• Title/Summary/Keyword: Atmospheric environmental capacity

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Utilization of Element-doping Titania-impregnated Granular Activated Carbon in a Plug-flow System for Removal of BTEX

  • Jo, Wan-Kuen;Shin, Seung-Ho;Hwang, Eun-Song;Yang, Sung-Bong
    • Asian Journal of Atmospheric Environment
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    • v.4 no.3
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    • pp.177-188
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    • 2010
  • The use of an activated carbon (AC) system alone has the limitation that the pollutants are not eliminated but only transferred to another phase with the consumed AC becoming hazardous waste itself. Therefore, the present study investigated the feasibility of using a combined system of granular AC (GAC) with S-doped visible-light-induced $TiO_2$ (GAC/S-doped $TiO_2$) to clean monocyclic aromatic hydrocarbons (MAHs) with concentrations at $\leq$ 3 mg $m^{-3}$, using a continuous air-flow reactor. This study conducted three different experiments: an adsorption test of pure GAC and GAC/S-doped $TiO_2$; a long-term adsorptional photocatalytic (AP) activity test of GAC/S-doped $TiO_2$; and an AP activity test of GAC/S-doped $TiO_2$ under different conditions. For the AP activity test, three parameters were evaluated: various weights of GAC/S-doped $TiO_2$ (0.9, 4.4, and 8.9 g); various flow rates (FRs) (0.5, 1 and 2 L $min^{-1}$); and various input concentrations (ICs) of the target MAHs (0.1, 1, 2 and 3 mg $m^{-3}$). The adsorption efficiencies were similar for the pure GAC and GAC/S-doped $TiO_2$ reactors, suggesting that S-doped $TiO_2$ particles on GAC surfaces do not significantly interfere with the adsorption capacity of GAC. Benzene exhibited a clear AP activity, whereas no other target MAHs did. In most cases, the AP efficiencies for the target MAHs did not significantly vary with an increase in weight, thereby suggesting that, under the weight range tested in this study, the weights or FRs are not important parameters for AP efficiency. However, ICs did influence the AP efficiencies.

Study on Sensitivity of different Standardization Methods to Climate Change Vulnerability Index (표준화 방법에 따른 기후변화 취약성 지수의 민감성 연구)

  • Nam, Ki-Pyo;Kim, Cheol-Hee
    • Journal of Environmental Impact Assessment
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    • v.22 no.6
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    • pp.677-693
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    • 2013
  • IPCC showed that calculation of climate vulnerability index requires standardization process of various proxy variables for the estimation of climate exposure, sensitivity, and adaptive capacity. In this study, four different methodologies of standardization methods: Z-score, Rescaling, Ranking, and Distance to the reference country, are employed to evaluate climate vulnerability-VRI (Vulnerability-Resilience Indicator) over Korean peninsula, and the error ranges of VRI, arising from employing the different standardization are estimated. All of proxy variables are provided by CCGIS (Climate Change adaptation toolkit based on GIS) which hosts information on both past and current socio-economic data and climate and environmental IPCC SRES (A2, B1, A1B, A1T, A1FI, and A1 scenarios) climate data for the decades of 2000s, 2020s, 2050s, and 2100s. The results showed that Z-score and Rescaling methods showed statistically undistinguishable results with minor differences of spatial distribution, while Ranking and Distance to the reference country methods showed some possibility to lead the different ranking of VRI among South Korean provinces, depending on the local characteristics and reference province. The resultant VRIs calculated from different standardization methods showed Cronbach's alpha of more than 0.84, indicating that all of different methodologies were overall consistent. Similar horizontal distributions were shown with the same trends: VRI increases as province is close to the coastal region and/or it close toward lower latitude, and decreases as it is close to urbanization area. Other characteristics of the four different standardization are discussed in this study.

