• 멤브레인
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• 제12권4호
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• pp.193-206
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• 2002

투과증발법은 공비혼합물 등의 분리하기 어려운 액체혼합물을 효과적으로 분리하기 위한 분리법으로 각광을 받아오고 있는 막분리공정 중의 하나이다. 수용액의 탈수에 초점을 맞추어서 발전을 거듭해온 투과 증발막의 개발은 에탄을 탈수막과 이소프로판을 탈수막의 상용화에 성공하였으며, 현재 여러 분야에서 응용이 되고 있는 공정이다. 특히 최근에 와서 석유화학공정과 휘발성유기화합물의 분리에 유용한 효과적인 막재료와 공정의 개발이 이루어지고 있다. 투과증발분리막과 공정의 발전과 그 응용분야에 관하여 서술하여 보고자 한다.

• 기술사
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• 제34권2호
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• pp.23-27
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• 2001

Until 1996, CFC refrigerants haven't been used because it destroyed ozone that affecting In ecosystem. And HCFC will prohibit until 2020. In Europe, they attempt to move up its fulfillment. Until now the change have completed CFC into HFC134a and is considerated HCFC into HFC410A and HFC407C. But HFC41 OA has high condenser temperature and HFC407C is non-azeotropic refrigerant mixture and gliding temperature phenomenon. New refrigerant ell POE, PVE, PAG was also developed.

• Bulletin of the Korean Chemical Society
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• 제30권6호
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• pp.1317-1324
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• 2009

Asymmetric transfer hydrogenation of α-functionalized arylketones has been studied. The chiral Rh-catalyst effectively performed in transfer hydrogenation of $\alpha$-mesyloxyketones with an azeotropic mixture of formic acid/triethylamine to produce optically active 1-arylethandiols with excellent enantioselectivity.

• Journal of Advanced Marine Engineering and Technology
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• 제20권3호
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• pp.91-100
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• 1996

Experimental results for forced convection condensation of non-azeotropic refrigerant mixtures inside a horizontal smooth tube are presented. The mixtures of R-22+R-134a and pure refrigerants R-22 and R-134a are used as the test fluids and a double pipe heat exchanger of 7.5mm ID and 4800mm long inside tube is used. The range of parameters are 100-300kg/h of mass flow rate, 0-1.0 of quality, and 0, 33, 50, 67, and 100 weight percent of R-22 mass fraction in the mixtures. The heat flux, vapor pressure, vapor temperature and tube wall temperature were measured. Using the data, the local and average heat transfer coefficients for the condensation have been obtained. In the same given experimental conditions, the liquid heat transfer coefficients for NARMs were considerally lower than that of the pure refrigerant of R-22 and R-134a. Local heat transfer characteristics for NARMs were different from pure refrigerant R-22 and R-134a. In some regions, local heat transfer coefficients for NARMs were increased in the following order ; Bottom$\rightarrow$Top$\rightarrow$Side. The condensation heat transfer coefficients for NARMs increased with mass velocity, heat flux, and quality, but were considerably lower than that of pure refigerant R-22 and R-134a.

• 설비공학논문집
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• 제26권7호
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• pp.315-321
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• 2014

In this study, external condensation heat transfer coefficients (HTCs) of two non-azeotropic refrigerant mixtures of HFC32/HFC152a at various compositions were measured on both 26 fpi low-fin and Turbo-C enhanced tubes, of 19.0 mm outside diameter. All data were taken at the vapor temperature of $39^{\circ}C$, with a wall subcooling of 3~8 K. Test results showed that the HTCs of the tested mixtures on the enhanced tubes were much lower than the ideal values calculated by mass fraction weighting of the pure component HTCs. Also, the reduction of HTCs due to the diffusion vapor film was much larger than that of a plain tube. Unlike HTCs of pure fluids, HTCs of the mixtures measured on enhanced tubes increased, as the wall subcooling increased, which was due to the sudden break-up of the vapor diffusion film with an increase in wall subcooling. Finally, the heat transfer enhancement ratios for mixtures were found to be much lower, than those of pure fluids.

