• Title/Summary/Keyword: BO

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Synthesis and Structures of $(NH_4)_{10}[Ni(H_2O)_5]_4[V_2P_2BO_{12}]_6{\cdot}nH_2O$ and $(NH_4)_{3.5}(C_3H_{12}N_2)_{3.5}[Ni(H_2O)_6]_{1.25}{[Ni(H_2O)_5]_2[V_2P_2BO_{12}]_6{\cdot}nH_2O$

  • Yun, Ho-Seop;Do, Jung-Hwan
    • Korean Journal of Crystallography
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    • v.15 no.1
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    • pp.35-39
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    • 2004
  • Two new nickel vanadium borophosphate cluster compounds, $(NH_4)_{10}[Ni(H_2O)_5]_4[V_2P_2BO_{12}]_6{\cdot}nH_2O$ (1) and $(NH_4)_{3.5}(C_3H_{12}N_2)_{3.5}[Ni(H_2O)_6]_{1.25}{[Ni(H_2O)_5]_2[V_2P_2BO_{12}]_6{\cdot}nH_2O$ (2) have been synthesized and structurally characterized. Inter-diffusion methods were employed to prepare the compounds. The cluster anion $[(NH_4)\;{\supset}\;V_2P_2BO_{12}]_6$ is used as a building unit in the synthesis of new compounds containing $Ni(H_2O){^{2+}_5}$ in the presence of pyrazine and 1,3-diaminopropane. Compounds contain isolated cluster anions with general composition ${[Ni(H_2O)_5]_n[(NH_4)\;{\supset}\;V_2P_2BO_{12}]_6}^{-(17-2n)}$ (n = 2, 4). Crystal data: $(NH_4)_{10}[Ni(H_2O)_5]_4[V_2P_2BO_{12}]_6{\cdot}nH_2O$, monoclinic, space group C2/m (no. 12), a = 27.538(2) ${\AA}$, b = 20.366(2) ${\AA}$, c = 11.9614(9) ${\AA}$, ${\beta}$ = 112.131(1)$^{\circ}$, Z = 8; $(NH_4)_{3.5}(C_3H_{12}N_2)_b[Ni(H_2O)_6]_{3.5}{[Ni(H_2O)_5]_2[V_2P_2BO_{12}]_6{\cdot}nH_2O$, triclinic, space group P-1 (no. 2), a = 17.7668(9) ${\AA}$, b = 17.881(1) ${\AA}$, c = 20.668(1) ${\AA}$, ${\alpha}$ = 86.729(1)$^{\circ}$, ${\beta}$ \ 65.77(1)$^{\circ}$, ${\gamma}$ = 80.388(1)$^{\circ}$, Z = 2.

Characterization of immunosuppressive factors in the mastitis-infected mammary gland of non-lactating cows I. Comparison of proportion of lymphocyte subpopulations from peripheral blood and mammary gland secretions of normal healthy cows and mastitic cows (건유기 유방염 감염우의 유방내 면역저하요인 규명에 관한 연구 I. 유방염 감염우와 정상우의 말초혈액 및 유즙내 림프구 아집단 분포율 비교)

  • Shin, Dong-baek;Park, Yong-ho;Nam, Hyang-mi;Moon, Jin-san;Joo, Yi-seok;Shin, Jong-uk
    • Korean Journal of Veterinary Research
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    • v.36 no.3
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    • pp.635-646
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    • 1996
  • To establish the effective ways to prevent bovine mastitis, the study has been performed to investigate the attributable factors causing down-regulation of immune responses in mammary gland of non-lactating cows. Lymphocytes from peripheral blood and mammary gland secretions(MGS) were obtained from normal healthy cows and mastitic cows, respectively. Cellular immune responses were examined by comparison of proportion of lymphocyte subpopulations using a set of monoclonal antibodies and flow cytometry. The results obtained are as follows. 1. Proportions of peripheral blood lymphocyte subpopulations expressing BoCD2 and BoCD4 molecules were 32.9%, 15.4% in mastitic cows and 43.3%, 28.3% in normal healthy cows, respectively. The ratios of BoCD4 to BoCD8 were 0.76 and 1.47, respectively. 2. Proportions of mammary gland lymphocyte subpopulations expressing BoCD2 and BoCD4 molecules were 18.5%, 8.3% in mastitic cows and 38.2%, 14.2% in normal healthy cows, respectively. The ratios of BoCD4 to BoCD8 were 0.6 and 2.0, respectively. 3. Proportions of T lymphocyte subpopulations from MGS were significantly lower than those from peripheral blood both in mastitic cows and normal healthy cows. However, lymphocyte subpopulations expressing ACT2 and ACT3, which represent activated T suppressor cells, were significantly higher in MGS than those in peripheral blood.

