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분자궤도론에 의한 반응성 결정 (제32보). 3-부테노산의 기체상 탈탄산반응에 미치는 치환기 효과의 분자궤도론적 연구 (Determination of Reactivity by MO Theory (Part 32). MO Studies of Substituent Effects on the Gas-Phase Decarboxylation of But-3-enoic Acid)

  • 조정기;이익춘;오혁근;조인호
    • 대한화학회지
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    • 제28권5호
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    • pp.279-283
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    • 1984
  • but-3-enoic acid의 retro-ene 탈탄산 반응에 있어서 그 반응성에 대한 ${\beta}$-치환기 효과를 이론적으로 연구하였다. 그 결과 전하 효과에서, 실험에서의 치환체에 의한 ${\pi}$-전자 전달만이 관여되는 것이 아니라, $CH_3$-치환같은 경우는 편극 효과도 상당히 관여됨을 알 수 있었다. 그러나 이들 반응성을 전하 효과로만 결정지을 수 없으며, HOMO와 LUMO간의 에너지 간격이 또한 반응성에 크게 영향을 미친다. 결과적으로, 일반적으로 논하는 치환체의 ${\pi}$-전자 주게 능력이 클수록 반응이 빨라진다는 사실에는 변함이 없었다.

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Superinfection exclusion of BVDV occurs not only at the level of structural protein -dispensable viral replication but also at the level of structural protein -required viral entry

  • Lee Y.-M.;Frolov I.;Rice C.M.
    • 한국미생물학회:학술대회논문집
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    • 한국미생물학회 2000년도 추계학술발표대회
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    • pp.66-77
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    • 2000
  • For a variety of viruses, the primary virus infection has been shown to prevent superinfection with a homologous secondary virus; however, the mechanism of exclusion has not been clearly understood. In this work, we demonstrated that BVDV -infected MDBK cells were protected from superinfection with a homologous superinfecting BVDV, one of the positive-sense RNA pestiviruses, but not with an unrelated rhabdovirus, such as vesicular stomatitis virus. Once superinfection exclusion was established by a primary infection with BVDV, the transfected infectious BVD viral RNA genome was shown to be competent for viral translation, but not viral replication. In addition, our results also demonstrated that upon superinfection, the. viral RNA genome of viral particles was not transferred into the cytoplasm of BVDV -infected cells. Using newly developed system involving rapid generation of the MDBK cells expressing BVD viral proteins, we subsequently found that expression of the viral structural proteins was dispensable for the block occurring at the level of viral RNA replication, but required for the exclusion at the level of viral entry step. Altogether, these findings provide evidence that the superinfection exclusion of BVDV occurs not only at the level of viral replication in which the viral replicase are involved, but also at the level of viral entry with which the viral structural proteins are associated, and that a cellular factor(s) play an essential role in this process.

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역사 속에 나타난 남성 화장의 특성 (The Characteristics of Men's Cosmetic through the History)

  • 김주애;이연희
    • 한국패션뷰티학회지
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    • 제2권3호
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    • pp.96-101
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    • 2004
  • This study suggests the basic resources for men's cosmetic which shows in history. Because not only ancient chief but also modern French noble men made up in the area where succeeded the traditional national cosmetic, when it was seen through historic or world, the men's cosmetic was generated and was more luxurious and presence than women. But since the French revolution, men was limited the collection of fashion, also the luxurious cloth and cosmetic disappeared. It was 1960s that men's cosmetic based rock musicians reappeared. And then, rock musicians made up luxuriously. The early cosmetic of rock musicians began from the protest's meaning for old fashioned value and fixed society. But gradually, it was changed the style that valued appearance's beauty. In the past, movie star's hair style and cloth were the basic fashion, but now the sportsmen are recognized heroes and their cosmetic is prevailing. Today, the basic meaning of men's presence fashion is that men and women's each role and self expression is allowed and appearance's decoration showed from sex roles disappeared. Men is limited body's beautiful expression and collective range but they fluently express each self imagination through work, special hobby, female attire and drag queen. From various men's beautiful expression, we will know that human beings want a society which is recognizing different self expressions.

