• Title/Summary/Keyword: BaP

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Piezoelectric and Dielectric Properties of (Na,Li)$NbO_3$ Ceramics According to the $BaTiO_3$ substitution ($BaTiO_3$ 치환에 따른 (Na,Li)$NbO_3$ 세라믹스의 압전 및 유전특성)

  • Lee, Sang-Ho;Lee, Kab-Soo;Ryu, Ju-Hyun;Ryu, Sung-Lim;Song, Hyun-Seon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.272-273
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    • 2007
  • In this study, in order to develop the composition ceramics of lead-free ultrasonic motor, (Na,Li)$NbO_3-BaTiO_3$ ceramics were fabricated using a conventional mixed oxide process and their piezoelectric and dielectric characteristics were investigated according to the $BaTiO_3$, substitution. $BaTiO_3$ substitution enhanced density, dielectric constants$({\varepsilon}_r)$ and electromechanical coupling factor$(k_p)$. However, mechanical quality factor was deteriorated. At the $BaTiO_3$ substitution of 4mol%, density, electromechanical coupling factor$(k_p)$, dielectric constants$({\varepsilon}_r)$ and piezoelectric constant$(d_{33})$ of specimen showed the optimum value of $4.493g/cm^3$, 0.236, 175, 70pC/N, respectively.

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Identification of Atherosclerosis Related Gene Expression Profiles by Treatment of Benzo(a)pyrene in Human Umbilical Vein Endothelial Cells

  • Lee, Sun-Hee;Lee, Seung-Eun;Ahn, Hyun-Jong;Park, Cheung-Seog;Cho, Jeong-Je;Park, Yong-Seek
    • Molecular & Cellular Toxicology
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    • v.5 no.2
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    • pp.113-119
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    • 2009
  • Benzo(a)pyrene (BaP) is a persistent environmental contaminant and is present in tobacco smoke. BaP is considered a major contributor of cardiovascular disease. While the activation of endothelial cells by stimuli including tobacco smoke and air pollution contributes importantly to cardiovascular disease, the nature of BaP's mechanism is unclear. In this study, gene expression profiles were investigated in BaPtreated human umbilical vein endothelial cells (HUVECs). Various atherosclerosis related genes could be up- and down-regulated more than 2-fold by BaP, and mRNA levels of atherosclerosis related genes encoding apolipoproteinC III, TLR 2, ICAM 1 and exportin 4 were significantly increased by BaP. Our data suggest that BaP-mediated changes in gene expression contribute to the progression of cardiovascular disease.

Studies on AlF3-(Mg+Sr+Ba)F2-P2O5 Glasses I. Glass Forming Ranges of Fluorophosphate System and Its Various Properties (AlF3-(Mg+Sr+Ba)F2-P2O5계 유리에 관한 연구 I. 유리화 범위와 특성)

  • 김정은;이종근
    • Journal of the Korean Ceramic Society
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    • v.24 no.2
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    • pp.117-122
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    • 1987
  • Glass forming ranges in the AlF3-(Mg+Sr+Ba)F2-P2O5 system are studied and ultraviolet transmission, infrared transmission, coefficient of refractive index, thermal expansion coefficient, density and chemical durability of the glasses are determined. Glass forming range is restricted MgF2 0-10wt%, SrF2 10-50wt%, BaF2 10-40wt% in this system. While BaF2 is substituted by SrF2, density and refractive index are decreased, micro hardness and thermal expansion coefficient are increased according to the increasing of SrF2 at fixed MgF2 contents. These samples represent high transmittance(93%) from 400nm to 3800nm and chemical durability of these samples show less than 0.3mg/$\textrm{cm}^2$$.$hy by weightloss.

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Preparation and Characterization of Hydrothermal BaTiO3 Powders and Ceramics (수열합성법에 의한 BaTiO3분말합성 및 소결체의 제조)

  • 이병우;최경식;신동우
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.577-582
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    • 2003
  • BaTiO$_3$ fine powders were synthesized by hydrothermal process from peroxo-coprecipitate precursors. The peroxo-coprecipitates were obtained by addition of the BaCl$_2$, TiCl$_4$, and $H_2O$$_2$ aqueous solution to an ammonium solution. Hydrothermal reaction was conducted at various reaction temperatures, times and pH ranges. Unlike the conventional hydrothermal synthesis which needs highly alkaline condition over pH 13 with KOH or NaOH, the present method offered well-developed crystalline (perovskite) BaTiO$_3$ powders synthesized below pH 12 with use of ammonium solution. It was found that the phase-pure fine powders were formed at temperatures as low as 11$0^{\circ}C$ and the properties of the powders synthesized over 13$0^{\circ}C$ were almost same regardless of the reaction time. BET surface area of the prepared powder was as high as 76 $m^2$/g and the calculated particle (particulate) size was below 20 nm. The ultrafine particulates formed weak agglomerates. The microstructure and dielectric properties of BaTiO$_3$ ceramics sintered at the temperature range of 1150~125$0^{\circ}C$ were evaluated.

