• 분석과학
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• 제8권4호
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• pp.411-418
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• 1995

A method for the direct determination of elemental content in each of aerosol particles by inductively coupled plasma atomic emission (ICP-AES) or mass spectrometry (ICP-MS) is described. This method is based upon the introduction of diluted aerosol into an ICP and the measurement of either the flash emission intensities of an atomic spectral line or ion intensities. A pulse-height analyzer is used for the measurement of the distribution of the elemental content. In order to calibrate the measuring system, monodisperse aerosols are used. The potentials of the method are shown by demonstrating the copper emission signals from the aerosols generated at a small electric switch, a study of the relation between the decreasing rate of particle number density and particle size, and measurements of calcium contents in the individual biological cells.

• 방사성폐기물학회지
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• 제18권4호
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• pp.497-508
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• 2020

In the geochemical field, the chemical speciation of hexavalent uranium (U(VI)) has been widely investigated by performing measurements to determine its luminescence properties, namely the excitation, emission, and lifetime. Of these properties, the excitation has been relatively overlooked in most time-resolved laser fluorescence spectroscopy (TRLFS) studies. In this study, TRLFS and continuous-wave excitation-emission matrix spectroscopy are adopted to characterize the excitation properties of U(VI) surface species that interact with amorphous silica. The luminescence spectra of U(VI) measured from a silica suspension and silica sediment showed very similar spectral shapes with similar lifetime values. In contrast, the excitation spectra of U(VI) measured from these samples were significantly different. The results show that distinctive excitation maxima appeared at approximately 220 and 280 nm for the silica suspension and silica sediment, respectively.

• 분석과학
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• 제12권4호
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• pp.1051-1056
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• 1999

• Nuclear Engineering and Technology
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• 제36권6호
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• pp.540-548
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• 2004

Check valve failure is one of the worst problems in nuclear power plants. Recently, many researches have been based on new technology using accelerometers and ultrasonic and magnetic flux detection have been carried out. Here, we have suggested a method that uses acoustic emission sensors for detecting the failures of check valves through measuring and analyzing backward leakage flow, a system that works without disassembling the check valve. For validating the suggested acoustic emission sensor methodology, we designed a hydraulic test loop with a check valve. We have assumed in this study that check valve failure is caused by disk wear or by the insertion of a foreign object. In addition, we have developed diagnostic algorithms by using a neural network model to identify the type and size of the failure in the check valve. Our results show that the proposed diagnostic algorithm with acoustic emission sensors is a good solution for identifying check valve failure without necessitating any disassembly work.

• Nuclear Engineering and Technology
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• 제35권1호
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• pp.25-34
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• 2003

The research on the development of the fault monitoring system for the thermal reduction reactor has been performed preliminarily in order to support the successful operation of the thermal reduction reactor. The final task of the development of the fault monitoring system is to assure the integrity of the thermal$_3$ reduction reactor by the acoustic emission (AE) method. The objectives of this paper are to identify and characterize the fault-induced signals for the discrimination of the various AE signals acquired during the reactor operation. The AE data acquisition and analysis system was constructed and applied to the fault monitoring of the small- scale reduction reactor, Through the series of experiments, the various signals such as background noise, operating signals, and fault-induced signals were measured and their characteristics were identified, which will be used in the signal discrimination for further application to full-scale thermal reduction reactor.

• 천문학회지
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• 제49권3호
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• pp.109-122
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• 2016

[Fe II] emission lines are prominent in the infrared (IR) and important as diagnostic tools for radiative atomic shocks. We investigate the emission characteristics of [Fe II] lines using a shock code developed by Raymond (1979) with updated atomic parameters. We first review general characteristics of the IR [Fe II] emission lines from shocked gas, and derive their fluxes as a function of shock speed and ambient density. We have compiled available IR [Fe II] line observations of interstellar shocks and compare them to the ratios predicted from our model. The sample includes both young and old supernova remnants in the Galaxy and the Large Magellanic Cloud and several Herbig-Haro objects. We find that the observed ratios of the IR [Fe II] lines generally fall on our grid of shock models, but the ratios of some mid-IR lines, e.g., [Fe II] 35.35 µm/[Fe II] 25.99 µm, [Fe II] 5.340 µm/[Fe II] 25.99 µm, and [Fe II] 5.340 µm/[Fe II] 17.94 µm, are significantly offset from our model grid. We discuss possible explanations and conclude that while uncertainties in the shock modeling and the observations certainly exist, the uncertainty in atomic rates appears to be the major source of discrepancy.

• Bulletin of the Korean Chemical Society
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• 제22권2호
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• pp.159-163
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• 2001

Si3N4 powder has been analyzed by inductively coupled plasma atomic emission spectrometry (ICP-AES). The sample was dissolved by high-pressure acid digestion with HF, H2SO4 (1+1), and HNO3 mix ture. This technique is well suited for the impurity analysis of Si3N4 because the matrix interference is eliminated. A round-robin samples trace elements, such as Ca, W, Co, Al, Fe, Mg, and Na, were determined. For the direct analysis, slurry nebulization of 0.96 mm Si3N4 powder also has been studied by ICP-AES. Emission intensities of Fe were measured as ICP operational conditions were changed. Significant signal difference between slurry particles and aqueous solution was observed in the present experiment. Analytical results of slurry injection and high-pressure acid digestion were compared. For the use of aqueous standard solution for calibration, k-factor was determined to be 1.71 for further application.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2004년도 추계학술발표회 발표논문집
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• pp.1007-1008
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• 2004

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2004년도 요약집 춘계학술발표대회
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• pp.57.1-57.1
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• 2004

• 한국방사성폐기물학회:학술대회논문집
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• 한국방사성폐기물학회 2018년도 추계학술논문요약집
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• pp.608-609
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• 2018