• Title/Summary/Keyword: B-doped

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Microstructure Development during Sintering of $Nb_2O_5$-doped $UO_2$ pellets under $H_2$ and $CO_2$ atmospheres ($Nb_2O_5$ 첨가 $UO_2$ pellet의 수소 분위기와 이산화탄소 분위기 소결 중 미세조직의 형성에 대한 연구)

  • Song, K.W.;Kim, S.H.;Kim, B.G.;Lee, Y.W.;Yang, M.S.;Park, H.S.
    • Nuclear Engineering and Technology
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    • v.26 no.4
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    • pp.484-492
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    • 1994
  • Microstructures of Nb$_2$O$_{5}$-doped UO$_2$ pellets have been investigated during sintering under H$_2$ and $CO_2$ atmospheres. Pellets are sintered at 1$700^{\circ}C$ in H$_2$ atmosphere and at 130$0^{\circ}C$ in $CO_2$ atmosphere for 1 to 41 hr. The addison of Nb$_2$O$_{5}$ causes the formation of large pores, which shrink to some extent in H$_2$ atmosphere but very little in $CO_2$. Fine pores in the Nb$_2$O$_{5}$-doped UO$_2$ pellet are almost annihilated when sintered under H$_2$ atmosphere but little changed under $CO_2$ atmosphere. The increase in grain size due to Nb$_2$O$_{5}$ addition is much larger in H$_2$ atmosphere than in $CO_2$. Thus the enhancement of uranium diffusion in UO$_2$ due to the Nb$_2$O$_{5}$ addition is thought to be more significant in H$_2$ atmosphere. Microstructures of Nb$_2$O$_{5}$-doped UO$_2$ pellets sintered in H$_2$ atmosphere are discussed from the viewpoint of in-reactor performance. Possible defects formation due to Nb$_2$O$_{5}$ addition is discussed to explain the enhancement of uranium diffusion in H$_2$ and $CO_2$ atmospheres.> atmospheres.

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Progress in $MgB_2$ Superconductor Wires and Tapes

  • Kim, Jung-Ho;Kumakura, Hiroaki;Rindflesich, Matthew;Dou, Shi Xue;Hwang, Soo-Min;Joo, Jin-Ho
    • Progress in Superconductivity
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    • v.12 no.2
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    • pp.75-81
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    • 2011
  • We report on the progress that has been made in developing $MgB_2$ superconducting wires and tapes for commercialization and research efforts. A number of techniques have been developed to overcome the obstacle posed by the poor critical current density ($J_c$) of pristine $MgB_2$. Chemical doping has proved to be the effective way to modify and enhance the superconducting properties, such as the $J_c$ and the irreversibility field ($B_{irr}$). More than 100 different types of dopants have been investigated over the past 8 years. Among these, the most effective dopants have been identified to be SiC and malic acid ($C_4H_6O_5$). The best results, viz. a $B_{irr}$ of 22 T and $J_c$ of $30,000\;A{\cdot}cm^{-2}$ at 4.2 K and 10 T, were reported for malic acid doped $MgB_2$ wires, which matched the benchmark performance of commercial low temperature superconductor wires. In this work, we discuss the progress made in $MgB_2$ conductors over the past few years at the University of Wollongong, Hyper Tech Research, Inc., and Ohio State University.

1.6 Tb/s (160x10 Gb/s) WDM Transmission over 2,000 km of Single Mode Fiber (1.6 Tb/s (160x10 Gb/s) WDM 신호의 단일 모드 광섬유 2,000 km 전송)

  • 한진수;장순혁;이현재
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.29 no.7A
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    • pp.712-718
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    • 2004
  • We report 1.6 Tb/s (160${\times}$10 Gb/s) WDM transmission over 2,000 km of single mode fiber using distributed hybrid(distributed Raman amplifier+Erbium-doped fiber amplifier) optical amplifiers. After transmission over 2,000 km of single mode fiber, average optical signal to noise ratios of C/L-band were 20.5 dB, 21.9 dB, respectively. The minimum Q-factors of each band were 14.65 dB (BER=5.8e-8) in C-band, 13.75 dB (BER=5.0e-7) in L-band without forward error correction. We performed 1.6 Tb/s error-free transmission over 2,000 km of single mode fiber using Reed-Solomon (255, 239) forward error correction code.

