• Title/Summary/Keyword: Atomic weight

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Assessment of Radiation Degradation of Insulating Materials using Thermogravimetry Analysis (열중량 분석에 의한 유기절연재료의 방사선 열화 평가)

  • Kim, K.Y.;Ryu, B.H.;Lee, C.;Lim, K.J.
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1537-1539
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    • 2001
  • The radiation degradation of five insulating materials such as silicone rubber, ethylene-propylene rubber polybutylene terephthalte, poly carbonate, nylon 66 were evaluated by using thermogravimetry analysis (TGA) and tensile properties as a function of radiation doses. The results of temperature at 5% weight loss and activation energy from TGA showed linearly decreasing and increasing tendency as radiation doses comparing with tensile properties. Consequently, the assessment of TGA for the radiation degradation of materials was effective.

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Electrochemical Degradation of Benzoquinone in a Flow through Cell with Carbon Fibers

  • Yoon, Jang-Hee;Yang, Jee-Eun;Shim, Yoon-Bo;Won, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.403-407
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    • 2007
  • The anodic degradation of benzoquinone(BQ), a model compound for wastewater treatment was carried out using a home-made flow-through electrochemical cell with carbon fibers. To optimize the controlled current electrolysis condition of an aqueous BQ solution, the experimental variables affecting the degradation of BQ, such as the applying current, pH, reaction time, and flow rate of the BQ solution were examined. The degradation products of the oxidation reaction were identified by High Performance Liquid Chromatography and Inductively Coupled Plasma Atomic Emission Spectrometer. Low molecular weight aliphatic acids, and CO2 were the major products in this experiment. The removal efficiency of BQ from the solution increased with the applying current and time. 99.23% of 1.0 × 10-2 M BQ was degraded to aliphatic acids and CO2 when the applying current is 175 mA in a 12 hr electrolysis.

Purification and Glycosylation Pattern of Human L-Ferritin in Pichia pastoris

  • Lee, Jong-Lim;Yang, Seung-Nam;Park, Cheon-Seok;Jeoung, Doo-Il;Kim, Hae-Yeong
    • Journal of Microbiology and Biotechnology
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    • v.14 no.1
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    • pp.68-73
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    • 2004
  • Ferritin is an iron storage protein found in most living organisms. For expression and industrial use, human light chain ferritin (L-ferritin) was cloned from human liver cDNA library and expressed in Pichia pastoris strain GS115. The recombinant L-ferritin in Pichia pastoris was glycosylated. In a fed-batch culture, the cell mass reached about 57 g/l of dry cell weight, and the L-ferritin in the cell was increased to about 95 mg/l after 150 h. In an atomic absorption spectrometry analysis, the intracellular content of iron in the L-ferritin transformant was measured as $1,694{\pm}85\;\mu\textrm{g}g/g$, which is 5.4-fold more than that of the control strain. This L-ferritin transformant could serve as iron-fortified nutrients in animal feed stock.

Adsorption Study on the Radioactive Liquids by Korean Vermiculite (한국산(韓國産) Vermiculite에 의(依)한 방사성동위원소(放射性同位元素) 흡착연구(吸着硏究))

  • Moon, Suc-Hyong
    • The Korean Journal of Nuclear Medicine
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    • v.7 no.1
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    • pp.51-54
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    • 1973
  • The use of ion-exchange resins for the treatment of radioactive wastes has many advantages, but thes eare rather expensive as compared with the Korean vermiculite. The Korean vermiculite has slightly different chemical constituents from the ones produced in other countries, and its physical properties might be applicable to the management of radioactive waste, in a small nuclear installation. The decontaminating effect of Korean vermiculite for the low-level radioactive liquid was investigated. $^{106}Ru,\;^{90}Sr,\;and\;^{137}Cs$ were utilized for the experiments. The removal rates by Korean vermiculite were calculated for $^{106}Ru,\;^{90}Sr\;and\;^{137}Cs$ and the removal rates increased as the weight of vermiculite in the exchange column increased. The decontaminating constants, $K_d$ of the Korean vermiculite for $^{106}Ru,\;^{90}Sr\;and\;^{137}Cs$ were 2.7, 69.3 and 263ml/g respectively. Through the results of experiments, the application of Korean vermiculite column to the treatment of low-level radioactive waste is quite feasible.

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Radiation Crosslinking and Shrinkable Properties of PVC (PVC의 방사선 가교와 열수축 특성)

  • Nho, Young Chang
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.341-348
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    • 1992
  • PVC was compounded with various crosslinking agents, plasticizers and acrylonitrile butadiene rubber(NBR) to evaluate their effects on the radiation gel percent, elongation at break, heat distortion and heat shrinkage. Gel yield of PVC increased with increasing unsaturation levels per molecular weight of crosslinking agents while PVC containing NBR was more sensitive to crosslinking than PVC itself regardless of the types of crosslinking agents and plasticizers. It was found that gel percent was increased with increasing radiation dose, while heat distortion was decreased with increasing gel percent. Heat shrinkage was increased with decreasing stretching temperature and increasing annealing temperature.

