• Title/Summary/Keyword: Atomic weight

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Dissolution Characteristics of Copper Oxide in Gas-liquid Hybrid Atmospheric Pressure Plasma Reactor Using Organic Acid Solution

  • Kwon, Heoung Su;Lee, Won Gyu
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.229-233
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    • 2022
  • In this study, a gas-liquid hybrid atmospheric pressure plasma reactor of the dielectric barrier discharge method was fabricated and characterized. The solubility of copper oxide in the organic acid solution was increased when argon having a larger atomic weight than helium was used during plasma discharge. There was no significant effect of mixing organic acid solutions under plasma discharge treatment on the variation of copper oxide's solubility. As the applied voltage for plasma discharge and the concentration of the organic acid solution increased, the dissolution and removal power of the copper oxide layer increased. Solubility of copper oxide was more affected by the concentration in organic acid solution rather than the variation of plasma applied voltage. The usefulness of hybrid plasma reactor for the surface cleaning process was confirmed.

Elemental analysis of rice using laser-ablation sampling: Determination of rice-polishing degree

  • Yonghoon Lee
    • Analytical Science and Technology
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    • v.37 no.1
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    • pp.12-24
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    • 2024
  • In this study, laser-induced breakdown spectroscopy (LIBS) was used to estimate the degree of rice polishing. As-threshed rice seeds were dehusked and polished for different times, and the resulting grains were analyzed using LIBS. Various atomic, ionic, and molecular emissions were identified in the LIBS spectra. Their correlation with the amount of polished-off matter was investigated. Na I and Rb I emission line intensities showed linear sensitivity in the widest range of polished-off-matter amount. Thus, univariate models based on those lines were developed to predict the weight percent of polished-off matter and showed 3-5 % accuracy performances. Partial least squares-regression (PLS-R) was also applied to develop a multivariate model using Si I, Mg I, Ca I, Na I, K I, and Rb I emission lines. It outperformed the univariate models in prediction accuracy (2 %). Our results suggest that LIBS can be a reliable tool for authenticating the degree of rice polishing, which is closed related to nutrition, shelf life, appearance, and commercial value of rice products.

Study on the Application of Soft Magnetic Material for Effective Neutron Shielding (효과적인 중성자 차폐를 위한 경량 연자성 물질 활용방안 연구)

  • Yeongchan Kim;Changwoo Kang
    • Journal of Radiation Industry
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    • v.17 no.1
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    • pp.93-100
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    • 2023
  • This study analyzes the neutron shielding performance of Soft Magnetic Material and proposes a military application. In general, the military protection facility has been constructed with thick concrete, so Soft Magnetic Material, consisting of boron, was used with concrete in this study. To do so, Monte-Carlo N-Particle (MCNP) was applied to simulate the Watt-fission neutron spectrum of 235U and 239Pu. As a result, a configuration of polyethylene and Soft Magnetic Material is evaluated about four times better than borated polyethylene concerning the atomic weight of boron inside each shielding material. Also, when a nuclear weapon explosion is simulated in MCNP, 1 mm of Soft Magnetic Material with 20 cm of concrete shows about 55% more additional neutron shielding performance compared to when Soft Magnetic Material is not used. In this work, the neutron shielding performance of Soft Magnetic Material could be identified and Soft Magnetic Material would be useful for neutron shielding if applicable to concrete structure.

Adsorption Removal of Sr by Barium Impregnated 4A Zeolite (BaA) From High Radioactive Seawater Waste (Barium이 함침된 4A 제올라이트 (BaA)에 의한 고방사성해수폐액에서 Sr의 흡착 제거)

