• Title/Summary/Keyword: Atomic parameters

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Development of the 'Three-stage' Bayesian procedure and a reliability data processing code (3단계 베이지안 처리절차 및 신뢰도 자료 처리 코드 개발)

  • 임태진
    • Korean Management Science Review
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    • v.11 no.2
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    • pp.1-27
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    • 1994
  • A reliability data processing MPRDP (Multi-Purpose Reliability Data Processor) has been developed in FORTRAN language since Jan. 1992 at KAERI (Korean Atomic Energy Research Institute). The purpose of the research is to construct a reliability database(plant-specific as well as generic) by processing various kinds of reliability data in most objective and systematic fashion. To account for generic estimates in various compendia as well as generic plants' operating experience, we developed a 'three-stage' Bayesian procedure[1] by logically combining the 'two-stage' procedure[2] and the idea for processing generic estimates[3]. The first stage manipulates generic plant data to determine a set of estimates for generic parameters,e.g. the mean and the error factor, which accordingly defines a generic failure rate distribution. Then the second stage combines these estimates with the other ones proposed by various generic compendia (we call these generic book type data). This stage adopts another Bayesian procedure to determine the final generic failure rate distribution which is to be used as a priori distribution in the third stage. Then the third stage updates the generic distribution by plant-specific data resulting in a posterior failure rate distribution. Both running failure and demand failure data can be handled in this code. In accordance with the growing needs for a consistent and well-structured reliability database, we constructed a generic reliability database by the MPRDP code[4]. About 30 generic data sources were reviewed and available data were collected and screened from them. We processed reliability data for about 100 safety related components frequently modeled in PSA. The underlying distribution for the failure rate was assumed to be lognormal or gamma, according to the PSA convention. The dependencies among the generic sources were not considered at this time. This problem will be approached in further study.

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Phase sequence in Codeposition and Solid State Reaction of Co-Si System and Low Temperature Epitaxial Growth of $CoSi_2$ Layer (Co-Si계의 동시증착과 고상반응시 상전이 및 $CoSi_2$ 층의 저온정합성장)

  • 박상욱;심재엽;지응준;최정동;곽준섭;백홍구
    • Journal of the Korean Vacuum Society
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    • v.2 no.4
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    • pp.439-454
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    • 1993
  • The phase sequence of codeposited Co-Si alloy and Co/si multilayer thin film was investigated by differential scanning calormetry(DSC) and X-ray diffraction (XRD) analysis, The phase sequence in codeposition and codeposited amorphous Co-Si alloy thin film were CoSilongrightarrow Co2Si and those in Co/Si multilayer thin film were CoSilongrightarrowCo2Silongrightarrow and CoSilongrightarrowCo2Si longrightarrowCoSilongrightarrowCoSi2 with the atomic concentration ration of Co to Si layer being 2:1 and 1:2 respectively. The observed phase sequence was analyzed by the effectvie heat of formatin . The phase determining factor (PDF) considering structural facotr in addition to the effectvie heat of formation was used to explain the difference in the first crystalline phase between codeposition, codeposited amorphous Co-Si alloy thin film and Co/Si multilayer thin film. The crystallinity of Co-silicide deposited by multitarget bias cosputter deposition (MBCD) wasinvestigated as a funcion of deposition temperature and substrate bias voltage by transmission electron microscopy (TEM) and epitaxial CoSi2 layer was grown at $200^{\circ}C$ . Parameters, Ear, $\alpha$(As), were calculate dto quantitatively explain the low temperature epitaxial grpwth of CoSi2 layer. The phase sequence and crystallinity had a stronger dependence on the substrate bias voltage than on the deposition temperature due to the collisional daxcade mixing, in-situ cleannin g, and increase in the number of nucleation sites by ion bombardment of growing surface.

