• Title/Summary/Keyword: B-doped

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The Anisotropy of the London Penetration Depth and the Upper Critical Field in C-doped $MgB_2$ Single Crystals from Reversible Magnetization

  • Kang, Byeong-Won;Park, Min-Seok;Lee, Hyun-Sook;Lee, Sung-Ik
    • Progress in Superconductivity
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    • v.12 no.1
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    • pp.36-40
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    • 2010
  • We have studied the anisotropy of the London penetration depth of carbon doped $MgB_2$ single crystals, which was obtained from reversible magnetization measurements with the magnetic field both parallel and perpendicular to the c-axis. Similar to the pure $MgB_2$, the anisotropy of the upper critical field ${\gamma}_H$ decrease with temperature while the anisotropy of the London penetration depth ${\gamma}_{\lambda}$ slowly increases with temperature. However, the temperature dependence of ${\gamma}_H$ is drastically reduced and the value of ${\gamma}_{\lambda}$ becomes nearly ~1 as C is introduced. These results indicate that C substitution increases impurity scattering mainly in the $\sigma$ bands. The temperature dependence of the anisotropies agree well with the theoretical predictions with impurity scattering.

Photoconductive properties of B-doped hydrogenated amorphous silicon thin films (붕소 도핑된 수소화 비정질 실리콘박막의 광도전특성)

  • Park, Wug-Dong;Park, Ki-Chul;Park, Chang-Bae;Kim, Ki-Wan
    • Proceedings of the KIEE Conference
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    • 1987.07a
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    • pp.497-500
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    • 1987
  • Photoconductive properties of B-doped hydrogenated amorphous silicon thin films prepared by the RF glow discharge decomposition of $SiH_4-B_2H_6$ gas mixtures have been investigated. Experimental results showed that the B-doped hydrogenated amorphous silicon thin films have high photosensitivity and good optical absorption. Therefore these thin films can be used for the photoconductive layer of the vidicon target.

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Photocatalytic Degradation of Rhodamine B Using Carbon-Doped Carbon Nitride under Visible Light

  • Wang, Zhong-Li;Zhang, Zai-Teng;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.279-284
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    • 2020
  • In this work, a carbon-doped carbon nitride photocatalyst is successfully synthesized through a simple centrifugal spinning method after heat treatment. The morphology and properties of the prepared photo catalyst are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis spectrophotometer (UV-vis), and specific surface area. The results show that the band gap of the prepared sample, g-CN-10 is 2.1 eV, is significantly lower than that of pure carbon nitride, 2.7 eV. As the amount of cotton candy increased, the absorption capacity of the prepared catalyst for visible light is significantly enhanced. In addition, the degradation efficiency of Rhodamine B (RhB) by sample g-CN-10 is 98.8 % over 2 h, which is twice that value of pure carbon nitride. The enhancement of photocatalytic ability is attributed to the increase of specific surface area after the carbon doping modifies carbon nitride. A possible photocatalytic degradation mechanism of carbon-doped carbon nitride is also suggested.

Deposition of B-doped ZnO Thin Films by Plasma Enhanced Chemical Vapor Deposition (플라즈마 화학기상 증착법에 의한 B이 첨가된 ZnO 박막의 증착에 관한 연구)

  • Choe, Jun-Yeong;Jo, Hae-Seok;Kim, Yeong-Jin;Lee, Yong-Ui;Kim, Hyeon-Jun
    • Korean Journal of Materials Research
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    • v.5 no.5
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    • pp.568-574
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    • 1995
  • We investigated the effects of B-doping on the growth mechanism of ZnO films. The B-doped ZnO films, which were widely applied for transparent conducting electrode, were deposited by plasma enhanced chemcial vapor depostion(PECVD) using diethylzinc(DEZ), No.sub 2/. and B$_{2}$H$_{6}$. The deposition conditions were a sbustrate temperature of 30$0^{\circ}C$, an rf power of 200, and a chamber pressure of 1 torr. At the given depostion condition, the growth rate of B-doped ZnO thin films was higher than that of undoped ones, but didn't change even with further increasing B$_{2}$H$_{6}$ flow rate and the interplanar distance between(0002) planes was reduced as B atoms substituted Zn sites.s.