Capacity assessment of existing corroded overhead power line structures subjected to synoptic winds

  • Niu, Huawei;Li, Xuan;Zhang, Wei
    • Wind and Structures
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    • v.27 no.5
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    • pp.325-336
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    • 2018
  • The physical infrastructure of the power systems, including the high-voltage transmission towers and lines as well as the poles and wires for power distribution at a lower voltage level, is critical for the resilience of the community since the failures or nonfunctioning of these structures could introduce large area power outages under the extreme weather events. In the current engineering practices, single circuit lattice steel towers linked by transmission lines are widely used to form power transmission systems. After years of service and continues interactions with natural and built environment, progressive damages accumulate at various structural details and could gradually change the structural performance. This study is to evaluate the typical existing transmission tower-line system subjected to synoptic winds (atmospheric boundary layer winds). Effects from the possible corrosion penetration on the structural members of the transmission towers and the aerodynamic damping force on the conductors are evaluated. However, corrosion in connections is not included. Meanwhile, corrosion on the structural members is assumed to be evenly distributed. Wind loads are calculated based on the codes used for synoptic winds and the wind tunnel experiments were carried out to obtain the drag coefficients for different panels of the transmission towers as well as for the transmission lines. Sensitivity analysis is carried out based upon the incremental dynamic analysis (IDA) to evaluate the structural capacity of the transmission tower-line system for different corrosion and loading conditions. Meanwhile, extreme value analysis is also performed to further estimate the short-term extreme response of the transmission tower-line system.

Development of Road Surface Temperature Prediction Model using the Unified Model output (UM-Road) (UM 자료를 이용한 노면온도예측모델(UM-Road)의 개발)

  • Park, Moon-Soo;Joo, Seung Jin;Son, Young Tae
    • Atmosphere
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    • v.24 no.4
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    • pp.471-479
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    • 2014
  • A road surface temperature prediction model (UM-Road) using input data of the Unified Model (UM) output and road physical properties is developed and verified with the use of the observed data at road weather information system. The UM outputs of air temperature, relative humidity, wind speed, downward shortwave radiation, net longwave radiation, precipitation and the road properties such as slope angles, albedo, thermal conductivity, heat capacity at maximum 7 depth are used. The net radiation is computed by a surface radiation energy balance, the ground heat flux at surface is estimated by a surface energy balance based on the Monin-Obukhov similarity, the ground heat transfer process is applied to predict the road surface temperature. If the observed road surface temperature exists, the simulated road surface temperature is corrected by mean bias during the last 24 hours. The developed UM-Road is verified using the observed data at road side for the period from 21 to 31 March 2013. It is found that the UM-Road simulates the diurnal trend and peak values of road surface temperature very well and the 50% (90%) of temperature difference lies within ${\pm}1.5^{\circ}C$ (${\pm}2.5^{\circ}C$) except for precipitation case.

The Impact of Air Temperature During the Growing Season on NEE of the Apple Orchard (사과 생육기의 기온이 사과원의 NEE에 미치는 영향)

  • Kim, Gun-Yeob;Lee, Seul-Bi;Lee, Jong-Sik;Choi, Eun-Jung;Ryu, Jong-Hee
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.1211-1215
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    • 2012
  • Terrestrial ecosystem are a strong sink of carbon. Forest ecosystem, one of them, has been expected to play an important role in climate changing process by absorbing atmospheric carbon dioxide. On the other hand, agricultural ecosystem that consists mainly of annual crops is regarded as poor contributor to carbon accumulation, because its production (carbon hydrate) is decomposed into carbon at a short period, which is emitted to the atmosphere. However, it is thought that fruit tree plays a great role in decreasing atmospheric carbon dioxide concentration, same as forest. Net ecosystem exchange of $CO_2$ (NEE) was measured to estimate carbon fixation capacity using an eddy covariance (EC) system method in 2 years from 2005 to 2006 at an apple orchard in Uiseong, Gyeongbuk. Average air temperature values were higher in 2006 than in 2005 during the dormant season, and lower by about $5^{\circ}C$ over the growing season causing visible cold injuries. Accordingly, we investigated long-term exchange of carbon to determine how much difference of carbon fixation capacity was shown between 2006 and 2005 in terms of environmental and plant variables such as NEE, leaf area index (LAI), and Albedo. NEE was $4.8Mg\;C\;ha^{-1}yr^{-1}$ in 2005 and $4.7Mg\;C\;ha^{-1}yr^{-1}$ in 2006, respectively. Low temperature after July in 2006 decreased LAI values faster than those in 2005. Meanwhile, Albedo values were higher after July in 2006 than in 2005. These results show that the low temperature after July in 2006 apparently affected apple growth.

