• 제목/요약/키워드: Austenitic Alloys

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질소와 탄소가 복합 첨가된 두 오스테나이트계 Fe-18Cr-10Mn 합금의 연성-취성 천이 거동 (Ductile-to-Brittle Transition Behavior of Two Austenitic Fe-18Cr-10Mn Alloys with the Combined Addition of Nitrogen and Carbon)

  • 이승용;김보영;황병철
    • 열처리공학회지
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    • 제28권1호
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    • pp.1-6
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    • 2015
  • The ductile-to-brittle transition behavior of two austenitic Fe-18Cr-10Mn alloys with the combined addition of nitrogen and carbon was investigated in this study. The alloys exhibited a ductile-to-brittle transition behavior because of unusual brittle fracture at low temperatures unlike conventional austenitic alloys. The alloy with higher carbon content had higher yield and tensile strengths than that with lower carbon content due to the solid solution strengthening effect resulting from carbon addition. However, the increase in carbon content promoted the occurrence of intergranular fracture, and thus deteriorated the impact toughness. In order to develop successfully the austenitic Fe-18Cr-10Mn alloys with the excellent combination of strength and toughness in the future, therefore, more systematic studies are required to find the appropriate amount and ratio of nitrogen and carbon.

Distinct properties of tungsten austenitic stainless alloy as a potential nuclear engineering material

  • Salama, E.;Eissa, M.M.;Tageldin, A.S.
    • Nuclear Engineering and Technology
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    • 제51권3호
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    • pp.784-791
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    • 2019
  • In the present study, a series of tungsten austenitic stainless steel alloys have been developed by interchanging the molybdenum in standard SS316 by tungsten. This was done to minimize the long-life residual activation occurred in molybdenum and nickel after decommissioning of the power plant. The microstructure and mechanical properties of the prepared alloys are determined. For the sake of increasing multifunction property of such series of tungsten-based austenitic stainless steel alloys, gamma shielding properties were studied experimentally by means of NaI(Tl) detector and theoretically calculated by using the XCOM program. Moreover, fast neutrons macroscopic removal cross-section been calculated. The obtained combined mechanical, structural and shielding properties indicated that the modified austenitic stainless steel sample containing 1.79% tungsten and 0.64% molybdenum has preferable properties among all other investigated samples in comparison with the standard SS316. These properties nominate this new composition in several nuclear application domains such as, nuclear shielding domain.

PWR 환경에서의 오스테나이트계 합금의 환경조장균열 (Environmentally-Assisted Cracking of Austenitic Alloys in a PWR Environment)

  • 홍종대;장훈;장창희
    • 부식과 방식
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    • 제12권1호
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    • pp.30-38
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    • 2013
  • 원전의 구조적 건전성에 문제가 될 수 있는, 오스테나이트계 합금의 환경조장균열(EAC)에 대한 거동을 실험적인 결과와 문헌 조사를 통해 분석하였다. 일차측 환경에서 주기적인 반복하중을 받을 때에는 기계적인 피로균열에 더해 수소유기균열이나 동적변형시효 등으로 인한 가속화 메커니즘을 통해 피로수명 감소가 나타났다. 따라서 EAF에 대한 저항성은 전반적인 부식저항성이 우수한 니켈기합금이 스테인리스강보다 크게 나타났다. 그러나 일정한 하중을 받을 때에는 내부산화에 의해 국부적인 취약부인 입계로의 빠른 균열의 생성과 진전이 나타나 일차수 응력부식균열(PWSCC)이라는 형태로 발생한다고 여겨진다. 이때는 니켈-크롬의 비율이 내부산화 저항성에 영향을 미쳐, 비율이 낮은 스테인리스강은 높은 저항성을 가지고, 비율이 높은 니켈기합금은 낮은 저항성을 가진다. 그러나 아직 이러한 균열 메커니즘에 대한 명확한 이해가 부족하므로, 명확히 규명하기 위해서는 추가적인 연구가 필요하다.

오스테나이트계 Fe-18Cr-10Mn-N-C 합금의 연성-취성 천이 거동에 미치는 결정립 크기의 영향 (Effect of Grain Size on Ductile-Brittle Transition Behavior of Austenitic Fe-18Cr-10Mn-N-C Alloys)

  • 이상인;이승용;남승훈;황병철
    • 한국재료학회지
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    • 제25권10호
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    • pp.559-565
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    • 2015
  • The ductile-brittle transition behavior of two austenitic Fe-18Cr-10Mn-N-C alloys with different grain sizes was investigated in this study. The alloys exhibited a ductile-brittle transition behavior because of an unusual brittle fracture at low temperatures unlike conventional austenitic alloys. The alloy specimens with a smaller grain size had a higher yield and tensile strengths than those with a larger grain size due to grain refinement strengthening. However, a decrease in the grain size deteriorated the low-temperature toughness by increasing the ductile-brittle transition temperature because nitrogen or carbon could enhance the effectiveness of the grain boundaries to overcome the thermal energy. It could be explained by the temperature dependence of the yield stress based on low-temperature tensile tests. In order to improve both the strength and toughness of austenitic Fe-Cr-Mn-N-C alloys with different chemical compositions and grain sizes, more systematic studies are required to understand the effect of the grain size on the mechanical properties in relation to the temperature sensitivity of yield and fracture stresses.

