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Effects of Neutral Particle Beam on Nano-Crystalline Silicon Thin Film Deposited by Using Neutral Beam Assisted Chemical Vapor Deposition at Room Temperature

  • Lee, Dong-Hyeok;Jang, Jin-Nyoung;So, Hyun-Wook;Yoo, Suk-Jae;Lee, Bon-Ju;Hong, Mun-Pyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.254-255
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    • 2012
  • Interest in nano-crystalline silicon (nc-Si) thin films has been growing because of their favorable processing conditions for certain electronic devices. In particular, there has been an increase in the use of nc-Si thin films in photovoltaics for large solar cell panels and in thin film transistors for large flat panel displays. One of the most important material properties for these device applications is the macroscopic charge-carrier mobility. Hydrogenated amorphous silicon (a-Si:H) or nc-Si is a basic material in thin film transistors (TFTs). However, a-Si:H based devices have low carrier mobility and bias instability due to their metastable properties. The large number of trap sites and incomplete hydrogen passivation of a-Si:H film produce limited carrier transport. The basic electrical properties, including the carrier mobility and stability, of nc-Si TFTs might be superior to those of a-Si:H thin film. However, typical nc-Si thin films tend to have mobilities similar to a-Si films, although changes in the processing conditions can enhance the mobility. In polycrystalline silicon (poly-Si) thin films, the performance of the devices is strongly influenced by the boundaries between neighboring crystalline grains. These grain boundaries limit the conductance of macroscopic regions comprised of multiple grains. In much of the work on poly-Si thin films, it was shown that the performance of TFTs was largely determined by the number and location of the grain boundaries within the channel. Hence, efforts were made to reduce the total number of grain boundaries by increasing the average grain size. However, even a small number of grain boundaries can significantly reduce the macroscopic charge carrier mobility. The nano-crystalline or polymorphous-Si development for TFT and solar cells have been employed to compensate for disadvantage inherent to a-Si and micro-crystalline silicon (${\mu}$-Si). Recently, a novel process for deposition of nano-crystralline silicon (nc-Si) thin films at room temperature was developed using neutral beam assisted chemical vapor deposition (NBaCVD) with a neutral particle beam (NPB) source, which controls the energy of incident neutral particles in the range of 1~300 eV in order to enhance the atomic activation and crystalline of thin films at room temperature. In previous our experiments, we verified favorable properties of nc-Si thin films for certain electronic devices. During the formation of the nc-Si thin films by the NBaCVD with various process conditions, NPB energy directly controlled by the reflector bias and effectively increased crystal fraction (~80%) by uniformly distributed nc grains with 3~10 nm size. The more resent work on nc-Si thin film transistors (TFT) was done. We identified the performance of nc-Si TFT active channeal layers. The dependence of the performance of nc-Si TFT on the primary process parameters is explored. Raman, FT-IR and transmission electron microscope (TEM) were used to study the microstructures and the crystalline volume fraction of nc-Si films. The electric properties were investigated on Cr/SiO2/nc-Si metal-oxide-semiconductor (MOS) capacitors.

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Evaluation of yield and growth responses on paddy rice under the extremely high temperature using temperature gradient field chamber (온도구배야외챔버를 이용한 고온에서의 벼 생육반응 및 수량성 평가)

  • Oh, Dohyeok;Ryu, Jae-Hyun;Cho, Yunhyeong;Kim, Wonsik;Cho, Jaeil
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.1
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    • pp.135-143
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    • 2018
  • The effect of elevated temperature on temperate paddy rice will be significant for dependable food supply in East Asia. Using temperature gradient field chamber (TGFC), which was designed to make the horizontal air temperature gradient by $0^{\circ}C$ to $3^{\circ}C$ higher than outside, we examined the measurement to understand the effects of extremely high temperature on paddy rice. In particular, the data of the year 2016, the worst heat wave in over 22 years, was analyzed in this study. The rice height in the relatively warmed condition was rapidly increased during early growth stage. However, the average grain weight and number of spikelet per panicle in the warmed chamber condition were gradually declined with increasing air temperature averaged for 40 days after first heading in each chamber. In particular, the grain yield was more dramatically decreased by the raising temperature because the percent ripened grain was quickly dropped as getting over the threshold temperature for pollination. Therefore, the surplus photosynthetic product by such lower grain filling rate may disturbed the decreases of the NDVI (Normalized Difference Vegetation Index) and SPAD chlorophyll values after first (normal) heading. In addition, the late-emerging head grain were appeared. However, this yield was too small to recover the normal yields decreased by extremely high temperature condition. Our result represented that the warmed condition in 2016 would be the critical limit for the stable yield of temperate paddy rice.