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A study on DongUiBoGam(東醫寶鑑) ChimGu Chapter(鍼灸篇) based on the NaeGyeong Chapter(內景篇) (『동의보감(東醫寶鑑)』 침구편(鍼灸篇)의 의사학적고찰(醫史學的考察) - 「내경편(內景篇)」에 나타난 침구법(鍼灸法)을 중심으로 -)

  • Oh, Jun Ho;Cha, Wung Seok;Kim, Nam Il
    • The Journal of Korean Medical History
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    • v.17 no.1
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    • pp.119-141
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    • 2004
  • DongUiBoGam(東醫寶鑑) is Joseon's classic medical text that has great significance in the medical history of Korea. However, the context of the treatments of accupuncuret&moxibustion in the book are hardly studied. This study is for the purpose of examining the treatments of accupuncuret&moxibustion in DongUiBoGam(東醫寶鑑), and it starts with studying the accupuncuret&moxibustion part of DongUiBoGam(東醫寶鑑)'s NaeGyeong Chapter(內景篇) for starters. Through this study, the following could be known. 1. In DongUiBoGam(東醫寶鑑)'s NaeGyeong Chapter(內景篇), it is written that it quoted many various books, but actually, most of the parts are quoted from LouYing(樓英)'s YiXueGangMu (醫學綱目). 2. LouYing(樓英)'s YiXueGangMu(醫學綱目) is a work of the Ming Dynasty, which is when China's study of accupuncure&moxibustion was completed and many books on accupuncure&moxibustion were published. 3. However, in DongUiBoGam(東醫寶鑑), it mainly quotes from YiXueGangMu(醫學綱目), instead of these professional acupuncture&moxibustion texts. This is because this book is a comprehensive medical text with various medical theories, which share the same flow with DongUiBoGam(東醫寶鑑), and at the same time, it organized the treatments of accupuncure&moxibustion in a big scale in various ways.

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Effects of H$_2$BO$_3$ on the Hydration of $C_4$A$_3$S Blended Rapid Hardign Cement (CSA계 혼합 시멘트 수화에 미치는 Boric Acid 의 영향)

  • Yoo, K.S.;Lee, K.H.;Kim, N.H.;Lee, Y.S.;Hun, K.H.;Lee, J.W.;Yim, Going
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.583-593
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    • 1998
  • The study was carried on the influence of {{{{ { {H }_{3 }BO }_{3 } }} for hydration of blended rapid hardening cement which was composed of {{{{ {{C }`_{4 } ^{ }A }_{3 } }} Adding {{{{ { {H }_{3 }BO }_{3 } }} to the mortar of blended rapid hardening cement delayed the setting time and increased the flow of the mortar. When {{{{ { {H }_{3 }BO }_{3 } }} added to the blended rapid hardening cement mono-sulfate was produced rather than ettringite and the existing time of monosulfate also prolonged. After hours monosulfate was converted to ettringite through being producted like gels. This monosulfate phase in-fluences on the setting time and flow of fresh mortar.

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Effect of Additives for Prevention of NaBO2 Precipitation on Hydrogen Generation Properties of NaBH4 Hydrolysis (NaBO2의 석출 방지를 위한 첨가제가 NaBH4 가수분해의 수소발생특성에 미치는 영향)