준안정 오스테나이트계 Fe-18Cr-10Mn-N 합금의 연성-취성 천이 거동에 미치는 Cu와 Ni의 영향 (Influence of Cu and Ni on Ductile-Brittle Transition Behavior of Metastable Austenitic Fe-18Cr-10Mn-N Alloys)

  • 황병철
    • 한국재료학회지
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    • 제23권7호
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    • pp.385-391
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    • 2013
  • The influence of Cu and Ni on the ductile-brittle transition behavior of metastable austenitic Fe-18Cr-10Mn-N alloys with N contents below 0.5 wt.% was investigated in terms of austenite stability and microstructure. All the metastable austenitic Fe-18Cr-10Mn-N alloys exhibited a ductile-brittle transition behavior by unusual low-temperature brittle fracture, irrespective of Cu and/or Ni addition, and deformation-induced martensitic transformation occasionally occurred during Charpy impact testing at lower temperatures due to reduced austenite stability resulting from insufficient N content. The formation of deformation-induced martensite substantially increased the ductile-brittle transition temperature(DBTT) by deteriorating low-temperature toughness because the martensite was more brittle than the parent austenite phase beyond the energy absorbed during transformation, and its volume fraction was too small. On the other hand, the Cu addition to the metastable austenitic Fe-18Cr-10Mn-N alloy increased DBTT because the presence of ${\delta}$-ferrite had a negative effect on low-temperature toughness. However, the combined addition of Cu and Ni to the metastable austenitic Fe-18Cr-10Mn-N alloy decreased DBTT, compared to the sole addtion of Ni or Cu. This could be explained by the fact that the combined addition of Cu and Ni largely enhanced austenite stability, and suppressed the formation of deformation-induced martensite and ${\delta}$-ferrite in conjunction with the beneficial effect of Cu which may increase stacking fault energy, so that it allows cross-slip to occur and thus reduces the planarity of the deformation mechanism.

오스테나이트계 Fe-18Cr-10Mn-2Ni 합금의 연성-취성 천이 거동에 미치는 침입형 원소의 영향 (Effect of Interstitial Elements on Ductile-Brittle Transition Behavior of Austenitic Fe-18Cr-10Mn-2Ni Alloys)

  • 황병철
    • 한국재료학회지
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    • 제23권11호
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    • pp.649-654
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    • 2013
  • The effect of interstitial elements on the ductile-brittle transition behavior of austenitic Fe-18Cr-10Mn-2Ni alloys with different nitrogen and carbon contents was investigated in this study. All the alloys exhibited ductile-brittle transition behavior because of unusual low-temperature brittle fracture, even though they have a faced-centered cubic structure. With the same interstitial content, the combined addition of nitrogen and carbon, compared to the sole addition of nitrogen, improved the low-temperature toughness and thus decreased the ductile-brittle transition temperature (DBTT) because this combined addition effectively enhances the metallic component of the interatomic bonds and is accompanied by good plasticity and toughness due to the increased free electron concentration. The increase in carbon content or of the carbon-to-nitrogen ratio, however, could increase the DBTT since either of these causes the occurrence of intergranular fracture that lead to the deterioration of the toughness at low temperatures. The secondary ion mass spectroscopy analysis results for the observation of carbon and nitrogen distributions confirms that the carbon and nitrogen atoms were significantly segregated to the austenite grain boundaries and then caused grain boundary embrittlement. In order to successfully develop austenitic Fe-Cr-Mn alloys for low-temperature application, therefore, more systematic study is required to determine the optimum content and ratio of carbon and nitrogen in terms of free electron concentration and grain boundary embrittlement.