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텔타규칙을 이용한 다단계 신경회로망 컴퓨터:Recognitron III (Multilayer Neural Network Using Delta Rule: Recognitron III)

  • 김춘석;박충규;이기한;황희영
    • 대한전기학회논문지
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    • 제40권2호
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    • pp.224-233
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    • 1991
  • The multilayer expanson of single layer NN (Neural Network) was needed to solve the linear seperability problem as shown by the classic example using the XOR function. The EBP (Error Back Propagation ) learning rule is often used in multilayer Neural Networks, but it is not without its faults: 1)D.Rimmelhart expanded the Delta Rule but there is a problem in obtaining Ca from the linear combination of the Weight matrix N between the hidden layer and the output layer and H, wich is the result of another linear combination between the input pattern and the Weight matrix M between the input layer and the hidden layer. 2) Even if using the difference between Ca and Da to adjust the values of the Weight matrix N between the hidden layer and the output layer may be valid is correct, but using the same value to adjust the Weight matrixd M between the input layer and the hidden layer is wrong. Recognitron III was proposed to solve these faults. According to simulation results, since Recognitron III does not learn the three layer NN itself, but divides it into several single layer NNs and learns these with learning patterns, the learning time is 32.5 to 72.2 time faster than EBP NN one. The number of patterns learned in a EBP NN with n input and output cells and n+1 hidden cells are 2**n, but n in Recognitron III of the same size. [5] In the case of pattern generalization, however, EBP NN is less than Recognitron III.

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우성안과 주동수가 길이 인지능력에 미치는 영향 (The Effect on Length Cognition Ability in Dominant Eye & Hand)

  • 남건우
    • 대한물리치료과학회지
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    • 제16권4호
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    • pp.59-65
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    • 2009
  • Background: Human body is formed of symmetric bilateral structures that are comprised of eye, upper arm, lower arm and etc. but, we are used only dominant components. The purpose of this study was to analysis length cognition ability in dominant eye & hand. Method: Total 180 persons (male 32, female 138) were participated in this study. They were tested with 'hole in the card' test for identification of dominant eye's side and the question for identification of dominant hand's side, then the length cognition ability was measured in right & left axillary level by describing 10cm line. Results: The results by independent t-test were as follows. In difference of length cognition ability in right axillary level between right dominant eyed group & left dominant eyed group, right dominant eyed group was superior to left dominant eyed group, but significant difference was not existed statistically(p>.05). In left axillary level, right dominant eyed group was superior to left dominant eyed group, but significant difference was not existed statistically(p>.05). In axillary level of dominant eye's side, non-crossed group was superior to crossed group, but significant difference was not existed statistically(p>.05). In axillary level of non-dominant eye's side, non-crossed group was superior to crossed group, but significant difference was not existed statistically(p>.05). Conclusion: These result can be applied to the learning of palpation & observation skill in physical therapy.

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Expansion of the Government Procurement Agreement: Time to Concentrate on Depth as well as Width

  • Yang, Junsok
    • East Asian Economic Review
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    • 제16권4호
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    • pp.363-394
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    • 2012
  • WTO Government Procurement Agreement (GPA) was designed to liberalize and expand trade in government procurement. Revised GPA was implemented in 1996 and the latest revision was completed (but not yet implemented) in 2012, but as a plurilateral agreement. Since the end of the UR, there has been attempts by various WTO members to liberalize trade in the government procurement market - through an expansion of Parties who are signatories to GPA, and through a negotiated agreement on transparency in government procurement. The attempt to expand the Parties who are signatories to the GPA - attempt to increase the width of the coverage of the agreement - has been somewhat successful, but I argue that the goal should be to further liberate the government procurement markets of the current Party members - to reduce thresholds and other barriers which limit market access even to other GPA members, in other words, to increase the depth of coverage. Taking cue from Korea's FTA, I propose a two-level liberalization of the government procurement market under the GPA: A "light" level which would be the same as the current level of liberalization; and a "deep" level with lower thresholds and less exemptions. I argue that, as seen in Korea, with FTAs, many GPA Parties already have multiple levels of liberalization (i.e, spaghetti-bowl effect of FTAs), but by limiting the levels of liberalization to two, we can seek the best of deep liberalization but reduce the spaghetti-bowl effect.

