• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2003.11a
• /
• pp.139-148
• /
• 2003

In this study, biodegradable base Li-greases were prepared by using Li-soap thickener and vegetable oils such as soybean oil, rapeseed oil, castor oil and synthetic ester. Also, EP-greases were formulated by blending base Li-greases, anti-wear additives, EP additives, anti-oxidants and corrosion inhibitor etc. And EP-greases were characterized by analysing physical properties such as worked penetration, dropping point, 4-ball wear, extreme pressure, thermal properties etc. Biodegradability of base Li-greases and EP-greases were evaluated by CEC-L-33-A-93 method using several inoculums of domestic sewage treatment plant. As the results, biodegradability of vegetable oils were shown at the range of 97.1 to $98.4\%$. And biodegradability of base Li-greases and EP-greases were $86.2\%\;\~\;89.3\%\;and\;83.4\%\;\~\;90.0\%$ which were lower value than those o( vegetable oils due to effect of Li-soap thickener, respectively. Therefore, the EP-greases prepared in this study were easily biodegraded by microorgnism.

• Tribology and Lubricants
• /
• v.19 no.5
• /
• pp.280-284
• /
• 2003

High performance characteristics are required for rolling bearings and the various functions of bearing are greatly influenced by grease. Recently, higher performance is being demanded of rolling bearing greases for bearing lubrication. Four special greases with different composition such as lithium soap/ester oil, urea/ester oil, urea/ether oil and PTFE/fluorine oil were synthesized to compare the performance of these greases with that of the conventional lithium soap/mineral oil grease. The grease properties were investigated using a series of typical grease testing methods and grease life test. After the life test, the greases were charaterized by FTIR analysis and a microscope. And the iron amount in the greases was analyzed by AAS after ashing. The composition and manufacturing process determined the grease performance. The grease with a base oil of synthetic oil showed higher performance and the urea/ester oil and PTFE/fluorine oil showed about three times longer life as compared with conventional lithium grease.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2001.11a
• /
• pp.179-185
• /
• 2001

High performance characteristics are required for rolling bearings and the various functions of bearing are greatly influenced by grease. Recently, higher performance is being demanded of rolling bearing greases for bearing lubrication. Four special greases with different composition such as lithium soap/ester oil, urea/ester oil, urea/ether oil and PTFE/fluorine oil were synthesized to compare the performance of these greases with that of the conventional lithium soap/mineral oil grease. The grease properties were investigated using a series of typical grease testing methods and grease life test. After the life test, the greases were charaterized by FTIR analysis and a microscope. And the iron amount in the greases was analyzed by AAS after ashing. The composition and manufacturing process determined the grease performance. The grease with a base oil of synthetic oil showed higher performance and the urea/ester oil and PTFE/fluorine oil showed about three times longer life as compared with conventional lithium grease.

• Tribology and Lubricants
• /
• v.31 no.5
• /
• pp.195-204
• /
• 2015

Several researches are focused on improving the value of fine chemicals based on biomass resources due to environmental and other concerns associated with the use of petroleum-based products. Therefore, the synthesis and application of estolides derived from plant-based waste oil materials and their application as lubricants and as processing oil for butyl rubber products have been studied. Four kinds of estolide were prepared with conversions of 71~92% over 24h using various vegetable oils, as determined by size exclusion chromatography (SEC) and nuclear magnetic resonance (NMR) spectroscopy. FT-IR spectroscopy determines the esterification of estolides using 2-ethylhexyl alcohol. The estolides have iodine values of 35~90, α-ester/α-acid ratios of 0.45~0.55, and total acid number of 114~134 mg KOH g^–1. Four ball wear tests show that the wear scar diameters (WSDs) of estolides as base oil significantly decreased to 0.328~0.494 mm, compared to WSDs of 0.735 and 0.810 mm of WSD for 150N and Yubase 6, respectively, as general base oil. Thus, the estolides have better wear resistance and satisfying design objectives for the engineering of a variety of lubricant base oils.

• KSBB Journal
• /
• v.20 no.2 s.91
• /
• pp.84-87
• /
• 2005

Toxicity test for biodiesel (BD), biodiesel-derived neopentyl polyol ester (NPE) lubricant oil base, lubricant oil for diesel engine oil (LODE) and petroleum diesel (PD) was carried out using earthworm, Eisenia fefida. According to the method by OECD 207, the $LC_{50}$ values of BD and NPE were estimated as 2,450 and 1,528 mg/kg, respectively, which indicate that these compounds are classified as slightly toxic compounds. The $LC_{50}$ values of LODE and PD were estimated as 500 and 603mg/kg, respectively, showing that theses compounds are evaluated as moderately toxic compounds.

