• Title/Summary/Keyword: B-doped

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Effects of B Doping on Structural, Optical, and Electrical Properties of ZnO Nanorods Grown by Hydrothermal Method

  • Kim, Soaram;Nam, Giwoong;Park, Hyunggil;Yoon, Hyunsik;Kim, Byunggu;Kim, Jin Soo;Kim, Jong Su;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.337-337
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    • 2013
  • ZnO seed layers were deposited on a quartz substrate using the sol-gel method, and B-doped ZnO (BZO) nanorods with different B concentrations ranging from 0 to 2.5 at.% were grown on the ZnO seed layers by the hydrothermal method. The structural, optical, electrical propertiesof the ZnO and BZO nanorods were investigated using field-emission scanning electron microscopy, X-ray diffraction (XRD), photoluminescence (PL), ultraviolet-visible spectroscopy, and hall effect. The ZnO and BZO nanorods grew well aligned on the surface of the quartz substrates. From the XRD data, it can be seen that the B doping is responsible for the distortion of the ZnO lattice. The PL spectra show near-band-edge emission and deep-level emission, and they also show that B doping significantly affects the PL properties of ZnO nanorods. The optical band gaps are changed by B doping, and thus the Urbach energy value changed with the optical band gap of the ZnO nanorods. From the hall measurements, it can be observed that the values of electrical resistivity, carrier concentration, and mobility are changed by B doping.

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The Effect of Non Magnetic ion Substitution for the FeCr2-xMxS4(M=Ga, In) by Mossbauer Spectroscopy (비자성 이온 Ga, In이 치환된 유화물 스피넬의 뫼스바우어 분광학 연구)

  • Son, Bae-Soon;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.6-10
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    • 2006
  • The sulphur spinel $FeCr_{2-x}M_xS_4$(M=Ga, In) have been studied with Mossbauer spectroscopy, x-ray diffraction (XRD), and vibrating sample magnetometer. The XRB patterns for samples $FeCr_{2-x}M_xS_4$(M=Ga, In: x=0.1, 0.3) reveal a single phase, which the Ga and In ions are partially occupied to the tetrahedral (A) site. The Neel temperature for the Ga substituted samples increases from 180 to 188 K, with increase from x=0.1 to 0.3. While, it decreases from 173 to 160 K, for the In substituted samples of the x=0.1 and 0.3, respectively. The Mossbauer spectra were collected from 4.2 K to room temperature. We have analyzed the Mossbauer spectra using eight Lorentzian lines fitting method for the $FeCr_{2-x}In_xS_4$(x=0.1) at 4.2 K, yielding the 1311owing results; $H_{hf}=146.0kOe,\;{\Delta}E_Q=1.88mm/s,\;\theta=36^{\circ},\;\phi=0^{\circ},\;\eta=0.6$, and R=1.9. The Ga ions enter into the both sites octahedral (B) and tetrahedral (A), simultaneously the same amounts of Fe ions migrate from the A to the B site, this result is an agreement with XRD results, too. The ${\Delta}E_Q$ of the A and B site in Mossbauer spectra of the samples $FeCr_{2-x}Ga_xS_4$(x=0.3) are 0.83 and 2.94mm/s, respectively. While they are 0.56 and 2.36mm/s for the $FeCr_{2-x}In_xS_4$(x=0.3). It is noticeable that the ${\Delta}E_Q$ for the Ga doped samples are larger than that of the corresponding In doped samples, in spite of the larger ionic radius for In ions. The bond lengths of Cr-S, for the Ga and In doped samples (x=0.3) are found to be 2.41 and $2.43\;{\AA}$, respectively. We interpret that the larger covalence effect from the smaller bond length induces a large asymmetric charge distribution. Finally, it gives a large quadrupole interaction.

The Burst Effect Analysis of 2.5 Gb/s TDM-PON Systems Using a SOA Link Extender (반도체광증폭기로 전송거리 확장된 2.5 Gb/s TDM-PON에서 버스트 효과에 의한 신호왜곡 분석)

  • Choi, Bo-Hun;Lee, Sang Soo
    • Korean Journal of Optics and Photonics
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    • v.23 no.1
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    • pp.6-11
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    • 2012
  • A bidirectional TDM-PON link to support 2.5 Gb/s upstream signals of 256 ONUs was considered for an extended transmission distance of 50 km. The power budget of the link was 58 dB for the upstream signal and a SOA was applied as a link extender which had a 25 dB gain. Receiver sensitivity of the upstream signal was -25 dBm for -30 dBm input power to the SOA. When the input power was -10 dBm, pulse overshooting caused by gain transient of the SOA was maximum at 45% and the signal performance degradation gave a power penalty of 1.55 dB for $10^{-12}$ BER. However the penalties diminished rapidly and became negligible as the input power went below -15 dBm. So this input power dynamic range of up to -15 dBm means that it is not positively necessary to use gain control methods for the next generation TDM-PON systems.