Investigation of aluminum-induced crystallization of amorphous silicon and crystal properties of the silicon film for polycrystalline silicon solar cell fabrication (다결정 실리콘 태양전지 제조를 위한 비정절 실리콘의 알루미늄 유도 결정화 공정 및 결정특성 연구)

  • Jeong, Hye-Jeong;Lee, Jong-Ho;Boo, Seong-Jae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.6
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    • pp.254-261
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    • 2010
  • Polycrystalline silicon (pc-Si) films are fabricated and characterized for application to pc-Si thin film solar cells as a seed layer. The amorphous silicon films are crystallized by the aluminum-induced layer exchange (ALILE) process with a structure of glass/Al/$Al_2O_3$/a-Si using various thicknesses of $Al_2O_3$ layers. In order to investigate the effects of the oxide layer on the crystallization of the amorphous silicon films, such as the crystalline film detects and the crystal grain size, the $Al_2O_3$ layer thickness arc varied from native oxide to 50 nm. As the results, the defects of the poly crystalline films are increased with the increase of $Al_2O_3$ layer thickness, whereas the grain size and crystallinity are decreased. In this experiments, obtained the average pc-Si sub-grain size was about $10\;{\mu}m$ at relatively thin $Al_2O_3$ layer thickness (${\leq}$ 16 nm). The preferential orientation of pc-Si sub-grain was <111>.

Chewing Activities of Selected Roughages and Concentrates by Dairy Steers

  • Moon, Y.H.;Lee, S.C.;Lee, S.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.7
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    • pp.968-973
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    • 2002
  • To evaluate the chewing activity of ruminant feeds, four Holstein steers (average body weight $742{\pm}15kg$) were employed. Experimental feeds were four roughages ($NH_3$-treated rice straw, alfalfa hay, corn silage, orchard grass hay) and four concentrate ingredients (cotton seed hull, beet pulp pellet, barley grain, oat grain). Regarding palatability for each experimental feeds which was overviewed during the adjustment period, animals were fed roughages alone, but with 50% $NH_3$-treated rice straw ($NH_3$-RS) for concentrate ingredients. Therefore, all the data for concentrate ingredients was derived by extracting the result per unit obtained from steers fed $NH_3$-RS alone. The experiment was conducted using a 4${\times}$4 Latin square designs for roughages and concentrate ingredients. Experimental feeds were fed during a 10 d adaptation and 2 d chewing data collection during each experimental period. Animals were gradually adjusted to the experimental diet. Dry matter intake (DMI) was restricted at a 1.4% of mean body weight (10.4 kg DM/d). Time spent eating and eating chews per kilogram of DMI were greatest for beet pulp pellet, and lowest for barley grain (p<0.05). Time spent rumination per kilogram of DMI was greatest for $NH_3$-RS, cotton seed hull and orchard grass, but rumination chews were greatest for cotton seed hull and orchard grass except $NH_3$-RS (p<0.05). Roughage index value (chewing time, minute/kg DMI) was 58.0 for cotton seed hull, 56.1 for beet pulp pellet, 55.5 for $NH_3$-RS, 53.1 for orchard grass hay, 45.9 for corn silage, 43.0 for alfalfa hay, 30.0 for oat grain, and 10.9 for barley grain. The ratio of rumination time to total chewing time (eating plus ruminating) was about 72% for the roughages except corn silage (66.9%), and followed by cotton seed hull (69.5%), and ranged from 49.5% to 52.9% for other feeds. Higher percentages of rumination in total chewing time may be evidently indicate the characteristics of roughage. Therefore, this indicate that the chewing activity of concentrate ingredients can be more fully reflects by the ruminating time than total chewing time (RVI), although it is reasonable to define the RVI for roughages.

Study of morphology on the Oxidation and the Annealing of High Burn-hp $UO_2$ Spent Fuel (고연소도 사용후 핵연료의 가열산화와 고온가열을 통한 미세조직 변화고찰)

  • Kim Dae Ho;Bang Jae Geun;Yang Yong Sik;Song Keun Woo;Lee Hyung Kwon;Kwon Hyung Moon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.4
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    • pp.301-307
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    • 2005
  • The morphology of the high burnup $UO_2$ spent fuel, which was oxidized and annealed in a PIA (Post Irradiation Annealing) apparatus, has been observed. The high burnup fuel irradiated in Ulchin Unit 2, average rod burnup 57,000 MWd/tU, was transported to the KAERI's PIEF. The test specimen was used with about 200 mg of the spent $UO_2$ fuel fragment of the local burnup 65,000 MWd/tU. This specimen was annealed at $1400^{\circ}C$ for 4hrs after the oxidation for 3hrs to grain boundary using the PIA apparatus in a hot-cell. In order to oxidize the grain boundary, the oxidation temperature increased up to $500^{\circ}C$ and held for 3hrs in the mixed gas (60 ml He and 100 ml STD-air) atmosphere. The amount of 85Kr during the whole test process was measured to know the fission gas release behavior using the online system of a beta counter and a gamma counter. The detailed micro-structure was observed by a SEM to confirm the change of the fuel morphology after this test. As the annealing temperature increased, the fission products were observed to move to the grain surface and grain boundary of the $UO_2$ matrix. This specimen was re-structured through the reduction process, and the grain sizes were distributed from 5 to $10\;{\mu}m$.