  • Oh, Taekyun;Kwon, Sejin
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.1
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    • pp.1-11
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    • 2013
  • Additives such as glycerol, methanol, acetone, and ethanol were used to prevent $NaBO_2$ from precipitation, and their effects on hydrogen generation properties of $NaBH_4$ hydrolysis were investigated. When the concentration of additives was 5 wt%, the additives such as methanol, acetone, and ethanol could not prevent $NaBO_2$ precipitation. Although glycerol prevented $NaBO_2$ precipitation, conversion efficiency decreased to 78.0% due to its viscosity. Based on test results, hydrogen generation tests were also performed at various concentration of glycerol and methanol to investigate the concentration effects on hydrogen generation properties. As the concentration of glycerol increased from 1 wt% to 3 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 5 wt%, conversion efficiency decreased due to its viscosity. As the concentration of methanol increased from 5 wt% to 10 wt%, conversion efficiency increased owing to additive effect. When its concentration increased to 15 wt%, conversion efficiency decreased due to $NaB(OCH_3)_4$ precipitate. Although conversion efficiency decreased about 1% when 3 wt% glycerol was added, $NaBO_2$ precipitation was prevented. Consequently, addition of 3 wt% glycerol to $NaBH_4$ solution improves stability of hydrogen generation system.

Scientific review of the aesthetic uses of botulinum toxin type A

  • Park, Mee Young;Ahn, Ki Young
    • Archives of Craniofacial Surgery
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    • v.22 no.1
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    • pp.1-10
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    • 2021
  • Botulinum toxin type A (BoNT-A), onabotulinumtoxinA (Botox) was approved by the United States Food and Drug Administration for temporary improvement of glabellar lines in patients 65 years and younger in 2002, and has also been used widely for aesthetic purposes such as hyperhidrosis, body shape contouring, and other noninvasive facial procedures. BoNT-A inhibits presynaptic exocytosis of acetylcholine (ACh)-containing vesicles into the neuromuscular junction at cholinergic nerve endings of the peripheral nervous system, thereby paralyzing skeletal muscles. ACh is the most broadly used neurotransmitter in the somatic nervous system, preganglionic and postganglionic fibers of parasympathetic nerves, and preganglionic fibers or postganglionic sudomotor nerves of sympathetic nerves. The scientific basis for using BoNT-A in various cosmetic procedures is that its function goes beyond the dual role of muscle paralysis and neuromodulation by inhibiting the secretion of ACh. Although the major target organs for aesthetic procedures are facial expression muscles, skeletal body muscles, salivary glands, and sweat glands, which are innervated by the somatic or autonomic nerves of the peripheral cholinergic nerve system, few studies have attempted to directly explain the anatomy of the areas targeted for injection by addressing the neural physiology and rationale for specific aesthetic applications of BoNT-A therapy. In this article, we classify the various cosmetic uses of BoNT-A according to the relevant component of the peripheral nervous system, and describe scientific theories regarding the anatomy and physiology of the cholinergic nervous system. We also review critical physiological factors and conditions influencing the efficacy of BoNT-A for the rational aesthetic use of BoNT-A. We hope that this comprehensive review helps promote management policies to support long-term, safe, successful practice. Furthermore, based on this, we look forward to developing and expanding new advanced indications for the aesthetic use of BoNT-A in the future.

Thermoluminescence Kinetics of LYGBO Crystal (LYGBO 단결정의 열형광 전자포획준위 인자)

  • Sunghwan, Kim
    • Journal of the Korean Society of Radiology
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    • v.17 no.1
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    • pp.17-23
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    • 2023
  • In this study, the thermoluminescence kinetics of electron trap in Li6Y0.5Gd0.5(BO3)3 (LY0.5G0.5BO) scintillator for neutron detection composed of Li, Gd, and B with a high neutron response cross-section were investigated. The thermoluminescence glow curve of the LY0.5G0.5BO scintillation single crystal was measured and analyzed using the peak shape method, the initial rise method, and the machine learning algorithm to evaluate the physical parameters of the electron trap. The glow curve of the LY0.5G0.5BO scintillation single crystal consisted of a single peak. As a result of analyzing this peak, the activation energy, emission order, and frequency factor of the electron trap were 0.61 eV, 1.1, and 1.7×107 s-1, respectively. In addition, the possibility of thermoluminescence analysis of scintillators using machine learning was confirmed.

