• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.64.2-64.2
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• 2010

In order to improve the overall power conversion efficiency in dye-sensitized solar cells (DSSCs), it is very important to secure the sufficient surface area of photocatalytic nanoparticles layer for absorbing dye molecules. It is because increasing the amount of dye absorbed generally results in increasing the amount of light harvesting. In this work, we proposed a new method for increasing the specific surface area of photocatalytic titanium oxide ($TiO_2$) nanoparticles by using an inorganic templating method. Salt-$TiO_2$ composite nanoparticles were synthesized in this approach by spray pyrolyzing both the titanium butoxide and sodium chloride solution. After aqueous removal of salt from salt-$TiO_2$ composite nanoparticles, mesoporous $TiO_2$ nanoparticles with pore size of 2~50 nm were formed and then the specific surface area of resulting porous $TiO_2$ nanoparticle was measured by Brunauer-Emmett-Teller (BET) method. Generally, commercially available P-25 with the average primary size of ~25 nm $TiO_2$ nanoparticles was used as an active layer for dye-sensitized solarcells, and the specific surface area of P-25 was found to be ~50 $m^2/g$. On the other hand, the specific surface area of mesoporous $TiO_2$ nanoparticles prepared in this approach was found to be ~286 $m^2/g$, which is 5 times higher than that of P-25. The increased specific surface area of $TiO_2$ nanoparticles will absorb relatively more dye molecules, which can increase the short curcuit current (Jsc) in DSSCs. The influence of nanoporous structures of $TiO_2$ on the performance of DSSCs will be discussed in terms of the amount of dye molecules absorbed, the fill factor, the short circuit current, and the power conversion efficiency.

• Korean Journal of Microbiology
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• v.9 no.3
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• pp.103-120
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• 1971

We have been studied on brewing sweet starch. We obtained the results as follows ; 1) 5 strains, T-T-2, T-T-4, T-K-2, T-T-18, T-T-1, were the most available in view of fermentative power by capacity of $CO_2$. 2) 5 strains, T-T-4, T-T-2, T-T-1, T-T-3, T-K-2, produced capacity of alcohol more than 5.78%. 3) 6 strains, T-T-2, T-K-2, T-T-4, T-S-2, T-I-3, T-I-1, are available not only taste and flavour, but productive power of alcohol in sweet potato starch. 4) The form of 6 strains are long oval and round and most of them are similar to the other yeast in size. 5) In giant colony the color was cream color and cream buff, and T-K-2 was formed by $15{\times}12mm$ on diameter and by 3.5mm on high. 6) Optimum temperature of most of all strains is 25~ $300^{\circ}C$but T-K-4 is 28-30.deg.C. 7) Optimum pH is 3.4-4.6. 8) T-S-2 was died off at 65.deg.C, the other strains died $60^{\circ}C$. 9( Making Bun-kok with non-heated wheat bran .alpha.-amylase was more increased by 4.5-13.5 mg of glucose in reaction solution and .betha.-amylase more 1.6-3.4ml of N/10-$KMnO_4$ Solution than Bun-kok with heated wheat bran. 10) It seems that mycellium grows better than original in substance containing 0.4 ~ 1.2% of HCl. 11) Making Bun-kok to add 0.8% HCl, .alpha.-amylase was increased 9.93-20.7mg of glucose and .betha.-amylase ws increased 2.6~4.3ml of N/10-$KMnO_4$ solution to reaction solution. 12) 1.2%-HCl, or higher concentration, acts as inhibitor, in the meanwhile the concentration between 0.4~0.8% of HCl acts as activator. 13) We must make Bun-kok for 42 hours, at 28~$30^{\circ}C$) After we made Bun-kok using S-O-II and R-J-I one by one, Bun-kok which mix each other in equal quantity is increased more than original on enzyme acrivity. 15) Oxidation is the best way of refining sweet potato starch in N/10-phosphate buffer solution (pH 7.5). 16) When we prepared sweet potato starch, first pH was 3.0.

• Journal of The Korean Society of Grassland and Forage Science
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• v.18 no.3
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• pp.243-250
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• 1998

This study was conducted to evaluate mineral content of Winter Rye, Nitrogen Balance, Soil chemical characteristics and NO,-N level in infiltration water as affected by different slurry application on the basis of N contents respectively and was arranged as a randomized complete block design with seven treatments (chemical fertilizer 160kg Nha, cattle slurry 160 . 320 - 480kg Nha, swine slurry 160 - 320 - 480kg Nha) and conducted at National Livestock Research Institute, RDA, in Suweon fiom Sep. 1996. to Apr. 1997. The results obtained are summarized as follows : Nirogen, Phosphorous, Calcium and Potassium of Winter Rye slightly increased as slurry application level was increased (p$NO_3$-N content ($\mu$g/g) of Winter Rye was shown fiom 780 to 1,462 in all treatments, especially , the swine slurry plots were significantly higher than that of cattle sluny plots (p < 0.05). As slurry application increased, show a marked trend toward surplus N input in all treatment. The pH of the topsoil (0~IOcm) was shown 6om 5.1 to 5.4 except the plot of chemical fertilizer before experiment pH of 5.1, but the pH of the subsoil (10~20cm) tended not to be regular. The content of available ,TEX>$P_2O_5$ inaeased with the increased application of slurry, particularly, the topsoil (O- 1Ocm) were much higher than the subsoil (10~20cm). The $NO_3$-N content of infiltration water (depth:lm) was increased as affected by sluny application.