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Studies on the Ripening Characteristics, Germination Speed and Quality among Different Floret of Japonica and Tongil Type of Rice under Different Growing Season (수도재배시기별 Japonica 및 Tongil형 품종의 영화간 등숙특성 발아세 및 미질연구)

  • 권규칠;박성규
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.34 no.3
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    • pp.310-323
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    • 1989
  • This study was carried out to find out the difference of ripening and growth characteristics among the different florets in same panicle. There were 2 different transplanting date (May 25 and June 10) and 6 varieties were used. Physiological ripening period, ripening speed, 1000 grain weight, germination speed and grain quality were studied among the different florets (1, 5 and 8 days after heading) in same panicle. Physiological ripening period was long in late transplanting, late flowering floret, and late varieties by 3-9 days in Japonica. Ripening speed and 1000 grain weight were high in early transplanting and early flowering florets. There was positive correlation among the ripening speed, 1000 grain weight and a average temperature but negative correlation between the ripening and physiological ripening period. Germination speed was excellent in early flowering floret after heading. There was difference in amylose content within varieties and different flowering grains and there was significant correlation between grain quality and meteorological factors in some varieties.

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Effects of Total Mixed Fermentations with Spent Mushroom (Flammuliua velutipes) and Wet Brewer's Grain on Growth Performance, Feed Intake and Nutrient Digestibility in Korean Black Goats (버섯폐배지와 맥주박 첨가 섬유질발효사료 급여가 흑염소의 생산성, 사료섭취량 및 영양소 소화율에 미치는 영향)

  • Hwangbo, Soon
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.34 no.1
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    • pp.45-51
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    • 2014
  • This study was conducted to investigate the feeding effects of total mixed fermentations (TMF) with spent mushroom (Flammuliua velutipes) and wet brewer's grain on estimating the productivity and nutrient utilization of Korean black goats. Four experimental groups were set up with each of the 5 animals for a 30-day feeding trial on growth performance. 12 black goats with regard to nutrient digestibility were allocated to 4 groups of 3 animals each by a latin-square design control group (offered concentrate and rice straw) and 3 treatment groups (TMF with 15% spent mushroom and 25% wet brewer's grain (T1), 10, 30% (T2) and 5, 35% (T3)). The average daily gain (ADG) of the control and T1 treatment groups was higher than that of the T3 treatment group (p<0.05). Dry matter (DM) and organic matter (OM) intake (kg/head) for T1 and T2 treatment groups were significantly higher than those of the control group (p<0.05). The digestibility of DM and OM for the control group (62.39~63.39%) and the T1 treatment group (65.02~65.25%) were significantly higher than those of the T3 treatment group (56.39, 59.01%) (p<0.05). Further, nitrogen retention was significantly higher in the T1 treatment group (p<0.05). Thus, these results conveyed that productivity and nutrient utilization were similar between TMF with spent mushroom and wet brewer's grain and commercial feeds. However, this study also suggested that feed must contain 25~30% spent mushroom due to the fact that the productivity of Korean black goats was decreased by increasing the content of spent mushroom.

Effect of Difference in Soil Salinity, Compost and Additional Fertilizer on the Grain Yield and Yield Components of Wheat in the Newly Reclaimed Tidal Lands in Korea (신간척지토양에서 토양염농도, 퇴비 및 추비량 차이가 밀의 수량 및 수량구성요소에 미치는 영향)

