• Title/Summary/Keyword: Band Layer

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First-Principles Study on the Electronic Structure of Bulk and Single-Layer Boehmite

  • Son, Seungwook;Kim, Dongwook;Na-Phattalung, Sutassana;Ihm, Jisoon
    • Nano
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    • v.13 no.12
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    • pp.1850138.1-1850138.6
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    • 2018
  • Two-dimensional (2D) or layered materials have a great potential for applications in energy storage, catalysis, optoelectronics and gas separation. Fabricating novel 2D or quasi-2D layered materials composed of relatively abundant and inexpensive atomic species is an important issue for practical usage in industry. Here, we suggest the layer-structured AlOOH (Boehmite) as a promising candidate for such applications. Boehmite is a well-known layer-structured material and a single-layer can be exfoliated from the bulk boehmite by breaking the interlayer hydrogen bonding. We study atomic and electronic band structures of both bulk and single-layer boehmite, and also obtain the single-layer exfoliation energy using first-principles calculations.

Multi-resolution hierarchical motion estimation in the wavelet transform domain (웨이브렛 변환된 다해상도 영상을 이용한 계층적 움직임 추정)

  • 김진태;장준필;김동욱;최종수
    • Journal of the Korean Institute of Telematics and Electronics B
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    • v.33B no.8
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    • pp.50-59
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    • 1996
  • In this paper, a new hierarchical motion estiamtion scheme using the wavelet transformed multi-resolution image layers is proposed. Compared with the full search motion estimation method, the existing hierarchical methods remarkably reduce the amount of the computation but their efficiencies are depreciated by the local minima problem. In order to solve the local minima problem, the multi-resolution image layers are composed using the wavelet transform and the number of layers participated in the motion estimation for a block is determined by considering of its low band energy and higher band energy on the first wavelet transformed layer. The ratio between higher band energy and low band energy of each block is evaluated and in the case of the blocks which include relatively large higher band energy, the motion estimation is carried out in the high resolution layer. Otherwise, all layers are used. The final motion vectors are obtained in the first wavelet transformed layer. So less bits for motion vectors are transmitted, and the decomposition of received image using inverse wavelet transform decreases the blocking effect.

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Design of Broad Band Electromagnetic Wave Absorbers with Cross-Shaped Ferrite. (십자형 광대역 페라이트 전자파흡수체의 설계)

  • 김동일;전상엽;정세모
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 1996.09a
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    • pp.125-134
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    • 1996
  • A design method of double layered electromagnetic wave absorbers with cross-shaped ferrite prominence in the second layer which has broad band frequency characteristics was proposed. The broad band electromagnetic wave absorber can be designed under some approximations by the theoretical model using the equivalent material constants method for the second layer. Based on the developed model broad band electromagnetic wave absorbers with excellent reflectivity frequency characteristics in the frequency range of 30MHz to 3,990MHz were designed.

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The Adsorption of Alkyl Aldehydes on Cations Supported by Layer Silicate. Complex Formation Theory (Layer Silicate에 지지된 양이온상에서의 알킬알데히드의 흡착기구. 착물형성 이론)

  • Kim Jong Taik;Sohn Jong Rack
    • Journal of the Korean Chemical Society
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    • v.18 no.3
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    • pp.180-188
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    • 1974
  • Adsorption mechanism of alkyl aldehydes, acetaldehyde, acrolein, and crotonaldehyde on cations supported by layer silicates was studied by means of IR spectroscopy and X-ray. An analysis of four characteristic split bands in the region of $1720∼1580㎝^{-1}$ was made. The carbonyl stretching band which shifted about $130㎝^{-1}$ to lower frequencies was observed only for $Ni^{2+}$ and Al^{3+}$ but slightly with $Ca^{2+}$ at high sample temperature and was attributed to >C=O…M complex formation. A sharp band which appeared as a shoulder at 1722 for acetaldehyde and 1690 for acrolein and crotonaldehyde was responsible for the interaction of carbonyl with surface hydroxyl. The second broad band which appeared at about 1710~1660 was responsible for hydrogen bonding between carbonyl oxygen and cationic hydroxyl group. The third band which appeared at about 1640~1660 was attributed to induced >C=C< double bond due to the strong carbonyl interaction. This was supported by the interlamellar spacings obtained by X-ray diffractometry.

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Multi-Band Internal Chip Antenna Using Multi-Layer Substrate for Mobile Handset (Multi-Layer 구조를 사용한 다중 대역 내장형 칩 안테나)

  • Cho, Sang-Hyeok;Cho, Il-Hoon;Lee, In-Young;Pyo, Seong-Min;Baik, Jung-Woo;Kim, Young-Sik
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.19 no.7
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    • pp.778-784
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    • 2008
  • In this paper, a chip antenna using multi-layer configuration for multi-band operation, such as GSM, DCS, pcs, WCDMA, and Mobile WiMAX for 2.3 GHz is proposed. This proposed antenna is a PIFA structure with multi-layer configuration fabricated on R04003 substrate(${\varepsilon}_r=3.4$) and its size is $22{\times}5.5{\times}4.0\;mm^3$. Multi-layer structure can effectively reduce the size of an antenna from a reuse of air-space and can achieve broad bandwidth due to decrement of parallel capacitances from the insertion air-gap to the middle layer. The proposed antenna has a broadband operation by the high order resonance modes and the resonance at the top layer. The measured bandwidths with over 45 % radiation efficiency are 80 MHz($880{\sim}960\;MHz$) at the lower band and 690 MHz($1,710{\sim}2,400\;MHz$) at the higher band.

