• Title/Summary/Keyword: Atmospheric conditions

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Characteristics of Silicon Oxide Thin Films Prepared by Atomic Layer Deposition Using Alternating Exposures of SiH2Cl2 and O3 (SiH2Cl2 와 O3을 이용한 원자층 증착법에 의해 제조된 실리콘 산화막의 특성)

  • Lee Won-Jun;Lee Joo-Hyeon;Han Chang-Hee;Kim Un-Jung;Lee Youn-Seung;Rha Sa-Kyun
    • Korean Journal of Materials Research
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    • v.14 no.2
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    • pp.90-93
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    • 2004
  • Silicon dioxide thin films were deposited on p-type Si (100) substrates by atomic layer deposition (ALD) method using alternating exposures of $SiH_2$$Cl_2$ and $O_3$ at $300^{\circ}C$. $O_3$ was generated by corona discharge inside the delivery line of $O_2$. The oxide film was deposited mainly from $O_3$ not from $O_2$, because the deposited film was not observed without corona discharge under the same process conditions. The growth rate of the deposited films increased linearly with increasing the exposures of $SiH_2$$Cl_2$ and $O_3$ simultaneously, and was saturated at approximately 0.35 nm/cycle with the reactant exposures over $3.6 ${\times}$ 10^{9}$ /L. At a fixed $SiH_2$$Cl_2$ exposure of $1.2 ${\times}$ 10^{9}$L, growth rate increased with $O_3$ exposure and was saturated at approximately 0.28 nm/cycle with $O_3$ exposures over$ 2.4 ${\times}$ 10^{9}$ L. The composition of the deposited film also varied with the exposure of $O_3$. The [O]/[Si] ratio gradually increased up to 2 with increasing the exposure of $O_3$. Finally, the characteristics of ALD films were compared with those of the silicon oxide films deposited by conventional chemical vapor deposition (CVD) methods. The silicon oxide film prepared by ALD at $300^{\circ}C$ showed better stoichiometry and wet etch rate than those of the silicon oxide films deposited by low-pressure CVD (LPCVD) and atmospheric-pressure CVD (APCVD) at the deposition temperatures ranging from 400 to $800^{\circ}C$.

Meteorological Characteristics of High-Ozone Episode Days in Daegu, Korea (대구시의 고농도 오존 발생 일에 나타나는 기상학적 특성)

  • Son, Im-Young;Kim, Hee-Jong;Yoon, Ill-Hee
    • Journal of the Korean earth science society
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    • v.23 no.5
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    • pp.424-435
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    • 2002
  • This study analyzes the surface ozone and meteorological data in Daegu for a period from 1997 to 1999. It also investigates the meteorological characteristics of high ozone episodes. For this study the high ozone episode has been defined as a daily maximum ozone concentration higher than 100ppb in at least one station among six air quality monitoring stations in Daegu, Korea. The frequency of episodes is 13 days. The frequency is the highest in May and September. The average value of daily maximum ozone concentration is 81.6ppb, and 8-hour average ozone concentration is 58.6ppb for the high episodes. This shows that ozone pollution is continuous and wide-ranging in Daegu. The daily maximum ozone concentration is positively correlated to solar radiation and daily maximum temperature, but negatively correlated to relative humidity, wind speed and cloud amount. The maximal correlation coefficient to solar radiation is 0.45. The differences between high ozone episode day's daily mean meteorological value and monthly mean value are +1.58hPa for sea level pressure, +3.45${\circ}$C for maximum temperature, -5.69% for relative humidity, -0.46ms$^{-1}$ for wind speed, -1.79 for cloud amount, and +3.97MJm$^{-2}$ for solar radiation, respectively. This shows that strong solar radiation, low wind speed and no precipitation between 0700${\sim}$1100LST are favorite conditions for high ozone episodes. It is related to the morning stagnant condition.

Preparation of Photocatalysts by Hydrothermal Precipitation Method and Their Photocatalytic Performance of Brilliant Blue FCF (수열합성법에 의한 광촉매 제조 및 Brilliant Blue FCF 분해 성능)

  • Kim, Seok-Hyeon;Jeong, Sang-Gu;Na, Seok-En;Koo, Su-Jin;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.152-156
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    • 2016
  • Experimental research on the preparation of photocatalyst for the decomposition of brilliant blue FCF ($C_{37}H_{31}O_9N_2S_3Na_2$) was performed. $TiO_2$ and ZnO powders were prepared from titanium (IV) sulfate and zinc acetate at low reaction temperature and atmospheric pressure by hydrothermal precipitation method without calcination. In addition, $TiO_2$ was prepared with cationic surfactant CTAB (Hexadecyltrimethyl ammonium bromide) at the same conditions. The physical properties of prepared $TiO_2$ and ZnO, such as crystallinity, average particle size and absorbance, were investigated by XRD, Zeta-potential meter and DRS. And, the photocatalytic degradation of brilliant blue FCF has been studied in the batch reactor under UV radiation. For the photocatalysts prepared without CTAB, $TiO_2$ has smaller particle size and larger absorbance and photocatalytic reaction rate than ZnO. And $TiO_2$, prepared with CTAB whose concentration is 1/10 of that of precursor, shows 15% higher than that prepared without CTAB in final photocatalytic degradation ratio of brilliant blue FCF.

