• Journal of Korean Society for Atmospheric Environment
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• v.22 no.2
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• pp.249-257
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• 2006

In this work, the adsorptive and desorptive behavior of reduced sulfur compounds (RSC) was investigated using the combination of the Peltier cooling (PC)/thermal desorption (TD) unit with the gas chromatographic (GC) detection technique. To examine the adsorptive characteristics of RSC on clothing materials, a total of nine experiments were conducted in a stepwise manner. Once small towel pieces are exposed to significant quantities of RSC standards with high concentrations (10 ppm), the desoprtion stage was then induced by deloading RSC with ultrapure $N_2$ at three different flow rates (FR) of 20, 40, and 60 mL/min. At each FR, the total deloading volume of 400, 800, and 1,600 mL were maintained. These results were then compared in terms of odoring efficiency by dividing the total amount of desorption with the total amount used for exposition or RSC loading. The results indicated that desorption reaction of certain compounds ($CH_3SH$ and DMS) can be influenced significantly with the reducing FR, while they are not affected directly by the total deloading volume. In addition, when the extent of adsorption was compared for most S compounds by the odoring efficiency term, the extent of absorption generally occurred at approximately 1/1000 level of original exposition.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.2
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• pp.131-157
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• 2016

A smog chamber has been an effective tool to study air quality, particularly secondary organic aerosol (SOA), which is typically formed by atmospheric oxidation of volatile organic compounds (VOCs). In controlled environments, smog chamber studies have validated atmospheric oxidation by identifying, quantifying and monitoring products with state-of-art instruments (e.g., aerosol mass spectrometer, scanning mobility particle sizer) and provided chemical insights of SOA formation by elucidating reaction mechanisms. This paper reviews types of smog chambers and the current state of smog chamber studies that have accomplished to find pathways of SOA formation, focusing on gas-particle partitioning of semivolatile products of VOC oxidation, heterogeneous reactions on aerosol surface, and aqueous chemistry in aerosol waters (e.g., cloud/fog droplets and wet aerosols). For future chamber studies, then, this paper discusses potential formation pathways of fine particles that East Asia countries (e.g., Korea and China) currently suffer from due to massive formation that gives rise to fatal health problems.

• Journal of the korean Society of Automotive Engineers
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• v.7 no.3
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• pp.94-101
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• 1985

The flame temperature of LPG-air premixture flame was measured by extrapolation of limiting case corresponding to the infinitely thin diameter of Platinum-resistance-hot-wire. LPG-air premixture flame, initially under atmospheric pressure and room temperature, propagates downward from top of the model combustion chamber maintained at constant pressure through the whole combustion process. Analytical calculation technique was also applied to determine full temperature history or spatial temperature distribution from flame reaction zone to burnt gas region.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2008.10a
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• pp.87-91
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• 2008

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2004.11a
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• pp.137-138
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• 2004

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2004.11a
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• pp.254-255
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• 2004

• Proceedings of the Korea Air Pollution Research Association Conference
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• 1999.10a
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• pp.215-216
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• 1999

연소시설, 소각시설 등에서 배출되는 아황산가스, 질소산화물, 염화수소, 불화수소 등의 산성가스를 경제적, 효율적으로 처리하는데 많은 관심의 대상이 되고 있는 건식 세정에는 석회석(CaCO$_3$, limestone), 생석회(CaO, lime), 소석회(Ca(OH)$_2$, hydrated lime) 등 calcium을 다량 함유하는 흡수제가 매우 효과적이라고 알려져 있다. 따라서 이러한 흡수제와 SO$_2$dml 화학반응에 관하여 많은 연구가 수행되어 왔으나, 대부분의 연구는 SO$_2$와 석회석이 고온에서 진행되는 화학반응에서 관한 것이다.(중략)

• Journal of the Korean Chemical Society
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• v.57 no.4
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• pp.525-528
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• 2013

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2003.11a
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• pp.455-456
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• 2003

광화학 스모그 현상을 재현하기 위한 메카니즘은 약 20,000개의 반응식과 수천개의 종이 포함되어야 하므로 자세한 반응 메카니즘을 포함하는 데는 한계가 있다(Dodge, 2000). 최근에 morphecule이라 부르는 대리종(surrogates)을 사용하는 방법(morphecule approach)이 개발되었다. 이 메카니즘은 반응 속도, 생성율, 생성물의 형태를 포함하여 lumped surrogates와 관련된 인자들이 모사하는 전체 시간 중 각 t시간 동안 일정하고 그 시간이후에는 인자들이 변화한다고 가정한다. 또한 특성이 비슷한 유기 화합물의 다양한 그룹을 표현할 때 morphecule이라 부르는 특정 화학종들을 사용한다. (중략)

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2001.11a
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• pp.417-418
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• 2001

석탄의 연소과정에서 필연적으로 발생하는 황(SOx) 및 질소산화물(NOx)을 제거하기 위한 방법중 하나인 동시처리기술중 PCD(pulsed corona discharge) 반응기의 반응조건은 첨가제의 성분 및 성상에 따라 다양하게 바뀌며 황 및 질소 산화물 제거반응에 큰 영향을 미친다(Akira M., 1995). 따라서 PCD 반응기에 유입되는 가스는 발전소 배기가스 조건을 적용한 상태에서 주입하는 첨가제의 종류 및 양을 변화시켜, 각종 첨가제의 주입이 탈황, 탈질 반응에 미치는 상승효과를 조사하였고 PCD 반응기에서 첨가제의 반응 현상을 규명코자 하였다(송영훈, 1997). (중략)