Germanium-based pinning dopants for MgB2 bulk superconductors

  • Chung, K.C.;Ranot, M.;Shinde, K.P.;Oh, Y.S.;Kang, S.H.;Jang, S.H.;Hwang, D.Y.
    • Progress in Superconductivity and Cryogenics
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    • v.21 no.2
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    • pp.36-39
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    • 2019
  • Effects of the spherically shaped Ge and the rod-like carbon-coated Ge on the superconducting properties of $MgB_2$ were investigated. Pure Ge and carbon-coated Ge nano-powders were synthesized under the different amount of $CH_4$ (0 to 5 kPa) by using DC thermal plasma method. When the $CH_4$ was added ~100 nm sized Ge with a spherical shape changed to rod-like morphology with a diameter of ~30-70 nm and a length of ~400-500 nm. Also it was confirmed that thin carbon layers of a few nanometers were formed along the rod length and the agglomerated carbons were found on the edges of rods. Pure spherical Ge and Ge/C rods were mixed and milled with Mg & B precursor to form the doped $MgB_2$ bulk samples by the solid-state reaction method. Almost no change of $T_c$ was noticed for the pure Ge-added $MgB_2$, whereas $T_c$ was found to decrease with the Ge/C-added $MgB_2$ samples. It was found that the pure spherical Ge showed to have a negative effect on the flux pinning of $MgB_2$. However, Ge/C rods can enhance the flux pinning property of $J_c$ due to the coated carbon on Ge rods.

Electrical conductivity of olivine type LiFe0.965Cr0.03B0.005PO4 and LiFe0.965Cr0.03Al0.005PO4 powders (올리빈형 LiFe0.965Cr0.03B0.005PO4 and LiFe0.965Cr0.03Al0.005PO4 분말의 전기전도도)

  • Kim, Chang-Sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.141-146
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    • 2010
  • $LiFePO_4$ doped with Cr showed improved electrochemical properties as a cathode material of lithium-ion batteries compared to the undoped. The improvement was thought that the doping would raise the electronic conductivity of the compounds. The electrical conductivity of $LiFe_{0.965}Cr_{0.03}B_{0.005}PO_4$ and $LiFe_{0.965}Cr_{0.03}Al_{0.005}PO_4$ powder was measured in the temperature range from 30 to $80^{\circ}C$. The doped powders were synthesized via mechanochemical milling and subsequent heat treatment at 675~$750^{\circ}C$ for 5~10h. The doping enhanced grain growth and electrical conductivity. The electrical conductivity of the $LiFe_{0.965}Cr_{0.03}Al_{0.005}PO_4$ powder at $30^{\circ}C$ was $1{\times}10^{-8}S/cm$, which was higher two orders of magnitude than that of the undoped.

Miniaturized DBS Downconverter MMIC Showing a Low Noise and Low Power Dissipation Characteristic (저잡음ㆍ저소비전력 특성을 가지는 위성방송 수신용 초소형 다운컨버터 MMIC)

  • Yun, Young
    • Journal of Navigation and Port Research
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    • v.27 no.4
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    • pp.443-447
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    • 2003
  • In this work. using 0.2 GaAs modulation doped FET(MODFET), a high performance DBS downconverter MMIC was developed for direct broadcasting satellite (DBS) application. Without LNA, the downconverter MMIC showed a very low noise of 4.8 dB, which is lower by 3 dB than conventional ones. A low LO power of -10 dBm was required for the normal DBS operation of the downconverter MMIC. which reduced the power consumption via a removal of LO amplifier on MMIC. It required only a low power consumption of 175 mW, which is lower than 70 percent of conventional ones. The LO leakage power at IF output was suppressed to a lower level than 30 dBm, which removes a bulky LO rejection filter on a board. The fabricated chip, which include a mixer, If amplifiers. LO rejection filter, and active balun, exhibited a small size of $0.84{\times}0.9\textrm{mm}^2$.

