• Title/Summary/Keyword: Base Potential

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Blood Electrolytes and Metabolites in Rat Model of Acute Metabolic and Respiratory Alkalosis (흰쥐 급성 대사성 알칼리증과 호흡성 알칼리증 모델에서 혈액 전해질 및 대사산물)

  • Kim, Shang-Jin;Lee, Mun-Young;Kim, Jin-Shang;Kang, Hyung-Sub
    • Journal of Veterinary Clinics
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    • v.27 no.3
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    • pp.257-261
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    • 2010
  • The development of blood ionic changes could be precipitated in acid-base disorder and subsequent treatment. As technology for detecting circulating ionized $Mg^{2+}$ (the most interesting form with respect to physiological and biological properties) is now available in veterinary clinical medicine. This present study investigated the changes of whole blood ionized $Mg^{2+}$ correlated with acute metabolic and respiratory alkalosis in rodent model. Metabolic alkalosis was induced by intravenous infusion with $NaHCO_3$ and mechanical hyperventilation was applied for respiratory alkalosis. We founded that the blood ionized $Mg^{2+}$ could be reversibly decreased by the $NaHCO_3$-induced acute metabolic alkalosis but irreversibly increased by the mechanical hyperventilation-induced respiratory acidosis and respiratory acidosis. We suggested that the potential change in blood suggested that the potential change in blood ionized $Mg^{2+}$ should be counted in treatment of acid-base disorders.

A Multi-Phase Decision Making Model for Supplier Selection Under Supply Risks (공급 리스크를 고려한 공급자 선정의 다단계 의사결정 모형)

  • Yoo, Jun-Su;Park, Yang-Byung
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.40 no.4
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    • pp.112-119
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    • 2017
  • Selecting suppliers in the global supply chain is the very difficult and complicated decision making problem particularly due to the various types of supply risk in addition to the uncertain performance of the potential suppliers. This paper proposes a multi-phase decision making model for supplier selection under supply risks in global supply chains. In the first phase, the model suggests supplier selection solutions suitable to a given condition of decision making using a rule-based expert system. The expert system consists of a knowledge base of supplier selection solutions and an "if-then" rule-based inference engine. The knowledge base contains information about options and their consistency for seven characteristics of 20 supplier selection solutions chosen from articles published in SCIE journals since 2010. In the second phase, the model computes the potential suppliers' general performance indices using a technique for order preference by similarity to ideal solution (TOPSIS) based on their scores obtained by applying the suggested solutions. In the third phase, the model computes their risk indices using a TOPSIS based on their historical and predicted scores obtained by applying a risk evaluation algorithm. The evaluation algorithm deals with seven types of supply risk that significantly affect supplier's performance and eventually influence buyer's production plan. In the fourth phase, the model selects Pareto optimal suppliers based on their general performance and risk indices. An example demonstrates the implementation of the proposed model. The proposed model provides supply chain managers with a practical tool to effectively select best suppliers while considering supply risks as well as the general performance.

Grape Pruning Stem Extract (GPSE) Suppresses Allergy and Skin Proliferation Inhibition against UVB Induced Skin Damage (포도전정가지 추출물이 UVB에 유도된 피부 손상에 대한 알레르기와 피부증식 억제효과)

  • Kim, Joung-Hee;Kim, Dae Hwan;Kim, Keuk-Jun
    • Korean Journal of Clinical Laboratory Science
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    • v.49 no.4
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    • pp.329-336
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    • 2017
  • This study examined the effects of polyphenols in grape pruning stem extracts (GPSE) using grape stems discarded after harvest. The inhibitory effects on allergy, proliferation, and apoptosis in UVB-induced HR-1 hairless mice were analyzed. The applicability as a material for functional food and functional cosmetics was evaluated. The contents of the active ingredients of GPSE were analyzed by HPLC. After UVB irradiation on the dermis of HR-1 hairless mice, the number of mast cells was determined by toluidine blue staining to confirm that the skin allergic reaction was caused by GPSE. The results were similar to the normal group in the group applied GPSE, and there was no allergic reaction in the GPSE application group and a significant decreased compared to the sun cream control. PCNA immunohistochemical staining of the epidermal proliferation factor had an inhibitory effect on epidermal epithelial cell proliferation in all concentrations of GPSE and serum base mixture as an average of 42% compared to the control group. The mixture of GPSE and serum base suppressed the apoptosis inhibition rate by 27% on average compared to the control. These results confirmed the inhibitory effects GPSE on the allergic, proliferation, and apoptosis activities by with a serum base on UVB-induced skin damage. GPSE is a functional ingredient with potential skin protection effects, and has a high utilization as an ingredient for functional cosmetics.