The Effects of Flow Velocity on the Adsorption Characteristics of Organic Phosphorus Compounds

  • Kim, Chul-Sung;Lim, Jong-Sun;Baeg, Seung-Jae;Byun, Yong-Gwan
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.E
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    • pp.19-25
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    • 1998
  • Adsorption characteristics of DMMP and IMPF were investigated using dynamic adsorption method. Adsorbate vapor was forced to Pass at fixed flow rate of 4 mg/I through Cu Cr impregnated activated carbon column at several different flow velocities until the effluent concentrations exceeded 4.0$\times$10$^{-5}$ mg/I. The kinetic adsorption capacity, adsorption kinetic constant, and critical bed weight of the activated carbon were determined for DMMP and IMPF vapors by plotting breakthrough time as a function of carbon weight. A mathematical expression was deduced from our experimental data to represent the relationships between kinetic adsorption capacity and flow velocity. According to our experimental results, the lifetime of DMMP was longer than that of IMPF under the same conditions. Their relationship can be expressed empirically as follows: Tb(DMMP) = 0.9825$\times$Tb(IMPF)-15.368

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Long-term Trend Analysis of Korean Air Quality and Its Implication to Current Air Quality Policy on Ozone and PM10 (국내 기준성 대기오염물질의 권역별 장기 추이 및 원인 분석: PM10과 오존을 중심으로)

  • Kim, Jeonghwan;Ghim, Young Sung;Han, Jin-Seok;Park, Seung-Myung;Shin, Hye-Jung;Lee, Sang-Bo;Kim, Jeongsoo;Lee, Gangwoong
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.1-15
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    • 2018
  • Nation-wide systematic and comprehensive measurements of air quality criteria species have been made over 340 sites currently in Korea since 1990. Using these data, temporal and spatial trends of $SO_2$, $PM_{10}$, $NO_2$, $O_3$, CO and $O_x(NO_2+O_3)$ were analyzed to characterize and evaluate implementing efficiency of air quality policy and regulations. Due to strict and effective policy to use cleaner fuels in late 1980s and 1990s, the primary pollutants, such as $SO_2$, CO, and $PM_{10}$ decreased sharply by early 2000s in all parts of Korea. After this period, their concentrations declined with much lower rates in most parts of Korea. In addition, isolated but noticeable numbers of places, especially in major ports, newly developing towns and industrial parks, sustained high levels or even showed further degradation. Despite series of emission control strategies were enforced since early 1990s, $NO_2$ concentrations haven't changed much till 2005, due to significant increase in number of automobiles. Nevertheless, we confirmed that the staggering levels of $NO_2$ and $PM_{10}$ improved evidently after 2005, especially in Seoul Metropolitan Area (SMA), where enhanced regulations for $NO_2$ and $PM_{10}$ emissions was imposed to automobiles and large emission sources. However, their decreasing trends were much lessened in recent years again as current air quality improvement strategies has been challenged to revise further. In contrast to these primary species, annual $O_3$, which is secondary product from $NO_2$ and volatile organic compounds (VOCs), has increased consistently with about 0.6 ppbv per year in every urban part of Korea, while yearly average of daily maximum 8-hour $O_3$ in summer season had a much higher rate of 1.2 ppbv per year. Increase of $O_3$ can be explained mainly by reductions of NO emission. Rising background $O_3$ in the Northeast Asia and increasing oxidizing capacity by changing photochemistry were likely causes of observed $O_3$ increase. The future air quality policy should consider more effective ways to lower alarming level of $O_3$ and $PM_{10}$.

Predicting the Methane Gas Generation Rate at Landfill Sites Using the Methane Gas Generation Rate Constant (k)