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Characteristics analysis of Piezoelectric Thin Film SAW filter using Mg-doped GaN/Sapphire Structure (Mg-Doped GaN/Sapphire 구조로 제작된 압전 박막 SAW 필터의 특성분석)

  • 장철영;정은자;정영철;최현철;이정희;이용현
    • Proceedings of the IEEK Conference
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    • 2003.07b
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    • pp.759-762
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    • 2003
  • The epitaxially grown Mg-doped GaN thin film was prepared by MOCVD (Metal Organic Chemical Vapor Deposition) for a SAW(Surface Acoustic Wave) filter. Mg-doped GaN thin film had enough properties for a SAW filter which include crystallinity and morphology. The surface morphology and crystalline of the Mg-doped GaN thin films were characterized using AFM and an X-ray rocking curve. The SAW filter, which was fabricated by lift-off process and frequency response, was measured by HP 8753C network analyzer. Center frequency was 96.687 MHz and SAW velocity was 5801 m/s when wavelength(λ) was 60${\mu}{\textrm}{m}$. Insertion loss was over -10 dB, Q was factor over 200, and side lobe attenuation was over 22 dB which was suitable for use as a SAW filter. Electro-mechanical coupling coefficient (k$^2$) was calculated from the measured data. k$^2$ was from 1 % to 1.44 %. The fabricated SAW filter using Mg-doped GaN/sapphire structure has good qualities as a filter and will be used as a SAW filter for operating RF frequency.

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Fabrication of Boron-Doped Activated Carbon for Zinc-Ion Hybrid Supercapacitors (아연-이온 하이브리드 슈퍼커패시터를 위한 보론 도핑된 활성탄의 제조)

  • Lee, Young-Geun;Jang, Haenam;An, Geon-Hyoung
    • Korean Journal of Materials Research
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    • v.30 no.9
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    • pp.458-464
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    • 2020
  • Zinc-ion hybrid supercapacitors (ZICs) have recently been spotlighted as energy storage devices due to their high energy and high power densities. However, despite these merits, ZICs face many challenges related to their cathode materials, activated carbon (AC). AC as a cathode material has restrictive electrical conductivity, which leads to low capacity and lifetime at high current densities. To overcome this demerit, a novel boron (B) doped AC is suggested herein with improved electrical conductivity thanks to B-doping effect. Especially, in order to optimize B-doped AC, amounts of precursors are regulated. The optimized B-doped AC electrode shows a good charge-transfer process and superior electrochemical performance, including high specific capacity of 157.4 mAh g-1 at current density of 0.5 A g-1, high-rate performance with 66.6 mAh g-1 at a current density of 10 A g-1, and remarkable, ultrafast cycling stability (90.7 % after 10,000 cycles at a current density of 5 A g-1). The superior energy storage performance is attributed to the B-doping effect, which leads to an excellent charge-transfer process of the AC cathode. Thus, our strategy can provide a rational design for ultrafast cycling stability of next-generation supercapacitors in the near future.

Effective of $Li_2CO_3$ and ZnBO for low temperature sintered $(Ba_{0.5},Sr_{0.5})TiO_3$ ceramics (BST 세라믹 저온소결에 $Li_2CO_3$와 ZnBO가 미치는 영향)