Electrochemical Properties of Oxygen Adducts Tetradentate Schiff Base Cobalt (II) Complexes in Pyridine (Ⅲ) (Pyridine 용액에서 네자리 Schiff Base Cobalt (II) 착물들의 산소첨가 생성물에 대한 전기화학적 성질 (제 3 보))

  • Ky Hyung Cho;Seong Seob Seo;Dong Chul Chon
    • Journal of the Korean Chemical Society
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    • v.33 no.3
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    • pp.295-303
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    • 1989
  • Tetradentate Schiff base cobalt(II) complex; Co(SND) and Co(SOPD) were synthesized, and these complexes were allowed to react with dry oxygen to form oxygen adducts cobalt(III) complexes such as $[Co(SND)(Py)]_2O_2$ and $[Co(SOPD)(Py)]_2O_2$ in pyridine. These complexes have been identified by IR specta, T.G.A., magnetic susceptibilities measurements and elemental analysis. It has been found that the oxygen adducts coblat(III) complexes have hexacoordinated octahedral configuration with tetradentate Schiff base cobalt(II), pyridine and oxygen, and the mole ratio of oxygen to cobalt(II) complexes are 1;2. The redox reaction processes of $Co(SND)(Py)_2$ and $Co(SOPD)(Py)_2$ complexes were investigated by cyclic voltammetry with glassy carbon electrode in 0.1M TEAP pyridine. The result of redox reaction processes of Co(III)/Co(II) and Co(II)/Co(I) for $Co(SND)(Py)_2$ and $Co(SOPD)(Py)_2$ complexes are reversible or quasi reversible process but oxygen adducts complexes are irreversible processes. Redox process for oxygen of oxygen adducts complexes was quasi reversible and redox range of potential was $E_{pc}\;=\;-0.96{\sim}-1.03V$ and $E_{pa}\;=\;-0.78{\sim}-0.80V.$

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Quantification of nonlinear seismic response of rectangular liquid tank

  • Nayak, Santosh Kumar;Biswal, Kishore Chandra
    • Structural Engineering and Mechanics
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    • v.47 no.5
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    • pp.599-622
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    • 2013
  • Seismic response of two dimensional liquid tanks is numerically simulated using fully nonlinear velocity potential theory. Galerkin-weighted-residual based finite element method is used for solving the governing Laplace equation with fully nonlinear free surface boundary conditions and also for velocity recovery. Based on mixed Eulerian-Lagrangian (MEL) method, fourth order explicit Runge-Kutta scheme is used for time integration of free surface boundary conditions. A cubic-spline fitted regridding technique is used at every time step to eliminate possible numerical instabilities on account of Lagrangian node induced mesh distortion. An artificial surface damping term is used which mimics the viscosity induced damping and brings in numerical stability. Four earthquake motions have been suitably selected to study the effect of frequency content on the dynamic response of tank-liquid system. The nonlinear seismic response vis-a-vis linear response of rectangular liquid tank has been studied. The impulsive and convective components of hydrodynamic forces, e.g., base shear, overturning base moment and pressure distribution on tank-wall are quantified. It is observed that the convective response of tank-liquid system is very much sensitive to the frequency content of the ground motion. Such sensitivity is more pronounced in shallow tanks.

공업용수배관의 캐비테이션-침식특성에 관한 연구 ( 1 ) ( Study on the Charactistics of Cavitation Erosion for Industrial Water Piping ( 1 ) )

  • 김윤곤
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.30 no.4
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    • pp.312-319
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    • 1994
  • Recently, with the rapid development in the industries such as an iron mill and chemical plants, there is enlarged by the use of the piping. Sepecially, the piping connected with a fluid, if it is increase the speed of running fluid, ought to generate cavitation phenomenon with unbalanced pressure. So, the cavitation phenomenon cause serious damage of the piping, because it generate erosion and corrosion in the piping. In this study, the steel pipe piping water (SPPW) and SPPW on weldment were tested by using of cavitation-erosion test apparatus with nozzle and were investigated under the marine environment of liquid. (specific resistance : 25 $Omega$. cm) The main results obtained are as follows : 1) The total weight loss and weight loss rate of affected zone of weldment by corrosion-erosion in the sea water are more increased than that of base metal. 2) The electrode potential by corrosion-erosion in the sea water becomes less noble than that of base metal, and current density is more increased. 3) As time goes by, the total weight loss and weight loss rate by cavitation erosion-corrosion in air-liquid 2 phase flow become more increased then those in only liquid solution. but these values turn to be decreased.