Structural dependences of the extinction in an 1.55 $1.55{\mu}m$ InGaAsP/InGaAsP multiple-quantum-well electro-absorption modulator (1.55 $1.55{\mu}m$ InGaAsP/InGaAsP MQW 광흡수 변조기에서 구조변수가 소광특성에 미치는 영향)

  • 민영선;심종인;어영선
    • Korean Journal of Optics and Photonics
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    • v.12 no.1
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    • pp.40-47
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    • 2001
  • The structural dependence of the performance of an 1.55 $1.55{\mu}m$ InGaAsPIInGaAsP MQW electro-absorption modulator for highspeed digital fiber communication was systematically investigated. The effects of n-doped SCH region length $t_n$ as well as the general structure parameters including quantum well number $N_w$, well-thickness $t_w$, detuning wavelength $\Delta\lambda$, and device length L were thoroughly analyzed. Thereby, a high-pelfoIDlance electro-absorption modulator with device length L of $100{\mu}m$ was successfully designed. The designed structure showed excellent characteristics that have residual loss less than -1.5 dB, operational voltage from 0 V to -2V, and extinction ratios of -2.92 dB at $V_{\alpha}$=-1 V and -10 dB at $V_{\alpha}$=-2V.X>=-2V.

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Effect of Constituent Ration NiO, CuO and B-Bi-Zn Addition on the Permeabilities of Hexagonal-ferrite (NiO, CuO 조성비와 B-Bi-Zn 첨가가 Hexagonal-Ferrite의 투자율에 미치는 영향)

  • Jeong, Seung-U;Kim, Tae-Won;Jeon, Seok-Tae;Myeong, Tae-Ho;Myeong, Tae-Ho
    • Korean Journal of Materials Research
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    • v.10 no.6
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    • pp.430-436
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    • 2000
  • In this paper, we have studied the effect of constituent ratio NiO, CuO and doped with B-Bi-Zn on proper-ties(microstructure, density, shrinkage, permeability as a function of frequency, etc.) of hexagonal-ferrite for high fre- quency chip-inductor material about several GHz. The permeability were analyzed by impedance analyzer(100 kHz∼ 40 MHz) and network analyzed(30 MHz∼3 GHz). As a result of the characteristics. the B-Bi-Zn glass ceramic was used to lower the sintering temperature for additive as function of frequency from 100kHz to 1.8 GHz showed con-stant tends. The maximum imaginary value of complex permeability was observed near the resonance frequency of 2 GHz.

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Power optimization of optical 40 wavelength division multiplexing channels at 3000 km transmission for link span variation (40 채널 파장 다중화 광신호 3000 km 전송에서 링크 구간 거리에 따른 광신호 세기 최적화)

  • Choi, Bo-Hun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.17 no.1
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    • pp.197-203
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    • 2013
  • Optical power optimization of 10 Gbps 40 wavelength division multiplexing channels was analyzed at the 3000 km long-haul transmission distance when the link span distance was changed between 40 km and 140 km. The signal performance of the transmission was obtained as a Q value and it was compared when input power into SSMF and input power into DCF on the transmission link were changed. The optimized input power into SSMF increased linearly to link span distance with 1 dB/km. The optimized power into DCF increased linearly with 0.5 dB/km up to 100 km link span, but it had no variation at longer link span than 100 km.

