• Journal of Magnetics
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• v.17 no.1
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• pp.6-8
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• 2012

M$\ddot{o}$ssbauer spectra of hexagonal $BaFe_{12}O_{19}$ single crystals were studied at various temperatures (4-300 K). It was found that the spin states in Fe atoms were parallel to the ${\gamma}$-ray's direction into a single crystal along the caxis. The location of the Fe ion in the 2b site is unusual in an oxide structure and has strong anisotropic lattice vibrations. Moreover, at room temperature, the zero absorption lines of the Fe ions at the 2b site were observed due to fast diffusion motion in a double well atomic potential. The two Fe ions of the single crystal mainly enter into the sites in the mirror plane of the trigonalbipyramidal structure.

• Journal of the Korean Vacuum Society
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• v.22 no.4
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• pp.181-187
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• 2013

$Dy^{3+}$-doped $BaMoO_4$ phosphor powders were synthesized by using the solid-state reaction method and their crystalline structure, morphology and size of particles, excitation and emission properties were investigated. The structure of all the phosphor powders, irrespective of the mol ratio of $Dy^{3+}$ ions, was found to be the tetragonal system with the main diffraction peak at (112) plane. The grain particles agglomerate together to form larger clusters with increasing the mol ratio of $Dy^{3+}$ ions. The excitation spectra were composed of a broad band centered at 293 nm and weak multiline peaked in the range of 230~320 nm, which were due to the transitions of $Dy^{3+}$ ions. The emission of the phosphors peaking at 666 and 754 nm, originating from the transitions of $^4F_{9/2}{\rightarrow}^6H_{11/2}$ and $^4F_{9/2}{\rightarrow}^6H_{9/2}$ of $Dy^{3+}$ ions, was rather weak, while the intensity of blue and yellow emission peaking at 486 nm and 577 nm due to the transitions of $^4F_{9/2}{\rightarrow}^6H_{15/2}$ and $^4F_{9/2}{\rightarrow}^6H_{13/2}$ of $Dy^{3+}$ ions was significantly stronger. The experimental results suggest that the white-light emission can be realized by controlling the yellow-to-blue intensity ratio of $Dy^{3+}$ emission.

• Progress in Superconductivity and Cryogenics
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• v.14 no.3
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• pp.1-4
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• 2012

Effects of artificial holes on the cooling efficiency of single grain YBCO bulk superconductors were studied. Single grain YBCO bulk superconductors without artificial holes, with six 2.4 mm holes and six holes filled with Bi-Pb-Cd-Sn metal solder were fabricated by a top-seeded melt growth process for powder compacts with/without holes. Simulation for the cooling rate to a liquid nitrogen temperature (77 K) of YBCO samples was carried out using a finite element method (FEM) and the results are compared with the actual cooling rates of samples in liquid nitrogen. The simulated cooling times for the YBCO sample without holes, with six holes and with six holes filled with the metal solder were 80, 47 and 75 sec. respectively, which are similar to the actual cooling times of 84, 52 and 78 sec. estimated for the same samples cooled in liquid nitrogen. The shorter cooling time of the sample with artificial holes are attributed to the increased surface areas associated with the presence of artificial holes. The metal filling into the holes did not give any remarkable effect on the cooling efficiency.