• Journal of Sericultural and Entomological Science
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• v.23 no.2
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• pp.50-54
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• 1982

This investigation was conducted to know the present conditions of the the chemical components in the soils and chemical fertilizer rates applied in the Yuyu village located Sanne myun, Buan gun, Jeonbug province. Total silkworm rearing farms in this village were 54 and 47 of them were chosen at random. Average fertilizer rate applied in this village was 40.8-13.7-13.9kg/10a as N-P$_2$O$\_$5/-K$_2$O. Farmers seemed to stress too much to nitrogen fertilizer. Available P$_2$O$\_$5/ in soils was below 7ppm (by Bray No. 1 method). However, 47% of the farms applied phosphate fertilizer less than 11kg/10a. The average of exchangeable K in soils was 0.68me/100g. Nine of the farms applied potassium fertilizer more than 20kg/10a and 7 farms of them had the soils contained above 0.4me/100g as the potassium content. The average soil pH was 5.3. All of the soils were below than pH 6.5. Exchangeable Ca and Mg were 3.62 and 0.83me/100g, respectively. The average lime requirement was 269kg/10a. The average organic matter content was 2.55% and for 72% of the total farms, organic matter content was below than 3%.

• Journal of the Korean Ceramic Society
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• v.41 no.5
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• pp.381-387
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• 2004

Recently developed Plasma Display Panels (PDP) require phosphors of high luminance at Vacuum Ultraviolet (VUV) excitation. The present investigation developed new PDP phosphors using combinatorial chemistry method. We applied T $b^{3+}$ -activated yttrium gadolinium phosphates system to our combinatorial fine-tuning technique. As a result, the optimum composition was determined to be (G $d_{0.74}$ $Y_{0.11}$T $b_{0.15}$) $P_{1.15}$ $O_{\delta}$ through the two-step combinatorial screening process including excess phosphorous and Gd replacement. We found that the sample of the optimum composition shows a higher luminescence efficiency at VUV excitation and a shorter decay time than the commercially available Z $n_2$ $SiO_4$:Mn phosphor.

• The Plant Pathology Journal
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• v.27 no.3
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• pp.266-271
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• 2011

Physicochemical characteristics and heavy metal content of soils located along the drainage way of an abandoned mine at Busan, Korea ($35^{\circ}31'N$, $129^{\circ}22'E$) (contaminated soil; CS) and uncontaminated soils (50-70 m apart from the drainage way) (NS) were examined. Growth of tomato plants (Solanum lycopersicom cv. Rutgers) in CS and NS, development of the root-knot nematode (Meloidogyne incognita) as root-knot gall formation on tomato plants, and non-parasitic nematode populations in soil were also examined. Growth of tomato plants, root-knot gall formation, and non-parasitic nematode populations were significantly reduced in CS with higher As content, lower pH, higher electrical conductivity (EC), and lower available phosphate (av. $P_2O_5$) than in NS. None of the other physicochemical characters examined differed significantly between CS and NS (low and no significance) and were above or below the critical levels detrimental to plant growth and nematode development, suggesting that As may be the primary hazardous heavy metal in CS. The toxicity of As might be enhanced at low pH in CS because exchangeable forms of some heavy metals increase with the decrease of soil pH. The heavy metals, especially As, may have contributed to increasing EC and decreasing av. $P_2O_5$. Therefore, the effects of mine drainage contamination from the abandoned mine were derived primarily from contamination by heavy metals such as As. These may have been enhanced in toxicity (solubility) by the lowered pH, increased soil salinity (EC) and decreased av. $P_2O_5$. Our results suggest synergistic adverse effects on the plant and the nematode by decreasing osmotic potential and nutrient availability.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.6
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• pp.813-818
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• 2016

Distribution of clay minerals separated from clay fraction of corn fields in Korea has been investigated along with their characterization. Crystalline phases of the clay minerals were identified by powder X-ray diffraction (XRD) pattern, and their relative chemical compositions were analyzed by X-ray fluorescence spectrometry (XRF). The soils were found to have pH 6.4, organic matter $37.2g\;kg^{-1}$, available $P_2O_5$ $599mg\;kg^{-1}$, respectively, and exchangeable K, Ca and Mg were 1.2, 7.3 and $1.8cmol_c\;kg^{-1}$, respectively. Major primary minerals consisted mainly of quartz and mica, and kaolinite and chlorite were identified as major secondary clay minerals. For most of soils, mica phase was identified to be muscovite rather than biotite. The average contents of $SiO_2$, $Al_2O_3$ and $Fe_2O_3$ were 43.7, 23.6 and 8.8%, respectively, although they were different with the locations.