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Emission Characteristics of Elemental Constituents in Fine Particulate Matter Using a Semi-continuous Measurement System (준 실시간 측정시스템을 이용한 미세입자 원소성분 배출특성 조사)

  • Park, Seung-Shik;Ondov, John M.
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.2
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    • pp.190-201
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    • 2010
  • Fine particulate matter < $1.8{\mu}m$ was collected as a slurry using the Semicontinuous Elements in Aerosol Sampler with time resolution of 30-min between May 23 and 27, 2002 at the Sydney Supersite, Florida, USA. Concentrations of 11 elements, i.e., Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn, in the collected slurry samples were determined off-line by simultaneous multi-element graphite furnace atomic absorption spectrometry. Temporal profiles of $SO_2$ and elemental concentrations combined with meteorological parameters such as wind direction and wind speed indicate that some transient events in their concentrations are highly correlated with the periods when the plume from an animal feed supplement processing facility influenced the Sydney sampling site. The peaking concentrations of the elemental species during the transient events varied clearly as the plume intensity varied, but the relative concentrations for As, Cr, Pb, and Zn with respect to Cd showed almost consistent values. During the transient events, metal concentrations increased by factors of >10~100 due to the influence of consistent plumes from an individual stationary source. Also the multi-variate air dispersion receptor model, which was previously developed by Park et al. (2005), was applied to ambient $SO_2$ and 8 elements (Al, As, Cd, Cr, Cu, Fe, Pb, and Zn) measurements between 20:00 May 23 and 09:30 May 24 when winds blew from between 70 and $85^{\circ}$, in which animal feed processing plant is situated, to determine emission and ambient source contributions rates of $SO_2$ and elements from one animal feed processing plant. Agreement between observed and predicted $SO_2$ concentrations was excellent (R of 0.99; and their ratio, $1.09{\pm}0.35$) when one emission source was used in the model. Average ratios of observed and predicted concentrations for As, Cd, Cr, Pb, and Zn varied from $0.83{\pm}0.26$ for Pb to $1.12{\pm}0.53$ for Cd.

A Study on the Phase Transformations of (TiAl)N Films Deposited by TFT Sputtering System (TFT(Two-Facing-Targets) 스퍼터장치에 의해 증착된 (TiAl)N 박막의 상변태에 관한 연구)

  • Han, Chang-Suk
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.5
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    • pp.281-287
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    • 2005
  • Titanium aluminium nitride((TiAl)N) film is anticipated as an advanced coating film with wear resistance used for drills, bites etc. and with corrosion resistance at a high temperature. In this study, (TiAl)N thin films were deposited both at room temperature and at elevated substrate temperatures of 573 to 773 K by using a two-facing-targets type DC sputtering system in a mixture Ar and $N_2$ gases. Atomic compositions of the binary Ti-Al alloy target is Al-rich (25Ti-75Al (atm%)). Process parameters such as precursor volume %, substrate temperature and Ar/$N_2$ gas ratio were optimized. The crystallization processes and phase transformations of (TiAl)N thin films were investigated by X-ray diffraction, field-emission scanning electron microscopy. The microhardness of (TiAl)N thin films were measured by a dynamic hardness tester. The films obtained with Ar/$N_2$ gas ratio of 1:3 and at 673 K substrate temperature showed the highest microhardness of $H_v$ 810. The crystallized and phase transformations of (TiAl)N thin films were $Ti_2AlN+AlN{\rightarrow}TiN+AlN$ for Ar/$N_2$ gas ratio of 1:3, $Ti_2AlN+AlN{\rightarrow}TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 1:1 and $TiN+AlN{\rightarrow}Ti_2AlN+TiN+AlN{\rightarrow}Ti_2AlN+AlN{\rightarrow}Ti_2AlN+TiN+AlN$ for Ar/$N_2$ gas ratio of 3:1. The above results are discussed in terms of crystallized phases and microhardness.