Structure and Magnetic Properties of Ho and Ni Co-doped BiFeO3 Ceramics

  • Hwang, J.S.;Yoo, Y.J.;Park, J.S.;Kang, J.H.;Lee, K.H.;Lee, B.W.;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.183-183
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    • 2014
  • Recently, multiferroic materials gain much attention due to their fascinating fundamental physical properties. These materials offer wide range of potential applications such as data storage, spintronic devices and sensors, where both electronic and magnetic polarizations can be coupled. Among single-phase multiferroic materials, $BiFeO_3$ is typical because of the room-temperature magnetoelectric coupling in view of long-range magnetic- and ferroelectric-ordering temperatures. However, $BiFeO_3$ is well known to have large leakage current and small spontaneous polarization due to the existence of oxygen vacancies and other defects. Furthermore the magnetic moment of pure $BiFeO_3$ is very weak owing to its antiferromagnetic nature. Recently, various attempts have been performed to improve the multiferroic properties of $BiFeO_3$ through the co-doping at the A and the B sites, by making use of the fact that the intrinsic polarization and magnetization are associated with the lone pair of $Bi^{3+}$ ions at the A sites and the partially-filled 3d orbitals of $Fe^{3+}$ ions at the B sites, respectively. In this study, $BiFeO_3$, $Bi_{0.9}Ho_{0.1}FeO_3$, $BiFe_{0.97}Ni_{0.03}O_3$ and $Bi_{0.9}Ho_{0.1}Fe_{0.97}Ni_{0.03}O_3$ bulk compounds were prepared by solid-state reaction and rapid sintering. High-purity $Bi_2O_3$, $Ho_2O_3$, $Fe_2O_3$ and $NiO_2$ powders with the stoichiometric proportions were mixed, and calcined at $500^{\circ}C$ for 24 h to produce the samples. The samples were immediately put into an oven, which was heated up to $800^{\circ}C$ and sintered in air for 1 h. The crystalline structure of samples was investigated at room temperature by using a Rigaku Miniflex powder diffractometer. The field-dependent and temperature-dependent magnetization measurements were performed with a vibrating-sample magnetometer and superconducting quantum-interference device.

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Influence of O2-Plasma Treatment on the Thin Films of H2 Post-Treated BZO (ZnO:B) (수소 플라즈마 처리된 BZO 박막에 산소 플라즈마의 재처리 조건에 따른 BZO 박막 특성)

  • Yoo, H.J.;Son, C.G;Yoo, J.H.;Park, C.K.;Kim, J.S.;Park, S.G.;Kang, H.D.;Choi, E.H.;Cho, G.S.;Kwon, G.C.
    • Journal of the Korean Vacuum Society
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    • v.19 no.4
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    • pp.275-280
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    • 2010
  • The influence of $O_2$-plasma treatment on $H_2$ post-treated BZO (ZnO:B) thin film using MOCVD (Metal-Organic Chemical Vapor Deposition) are investigated. An $O_2$-plasma treatment of the $H_2$ post-treated BZO thin films resulted in XRD peak of (100), (101) and (110). Also, electrical properties resulted in an increase in sheet resistance and work function. The weighted optical transmittance and haze at 300~1,100 nm of BZO thin films with $O_2$-plasma treatment on the $H_2$ post-treatment show approximately 86% and 15%, respectively.

Line-shape analysis of the Raman-spectrum from B1g bond buckling phonon in Bi2Sr2CaCu2O8+x

  • Jeong, J.;Oh, D.;Song, D.;Eisaki, H.;Kim, C.;Park, S.R.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.4
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    • pp.9-12
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    • 2019
  • We performed Raman spectroscopy on two different over-doped Bi2Sr2CaCu2O8+x (BSCCO), of which superconducting transition temperatures are 89 K and 77 K. Line-shape analysis of the Raman-spectrum was done, focused on B1g bond buckling mode which have drawn a lot of attention, since photoemission studies showed an evidence for strong coupling between the mode and electron. The line-shapes show asymmetry and are well fitted by the Fano line-shape formula. Remarkably, we found that the peak line-widths from B1g bond buckling mode in BSCCO show much broader than those in YBa2Cu3O7-x. The broad line width can be attributed to the superstructure modulation of BSCCO. Our results imply that B1g bond buckling mode may have close relation to the origin of superconductivity or to boosting the superconducting transition temperature in BSCCO.

Fabrication and Hydrogen Permeation Properties of $V_{99.8}B_{0.2}$ Alloy Membrane for Hydrogen Separation (수소 분리를 위한 $V_{99.8}B_{0.2}$ 분리막의 제조와 수소투과특성)

  • Jung, Yeong-Min;Jeon, Sung-Il;Park, Jung-Hoon
    • Membrane Journal
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    • v.21 no.4
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    • pp.345-350
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    • 2011
  • No investigation has yet been accomplished to screen the boron-doped effects on vanadium based metal membranes. The synthesis, hydrogen permeation properties and chemical stability of a novel Pd-coated $V_{99.8}B_{0.2}$ alloy membrane are presented in this report. Hydrogen permeation experiments have been performed to investigate the hydrogen transport properties through the Pd-coated $V_{99.8}B_{0.2}$ alloy membrane in the absolute pressure range 1.0~3.0 bar under pure hydrogen, hydrogen-carbon dioxide gas mixture at $400^{\circ}C$. The maximum hydrogen permeation flux was $48.5mL/min/cm^2$ for a 0.5 mm thick membrane under pure hydrogen. This results offer new direction in the synthesis of novel non-Palladium-based metal membranes for hydrogen separation in water-gas shift reaction.