Structure of SrO-B2O3-Al2O3 and SrO-B2O3-SiO2 glasses Using 11B Nuclear Magnetic Resonance (11B NMR 방법에 의한 SrO-B2O3-Al2O3와 SrO-B2O3-SiO2 유리들의 구조에 관한 연구)

  • Moon, Seong-Jun
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.2
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    • pp.19-25
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    • 2002
  • Ternary $xSrO-yB_2O_3-0.1Al_2O_3$ and $xSrO-yB_2O_3-0.1SiO_2$ glasses were prepared as a function of R(${\equiv}x/y$). The fraction of four-coordinated brans ($N_4$), symmetric three-coordinated barons ($N_{3S}$), and asymmetric three-coordinated barons ($N_{3A}$) were determined quantitatively to study the structures of these glasses by $^{11}B$ NMR. The values of $Q_{cc}$ and ${\eta}$ for $BO_3$ unit in the glasses were 2.74MHz and 0.22, those for $BO_3{^-}$ unit were 2.54MHz and 0.55, and those for $BO_4$ unit 0.60~0.75MHz and 0.00, respectively. The structure of SrBAl glass at $R_{1st}$ consisted of tetraborate ($[B_8O_{13}]^{-2}$) units and 1st-modified diborate ($[B_2Al_2O_7]^{-2}$) units, and those for the glass at $R_{max}$consisted of diborate ($[B_4O_7]^{-2}$) units, metaborate ($[BO_2^{-1}]$), 1st-modified diborate units, and 2nd-modified diborate ($[B_2Al_2O_8]^{-4}$) units. Due to the oxygens introduced from the strontium oxide. $AlO_4$ units were preferably formed rather than $BO_4$ units. And, the structure of SrBSi glasses in the region $R{\leq}0.5$ could be viewed as binary $SrO-B_2O_3$ glasses structure diluted by silicate oxide: therefore, the Si atoms of the glasses did not contributed to the change the configuration around the boron atoms. The silicate oxide was formed the $SiO_4{^-}$ units rather than the $BO_3{^-}$ units by the oxygens introduced from the storntium oxide in the region of $R{\geq}R_{max}$, and structure of those glass at $R_{max}$ consisted of diborate units, metaborate units loose $BO_4([BO_2]^{-1})$, and $SiO_4{^-}([SiO_{2.5}]^{-1})$ units.

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A case study on patient with diplopia caused by stroke (뇌경색(腦梗塞)으로 인한 복시(複視) 증상 치료(治療) 1례(例)에 대한 증례보고(證例報告))

  • Lee, Han-Eol;Ahn, Taek-Won
    • Journal of Haehwa Medicine
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    • v.16 no.1
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    • pp.199-206
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    • 2007
  • Objective : The purpose of this study is to report treated case about patient with diplopia caused by stroke. Methods : The improvement of diplopia was observed as he was treated with acupuncture therapy and herb medicine named Bo-gan-san(保肝散). Results : Diplopia improved and disappeared gradually with acupuncture therapy and herb medicine named Bo-gan-san(保肝散). The patient was discharged with favorable recovery. Conclusion : In traditional Korean medicine, diplopia is caused by disorder of JungKi(精氣), intrusion of PoongSa(風邪) into Neoi(腦), and hollowness of Gan(肝), Shin(腎). Treating it is by expelling PoongSa(風邪) or strengthening Gan(肝), Shin(腎). The patient was diagnosed as cerebral infarction according to Brain MRI. Diplopia was improved after acupunctural therapy and intaking Bo-gan-san(保肝散), herbal prescription selected from DongYiBoGam(東醫寶鑑).

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A study on the Classification of Disease in 『DongEuiBoGam』 (4) (『동의보감』의 질병문류에 대한 연구(4) -「잡병편」 (권2)의 ‘풍문’ 중 ‘파상풍’을 중심으로-)

  • Jeong Woo Yeal
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.16 no.2
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    • pp.209-214
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    • 2002
  • At this paper, I classified ‘tetanus’ in 『DongEuiBoGam』 and studied the concept, causes, symptoms, pathological mechanisms of that disease and then I had a new understanding that concept of tetanus in 『DongEuiBoGam』 is different with concept of tetanus in Western Medicine. In the mean time, I investigated the classification in 「Classification of Korean Standard Cause of Death(Oriental Medicine)」 (1995, The Korean Economic Planning Board), and concluded the concept of tetanus in "DongEuiBoGam".