A Study on Development of Broad-band Electromagnetic Wave Absorber for EMI/EMC (EMI/EMC 대책용 광대역화 전파흡수체의 개발에 관한 연구)

  • Jun, Sang-Yup;Kim, Dong-Il
    • Journal of the Korean Institute of Navigation
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    • v.15 no.4
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    • pp.13-25
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    • 1991
  • Recently, according to the development of electromagnetic wave technique, more frequent and powerfull wave radiation becomes inevitable and so electromagnetic environments has become worse accordingly. Electromagnetic wave absorber is known the most effective preventive remedy to cope with the EMI/EMC problem. To realize broad-band electromagnetic wave absorber, triple layered structure where an air layer is interposed between a sintered ferrite layer and a ruber ferrite layer was adopted. Computer simulation for optimum design and evaluation of absorption characteristics has been made. The results shows that designed broad-band electromagnetic wave absorber can be useful for EMI/EMC problem, especially reducing TV ghosts in both VHF and UHF bands by additionally an air layer and a thin rubber ferrite layer on the surface of conventional ferrite, without replacing it.

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Study of ZnS/CIGS Hetero-interface for Cd-free CIGS Solar Cells (Cd-free 태양전지를 위한 ZnS/CIGS 이종접합 특성 향상 연구)

  • Shin, Donghyeop;Kim, Jihye;Go, Youngmin;Yun, Jaeho;Ahn, Byungtae
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.106.1-106.1
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    • 2011
  • The Cu(In,Ga)Se2 (CIGS) thin film solar cells have been achieved until almost 20% efficiency by NREL. These solar cells include chemically deposited CdS as buffer layer between CIGS absorber layer and ZnO window layer. Although CIGS solar cells with CdS buffer layer show excellent performance, the short wavelength response of CIGS solar cell is limited by narrow CdS band gap of about 2.42 eV. Taking into consideration the environmental aspect, the toxic Cd element should be replaced by a different material. Among Cd-free candidate materials, the CIGS thin film solar cells with ZnS buffer layer seem to be promising with 17.2%(module by showa shell K.K.), 18.6%(small area by NREL). However, ZnS/CIGS solar cells still show lower performance than CdS/CIGS solar cells. There are several reported reasons to reduce the efficiency of ZnS/CIGS solar cells. Nakada reported ZnS thin film had many defects such as stacking faults, pin-holes, so that crytallinity of ZnS thin film is poor, compared to CdS thin film. Additionally, it was known that the hetero-interface between ZnS and CIGS layer made unfavorable band alignment. The unfavorable band alignment hinders electron transport at the heteo-interface. In this study, we focused on growing defect-free ZnS thin film and for favorable band alignment of ZnS/CIGS, bandgap of ZnS and CIGS, valece band structure of ZnS/CIGS were modified. Finally, we verified the photovoltaic properties of ZnS/CIGS solar cells.

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Improvement of hole transport from p-Si with interfacial layers for silicon solar cells

  • Oh, Gyujin;Kim, Eun Kyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.239.2-239.2
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    • 2016
  • Numerous studies and approaches have been performed for solar cells to improve their photoelectric conversion efficiencies. Among them, the study for electrode containing transparent conducting oxide (TCO) layers is one of issues as well as for the cell structure based on band theory. In this study, we focused on an interfacial layer between p-type silicon and indium tin oxide (ITO) well-known as TCO materials. According to current-voltage characteristics for the sample with the interfacial layers, the improvement of band alignment between p-type silicon and ITO was observed, and their ohmic properties were enhanced in the proper condition of deposition. To investigate cause of this improvement, spectroscopic ellipsometry and ultraviolet photoelectron spectroscopy were utilized. Using these techniques, band alignment and defect in the band gap were examined. The major materials of the interfacial layer are vanadium oxide and tungsten oxide, which are notable as a hole transfer layer in the organic solar cells. Finally, the interfacial layer was applied to silicon solar cells to see the actual behavior of carriers in the solar cells. In the case of vanadium oxide, we found 10% of improvement of photoelectric conversion efficiencies, compared to solar cells without interfacial layers.

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Analysis of Forming Limit for Circular Bonded Sheet Metals by Shear Band Formation (전단띠 형성에 의한 원형접합판의 변형한계 해석)

  • 정태훈
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.10 no.1
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    • pp.127-132
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    • 2001
  • By the use of a similar numerical method as the forming limit strain by coating method of coated sheet metals is investigated, in which the FEM is applied and J2G(J2-Gotohs Corner Theory) is utilized as the plasticity constitutive equa-tion. Circular bonded sheet metals with dissimilar sheets on both surface planes are stretched in a plane -strain state, with various work-hardening exponent n-values and thicknesses of each layer. Processes of shear-band formation in such com-posite sheets are clearly illustrated. It is concluded that, it the bonded state, the higher limiting strain of one layer is reduced due to the lower limiting strain of the other layer and vice versa, and does not necessarily obey the rule of linear combination of the limiting strain of each layer weighed according thickness.

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Design of Broadband Electromagnetic Wave Absorber with Square Ferrite Cylinders in the Second Layer (초광대역특성을 갖는 정방형 페라이트 기둥구조의 전파흡수체 설계법)

  • 김동일;전상엽;이창우;정세모
    • Journal of the Korean Institute of Navigation
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    • v.19 no.2
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    • pp.99-106
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    • 1995
  • A wide band design method of an electromagnetic wave absorber with square ferrite cylinders in the second layer, which has very wide band frequency characteristics, is proposed and discussed. A theoretical model using the equivalent material constants method is also evaluated and proposed for its accuracy by comparison with Hashin-Shtrikman formulas. Based on the developed model, wide band electromagnetic wave absorbers with excellent reflective frequency characteristics in the frequency range of 30MHz to 3, 690MHz were designed.

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