of the pipe is interrupted. The effect is usually to produce pitting on the downstream side of the turbulence. However, stress corrosion cracking behavior under cavitation erosion-corrosion was neatly unknown. In this study, therefore, some were investigated of stress corrosion cracking behavior, others were stress corrosion cracking behavior under cavitation erosion-corrosion of water injection. And datas obtained as the results of experiment were compared between the two. Mainresult obtained are as follows: 1) Stress corrosion cracking growth rate of heat affected zone under cavitation erosion-corrosion becomes most rapid, and stress intensity factor $K_1$becomes most high. 2) Stress corrosion cracking growth mechanism by cavitation erosion-corrosion is judgement on the strength of the film rupture model and the tunnel model. 3) The range of potential as passivation of heat affected zone is less noble than that of base metal, and that value is smaller. 4) Corrosion potential under cavitation erosion-corrosion in loaded stress is less noble than that of stress corrosion, and corrosion current density is higher.

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An Investigation on Quantity of Unused Energy Using Temperature Difference Energy as Heat Source and Its Availability (온도차에너지를 열원으로 하는 미활용에너지의 부존량과 이용가능성에 관한 조사연구)

  • 박준택;장기창
    • Journal of Energy Engineering
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    • v.11 no.2
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    • pp.106-113
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    • 2002
  • While the demand for energy has shown a sharp increase recently, the supply seems to be limited by the fact that the conventional fossil fuel energy or nuclear energy has its own environmental problems such as, for example, global warming or nuclear waste disposal. To overcome such limited supply of energy, the utilization of natural thermal energy such as river water and sea water as well as treated sewage can be a substantial supplement. The potential use of the unused energy has become more and more feasible these days as the heat pump technology has been advanced. In the present study, the unused energy reserves are estimated on regional and monthly basis for each resource based on the method developed here in order to establish the base data for its utilization. The potential use of the unused energy is also discussed.

Environmental Impact Evaluation of Virgin Pulp Using Life Cycle Assessment Methodology (LCA기법을 이용한 천연펄프의 환경 영향 평가)

  • 김형진;조병묵;황용우;박광호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.49-60
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    • 2004
  • Life Cycle Assessment for the pulp, which is mainly used as the raw material of fine paper, base paper for food packaging and paper cup, has been carried out in this study to consider environmental aspects by quantifying the environmental emission and to evaluate its environmental impact potential. The system boundary was selected from cradle to gate stage(raw material acquisition, transportation of raw material and product manufacturing) of the product. Environmental impact was divided into 8 categories considering Korean situation: abiotic resource depletion, global warming, ozone depletion, acidification, eutrophication, photochemical oxidant creation, ecotoxicity and human toxicity. In Life Cycle Impact Assessment(LCIA) methodology phase, Ecopoint, Eco-indicator 95 and Korean eco-indicator were used and the results carried out by each methodology were compared. The results from this study were also compared with those of foreign study to verify the reliability of the results. The results of the study could be utilized as the basic data for Environmental Management System(EMS), Design for Environment(DfE) and Type III eco-labeling in the paper and paper-related industry.

Development of Site Index Equation and Curves for Site Quality Assessment of Pinus caribea Monoculture Plantations in Southwestern Nigeria

  • Oyebade, Bukola Amoo;Osho, Johnson Sunday Ajose;Adesoye, Peter Oluremi
    • Journal of Forest and Environmental Science
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    • v.30 no.4
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    • pp.315-321
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    • 2014
  • Forest timber production potential of any site is oftentimes measured quantitatively by site index, which is defined as dominant height of a particular stand at a specified age. A site index was developed for estimating site quality of monoculture Pinus caribaea plantations in southwestern Nigeria using a base age of 25 years. Dominant height data were collected from 60 Temporary Sample Plots (TSPs) of $20{\times}20m$ in plantations of 15 to 37 years. Linear and non-linear models as been widely applied in quantitative forest measurements were fitted to dominant height-age data and the best site index equation is : $SI=Exp^{(InHd-23.495(A^{-2}-0.04)}$. The site index curves constructed for the three sites (Omo Forest Reserve - OFR (J4), Oluwa Forest Reserve - OLFR and Shasha Forest Reserve - SFR) across the southwestern Nigeria using the chosen equation revealed that a 15 year old Pinus caribaea in the study area attained average dominant heights of 25, 22 and 21 m in OFR (J4), OLFR and SFR respectively. The site index equation and curves proffer veritable insight into better silvicultural options and management practices for the future plantations suitable sites.

The Effect of Heat Treatment on the Corrosion-Resistance for Ti-6Al-4V Alloy (Ti-6Al-4V합금의 열처리가 내식성에 미치는 영향)

  • 백신영;나은영
    • Journal of Advanced Marine Engineering and Technology
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    • v.27 no.3
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    • pp.453-459
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    • 2003
  • In this study, the effect of heat treatment to the electrochemical polarization resistance for the Ti-6Al-4V alloy was measured. The solution heat treatments were carried out at $1066^{circ}E, 966^{\circ}$E$, followed by aging heat treated $550^{circ}E, 600^{circ}E, and 650^{circ}E$. The electrochemical polarization resistance behavior was measured by potentio-dynamic polarization in the 1N $HNO_3$ + 15ppm HF solution. The obtained results were as follows. 1. As solution heat temperature increased. the corrosion potential was increased, whereas passive current density and critical current density were decreased. 2. As aging heat temperature increased, the corrosion potential was almost constant, but passive current density was decreased 3. The results of composition test measured by EDS at grain boundary and near $\gamma'$ precipitates indicated that S, Cl. and Si which originated from base metal were segregated at the grain boundaries Al and Ti which were the main alloying element in $\gamma'$ were depleted at the $\gamma'$ precipitated. The depletion of Al and Ti in $\gamma'$ was caused to early breakdown of passive film.