Probabilistic Approach for Predicting Degradation Characteristics of Corrosion Fatigue Crack (환경피로균열 열화특성 예측을 위한 확률론적 접근)

  • Lee, Taehyun;Yoon, Jae Young;Ryu, KyungHa;Park, Jong Won
    • Journal of Applied Reliability
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    • v.18 no.3
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    • pp.271-279
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    • 2018
  • Purpose: Probabilistic safety analysis was performed to enhance the safety and reliability of nuclear power plants because traditional deterministic approach has limitations in predicting the risk of failure by crack growth. The study introduces a probabilistic approach to establish a basis for probabilistic safety assessment of passive components. Methods: For probabilistic modeling of fatigue crack growth rate (FCGR), various FCGR tests were performed either under constant load amplitude or constant ${\Delta}K$ conditions by using heat treated X-750 at low temperature with adequate cathodic polarization. Bayesian inference was employed to update uncertainties of the FCGR model using additional information obtained from constant ${\Delta}K$ tests. Results: Four steps of Bayesian parameter updating were performed using constant ${\Delta}K$ test results. The standard deviation of the final posterior distribution was decreased by a factor of 10 comparing with that of the prior distribution. Conclusion: The method for developing a probabilistic crack growth model has been designed and demonstrated, in the paper. Alloy X-750 has been used for corrosion fatigue crack growth experiments and modeling. The uncertainties of parameters in the FCGR model were successfully reduced using the Bayesian inference whenever the updating was performed.

Characterization and Fabrication of Tin Oxide Thin Film by RF Reactive Sputtering (RF Reactive Sputtering법에 의한 산화주석 박막의 제조 및 특성)

  • Kim, Young-Rae;Kim, Sun-Phil;Kim, Sung-Dong;Kim, Sarah Eun-Kyung
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.494-499
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    • 2010
  • Tin oxide thin films were prepared on borosilicate glass by rf reactive sputtering at different deposition powers, process pressures and substrate temperatures. The ratio of oxygen/argon gas flow was fixed as 10 sccm / 60 sccm in this study. The structural, electrical and optical properties were examined by the design of experiment to evaluate the optimized processing conditions. The Taguchi method was used in this study. The films were characterized by X-ray diffraction, UV-Vis spectrometer, Hall effect measurements and atomic force microscope. Tin oxide thin films exhibited three types of crystal structures, namely, amorphous, SnO and $SnO_2$. In the case of amorphous thin films the optical band gap was widely spread from 2.30 to 3.36 eV and showed n-type conductivity. While the SnO thin films had an optical band gap of 2.24-2.49 eV and revealed p-type conductivity, the $SnO_2$ thin films showed an optical band gap of 3.33-3.63 eV and n-type conductivity. Among the three process parameters, the plasma power had the most impact on changing the structural, electrical and optical properties of the tin oxide thin films. It was also found that the grain size of the tin oxide thin films was dependent on the substrate temperature. However, the substrate temperature has very little effect on electrical and optical properties.

Reactor Neutron Activation Analysis by a Single Comparator Method

  • Lee, Chul
    • Nuclear Engineering and Technology
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    • v.5 no.2
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    • pp.137-149
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    • 1973
  • A method of activation analysis, based on the irradiation and counting of an iron wire which contains manganese impurity as the single comparator. has been elaborated by critical evaluation of nuclear data involved in activation and activity measurement. The variation of effective cross section is investigated as a function of the spectral index and other parameters such as a measure of the proportion of epithermal neutrons in the reactor spectrum. The errors induced by shifts in the neutron spectrum in the irradiation positions are discussed. The known amount of each element is irradiated simultaneously together with the single comparator, and the obtained values are compared with the known amount of each element. The results show that en general the random errors are not greater than those obtained by using the conventional relative method, but the systematic errors were up to about 20%. This method is applied to the determinations of fourteen rare earth elements in monazite as well as other seven elements in the standard kale powder. The satisfactory reproducibility of the present method makes possible the determination of the elements with an accuracy attainable with the conventional relative method.