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A Concept of Buoyant Hybrid Power Generation System by using Solar Cell Modules and Power Generator in the Sea (태양전지 모듈 및 발전기를 사용한 해상 태양광-풍력 복합발전시스템 개념)

  • Cha, Kyung-Ho;Cha, Min-Jae;Lee, Hee-Sei
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.91-93
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    • 2008
  • A Buoyant Hybrid Power Generation System (BHPGS) described in this paper, is a conceptual approach to a hybrid solar-wind power generation in the near sea. The primary purpose of the BHPGS is given to improve utilization of solar cell modules. Main components of the BHPGS include a solar cell module, buoyant object, power generator, and support assembly including weight. Components such a generator controller, DC/AC converter, etc., are not configured in the current BHPGS because they can easily be purchased as a commercial-off-the-shelf product. In addition, some of the BHPGS applications are discussed.

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Characterization of Inorganic Chemicals in Total Suspended Particulates and a Source Apportionment by Chemical Mass Balance Model (대기 분진의 무기 화학적 조성 분석과 Chemical Mass Balance에 의한 오염원 기여도 산출)

  • Seo, Young-Hwa;Koo, Ja-Kong
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.2
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    • pp.112-120
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    • 1992
  • Twenty four metal, nonmetal elements and 4 major anions in total suspended particulates (TSP) collected at two sites in Daejon city from october to december in 1991 by a Hi-vol sampler were thoroughly analyzed by Inductively Coupled Plasma/ Atomic Emission Spectrometry (ICP/AES) and Ion Chromatography (IC). These analyzed data were used to perform a receptor modeling using the Chemical Mass Balance (CMB) for the source apportionment of TSP sample. Approximately 60% TSP weight in industrial complex area was influenced by potential industrial sources and 25% was by heating fuels and automobile emissions, whereas a half of TSP in residential area was influenced by surrounding environment and more than 35% of TSP was influenced by heating fuels. The CMB model provided source apportionment results reasonably and scientifically with a minor limitation.

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Development Trend of Magnesium Casting Technology (마그네슘 주조성형기술의 개발동향)

  • Kim, Hyun-Sik;Ye, Dea-Hee;Kang, Min-Cheol
    • Journal of Korea Foundry Society
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    • v.31 no.5
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    • pp.243-248
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    • 2011
  • Magnesium alloys have many advantages such as light-weight, high machinability, damping capacity, etc. So magnesium alloy parts have been used in transportation, mobile phone, military industries. Because of HCP atomic structure, Magnesium is very difficult in plastic deformation process, so most of magnesium products are fabricated by casting process. Magnesium alloys have low heat-capacity, high fluidity and low Fe solubility. For these reasons it is more suitable than aluminum in mass-production by casting. And various casting technologies have been developed. So casting technologies for magnesium developed recently is discussed in this paper.

Preparation of $Al_2O_3$.$2SiO_2$ glass by the sol-gel process (졸-겔법에 의한 $Al_2O_3$.$2SiO_2$ 유리의 제조)

  • Rhee, Jhun;Chi, Ung-Up;Jo, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.20 no.1
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    • pp.3-12
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    • 1983
  • In the present study an attempt was made to synthesize the $Al_2O_3$.$2SiO_2$ glass in which atomic ratio is Al:Si=1:1 by sol-gel process. And at such a low temperature as 55$0^{\circ}C$ clear amorphous gel derived glass with Si-O-Al bonding was obtained. $Si(OC_2H_5)_4$ and $Al(NO_3)_3$.$9H_2O$ were used as the precursor and among the mutual solvents only n-butanol gave good results for the synthesis of the gel derived glass. Partial hydrolysis of TEOS with one-fold mol of $H_2O$ prior to the reaction with aluminum nitrate gave the better results., Total oxide content to the total reactants by weight was affective to the results.

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Preparation and Characterization of Spherical Silica-coated Ceria Nanoparticles by Sol-Gel Method

  • Ahn, Yang-Kyu;Jeoung, Hae-Chan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.96-96
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    • 2010
  • Monodispersed spherical silica-coated ceria nanoparticles were prepared through a sol-gel process using tetraethylorthosilicate (TEOS) and ceria fine particles. In this process, ceria fine particles were also prepared from cerium nitrate. The mean size of ceria particles was 300nm. Silica nanoparticles with narrow particle size distribution were prepared by controlled hydrolysis of TEOS solution. The silica sols were obtained by peptization, the process of redispersing a coagulated colloid, and were coated on ceria particles by the control of the weight ratio of silica/ceria and the pH of the mixture in aqueous solution. The morphologies of particles were characterized with scaning electron microscopy(SEM), transmission electron microscopy(TEM) and atomic force microscopy(AFM). The coating thickness of silica particles obtained by using this method was controlled in the range of 30 - 70nm.

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