Analysis and Detection of Coast Protein Gene of Barley Yellow Mosaic Virus and Barley Mield Mosaic Virus by RT-PCR (RP-PCR을 이용한 보리누른모자이크바이러스 (BaYMV)와 보리마일드모자이크바이러스(BaMMV)의 외피단백질 유전자 검정 및 해석)

  • 이귀재
    • Korean Journal Plant Pathology
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    • v.14 no.4
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    • pp.314-318
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    • 1998
  • Using the reverse transcription polymerase chain reaction (RT-PCR), a rapid and sensitive assay method for the detection and identification of barley yellow mosaic virus (BaYMV) and barley mild mosaic virus (BaMMV) was adapted. Two units of primers from each virus were selected and used for the determination of two different viruses. PCR fragments of BaYMV (ca. 0.9kb) and BaMMV (ca. 0.8kb) were obtained from the designed method for the assay of BaYMV and BaMMV coat protein. PT-PCR fragments were cloned using vector pT7 Blue and the sequences of the selected clones were analyzed. coat protein of BaYMV and that of BaMMV consisted of 297 amino acids (891 nucleotides) and 251 amino acids (753 nucleotides), respectively. The snalysis of coat protein genes from these two viruses showed that 45.6% of nucleotides sequence ad 34.9% of amino acid in BaYMV were homologous to those in BaMMV.

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A Stochastic Approach for Prediction of Partially Measured Concentrations of Benzo[a]pyrene in the Ambient Air in Korea

  • Kim, Yongku;Seo, Young-Kyo;Baek, Kyung-Min;Kim, Min-Ji;Baek, Sung-Ok
    • Asian Journal of Atmospheric Environment
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    • v.10 no.4
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    • pp.197-207
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    • 2016
  • Large quantities of air pollutants are released into the atmosphere and hence, must be monitored and routinely assessed for their health implications. This paper proposes a stochastic technique to predict unobserved hazardous air pollutants (HAPs), especially Benzo[a]pyrene (BaP), which can have negative effects on human health. The proposed approach constructs a nearest-neighbor structure by incorporating the linkage between BaP and meteorology and meteorological effects. This approach is adopted in order to predict unobserved BaP concentrations based on observed (or forecasted) meteorological conditions, including temperature, precipitation, wind speed, and air quality. The effects of BaP on human health are examined by characterizing the cancer risk. The efficient prediction provides useful information relating to the optimal monitoring period and projections of future BaP concentrations for both industrial and residential areas within Korea.

Benzo(a) pyrene Level in Indoor Environment due to the Use of Unvented Heating Facilities (煖房器具를 사용하는 室內空氣중의 벤조(a) 피렌 成分濃度에 관한 硏究)

  • 董宗仁
    • Journal of Korean Society for Atmospheric Environment
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    • v.3 no.1
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    • pp.65-73
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    • 1987
  • Indoor air pollution problems, in fact, have been neglected due to the unawareness of its seriousness and the lack of accumulated data. Recently, some movement of research and regulations, however, have been made for several indoor air pollutants. In this study, one of the carcinogenic polynuclear aromatic hyrocarbon, Benzo(a) pyrene in indoor airborne particulate, was measured and analyzed to estimate emission strength of BaP from an unvented kerosene heater and to know its level in indoor environment with use of a kerosene heater and a wood-burning fireplace. By the measurement of BaP level in a dark room with air exchange rate of app. 3.0, BaP emission strength of a kerosene heater (11,000Btu/hr) was estimated to be 326.6ng/hr (or 29.7 ng/$10^3$ Btu). With 4-hr operation a day of the kerosene heater in an apartment, the BaP level became 2.97ng/m$^3$ from 0.27ng/m$^3$ of background level. The operation of a wood-burning fireplace app. 2hr a day, on the other hand, increased the BaP level from 0.16ng/m$^3$ of background to 3.53ng/m$^3$. So proper ventilation must be considered seriously when unvented heating facilities are used in indoor environment.

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Determination of benzo(a)pyrene in Soil, Sediment and Water by Gas Chromatography- Mass Spectrometry (기체크로마토그래피/질량분석기에 의한 토양, 저질 및 수질시료 중 benzo(a)pyrene의 분석)

  • Jeon Ree Kyung;Choi Rae Yeon;Ryu Jae-Chun
    • Environmental Analysis Health and Toxicology
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    • v.20 no.1
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    • pp.47-55
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    • 2005
  • 본 연구는 GC/MS를 이용하여 수질, 토양 및 저질 시료 중의 benzo(a)pyrene(BaP)을 분석하는 방법을 확립하고자 하였다. BaP은 수질 시료(100mL)에서 n-hexane으로 추출하였으며, 토양 및 저질 시료(l0g) 에서는 먼저 메탄올로 추출한 후 hexane으로 다시 추출하여 농축시켜 분석하였다. 수질 시료 중의 BaP 회수율은 94.8% 이상이었으며 토양에서의 회수율은 약 93%를 보였고 재현성은 10.49% 이하였다. 검정 곡선은 상관계수(R²)값이 수질과 토양 모두에서 0.996 이상의 좋은 직선성을 보여주었다. 토양 시료의 경우 35지역 중 6지역의 토양에서 0.5~223.5㎍/kg의 농도 범위로 BaP가 검출되었으며 수질과 저질 시료에서는 모든 지역에서 검출한계 이하로 나타났다. 이 분석방법은 환경 중에 미량으로 존재하는 BaP의 분석과 모니터링에 유용하게 사용할 수 있는 적합한 방법이라 사료된다.