• 설비공학논문집
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• 제12권5호
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• pp.502-510
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• 2000

Evaporation heat transfer characteristics were studied in a horizontal tube using R22/R114 non-azotropic refrigerant mixture. the heat transfer coefficient was high in the upper part for pure refrigerants, and heat transfer coefficient was low in the lower part for refrigerant mixtures. In the low quality region where nucleate boiling was dominant, the average heat transfer coefficient was low. In the region where forced convection was dominant, heat transfer coefficient was high. Results show that the heat transfer coefficient for pure refrigerants obtained by experiments were lower than those of Yoshida et al. but agreed well with Jung et al., and Chen et al. data. But the heat transfer coefficients for refrigerant mixtures were lower about 20% than those predicted by the equation for pure refrigerant.

• 설비공학논문집
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• 제12권12호
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• pp.1049-1056
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• 2000

In this study, condensation heat transfer coefficients(HTCs) of 2 nonazeotropic refrigerant mixtures of HFC32/HFC134a and HFC134a/HCFC123 at various compositions were measured on a horizontal smooth tube. All data were taken at the vapor temperature of 39$^{\circ}C$ with a wall subcooling of 3~8K. Test results showed that HTCs of tested mixtures were 11.0~85.0% lower than the ideal values calculated by the mass fraction weighting of the pure components HTCs. Thermal resistance due to the diffusion vapor film was partly responsible for the significant reduction of HTCs with these nonazeotropic mixtures. The measured data were compared against the predicted ones by Colburn and Drew\`s film model and a good agreement was observed.

• 설비공학논문집
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• 제25권9호
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• pp.484-492
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• 2013

Nucleate pool boiling heat transfer coefficients (HTCs) are measured with HFC32/HFC152a mixture at several compositions. All data are taken at the liquid pool temperature of $7^{\circ}C$, on a horizontal plain square surface of $9.53{\times}9.53$ mm, with heat fluxes of 10 $kW/m^2$ to 100 $kW/m^2$ with an interval of 10 $kW/m^2$, in the increasing order of heat flux. Test results show that the HTCs of these mixtures are up to 45% lower than those of the ideal HTCs calculated by a linear mixing rule with pure fluids' HTCs, due to the mass transfer resistance associated with non-azeotropic refrigerant mixtures. Pool boiling data show the deduction in HTCs with an increase in GTD of the mixture. The present mixture data agree well with five well known correlations, within 20% deviation.

• 한국산학기술학회논문지
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• 제11권5호
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• pp.1747-1753
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• 2010

본 연구에서는 최대 공비점 압력을 가지는 에탄올과 벤젠 이성분계 혼합물의 기액 상평형 추산을 위하여 상태방정식 모델식과 액체활동도계수 모델식 사이의 비교 연구를 수행하였다. 상태방정식 모델식으로는 Peng-Robinson (PR) 상태방정식을 이용하였으며, Panagiotopoulos 혼합규칙(PRP)을 적용하였다. 한편, 액체 활동도계수 모델식으로는 Renon이 제안한 NRTL 액체 활동도계수 모델식을 이용하였다. PRP 모델식은 2개의 매개변수를 가짐에도 불구하고 3개의 매개변수를 가지는 NRTL 모델식에 비하여 에탄올-벤젠 이성분계에 대해서 저압 영역에서는 유사한 정확성을 고압 영역에서는 좀 더 정확성이 우수함을 확인하였다.

• 대한화학회지
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• 제12권4호
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• pp.155-159
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• 1968

On the extraction of humic acid from peat, the optimum conditions were studied and the effects of them on the characteristics of humic acid were also examined by means of infrared spectroscopy. 1. Pretreatment of peat with diluted 6-8% HCl solution for 5 hrs. prior to extraction with alcohol-benzol azeotropic mixture have resulted the better yield of humic acid. The water soluble Na-humates were obtained by the subsequent extraction with one hundred times quantity of caustic soda solutieon for 1hr. at 90 $^{\circ}C$. Thus the pure humic acids have been yielded approximately 40% (by wt.) from the raw peat. 2. In characteristics of humic acid, the chemical structure, mainly the contents of such functional groups as -COOH, -OH (phenol type), $-CH_2CO-$, $-CH_2{\cdot}O{\cdot}CH_2-$ and aromatic rings were varied according to the concentration of alkaline solution, temperature and time when the humic acids were extracted with alkali.