  • Lee, Eil-Hee;Lee, Keun-Young;Kim, Kwang-Wook;Kim, Ik-Soo;Chung, Dong-Yong;Moon, Jei-Kwon;Choi, Jong-Won
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.14 no.2
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    • pp.101-112
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    • 2016
  • This study investigated the removal of Sr, which was one of the high radioactive nuclides, by adsorption with Barium (Ba) impregnated 4A zeolite (BaA) from high-radioactive seawater waste (HSW). Adsorption of Sr by BaA (BaA-Sr), in the impregnated Ba concentration of above 20.2wt%, was decreased by increasing the impregnated Ba concentration, and the impregnated Ba concentration was suitable at 20.2wt%. The BaA-Sr adsorption was added to the co-precipitation of Sr with $BaSO_4$ precipitation in the adsorption of Sr by 4A (4A-Sr) within BaA. Thus, it was possible to remove Sr more than 99% at m/V (adsorbent weight/solution volume)=5 g/L for BaA and m/V >20 g/L for 4A, respectively, in the Sr concentration of less than 0.2 mg/L (actual concentration level of Sr in HSW). It shows that BaA-Sr adsorption is better than 4A-Sr adsorption in for the removal capacity of Sr per unit gram of adsorbent, and the reduction of the secondary solid waste generation (spent adsorbent etc.). Also, BaA-Sr adsorption was more excellent removal capacity of Sr in the seawater waste than distilled water. Therefore, it seems to be effective for the direct removal of Sr from HSW. On the other hand, the adsorption of Cs by BaA (BaA-Cs) was mainly performed by 4A within BaA. Accordingly, it seems to be little effect of impregnated Ba into BaA. Meanwhile, BaA-Sr adsorption kinetics could be expressed the pseudo-second order rate equation. By increasing the initial Sr concentrations and the ratios of V/m, the adsorption rate constants ($k_2$) were decreased, but the equilibrium adsorption capacities ($q_e$) were increasing. However, with increasing the temperature of solution, $k_2$ was conversely increased, and $q_e$ was decreased. The activation energy of BaA-Sr adsorption was 38 kJ/mol. Thus, the chemical adsorption seems to be dominant rather than physical adsorption, although it is not a chemisorption with strong bonding form.

Stiffness Analysis of Spring Mechanism for Semi-Automatic Gripper Motion of Tendon-Driven Remote Manipulator (와이어 구동방식 원격조작기용 그리퍼의 반자동 파지 및 해제 동작을 위한 스프링 강성 분석)

  • Yu, Seung-Nam;Lee, Jong-Kwang
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.11
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    • pp.1405-1411
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    • 2012
  • Remote handling manipulators are widely used for performing hazardous tasks, and it is essential to ensure the reliable performance of such systems. Toward this end, tendon-driven mechanisms are adopted in such systems to reduce the weight of the distal parts of the manipulator while maintaining the handling performance. In this study, several approaches for the design of a gripper system for a tendon-driven remote handling system are introduced. Basically, this gripper has an underactuated spring mechanism that is combined with a slave manipulator triggered by a master operator. Based on the requirements under the specified tendon-driven mechanism, the connecting position of the spring system on the gripper mechanism and kinematic influence coefficient (KIC) analysis are performed. As a result, a suitable combination of components for the proper design of the target system is presented and verified.

Studies on the Formation of Pyrophosphate-$^{99m}T_c$ complex

  • Kim, Jae-Rok;Awh, Ok-Doo
    • Nuclear Engineering and Technology
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    • v.12 no.1
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    • pp.19-28
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    • 1980
  • An instant labelling technique for lyophilized pyrophosphate with $^{99m}$Tc is described labelling yield of about 90% is obtained at the pH range 3.5-5.5 on reconstitution with sodium pertechnetate-$^{99m}$ Tc solution. The final product is controlled by a modified two dimensional paper chromatography using 85% methanol and 0.85% saline, and biodynamic investigations are performed on white mice. Generally, the less amount of stannous chloride is used. the higher labelling yield is obtained. The molar ratio of pyrophosphate to stannous chloride of 10 : 1 ~ 50 : 1 is sufficient. The more amount of reduced unbound $^{99m}$Tc is injected, the more radioactivity is incorporated in the liver. Thus. the cause of the false bone-imaging is attributable to the presence of reduced unbound $^{99m}$Tc which is known to be well adsorbed to oxidized tin colloidals. The maximum uptake ratio of bone: liver in mice, in weight basis, 35 : 1 is achieved in lime of 60 min. or so. Tile preparation is suitable for clinical investigations on patients with bone diseases.iseases.

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Effects of Ionizing Radiation on Sprout Inhibition and Nutritive Value of Potato Tubers (방사선(放射線) 조사(照射)가 감자 괴경(塊莖)의 맹아억제(萌芽抑制) 및 영양가(營養價)에 미치는 영향(影響))

  • Lee, Mie-Soon;Kim, Hong-Lyour
    • Korean Journal of Food Science and Technology
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    • v.4 no.1
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    • pp.29-35
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    • 1972
  • Effects of various dosages of gamma ray ranging from 0 to 16 krad on sprout inhibition and nutritive value of potato tubers were investigated with Irish Cobbler variety. Sprout growth was gradually suppressed with increasing dosage, and completely inhibited with 16 krad treatment. Under this optimum dosage, weight loss of tubers was markedly reduced and tubers kept firm throughout the 2 month storage period. Irradiation had no adverse effects on the cooking quality of potato tubers. Moisture content of stored potato tubers was shown to be in inverse proportion to sprout growth. Tubers treated with 16 krad tended to contain somewhat higher percentage of total carbohydrate than those treated with lower dosages. Significantly larger amounts of ascorbic acid were retained in 8 and 16 krad treatments than in 0 and 2 krad treatments.

