• Title/Summary/Keyword: BLN-PZT ceramics

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Quadratic Electrooptic Properties of the BLN-PZT Ceramics (BLN-PZT 세라믹의 2차 전기광학 특성)

  • Ryu, Ki-Won;Park, In-Gil;Bae, Seon-Gi;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1110-1112
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    • 1993
  • Optical and quadratic electrooptic properties were studied for some compositions(BLN/PZ/PT=9.0/70/30,9.0/65/35,8.5/70/30,8.5/65/35) of the two-stage sintered BLN-PZT ceramics. Effective birefringences(${\Delta}n$), quadratic electrooptic coefficients(R) and half-wave voltages($V_{\pi}$) were measured with electric field and temperature. Also, switching times and contrast ratios were measured.

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Effects of $Ba(La_{1/2}Nb_{1/2})O_3$ content and Zr/Ti composition ratio on electrooptic properties of the $Ba(La_{1/2}Nb_{1/2})O_3-Pb(Zr, Ti)O_3$ ceramics ($Ba(La_{1/2}Nb_{1/2})O_3$의 고용량과 Zr/Ti 조성비가 $Ba(La_{1/2}Nb_{1/2})O_3-Pb(Zr, Ti)O_3$ 세라믹의 전기광학 특성에 미치는 영향)

  • 류기원;이성갑;배선기;이영희
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.44 no.5
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    • pp.644-648
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    • 1995
  • Transparent xBa(La$_{1}$2/Nb$_{1}$2/)O$_{3}$-(1-x)Pb(Zr, Ti)O$_{3}$ (x=8.5, 9.0[mol.%], Zr/Ti=70/30~40/60) ceramics were fabricated by the two-stage sintering method, the electrooptic properties were investigated with Ba(La$_{1}$2/Nb$_{1}$2/)O$_{3}$ content and Zr/Ti composition ratio. Decreasing the Zr/Ti ratio, the electrooptic property was changed from a quadratic electrooptic effect to a linear electrooptic effcet. In the BLN-PZT 9.0/50/50 specimen having the tetragonal structure, the linear electrooptic coefficient had the highest value of 6.01*10$^{-10}$ [m/V] and in the BLN-PZT 9.0/55/45 specimen which located near the MPB region, the quadratic electrooptic coefficient had the highest value of 10.53*10$^{-16}$ [m$^{2}$/V$^{2}$].

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Phase Transition Characteristics of the BLN - PZT Ceramics. (BLN-PZT 세라믹의 상전이 특성)

  • 류기원;이영종;배선기;이영회
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.25-33
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    • 1994
  • Temperature dependences of the remanent polarization $P_{\gamma}$/(T), effective birefringence ㅿn(T). dielectric constant K(T) and quadratic electro-optic coefficient R(T) of the two-stage sintered xBa(La$_{1/2}$Nb$_{1/2}$)O$_3$Pb$(Zr_{y}Ti_{1-y})O-{3}$(x=0.085, 0.09, 0.40$\leq$y$\leq$0.70)ceramics were investigated. Increasing the PbZrO$_3$ contents, the crystal structure of a specimen was varied from tetragonal and rhombohedral to cubic, and the phase transition was showed a diffuse phase transition(DPT) characteristics. Especially. in the compositions which located on the PE-FE phase boundary were showed a discrepancy between curie temperature and temperature range which a macroscopic polarization and a effective birefringence were disappeared.

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A study on the phase transition characteristics of the $Ba(La_{1/2} Nb_{1/2})O_3-Pb(Zr, Ti)O_3$ ceramics ($Ba(La_{1/2} Nb_{1/2})O_3-Pb(Zr, Ti)O_3$ 세라믹의 상전이 특성에 관한 연구)

  • 류기원;배선기;박인길;이영희
    • Electrical & Electronic Materials
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    • v.8 no.2
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    • pp.190-195
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    • 1995
  • Temperature dependences of the dielectric constant K(T), remanent polarization $P_{r}$, (T), effective birefringence overbar .DELTA.n(T), transmitted light intensity and quadratic electro optic coefficient R(T) of the two-stage sintered xBa(L $a_{1}$2/N $b_{1}$2/) $O_{3}$-(1-x)Pb(Z $r_{y}$ $Ti_{1-y}$) $O_{3}$(x=0.085, 0.09, 0.40.leq.y.leq.0.70) ceramics were investigated. Increasing the PbZr $O_{3}$ contents, the crystal structure of a specimen was changed from a tetragonal phase to a rhombohedral and cubic phase, and the phase transition was showed a diffuse phase transition(DPT) characteristics. In the compositions which located on the PE-FE phase boundary, the discrepancy was observed between the Curie temperature and temperature which a microscopic polarization and effective birefringence were disappeared.red.d.

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Light modulation properties of the penferroelectric BLN-PZT ceramics (준강유전 BLZ-PZT 세라믹의 광변조특성)

  • 류기원;정장호;박인길;이영희
    • Electrical & Electronic Materials
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    • v.6 no.5
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    • pp.454-460
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    • 1993
  • 본 연구에서는 준강유전 특성을 갖는 xBa(L $a_{1}$2/N $b_{1}$2/) $O_{3}$- (1-x)Pb(Z $r_{y}$ $Ti_{1-y}$) $O_{3}$ (x=8.5, 9.0[mol.%], y=65, 70[mol.%]) 세라믹을 2단 소성법으로 제작한 후, 조성 및 인가전계에 따른 전기광학 특성 및 광변조 특성을 측정하였다. 인가전계가 증가함에 따라 8.5/65/35 시편을 제외한 전조성에서 유효복굴절이 2차 함수적으로 변화하는 2차 전기광학 특성을 나타내었으며 2차 전기광학계수, 반파장전압 및 ON-OFF ratio는 9.0/65/35 시편에서 각각 6.17x$10^{-16}$[ $m^{2}$/ $v^{2}$], 136[V], 252의 가장 우수한 값을 나타내었다. 9.0/70/30, 9.0/65/35 및 8.5/70/30 시편에 대해 광변조 특성을 측정한 결과, 입사광의 세기를 인가전압에 의해 변조시킬 수 있음을 관찰하였다.다.

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