Blue Light Photosensitization in Mitochondrial Membrane of Plant Cells (식물세포 미토콘드리아막에서 일어나는 청색광 Photosensitization)

  • Kim, Kyung-Hyun;Kim, Jong-Pyung;Jung, Jin
    • Korean Journal of Environmental Agriculture
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    • v.6 no.2
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    • pp.94-100
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    • 1987
  • Plant mitochondria, irradiated with blue-colored $sunlight(350{\sim}500nm)$ under aerobic and anaerobic conditions, were assayed as to the electron transfer activity of respiratory enzyme system, and compared with those irradiated with orange-colored light(white sunlight minus blue-colored light). The respiratory activity of mitochondria was most seriousely inhibited by illumination with blue-colored light under aerobic condition. Deaeration of mitochondrial suspension resulted in substantial decrease of the photoinhibition by blue-colored light. Meanwhile, orange-colored light demonstrated much less effectiveness-almost ineffectiveness-in causing the inhibition of mitochondrial respiration system. The results of enzymatic assay revealed a strong possibility that FMN in NDH and heme group at least in cytochrome c oxidase, but not FAD in SDH, are the photodynamic sensitizers in mitochondrial inner membrane. Also worthwhile to note is the significant difference from the others of SDH in its photoinhibitory response to the light quality of visible light; that the inhibition of SDH by irradiation was not affected by atmospheric condition and that orange-colored light gave rise to considerable extents of inhibition to the enzyme. This observation was tentatively interpreted in terms of photosensitized reaction not involving molecular oxygen possibly catalyzed by Fe-S centers in the enzyme. The superoxide production and the membrane peroxidation of mitochondria under various treatments also indicated that there was blue-light photodynamic reaction in mitochondria involving active oxygens.

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IONOSPHERE-THERMOSPHERE INTERACTIONS BASED ON NCAR-TIEGCM: THE INFLUENCE OF THE INTERPLANETARY MAGNETIC FIELD (IMF)-DEPENDENT IONOSPHERIC CONVECTION ON THE HIGH-LATITUDE LOWER THERMOSPHERIC WIND (NCAR-TIEGCM을 이용한 이온권-열권의 상호작용 연구: 행성간 자기장(IMF)에 의존적인 이온권 플라즈마대류의 고위도 하부 열권 바람에 대한 영향)

  • 곽영실;안병호;원영인
    • Journal of Astronomy and Space Sciences
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    • v.21 no.1
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    • pp.11-28
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    • 2004
  • To better understand how high-latitude electric fields influence thermospheric dynamics, winds in the high-latitude lower thermosphere are studied by using the Thermosphere-ionosphere Electrodynamics General Circulation Model developed by the National Conte. for Atmospheric Research (NCAR-TIEGCM). The model is run for the conditions of 1992-1993 southern summer. The association of the model results with the interplanetary magnetic field(IMF) is also examined to determine the influences of the IMF-dependent ionospheric convection on the winds. The wind patterns show good agreement with the WINDII observations, although the model wind speeds are generally weaker than the observations. It is confirmed that the influences of high-latitude ionospheric convection on summertime thermospheric winds are seen down to 105 km. The difference wind, the difference between the winds for IMF$\neq$O and IMF=0, during negative IMF $B_y$ shows a strong anticyclonic vortex while during positive IMF $B_y$ a strong cyclonic vortex down to 105 km. For positive IMF $B_z$ the difference winds are largely confined to the polar cap, while for negative IMF B, they extend down to subauroral latitudes. The IMF $B_z$ -dependent diurnal wind component is strongly correlated with the corresponding component of ionospheric convection velocity down to 108 km and is largely rotational. The influence of IMF by on the lower thermospheric summertime zonal-mean zonal wind is substantial at high latitudes, with maximum wind speeds being $60\;ms^-1$ at 130 km around $77^{\circ}$ magnetic latitude.