• Korean Journal of Soil Science and Fertilizer
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• v.34 no.2
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• pp.110-116
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• 2001

This experiment was carried out to investigate the effects of amount of nitrogen application with the barley straw application on the changes in soil physical and chemical properties. nutrient uptake and percentage recovery of chemical fertilizer N in the rice plant from 1997 to 1998. The soil physical properties, such as bulk density, hardness, porosity and gaseous phase were improved by barley straw application. There was also improvement or increment in the soil chemical properties, such as pH, organic matter, T-C. T-N, available $SiO_2$, exchangeable K and cation exchange capacity, but decrease in available $P_2O_5$. The $Fe^{+{+}}$ content in soil after barley straw application was high from tillering stage to panicle forming stage, but becoming lowered toward the heading stage, while $Mn^{+{+}}$ content was increased. N uptake with barley straw application was increased in the N $126kg\;ha^{-1}$ plot, but decreased in the N $141kg\;ha^{-1}$ plot. The uptake of fertilized N was continued longer in barley straw application than none-application plot. Percentage recovery of chemical fertilizer N in rice straw was around 1% at tillering stage, but was highly increasing till maximum tillering stage, while the recovery was generally low in barley straw application. Meanwhile, fertilizer P uptake in barley straw application was high, but potassium uptake was low at all different levels of N application.

• Journal of Sericultural and Entomological Science
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• v.34 no.2
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• pp.6-12
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• 1992

To study the effects of irrigation on the mulberry, 3 experiments were conducted. In experiment 1, four treatments, conventional (no irregation), drip irrigation, fertigation and fertigation with 20% extra fertilizer were examined. Irrigation hose was hurried at 20cm depth under the surface (Experiment 1). Water potential was controled at 0.1, 0.2, 0.5 and 1.0 bar to understand the optimum irrigation potential under rain-block system with plastic film hose(experiment 2). Five leading mulberry varieties, Cheongilppong, Youngcheonppong, Suseongppong, Kaeryangppong and Shinilppong were examined for irrigation response(experiment 3). Fertigation and fertigation with extra fefilizer increased yield by 22%, repectively compared with conventional. Irrigation increased by 8%, but with no significance statistically compared with the conventional. Irrigation, especially fertigation increased water content, P$_2$O$_{5}$, $K_2$O and CaO in leaves, suggested improving leaf quality in fall. Fertigation increased available P$_2$O$_{5}$ content in the sub-soil. More root distribution showed at the sub-soil in fertigation. Weed did not occured in fertigation due to sub-soil fertilization, whereas the conventional received surface fertilization showed 931kg/10 a weed in fresh weight. No effect showed at the 20% extra fertilizer than the conventional amount Maximun yield showed at the 0.5 bar water potential. Irrigation increased yield by 22-25% with Cheongilppong and Yongcheonppong, and by 9-13% with Suseongppong, Shinilppong and Kaeryangppong.

• Environmental Engineering Research
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• v.24 no.1
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• pp.45-53
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• 2019

Water and soil properties in paddy fields subjected to organic and conventional farming were characterized over the rice cycle in South Korea. To achieve the goals of this study, we sampled and analyzed soil and water from 24 organic paddy plots and 11 conventional paddy plots in March, May, August, and October 2016. The results were analyzed using statistical analyses, including analysis of variance (ANOVA), cluster analysis, and principal component analysis. The ANOVA results showed that water content (WC), electrical conductivity (EC), organic matter (OM), and available phosphorus ($P_2O_5$) in soil varied significantly (p < 0.01) depending on the farming method. Higher OM, EC, and $P_2O_5$ of soil were observed in the conventional paddies than in the organic paddies. All soil properties, except pH and ammonium, depended on seasonal variation. Cluster analysis revealed that soil properties in May were distinctly separated from those in other seasons mainly due to basal fertilization. The principal component analysis distinguished the soil properties in different seasons, but such a distinction was not observed between the soil properties in organic and conventional paddies. Low contents of WC, OM, and total N were observed in March. High concentrations of nitrate and total P were observed in May, but these were low in August and October. The soils from October were also characterized by high concentrations of EC and $P_2O_5$. These results indicate that the sampling time for soil and water can significantly influence the evaluation of soil properties with different farming methods.