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카페인 첨가가 흰쥐 간의 항산화 활성에 미치는 영향 (The Effect of Caffeine on the Antioxidative Activities of Mouse Liver)

  • 성종환;장재철;장영상
    • 한국식품영양학회지
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    • 제17권4호
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    • pp.442-449
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    • 2004
  • The purpose of this study was to examine the antioxidative activities and tissue cell of mouse liver added caffeine. The body weight of all experimental groups increased during experimental periods, but the body weight of caffeine-containing groups were lower than those of any other experimental groups. Superoxide dismutase and catalase activities tended to decrease significantly with caffeine-containing groups, but increased in control and ginseng-containing groups. Hydroperoxide contents were increase significantly with caffeine-containing groups. Lipid peroxidation levels decreased in ginseng-containing groups, but it increased significantly with caffeine-containing group. Protein contents were a tendency of similar between control and ginseng-containing groups, but it showed a increasing tendency in caffeine-containing groups. Microscopic observation of mouse liver cell were similar tissue in ginseng and caffeine-containing groups, but it showed somewhat more injuring only at the liver cell of anhydrous caffeine group, and became the suspicion in liver diseases. This results show that antioxidative activities are slightly higher in non-caffeine and ginseng-containing drinks than caffeine-cotaining drinks. From this standpoint, we suggest that too much drinking of caffeine-containing drinks for a long time is undesirable.

재팽창성 폐부종 (Reexpansion Pulmonary Edema)

  • 지청현
    • Journal of Chest Surgery
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    • 제24권8호
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    • pp.797-801
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    • 1991
  • Reexpansion pulmonary edema following pneumothorax, atelectasis, massive pleural effusion are clinically uncommon, but sometimes life threatening progression. Reexpansion pulmonary edema is usually ipsilateral but rarely contralateral or both. Reexpansion pulmonary edema was occurred when chronically collapsed lung is rapidly reexpanded by evacuation of large amounts of air or fluid. The pathogenesis of the reexpansion pulmonary edema is unknown but is probably mutifactorial. The etiological factors of the reexpansion pulmonary edema are chronicity of the lung collapse, technique of the reexpansion, airway obstruction, loss of the surfactant, and pulmonary artery pressure changes. In the treatment of the chronically collapsed lung, physician must be remembered the possible events, and to prevent of the complication.

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가사노동에 관한 인식의 변화고찰 (A Study on the Perceptional Transition of Housework)

  • 문숙재
    • 가정과삶의질연구
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    • 제15권3호
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    • pp.153-162
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    • 1997
  • The purpose of this study is to investigate the perceptional transition of housework from the ancient society to the modern society. In the ancient society, there was no difference in the meaning between domestic life and housework, it was thought that they were whole unity. In the medieval society, there was a beginning to differenciate the meaning between domestic life and housework, but there was no actual division between the one and the other. But in the modern society, it is thought that domestic life and housework is not only differenciated in concept, but also divided actually.

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여백에 관하여 (A Study on Margin)

  • 진정식
    • 한국콘텐츠학회:학술대회논문집
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    • 한국콘텐츠학회 2004년도 춘계 종합학술대회 논문집
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    • pp.121-127
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    • 2004
  • 우주의 암흑이 빛이 없음이 아니고 암흑물질이며, 무극ㆍ태극이 하나이고 빈 공간을 비어 있다고 하지 않고 무로 꽉 차 있다 하는 것처럼 미술에서 여백은 따로 존재하는 것이 아니고 negative space와 positive shape가 서로 연결되어 하나의 통일된 공감을 형성하고 소멸되는 살아있는 공간이다.

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