  • Chung, Jin-Do;Kim, Jung-Tae
    • Asian Journal of Atmospheric Environment
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    • v.2 no.2
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    • pp.116-124
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    • 2008
  • In this study, the Tier 2 method recommended by the Intergovernmental Panel on Climate Change (IPCC) was used to predict the methane generation rate at two landfill sites, designated as Y and C for purposes of this study, in South Korea. Factors such as the average annual waste disposal, methane emissions ($L_0$) and methane gas generation rate constant (k) were estimated by analyses of waste and the historical data for the landfills. The value of k was estimated by field experiments and then the changes in the methane generation rate were predicted through the year 2050, based on the value of k. The Y landfill site, which was in operation until the year 2008, will generate a total of 17, 198.7 tons by the end of 2018, according to our estimations. At the C landfill site, which will not be closed until the end of 2011, the amount of methane gas generated in 2011 will be 3,316 tons and the total amount of gas generated by 2029 will be 61,200 tons. The total production rate of methane gas at the C landfill is higher than that of the Y landfill. This indicates that the capacity of a landfill site affects the production rate of methane gas. However, the interrelation between the generation rate of methane and the value of k is weak. In addition, the generation of methane gas does not cease even when the operations at a landfill site come to a close and the methane gas production rate is at its highest at end of the operating life of a landfill site.

Specific Surface Area and Pore Structure Changes of Calcined Lime with Calcination and Sulfation Reaction (소성과 황화반응에 따른 생석회의 비표면적 및 기공구조 변화)

  • 강순국;정명규
    • Journal of environmental and Sanitary engineering
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    • v.13 no.3
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    • pp.19-29
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    • 1998
  • The calcination reactivity of limestone and physical property changes of calcined lime were investigated with a temperature($720~1000^{\circ}C$ under atmospheric gas($N_2$, $CO_2$) conditions. The mechanisms of mass transport in a lime matrix were represented by the evaporation and condensation (${\gamma}=1.7$) at $1000^{\circ}C$ and the volume diffusion (${\gamma}=2.7$) at $800^{\circ}C$, which was obtained by the specific surface area of calcined lime with sintering conditions. Also, the effect of physical property on the reactivity of sulfation reaction was determined by the changes of pore size with $lime-SO_2$ reaction in this work. The initial sulfation rate of calcined lime increased with increasing temperature, whereas the capture capacity of $SO_2$ exhibited a maximum value at $900^{\circ}C$. The pore volume of sulfated lime was decreased with increasing sulfation time, but the major pores shifted to the distribution of larger size at a temperature of $850{\;}~{\;}1000^{\circ}C$. The mean pore size of sulfated lime based on pore volume decreased gradually at $1000^{\circ}C$; however, it increased with sulfation time up to 40 min and rapidly decreased thereafter.

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Methane Oxidizing Capacity of Landfill Cover Soils to Reduce Atmospheric Methane Emissions (메탄의 대기 배출량을 저감시키는 매립지 복토층의 메탄 산화능력에 관한 연구)

  • Park, Soyoung
    • Journal of Environmental Impact Assessment
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    • v.13 no.4
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    • pp.187-196
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    • 2004
  • 매립지에서 배출되는 메탄가스는 이산화탄소에 이어 두 번째로 많이 배출되는 지구온난화 가스이지만 열을 흡수하는 능력에 있어서는 이산화탄소 보다 25에서 35배 정도 더 크기 때문에 지구 온난화 현상에 대한 메탄가스의 영향은 중요하다고 할 수 있다. 매립지로부터 배출되는 메탄가스는 호기성 상태의 매립지 복토층을 통과 할 때 산화될 수 있으므로 매립지 복토층은 메탄가스의 배출을 저감시키는 바이오필터의 역할을 할 수 있다. 본 연구에서는 batch 실험을 통하여 매립지 복토층에서의 메탄산화속도에 대한 토양수분과 온도의 영향을 연구하였다. 최대 산화속도는 토양수분 15%(w/w), 배양온도 $35^{\circ}C$의 환경조건에서 $1.03{\mu}mol\;CH_4g^{-1}soil\;h^{-1}$으로 나타났다. 이러한 실험결과를 이용하여 토양수분과 온도를 함수로 하는 회귀모형을 개발하였다. 또한 전국에 4 군데 지역을 선발하여 각 지역의 토양수분과 온도 데이타를 수집하고 개발된 모형을 이용하여 각 지역에 위치하고 있는 매립장에서의 월 평균 메탄산화량을 예측하였다. 예측 결과 환경조건이 양호한 지역의 매립지 복토는 메탄의 배출량을 저감시킬 수 있는 효율적인 바이오필터의 효과를 가지지만 환경조건이 불리한 지역의 매립지 복토에서는 바이오필터의 효과가 크지 않는다고 할 수 있다.