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The control of the structure and properties of tetrahedral amorphous carbon films prepared by Filtered Vacuum Arc (FVA 증착법에 의해 합성된 ta-C 박막의 구조 및 물성 제어)

  • 이철승;신진국;김종국;이광렬;윤기현
    • Journal of the Korean Vacuum Society
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    • v.11 no.1
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    • pp.8-15
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    • 2002
  • Tetrahedral amorphous carbon(ta-C) films were deposited by the filtered vacuum arc(FVA) process. The FVA process has many advantages such as high ionization ratio and the ion energy, which is suitable for dense amorphous carbon film deposition. However, the energy of the carbon ion cannot be readily controlled by manipulating the arc source parameters. In order to control the film properties in wide range, we investigated the dependence of the film properties on the substrate bias voltage. The mechanical properties and the density of the film exhibit the maximum values at about -100 V of the bias voltage. The maximum values of hardness and density were respectively 54$\pm$3 GPa and 3.6$\pm$0.4 g/㎤, which are 3 to 5 times higher than those of the films deposited by RF PACVD or ion beam process. The details of the atomic bond structure were analysed by Raman and NEXAFS spectroscopy. The change in the film properties for various bias voltages could be understood in the view of the $sp^2$ and $sp^3$ bond fraction in the deposited films.

Comparison of the optical properties of pre-colored dental monolithic zirconia ceramics sintered in a conventional furnace versus a microwave oven

  • Kim, Hee-Kyung;Kim, Sung-Hun
    • The Journal of Advanced Prosthodontics
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    • v.9 no.5
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    • pp.394-401
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    • 2017
  • PURPOSE. The purpose of this study was to compare the optical properties of pre-colored dental monolithic zirconia ceramics of various thicknesses sintered in a microwave and those in a conventional furnace. MATERIALS AND METHODS. A2-shade of pre-colored monolithic zirconia ceramic specimens ($22.0mm{\times}22.0mm$) in 3 thickness groups of 0.5, 1.0, and 1.5 mm were divided into 2 subgroups according to the sintering methods (n=9): microwave and conventional sintering. A spectrophotometer was used to obtain CIELab color coordinates, and translucency parameters and CIEDE2000 color differences (${\Delta}E_{00}$) were measured. The relative amount of monoclinic phase ($X_m$) was estimated with x-ray diffraction. The surface topography was analyzed by atomic force microscope and scanning electron microscope. Statistical analyses were conducted with two-way ANOVA (${\alpha}=.05$). RESULTS. There were small interaction effects on CIE $L^*$, $a^*$, and TP between sintering method and thickness (P<.001): $L^*$ (partial eta squared ${{\eta}_p}^2=0.115$), $a^*$ (${{\eta}_p}^2=0.136$), and TP (${{\eta}_p}^2=0.206$), although higher $b^*$ values were noted for microwave sintering regardless of thickness. Color differences between two sintering methods ranged from 0.52 to 0.96 ${\Delta}E_{00}$ units. The $X_m$ values ranged from 7.03% to 9.89% for conventional sintering, and from 7.31% to 9.17% for microwave sintering. The microwave-sintered specimen demonstrated a smoother surface and a more uniform grain structure compared to the conventionally-sintered specimen. CONCLUSION. With reduced processing time, microwave-sintered pre-colored dental monolithic zirconia ceramics can exhibit similar color perception and translucency to those by conventional sintering.

Application of the Fuzzy Set Theory to Uncertain Parameters in a Countermeasure Model (비상대응모델의 불확실한 변수에 대한 퍼지이론의 적용)

  • Han, Moon-Hee;Kim, Byung-Woo
    • Journal of Radiation Protection and Research
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    • v.19 no.2
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    • pp.109-120
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    • 1994
  • A method for estimating the effectiveness of each protective action against a nuclear accident has been proposed using the fuzzy set theory. In most of the existing countermeasure models in actions under radiological emergencies, the large variety of possible features is simplified by a number of rough assumptions. During this simplification procedure, a lot of information is lost which results in much uncertainty concerning the output of the countermeasure model. Furthermore, different assumptions should be used for different sites to consider the site specific conditions. Tn this study, the diversity of each variable related to protective action has been modelled by the linguistic variable. The effectiveness of sheltering and evacuation has been estimated using the proposed method. The potential advantage of the proposed method is in reducing the loss of information by incorporating the opinions of experts and by introducing the linguistic variables which represent the site specific conditions.

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