Soil buffer capacities from the differrent host rocks by the treatment of artificial acid precipitation

  • Min, Ell-Sik;Kim, Myung-Hee;Song, Suck-Hwan
    • Proceedings of the Zoological Society Korea Conference
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    • 1999.10b
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    • pp.150.2-150
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    • 1999
  • To investigate the weathering soil buffering capacities of the artificial acidic precipitation, the weathering soils and their leachate solutions were sampled from the host rocks(granite;GR, rhyolite;RH, gabbro;GA, basalt;BA, two serpentinite;SE1, SE2 and limestone;LI) and analyzed for pH and chemical properties. 1n the soil pH of the GR and RH ,the acidic rocks, were 5.02 and 5.95, respectively. And the GA and BA, basic rocks, were 6.52 and 7.57. The SE1 and SE2 were 8.90 and 8.89. While the LI was 7.84. These results means the typical soil pH properties by host rocks. After the artificial acidic precipitation input 5OOml, the average changes of soil leachate solutions treated by pH levels(pH 5.0, 4.0 and 3.0), were pH 5.73, 5.00 and 4.40. in GR soil, and pH 6.19, 5.99 and 5.57 in RH. GA were pH 6.31, 6.04 and 5.86, BA were pH 7.05, 6.85 and 6.56 and SE1 were pH 8.31, 8.26 and 7.71. SE2 were pH 8.29, 8.24 and 7.96. LI were pH 7.55, 7.46 and 6.79. The soil leachate pHs from volcanic rocks were higher than those from the plutonic rocks and GR soils showed greater response than other soils. With increasing 100ml input-solution, the soil leachate pHs were mainly decreased. Cation concentrations, CEC, EC and total nitrogen concentrations of RH and BA soils, the volcanic rocks, were higher than those of GR and GA soil, the plutonic rocks. On the contrary, Al concentrations of the GR and GA soils were higher than those of RH and BA soils, partly because of high quartz content in GR and Al content in the biotite and plagioclase in GA.

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Use of Paper Mill Sludge and Briquet Ash as Root Zone Soil Mixtures for Thrfgrass Culture (잔디상토로서의 제지스럿지와 연탄재 이용에 관한 연구)

  • 구자영;김태일;안주원
    • Asian Journal of Turfgrass Science
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    • v.6 no.1
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    • pp.11-22
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    • 1992
  • To determine the use of waste materials as root zone soil mixtures for turfgrass culture, the effects of paper mill sludge and briquet ash on physical and chemical properties of soil and growth of turfgrasses were examined. Three turfgrass species of zoysiagrass(Zoysia japonicaSteud.). kentycky bluegrass(Poa pratensis L. 'Ram I') and creeping bentgrass(Agrostis panistris Huds 'Persucross') were cultured in 32cm diameter plastic pots containing various soil mixtures. The basic ingredients used for mixtures included sand(SD), field soil(SL), paper mill sludge(PS), sphagnum peat moss(PM) and briquet ash(BA). Seven combinations using these ingreients were mixed in different percentage by volume as follows: SD+SL+PM(80:10.10), SH+SL+PS(80:10:10), SD-PM(80:20), SD+PS (80:20), SD+BA(80:20), SD+BA+PM(60:20:20) and SD+BA+PS(60:20:20). 1. Paper mill sludge showed pH of 6.6, more than 30% of organic matter content, and higher concentrations of total N, P, k, Ca, Mg and CEC. Bulk density, fild moisture capacity and electrical conductivity of soil mixtures were increased by the comimation of 10~20% PS by volume. 2. Briquet ash showed pH of 8.0, and higher levels of P, k, Ca and Mg than those of field soiks. Bulk density, field moisture capacity and hardenss of soil mixtures were increased but vertical water flow rate and electrical conductivity were decreased by the combination of 20% BA by volume. 3. Phytotoxic effects of PS and BA on growth of turfgrasses were not found. Shoot growth of all three species was higher in soil combination of SD+BA+PS than that of SD+SL+PM added with fertilizer. However, root growth was better in soil mixtures combined with PM. Soil mixtureomposed of 60% SD, 20% BA and 20% PS by volume was most effective on growth of all three species. 4. Paper mill sludge resulted in higher N level in the leaf tissue. The contents of heavy metals such as Cd and Ph did not vary significantly among soil mixtures and species. However, the Mn level was 2~3 times higher in plants growh in mixtures containing PM compared with others, and especially it was higher in creeping bentgrass than other species.

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