  • Sohn, Yong-Man;Song, Jae-Do;Jeon, Geon-Yeong;Kim, Doo-Hwan;Park, Moo-Eon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.5
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    • pp.752-761
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    • 2011
  • Recently, upland crops cultivation instead of paddy crops are more popular and highlighted by increase of social demand in agricultural land use. Especially, wheat cultivation for replacing of import food grain are more interested by government, and it is urgently needed that possibility of wheat cultivation is evaluated in the reclaimed tidal land. Crop cultivation is closely related with soil salinity and cultivation method in the reclaimed tidal land. In order to evaluate possibility of wheat cultivation, effect of different application level of compost and nitrogen additional fertilizer, also soil salinity on the grain yield and yield components of three wheat cultivars was studied at the newly reclaimed Saemangeum and Hwanong tidal lands in Korea. $270-300kg\;10a^{-1}$ of grain yield were obtained at the experimental site in the Saemangeum reclaimed tidal land where soil salinity was less than $4dS\;m^{-1}$ during growing periods from December, 2009 to June, 2010. However, almost no grain yield was obtained at the experimental site in the Hwaong reclaimed tidal land, where soil salinity was more than average $8dS\;m^{-1}$ ranged from 2.0 to $25.9dS\;m^{-1}$ during growing period and then salt demage was severe. Yield was significantly different among application level of compost and nitrogen additional fertilizer in the newly reclaimed Saemangeum tidal land. However, it is considered that three cultivars such as Chopum, Chogyung and Geumgang, have similar sensibility to soil salinity and fertilizer level, because there is statistically no difference among ciltivars in Hwaong and Saemangeum, and also among cultivars in the different levels of compost and fertilizer. Finally, it is concluded that wheat can be possibly produced by reasonable fertilizer application in the Saemangeum reclaimed tidal land, but wheat cultivation is impossible because of high soil salinity in the Hwaong reclaimed tidal land.

The effect of Dy2O3 addition on crystal structure, grain growth, and dielectric properties in BaTiO3 (BaTiO3에서 Dy2O3 첨가가 결정구조, 입자성장 및 유전특성에 미치는 영향)

  • Ahn, Won-Gi;Choi, Moonhee;Kim, Minkee;Moon, Kyoung-Seok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.32 no.4
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    • pp.136-142
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    • 2022
  • The crystal structure, grain growth behavior, and dielectric properties of BaTiO3 have been studied with the addition of Dy2O3. The powders were synthesized at ratios of (100-x)BaTiO3-xDy2O3 (mol%, x = 0, 0.5, 1.0, 2.0) by a conventional solid-state synthesis, and the powder compacts were sintered at 1250℃ for 2 hours in air. As the amount of added Dy2O3 was increased, the crystal structure of the sintered samples changed from a tetragonal to a pseudo-cubic structure, and the tetragonality decreased. In addition, a secondary phase of Ba12Dy4.67Ti8O35 appeared when Dy2O3 was added. The average grain size after sintering decreased and abnormal grains appeared as the amount of Dy2O3 increased. It can be explained that the grain growth behavior of the Dy2O3 added-BaTiO3 occurs due to the two-dimensional nucleation and growth, and is governed by the interface reaction. Further, the correlation between crystal structure, microstructure, and dielectric properties was discussed.

Effects of Expander Conditioning of Corn- and Sorghum-Based Diets on Pellet Quality and Performance in Finishing Pigs and Lactating Sows

  • Johnston, S.L.;Hancock, J.D.;Hines, R.H.;Kennedy, G.A.;Traylor, S.L.;Chae, B.J.;Han, In K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.4
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    • pp.565-572
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    • 1999
  • Two experiments were conducted to determine the effects of conditioning (conventional vs expander) corn- and sorghum-based diets on production traits for lactating sows and finishing pigs. In Exp. 1, one hundred sixty-eight sows (parity 1-4, PIC line C15) were fed the corn or sorghum grain diets as a meal, standard (steam) conditioned pellets, or expanded pellets to give a $2{\times}3$ factorial arrangement of treatments. Pellet durability index (PDD was similar for the sorghum- vs corn-based diets, but increased when diets were expanded pellets for both corn- and sorghum-based diets. The corn-based meal diet supported 3.3% greater litter weight gain than the sorghum-based meal diet (44.0 kg vs 42.8 kg). However, the advantage for the corn-based diet disappeared with expander processing (ie., sows fed the sorghum-based diet responded more to diets processed with the alternative processing technology). Sow weight change during lactation was similar (p>0.15) among treatments, although average daily feed intake tended to be greater (p<0.09) for the sows fed sorghum. For Exp. 2, a total of 71 barrows (average initial weight of 58.0 kg) were used in a growth assay to determine the effects of feeding com- and sorghum-based diets, as meal or pellets, after processing with a conventional steam conditioner or an expander (high-shear) conditioner. PDI was not different for the sorghum- vs corn-based diets, but increased from 84 to 95% with expander conditioning compared to conventional steam conditioning. Rate and efficiency of gain, and carcass leanness were similar for pigs fed sorghum and corn (p>0.15). Efficiency of gain was greater (p<0.04) for pigs fed the pelleted (356 g/kg) diets compared to those given the meal (348 g/kg) diets. However, efficiencies of gain were similar (p>0.11) for pigs fed the conventional- and expander-conditioned diets. Pelleting increased (p<0.01) the incidence and severity of stomach lesions regardless of grain type. In conclusion, corn-based meal diet resulted in a greater litter weight gain than the sorghum-based meal diet. However, that advantage disappeared when the diets were expanded and pelleted. Finishing pigs fed pelleted diets were more efficient than those fed meal diets.