RRT Study for the Quantitative Analysis of Boron in Silicon (실리콘에 도핑된 붕소의 정량분석에 대한 공동분석연구)

  • 김경중;김현경;문대원;홍태은;정칠성;김이경;김재남;임철호;김정호
    • Journal of the Korean Vacuum Society
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    • v.11 no.4
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    • pp.218-224
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    • 2002
  • A domestic round robin test(RRT) for the quantitative analysis of minor impurities was performed by a standard procedure and standard reference material. The certified reference material(CRM)s for B-doped Si thin film and analysis specimens and the analysis specimens were prepared by an ion beam sputter deposition method. These samples were certified by inductively coupled plasma mass spectrometry(ICP-MS) with isotope dilution method which il one of the most quantitative methods in chemical analysis. By using an international standard procedure(ISO/DIS-l4237) for the quantitative analysis of B in Si by SIMS, a domestic RRT was performed for these specimens. Although only a few laboratories participated in this RRT, the average B concentration well agreed with the certified value within 2% error.

Effects of α-particle beam irradiation on superconducting properties of thin film MgB2 superconductors

  • Kim, Sangbum;Duong, Pham van;Ha, Donghyup;Oh, Young-Hoon;Kang, Won Nam;Hong, Seung Pyo;Kim, Ranyoung;Chai, Jong Seo
    • Progress in Superconductivity and Cryogenics
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    • v.18 no.2
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    • pp.8-13
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    • 2016
  • Superconducting properties of thin film MgB2 superconductors irradiated with 45 MeV ${\alpha}$-particle beam were studied. After the irradiation, enhancement of the critical current density and pinning force was observed, scaling close to strong pinning formula. Double logarithmic plots of the maximum pinning force density with irreversible magnetic field show a power law behavior close to carbon-doped MgB2 film or polycrystals. Variation of normalized pinning force density in the reduced magnetic field suggests scaling formulas for strong pinning mechanism like planar defects. We also observed a rapid decay of critical current density as the vortex lattice constant decreases, due to the strong interaction between vortices and increasing magnetic field.

Effect of Boron Concentration on the UV Photosensitivity of Silica Glass Film for Planar Lightwave Circuit (Boron 첨가량이 평면광회로용 실리카 박막의 UV 감광성에 미치는 영향)

  • Kwon Ki Youl;Cho Seung-Hyun;Shin Dong Wook;Song Kug-Hyun;Lee Nak Kyu;Na Kyoung Hwan
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.826-833
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    • 2004
  • In this study, photosensitivity dynamics in SiO$_2$ glass with the composition similar to that of silica Planar Lightwave Circuit (PLC) devices was investigated as a fundamental study prior to the device fabrication. Silica bulk glasses with similar composition to the core layer of PLC devices were prepared with variable composition of B$_2$O$_3$. The photosensitivity in boron and germanium co-doped SiO$_2$ glass yields refractive index change $\Delta$n as high as 10$\^$-3/. However such index modulation disappeared after annealing. From the result of annealing experiment and W absorption / Raman spectra, we conclude the compaction model is applicable to our glass system.

Implemeention and performance measurement of a novel in-service supervisory system for WDM transmission link (파장분할다중화방식 전송로의 In-service 감시를 위한 새로운 감시시스템의 구현 및 성능평가)

  • 김필한;윤호성;박남규;서재은;정기태;유기원;이규행
    • Korean Journal of Optics and Photonics
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    • v.12 no.2
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    • pp.129-134
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    • 2001
  • Novel supervisory system for WDM transmission link using conventional optical time domain reflectometry was presented. By modifying the structure of erbuim doped fiber amplifier to support bi-directional transmission at arDR pulse wavelength and launching the optical pulse into transmission link in the opposite direction of data signal propagation to avoid the distortion by cross-gain modulation, it is possible to monitor the WDM link in service. To prove the validity of proposed scheme, the supervision result of 2.5 Gbps $\times$ 8 channel WDM 320 km transmission system in service by arDR was presented. And power penalty due to monitoring was measured as smaller than 0.3 dB. .3 dB.

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