Effects of Thermal Properties and Water Retention Characteristics of Permeable Concrete Pavement on Surface Temperature (투.보수성 시멘트 콘크리트 포장의 열물성 및 수분보유특성이 표면온도에 미치는 영향)

  • Ryu Nam-Hyang;Yoo Byung-Rim
    • Journal of the Korean Institute of Landscape Architecture
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    • v.34 no.1 s.114
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    • pp.21-36
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    • 2006
  • This study was undertaken to analyze the effects of pavement thermal properties and water retention characteristics on the surface temperature of the gray permeable cement concrete pavement during the summer. Following is a summary of major results. 1) The hourly surface temperature of pavement could be well predicted with a heat transfer model program that incorporated the input data of major meteorological variables including solar radiation, atmospheric temperature, dew point, wind velocity, cloudiness and the evaporation rate of the pavements predicted by the time domain reflectometry (TDR) method. 2) When the albedo was changed to 0.5 from an arbitrary starting condition of 0.3, holding other variables constant, the peak surface temperature of the pavement dropped by 11.5%. When heat capacity was changed to $2.5\;kJm^{-3}K^{-1}\;from\;1.5\;kJm^{-3}K^{-1}$, surface temperature dropped by 8.0%. When daily evaporation was changed to 1 mm from 2 mm, temperature dropped by 5.7%. When heat conductivity was changed to $2.5\;Wm^{-1}K^{-1}\;from\;1.5\;Wm^{-1}K^{-1}$, the peak surface temperature of the pavement fell by 1.2%. The peak pavement surface temperature under the arbitrary basic condition was $24.46^{\circ}C$ (12 a.m.). 3) It accordingly became evident that the pavement surface temperature can be most effectively lowered by using materials with a high albedo, a high heat capacity or a high evaporation at the pavement surface. The glare situation, however, is intensified by raising of the albedo, moreover if reflected light is absorbed into surrounding physical masses, it is changed into heat. It accordingly became evident that raising the heat capacity and the evaporative capacity may be the moot acceptable measures to improve the thermal characteristics of the pavement. 4) The sensitivity of the surface temperature to major meteorological variables was as follows. When the daily average temperature changed to $0^{\circ}C\;from\;15^{\circ}C$, holding all other variables constant, the peak surface temperature of the pavement decreased by 56.1 %. When the global solar radiation changed to $200\;Wm^{-2}\;from\;600\;Wm^{-2}$, the temperature of the pavement decreased by 23.4%. When the wind velocity changed to $8\;ms^{-1}\;from\;4\;ms^{-1}$, the temperature decreased by 1.4%. When the cloudiness level changed to 1.0 from 0.5, the peak surface temperature decreased by 0.7%. The peak pavement surface temperature under the arbitrary basic conditions was $24.46^{\circ}C$ (12 a.m.)

Derivation and Evaluation of Surface Reflectance from UAV Multispectral Image for Monitoring Forest Vegetation (산림 식생 모니터링을 위한 무인기 다중분광영상의 반사율 산출 및 평가)

  • Lee, Hwa-Seon;Seo, Won-Woo;Woo, Choongshik;Lee, Kyu-Sung
    • Korean Journal of Remote Sensing
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    • v.35 no.6_2
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    • pp.1149-1160
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    • 2019
  • In this study, two radiometric correction methods deriving reflectance from UAV multispectral image for monitoring forest vegetation were applied and evaluated. Multispectral images were obtained from a small multispectral camera having 5 spectral bands. Reflectance were derived by applying the two methods: (1) the direct method using downwelling irradiance measurement and (2) the empirical line correction method by linking a set of field reflectance measured simultaneous with the image capture. Field reflectance were obtained using a spectroradiometer during the flight and used for building the linear equation for the empirical method and for the validation of image reflectance derived. Although both methods provided the high correlations between field reflectance and image-derived reflectance, their distributions were somewhat different. While the direct method provided rather stable and consistent distribution of reflectance all over the entire image area, the empirical method showed very unstable and inconsistent reflectance distribution. The direct method would be more appropriate for relatively wide area that requires more time to acquire image and may vary in downwelling irradiance and atmospheric conditions.