Ni-Cr-Fe 및 Ni-Fe-Cr-Mo계 합금의 용접부 균열특성에 관한 연구 Part II : 열영향부의 액화균열 (A Study on the Cracking Behavior in the Welds of Ni-Cr-Fe and Ni-Fe-Cr-Mo Alloys)

  • 김희봉;이창희
    • Journal of Welding and Joining
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    • 제15권5호
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    • pp.46-55
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    • 1997
  • This study has evaluated the liquation cracking behavior in the heat affected zone of several Ni base superalloys (Incoloy 825, Inconel 718 and Inconel 600). 304 and 310S austenitic stainless steels were also included for comparison. In addition, the mechanism of liquation cracking in the HAZ was postulated based on the extensive microstructural examinations with SEM, EDAX and TEM. The liquation cracking resistance of Ni base alloys was found to be far inferior to that of austenitic stainless steels. The liquation cracking of Incoloy 825 and Inconel 718 was believed to be closely related with the Laves-austenite(Ti rich in 825 and Nb rich in 718) and MC-austenitic eutectic phases formed along the grain boundaries by constitutional liquation and incipient melting under rapid welding thermal contraction. Further, liquation cracking resistance of the HAZ was dependent not only upon the type and amount of low melting phases but also on the grain size.

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오스테나이트계 스테인리스강 용접부의 금속학적 현상에 관한 연구(I) - 시판 오스테나이트계 스테인리스강의 용접성 - (A Study of Metallurgical Phenomena in Austenitic Stainless Steel Fusion Welds (I) -Weldability of Commercial Austenitic Stainless Steels-)

  • 이종섭;김숙환
    • Journal of Welding and Joining
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    • 제16권3호
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    • pp.111-120
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    • 1998
  • To predict and evaluate metallurgical and mechanical behavior of th welds, it is essential to understand solidification behavior and microstructural evolution experienced in the welds, neither of which follows the equilibrium phase diagram because of rapid heating and cooling conditions. Metallurgical phenomena in austenitic stainless steel fusion welds, types 304, 309S, 316L, 321 and 304N, were investigated in this study. Autogenous GTA welding was performed on weld coupons, and primary solidification mode and phase distribution were investigated from the welds. Varestraint test was employed to evaluate solidification cracking susceptibilities of the alloys. GTA weld fusion zones in type 304, 321 and 304N stainless steels experienced primary ferrite solidification while those in type 309S primary austenite solidification. Type 316L exhibited a mixed type of primary ferrite and primary austenite solidification. The primary solidification mode strongly depended on $Cr_{eq}/Ni_{eq}$ ratio. In terms of solidification cracking susceptibility, type 309S that solidified as primary austenite exhibited high cracking susceptibility while the alloys experienced primary ferrite solidification showed low cracking susceptibility. The relative ranking in solidification cracking susceptibility was type 304=type 304N < type 321 < type 316L < type 309S.

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오스테나이트계 스텐리스 강의 물성에 미치는 초정응고 형식의 영향 (The Effect of Primary Solidification Mode on Physical Properties of Austenitic Stainless Steels)

  • 정호신
    • 수산해양기술연구
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    • 제26권4호
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    • pp.372-379
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    • 1990
  • The effect of primary solidification phase on the solidification cracking sensitivity, corrosion resistance and toughness at cryogenic temperature was investigated for the austenitic stainless steel welds. The conclusions were summarized as follows; 1. Soldification crack sensitivity of austenitic stainless steel welds depends on the primary solidification mode. 2. Austenitic stainless steels were very susceptible to solidification cracking in case of solidification as primary ${\gamma}$ and immune when solidified as primary $\delta$. 3. When the ratio of Creq/Nieq is in the range of 1.46 to 1.55, the most resistance against solidification cracking was obtained. These results agreed well with the relationship between primary solidification mode, corrosion resistance and toughness at cryogenic temperature. 4. Optimum toughness, corrosion and solidification cracking resistance can be obtained when alloys having chemical compositions described above and solidifies as primary $\delta$ containing no ferrite at room temperature.

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고질소 오스테나이트계 스테인리스강의 인장물성에 미치는 변형속도의 영향 (Strain-rate Effect on Tensile Properties of High-nitrogen Austenitic Stainless Steel)

  • 이승한;김동욱;김양곤;강지현
    • 소성∙가공
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    • 제33권5호
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    • pp.322-329
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    • 2024
  • Because a high strain rate suppresses cross slip and delays dynamic recovery in the alloys with a face-centered cubic (FCC) structure, it is generally accepted that the influence of strain rate on strain hardening rate and tensile strength is greater than that on the yield strength of FCC alloys. The present study examined the tensile behavior of an austenitic stainless steel exhibiting an FCC structure, and revealed that the increment in yield strength was greater than that in tensile strength as the strain rate increased from 5.21×10-5s-1 to 4.17×10-1s-1. This indicated that the strain hardening rate was reduced by increasing the strain rate, which was inconsistent with the conventional explanation. Adiabatic heating was detected at high strain rates from 5.21×10-5s-1, and the resulting temperature increase could elevate stacking fault energy. The tendency for sip planarity was investigated by applying the Ludwigson model to the tensile curves, which suggested that higher stacking fault energy due to adiabatic heating could accelerate cross slip and dynamic recovery, thereby reducing the strain hardening rate.