• Journal of Advanced Marine Engineering and Technology
• /
• v.31 no.6
• /
• pp.744-752
• /
• 2007

Recently a fuel oil of the diesel engine in the ship is being changed with low quality as the oil price is higher more and more. Therefore the wear and corrosion in all parts of the engine like cylinder liner ring groove of piston crown, spindle and seat ring of exhaust valve are increased with using of heavy oil of low quality In particular the degree of wear and corrosion in between valve spindle and seat ring are more serious compared to the other parts of the engine due to operating in severe environment such as the high temperature of exhaust gas and repeating impact. Thus the repair weld to the valve spindle and seat ring is a unique method to prolong the life of the exhaust valve in an economical point of view In this study. corrosion property of both weld metal zone and base metal was investigated with some electrochemical methods such as measurement of corrosion potential, cathodic and anodic polarization curves, cyclic voltammogram and polarization resistance etc. in 5% $H_2SO_4$ solution. in the case of being welded with some welding methods and welding materials to the exhaust valve specimen as the base metal. In all cases. the values of hardness of the weld metal zone were more high than that of the base metal. And their corrosion resistance were also superior to the base metal. The weld metal of A2F(AC SMAW: 2 pass welding with foreign electrode) showed a relatively good results to the corrosion resistance as well as the hardness compared to the ether welding methods and welding materials. Moreover it indicated that hardness of the weld metal by the domestic electrode was considerably high compared to that of the foreign electrode.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.29 no.3
• /
• pp.127-133
• /
• 2017

Performance analysis has been carried out on a high side scroll compressor that had a fixed scroll equipped with a circular oil groove on its thrust surface. Oil was supplied to the oil groove through an intermittent opening from a high pressure oil reservoir formed inside the orbiting scroll hub. Oil in the groove was then delivered to both suction and back pressure chambers by pressure differentials and viscous pumping action of the orbiting scroll base plate. Mathematical modeling of this oil groove system was incorporated into a main compressor performance simulation program for an optimum oil groove design. The study findings were as follows. Pressure in the oil groove can be controlled by changing its configuration and the oil passage area. With an enlarged oil passage, the pressure in the oil groove heightens due to an increased flow rate, but the pressure elevation in the back pressure chamber is small, resulting in reduced friction loss at the thrust surface between the two scrolls. On the other hand, by increasing the oil passage area, the oil content in the refrigerant flow increases. Considering all these factors, the energy efficiency ratio could be improved by about 3.6% under the ARI condition by an optimal oil groove design.

• Polymer(Korea)
• /
• v.27 no.5
• /
• pp.464-469
• /
• 2003

In this work, the fragrant oil release behavior of poly($\varepsilon$-caprolactone) (PCL) microcapsules containing SiO$_2$ was investigated. The SiO$_2$ was chemically treated in 10, 20, and 30 wt% hydrochloric acid and sodium hydroxide. The acid and base values were determined by Boehm's titration technique and $N_2$/77 K adsorption isotherm characteristics, the specific surface area and total pore volume were studied by BET. The PCL microcapsules containing SiO$_2$ and fragrant oil were prepared by oil-in-water (o/w) emulsion solvent evaporation method. The shape and surface of PCL microcapsules were observed using image analyzer and scanning electron microscope (SEM). The fragrant oil release behavior of PCL microcapsules was characterized using UV/vis. spectra. The average diameters of PCL microcapsules were decreased from 35 to 21 $\mu$m with increasing stirring rate. It was found that in the case of acidic treatment the fragrant oil adsorption capacity and release rate were increased due to the increase of specific surface area and acid value. In the case of basic treatment, the fragrant oil adsorption capacity and release rate were decreased due to the decrease of sp ecific surface area and the increase of acid-base interactions between SiO$_2$-NaOH and fragrant oil with increasing base value of SiO$_2$.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.41 no.3
• /
• pp.209-218
• /
• 2015

Once powder base makeup products are applied to the skin, the products are formed a film and attached on the skin for 8 to 12 hours. The makeup film is deformed by secretions such as sweat and sebum secreted from the skin. Thus, durability of the film is an important quality factor in the makeup and its evaluation is also important. In this study, characteristics of the semi-finished powder products such as water absorption, oil absorption, water repellent and oil repellent were evaluated in a number of ways. Also, simple methods, which are not affected by evaluation conditions such as a difference between sweat and sebum secretion, temperature and humidity, were examined to predict the durability of the products. We measured water absorption, oil absorption, water repellent and oil-repellent properties of semifinished product by tablet, capillary and dipping method and then compared with the data of color difference meter and ROBO skin analyzer. Results showed that the durability of powder base makeup products was associated with more oil absorption and water-repellent characteristics than water absorption and oil-repellent. Oil absorption characteristics by tablet and capillary method and water-repellent characteristics by dipping method provides a simple and quick method to precdict the durability of the makeup products.

• Explosives and Blasting
• /
• v.9 no.2
• /
• pp.13-18
• /
• 1991

It was described Several Tuneling method for applying petrolum oil storage. The most Important factor of Tunneling is not only reinforcing works such as pre-grouting and after grouting but also rock bolting and shotcrete. The efficent works should be done by professional skillman, and also the classification of rock should be decided by professional engineers.