Spatio-Temporal Variations of Harmful Algal Blooms in the South Sea of Korea

  • Kim, Dae-Hyun;Denny, Widhiyanuriyawan;Min, Seung-Hwan;Lee, Dong-In;Yoon, Hong-Joo
    • Korean Journal of Remote Sensing
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    • v.25 no.6
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    • pp.475-486
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    • 2009
  • Harmful algal blooms (HAB) caused by the dominant species Cochlodinium polykrikoides (C. polykrikoides) appear in the South Sea of Korea and are particularly present in summer and fall seasons. Environmental factors such as water temperature, weather conditions (air temperature, cloud cover, sunshine, precipitation and wind) influence on the initiation and subsequent development of HAB. The purpose of this research was to study spatial and temporal variations of HAB in the Yeosu area using environmental (oceanic and meteorological) and satellite data. Chlorophyll-a concentrations were calculated using Sea-viewing Wide Field-of-view Sensor (SeaWiFS) images by an Ocean Chlorophyll 4 (OC4) algorithm, and HAB were estimated using the Red tide index Chlorophyll Algorithm (RCA). We also used the surface velocity of sequential satellite images applying the Maximum Cross Correlation method to detect chlorophyll-a movement. The results showed that the water temperature during HAB occurrences in August 2002-2008 was $19.4-30.2^{\circ}C$. In terms of the frequency of the mean of cell density of C. polykrikoides, the cell density of the HAB found at low (<300 cells/ml), medium (300-1000 cells/ml), and high (>1000 cells/ml) levels were 27.01%, 37.44%, and 35.55%, respectively. Meteorological data for 2002-2008 showed that the mean air temperature, precipitation, wind speed and direction, and sunshine duration were $22.39^{\circ}C$, 6.54 mm/day, 3.98 m/s (southwesterly), and 1-11.7 h, respectively. Our results suggest that HAB events in the Yeosu area can be triggered and extended by heavy precipitation and massive movement of HAB from the East China Sea. Satellite images data from July to October 2002-2006 showed that the OC4 algorithm generally estimated high chlorophyll-a concentration ($2-20\;mg/m^3$) throughout the coastal area, whereas the RCA estimated concentrations at $2-10\;mg/m^3$. The surface velocity of chlorophyll-a movement from sequential satellite images revealed the same patterns in the direction of the Tsushima Warm Current.

Estimation of Typhoon Center Using Satellite SAR Imagery (인공위성 SAR 영상 기반 태풍 중심 산정)

  • Jung, Jun-Beom;Park, Kyung-Ae;Byun, Do-Seong;Jeong, Kwang-Yeong;Lee, Eunil
    • Journal of the Korean earth science society
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    • v.40 no.5
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    • pp.502-517
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    • 2019
  • Global warming and rapid climate change have long affected the characteristics of typhoons in the Northwest Pacific, which has induced increasing devastating disasters along the coastal regions of the Korean peninsula. Synthetic Aperature Radar (SAR), as one of the microwave sensors, makes it possible to produce high-resolution sea surface wind field around the typhoon under cloudy atmospheric conditions, which has been impossible to obtain the winds from satellite optical and infrared sensors. The Geophysical Model Functions (GMFs) for sea surface wind retrieval from SAR data requires the input of wind direction, which should be based on the accurate estimation of the center of the typhoon. This study estimated the typhoon centers using Sentinel-1A images to improve the problem of typhoon center detection method and to reflect it in retrieving the sea surface wind. The results were validated by comparing with the typhoon best track data provided by the Korea Meteorological Administration (KMA) and Japan Meteorological Agency (JMA), and also by using infrared images of Himawari-8 satellite. The initial center position of the typhoon was determined by using VH polarization, thereby reducing the possibility of error. The detected center showed a difference of 23.76 km on average with the best track data of the four typhoons provided by the KMA and JMA. Compared to the typhoon center estimated by Himawari-8 satellite, the results showed an average spatial variation of 11.80 km except one typhoon located near land with a large difference of 58.73 km. This result suggests that high-resolution SAR images can be used to estimate the center and retrieve sea surface wind around typhoons.

Operational Properties and Microbial Inactivation Performance of Dielectric Barrier Discharge Plasma Treatment System (유전체장벽방전 플라즈마 장치의 조작특성과 살균력)

  • Mok, Chulkyoon;Lee, Taehoon
    • Food Engineering Progress
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    • v.15 no.4
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    • pp.398-403
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    • 2011
  • A dielectric barrier discharge plasma (DBDP) treatment system was fabricated and the optimum operating conditions for the plasma generation were determined in order to explore the potential of cold plasma as a non-thermal proessing technology. The microbial inactivation performance of the system was also evaluated against Staphyloocus aureus. The system consisted of power supply, transformer, electrode assembly and sample treatment plate. The input power was 220 V single phase AC and amplified to 10.0-50.0 kV on a transformer. A pulsed sine wave of frequency 10.0-50.0 kHz was introduced to the electrode embedded in ceramic as a dielectric barrier material in order to generate plasma at atmospheric pressure. Higher currents and consequently greater power were required for the plasma generation as the frequencies increased. A homogeneous and stable plasma was generated at currents of 1.0-2.0, and frequencies of 32.0-35.3 kHz. The optimum electrode-gaps for the plasma generation were 1.85 mm without loaded samples. More power was consumed as the electrode-gaps increased. The practically optimum electrode- gap was, however, 2.65 mm when samples were treated on slide-glasses for microbial inactivation. The maximum temperature increase after 10 min treatment was less than 20$^{\circ}C$, indicating no microbial inactivation effect by heat and thereby insuring a non-thermal method. The DBDP inactivation effect against Staphyloocus aureus increased linearly with treatment time up to 5 min, but plateaued afterward. More than 5 log reduction was achieved by 10 min treatment at 1.25 A.