Occurrence of Leaf Spot Disease Caused by Alternaria crassa (Sacc.) Rands on Jimson Weed and Potential Additional Host Plants in Algeria

  • Bessadat, Nabahat;Hamon, Bruno;Bataille-Simoneau, Nelly;Chateau, Corentin;Mabrouk, Kihal;Simoneau, Philippe
    • The Plant Pathology Journal
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    • v.36 no.2
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    • pp.179-184
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    • 2020
  • A leaf spot pathogen Alternaria sp. was recovered from jimson weed, tomato, parsley, and coriander collected during surveys of blight diseases on Solanaceae and Apiaceae in Algeria. This species produced large conidial body generating long apical beaks that tapered gradually from a wide base to a narrow tip and short conidiophores originating directly from the agar surface. This species exhibited morphological traits similar to that reported for Alternaria crassa. The identification of seven strains from different hosts was confirmed by sequence analyses at the glyceraldehyde-3-phosphate dehydrogenase, RNA polymerase second largest subunit, and translation elongation factor 1-alpha loci. Further the pathogen was evaluated on jimson weed, coriander, parsley, and tomato plants, and this fungus was able to cause necrotic lesions on all inoculated plants. A. crassa is reported for the first time as a new species of the Algerian mycoflora and as a new potential pathogen for cultivated hosts.

The Theory and Application of Diffusive Gradient in Thin Film Probe for the Evaluation of Concentration and Bioavailability of Inorganic Contaminants in Aquatic Environments (박막분산탐침(diffusive gradient in thin film probe)의 수중 생물학적 이용가능한 중금속 측정 적용)

  • Hong, Yongseok
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.691-702
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    • 2013
  • This review paper summarizes the theory, application, and potential drawbacks of diffusive gradient in thin film (DGT) probe which is a widely used in-situ passive sampling technique for monitoring inorganic contaminants in aquatic environments. The DGT probe employs a series of layers including a filter membrane, a diffusive hydrogel, and an ionic exchange resin gel in a plastic unit. The filter side is exposed to an aquatic environment after which dissolved inorganic contaminants, such as heavy metals and nuclides, diffuse through the hydrogel and are accumulated in the resin gel. After retrieval, the contaminants in the resin gel are extracted by strong acid or base and the concentrations are determined by analytical instruments. Then aqueous concentrations of the inorganic contaminants can be estimated from a mathematical equation. The DGT has also been used to monitor nutrients, such as ${PO_4}^{3-}$, in lakes, streams, and estuaries, which might be helpful in assessing eutrophic potential in aquatic environments. DGT is a robust in-situ passive sampling techniques for investigating bioavailability, toxicity, and speciation of inorganic contaminants in aquatic environments, and can be an effective monitoring tool for risk assessment.

A Study on the Variation of HAA Precursors by Ozonation of Phenol (페놀의 오존 산화시 관찰된 HAA 전구물질 변화에 관한 연구)

  • Oh, Byung Soo;Kim, Kyoung Suk;Kang, Joon-Wun
    • Journal of Korean Society on Water Environment
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    • v.21 no.2
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    • pp.153-157
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    • 2005
  • The purpose of this study was to find out the effect of oxidation by-products for the formation of haloacetic acid (HAA) during ozonation. The phenol was used as a model precursor of HAA, and its oxidation by-products, such as hydroquinone, catechol, glyoxal, glyoxylic acid and oxalic acid were investigated to find out how much HAA formation potential (HAAFP) they have. As the result, among the phenol and its oxidation by-products, the highest reactivity with chlorine was found from the phenol, showing the highest HAAFP. Even though the tested by-products had a lower HAAFP than phenol, it was confirmed that all of them can act as the precursor of HAA. From the ozonation of phenol-containing water, it was found that the efficiency of ozone in controlling of HAAs can be reduced due to the oxidation by-products. In addition, the ozonation of HAAFP was performed under the both pH conditions (acid and base), and the result indicates that OH radical play a important role to decrease HAAFP.

UV-induced Crosslinking of Poly(vinyl acetate) Films Containing Benzophenone (벤조페논을 함유한 폴리비닐아세테이트 필름의 자외선 조사에 의한 가교)

  • Sim, Young-Jae;Seo, Eun-Kyo;Choi, Gyong-Jun;Yoon, Sung-Jong;Jang, Jin-Ho
    • Textile Coloration and Finishing
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    • v.21 no.4
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    • pp.33-38
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    • 2009
  • Poly(vinyl acetate) films containing benzophenone were photocrosslinked by continuous UV irradiation.UV irradiation of PVAc film containing 5% benzophenone induced bulk crosslinking of the polymer indicated by 84.1% of gel fraction after ethyl acetate extraction. The crosslinking was attributed to the recombination of tertiary polymer radicals generated upon UV irradiation, which was enhanced by the hydrogen abstraction of benzophenone. Also the UV irradiation resulted in scission of ester linkage and photooxidation of PVAc surface, which was verified by ATR and zeta potential analysis, implying that the PVAc surface became more polar and hydrophilic. The zeta potential proportionally increased from +4.5mV to -26.8 mV with increasing UV irradiation. Also the surface energy of the PVAc film increased with higher UV irradiation upto 56.5 $mJ/m^2$ by the enhanced Lewis acid/base component with larger contribution of Lewis acid parameter. Accordingly the crosslinked PVAc showed higher thermal stability with increasing UV energy.