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Heat Treatment Effect on Super Duplex Stainless Steel UNS S32750 FCA Multipass Welds (슈퍼 듀플렉스 스테인리스강 UNS S32750의 FCA 다층 용접부의 용접 후 열처리 영향)

  • Jang, Bok-Su;Moon, In-June;Lim, Myung-Jin;Kim, Se-Cheol;Kim, Soo-Sung;Lee, Jung-Won;Park, Hai-Woong;Koh, Jin-Hyun
    • Journal of Welding and Joining
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    • v.32 no.2
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    • pp.48-53
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    • 2014
  • This study was carried out to investigate the effect of postweld heat treatment(PWHT, 930, 1080, $1230^{\circ}C$) on the microstructure, phase formation, pitting corrosion and mechanical properties such as hardness, tensile strength and impact values of super duplex stainless steel(UNS S32750) multipass welds. Based on the microstructural examination and X-ray diffraction analysis, it was found that the ${\sigma}$ phase was formed in the welds heat treated at $930^{\circ}C$ in which the ferrite content greatly decreased into 5~10% in the welds. The secondary austenite was formed in the reheated zone of welds and redissolved into ferrite with increasing heat treatment temperatures. The tensile strength and impact values of welds heat treated at $930^{\circ}C$ were the lowest and revealed the brittle fracture surface. The weight loss by pitting corrosion increased with test temperatures. It was confirmed that pitting corrosion occurred mainly in secondary austenite of reheated zones. The postweld heat treatment temperature is recommended to be in the range of $1050{\sim}1150^{\circ}C$.

The Study for the Fast Detection of the Stereo Radiation Detector using the Image Processing (영상처리기반 스테레오 감마선 탐지장치의 고속탐지에 관한 연구)

  • Hwang, Young-gwan;Lee, Nam-ho
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2015.10a
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    • pp.1103-1105
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    • 2015
  • Leaked Radioactive source in nuclear power station, radiation related facilities and the aging nuclear power plant for the dismantling must need to detect and remove early to prevent major accidents. In this paper, we implemented a single sensor-based gamma-ray detectors stereo which can provide the distance to the radiation source, a direction and doserate information for fast and efficient decontamination work the radiation source. And we have carried out an algorithm development for high-speed detection of the detection equipment. Two detectors are required for stereo structure for obtaining the distance information of the radioactive source, but we designed the only sensor-based detection device for the weight reduction. We have extracted the region of interest and obtained the distance calculation result and distribution of radiation source in order to minimize a stereo image acquisition time. Detection time of the algorithm showed a shorter time of about 41%.

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Development of A Computer Program for Drop Time and Impact Velocity of the Rod Cluster Control Assembly (제어봉집합체의 낙하시간과 충격속도 계산을 위한 프로그램 개발)

  • Park, Ki-Seong;Kim, Il-Kon
    • Nuclear Engineering and Technology
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    • v.26 no.2
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    • pp.197-204
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    • 1994
  • In a PWR rod cluster control assembly(RCCA) for shutdown is released upon action of control rod drive mechanism and falls down through the guide thimble by its weight. Drop time and impact velocity of the RCCA are two key parameters with respect to reactivity insertion time and the mechanical integrity of fuel assembly. Therefore, the precise control of drop time and impact velocity is prerequisite to modifying the existing design features of the RCCA and guide thimble or newly designing them. During its falling down into the core, the RCCA is retarded by various forces acting on it such as fluid resistance caused by the RCCA movement, buoyance and mechanical friction caused by contacting inner surface of the guide thimble, etc. However, complicated coupling of the various forces makes it difficult to derive an analytical dynamic equation for the drop time and impact velocity. This paper deals with the development of a computer program containing an analytical dynamic equation applicable to the Korean Fuel Assembly(KOFA). The computer program is benchmarked with an available single control rod drop tests. Since the predicted values are in good agreement with the test results, the computer program developed in this paper can be employed to modify the exiting design features of the RCCA and guide thimble and to develope their new design features for advanced nuclear reactors.

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