  • Kim, Se-Ho;You, Hee-Wook;Koo, Sang-Mo;Ha, Jae-Geun;Lee, Young-Hie;Koh, Jung-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.297-297
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    • 2007
  • The $(B_{0.5},Sr_{0.5})TiO_3$ ceramics, which added with low sintering materials $Li_2CO_3$ and ZnBO, was investigated for LTCC(low temperature co-fired ceramic) applications. To compare sintering temperature of $(B_{0.5},Sr_{0.5})TiO_3$ respectively, we added 1, 2, 3, 4, and 5wt% of $Li_2CO_3$ and ZnBO to $(B_{0.5},Sr_{0.5})TiO_3$. For confirming the sintering temperature, the respective specimens were sintered from $750^{\circ}C$ to $1200^{\circ}C$ by $50^{\circ}C$. The case of $Li_2CO_3$ greatly lowered the sintering temperature of $(B_{0.5},Sr_{0.5})TiO_3$ ($1350^{\circ}C$) below $900^{\circ}C$. The addition of ZnBO improved the loss tangent of $(B_{0.5},Sr_{0.5})TiO_3$. The crystalline structure of $LiCO_3$ doped $(B_{0.5},Sr_{0.5})TiO_3$ and ZnBO doped $(B_{0.5},Sr_{0.5})TiO_3$ was analyzed with the X-ray diffraction (XRD) analysis. The dielectric permittivity and loss tangent of $Li_2CO_3$ doped BST and ZnBO doped BST were measured with the HP 4284A precision. From the electrical characterization, we respectively obtained the dielectric permittivity 1361, loss tangent $6.94{\times}10^{-3}$ at $Li_2CO_3$ doped $(B_{0.5},Sr_{0.5})TiO_3$ (3wt%) and the dielectric constant 1180, loss tangent $3.70{\times}10^{-3}$ at ZnBO doped $(B_{0.5},Sr_{0.5})TiO_3$(5wt%).

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Carbon Monoxide Sensor Based on a B2HDDT-doped PEDOT:PSS Layer

  • Memarzadeh, R.;Noh, Hui-Bog;Javadpour, S.;Panahi, F.;Feizpour, A.;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.8
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    • pp.2291-2296
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    • 2013
  • An efficient carbon monoxide (CO) sensor was developed based on poly(3,4-ethylenedioxy)thiophenepoly(styrenesulfonate) (PEDOT:PSS) modified with a new pyrimidine-fused heterocyclic compound, bis(2-hydroxyphenyl)dihydropyrido[2,3-d:6,5-d]dipyrimidine-tetraone (B2HDDT). B2HDDT remains stable in the polymer matrix through interactions with functional groups of the polymer. It created prominent sites that captured CO gas, and the experimental parameters, including the amount of doped B2HDDT in the PEDOT:PSS film, were optimized. The sensor probe was also examined to verify its reliability for detecting CO in the presence of atmospheric gases in a discriminating manner. NMR, AFM, and FT-IR spectra were obtained to evaluate the structure and morphology of the B2HDDT-doped PEDOT:PSS (PEDOT:PSS/B2HDDT) film. The content of 35 vol % B2HDDT (7.0 mM) in PEDOT:PSS provided the largest response factor (${\Delta}R/R_o$) for the CO gas. The sensor response was reproducible, with a relative standard deviation < 5% (n = 5). The detection limit was determined to be $0.44{\pm}0.05$ vol %.

An Extended L-band Erbium-doped Fiber Amplifier to Amplify 1625 nm OTDR Signal for a Long Distance Monitoring System (장거리 광선로 감시용 1625 nm OTDR 신호 증폭을 위한 효율적인 Extended L-band Erbium-doped Fiber Amplifier)

  • Lee, Han-Hyub;Seo, Dae-Dong;Lee, Dong-Han;Choi, Hyun-Beom;Jeon, Jeon-Gu
    • Korean Journal of Optics and Photonics
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    • v.16 no.5
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    • pp.411-416
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    • 2005
  • We have designed an extended L-band Erbium-doped fiber amplifier to amplify 1625 nm optical time domain reflectometry signal for a long distance monitoring system. The proposed amplifier has a dual-stage structure without an isolator. Gain improvement of 5.1 dB has been achieved by adding a fiber Bragg grating and a narrow band pass filter. As a result, the 16.3 dB gain and 7.1 dB noise figure has been successfully accomplished.