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The Coordinates Computation of the GPS Base Station by Precise Point Positioning (정밀절대측위(PPP)기법에 의한 GPS 기준점 좌표의 산정)

  • 이용창
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.17 no.2
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    • pp.145-152
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    • 1999
  • JPL(Jet Propulsion Laboratory) has been routinely produced the precise GPS ephemeris and clock's correction parameter using data collected from globally distributed permanent GPS tracking stations, and has been offering the automated GPS data analysis(Precise Point Positioning: PPP) service by using them. In this study, after investigating the potential capacity of JPL's PPP service, the coordinates computation of the GPS base station by this service were investigated. For this, the dual frequency P codes data of 24 hours were observed from continuously operating four reference stations in USA. sent to the JPL's main computer through E-mail and/or ftp, and then were processed by Gipsy/Oasis-II (GOA-II) software with the precise GPS transmitter parameters. Centimeter-level positioning results were available to obtain in X, Y, Z geocentric rectangular coordinate system.

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Molecular Characterization of AceB, a Gene Encoding Malate Synthase in Corynebacterium glutamicum

  • Lee, Heung-Shick;Anthony J. Sinskey
    • Journal of Microbiology and Biotechnology
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    • v.4 no.4
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    • pp.256-263
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    • 1994
  • The aceB gene, encoding for malate synthase, one of the key enzymes of glyoxylate bypass, was isolated from a pMT1-based Corynebacterium glutamicum gene library via complementation of an Escherichia coli aceB mutant on an acetate minimal medium. The aceB gene was closely linked to aceA, separated by 598 base pairs, and transcribed in divergent direction. The aceB expressed a protein product of Mr 83, 000 in Corynebacterium glutamicum which was unusually large compared with those of other malate synthases. A DNA-sequence analysis of the cloned DNA identified an open-reading frame of 2, 217 base pairs which encodes a protein with the molecular weight of 82, 311 comprising 739 aminoo acids. The putative protein product showed only limited amino acid-sequence homology to its counteliparts in other organisms. The N-terminal region of the protein, which shows no apparent homology with the known sequences of other malate synthases, appeared to be responsible for the protein s unusually large size. A potential calciumbinding domain of EF-hand structure found among eukaryotes was detected in the N-terminal region of the deduced protein.

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Structures of (4-Nitro-benzylidene)-(3-nitro-phenyl)-amine and trans-Dichlorobis (3-nitroaniline) palladium(II) ((4-Nitro-benzylidene)-(3-nitro-phenyl)-amine 및 trans-Dichlorobis(3-nitroaniline) palladium(II)의 구조)

  • Lee Hee K.;Lee Soon W.
    • Korean Journal of Crystallography
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    • v.16 no.1
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    • pp.6-10
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    • 2005
  • A novel potential linking ligand (4-nitro-benzylidene)-(3-nitro-phenyl)-amine (1) was prepared from 4-nitrobenzaldehyde and 3-nitroaniline by the Schiff-base condensation. From the reaction between 1 and dichlorobis(benzonitrile)palladium (II) $(PdCl_2(NCPh)_2)$, an unexpected product $trans-PdCl_2(NO_2-C_6H_4-NH_2)_2$ (2) was isolated. Compounds 1 and 2 were structurally characterized by X-ray diffraction. In compound 2, the $NH_2$ hydrogen atoms in the 3-nitroaniline ligand participate in intermolecular N-H${\cdot}\;{\cdot}\;{\cdot}\;$Cl hydrogen bonds.

Theoretical and Experimental Studies on the Adsorption of N-[(E)-Pyridin-2-ylmethylidene] Aniline, a Schiff Base, on Mild Steel Surface in Acid Media

  • N, Mohanapriya.;M, Kumaravel.;B, Lalithamani.
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.117-131
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    • 2020
  • The adsorption of N-[(E)-Pyridin-2-ylmethylidene] aniline, a Schiff base, on to mild steel surface in 1M HCl and 0.5 M H2SO4 solutions and the consequent corrosion protection were studied employing weight loss method, electrochemical impedance spectroscopy and potentiodynamic polarization measurements. DFT calculations were performed to investigate its interaction with the metal surface at the atomic level to understand its inhibition mechanism. The adsorption process is well described by the Langmuir isotherm. The thermodynamic parameters indicated that the adsorption is spontaneous and the interaction of the inhibitor at the mild steel surface is mainly through physisorption. The Ra values obtained in AFM studies for the uninhibited and inhibited sample in HCl media respectively are 0.756 and 0.559 ㎛, and that in H2SO4 media are 0.411 and 0.406 ㎛. The lesser roughness values of the inhibited sample shows the adsorption of the molecules onto the mild surface. The inhibition efficiencies were found to improve with concentration of the inhibitor and the maximum efficiency was observed at 400ppm in all the investigation methods adopted. The inhibitor was found to exhibit a higher efficiency in HCl media (95.7%) than in H2SO4 (92.8%). The theoretical and experimental results are found to be in good agreement.