• Journal of the Korean institute of surface engineering
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• v.36 no.5
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• pp.357-363
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• 2003

The aim of this work is the synthesis of a-C:H films from methane gas using surface spark discharge at the atmospheric pressure. Properties of these films have been investigated as functions of energy W delivered per a methane molecule in the discharge. The method enables the coatings to be deposited with high growth rates (up to $100 \mu\textrm{m}$/hour) onto large-area substrates. It is shown that the films consist of spherical granules with diameter of 20∼50 nm formed in the spark channel and then deposited onto the substrate. The best film characteristics such as minimum hydrogen-to-carbon atoms ratio H/C=0.69, maximum hardness $H_{v}$ =3 ㎬, the most dense packing of the granules and highest scratch resistance has been obtained under the condition of highest energy W of 40 eV. The deposited a-C:H coatings were found to be more soft and hydrogenated compared to the diamond-like hydrogenated (a-C:H) films which obtained by traditional plasmaenhanced chemical vapor deposition methods at low pressure (＜10 Torr). Nevertheless, these coatings can be potentially used for scratch protection of soft plastic materials since they are of an order harder than plastics but still transparent (the absorption coefficient is about $10^4$∼$10^{5}$ $m^{-1}$ At the same time the proposed method for fast deposition of a-C:H films makes this process less expensive compared to the conventional techniques. This advantage can widen the application field of. these films substantially.y.

• Journal of Korean Society for Atmospheric Environment
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• v.4 no.2
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• pp.20-27
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• 1988

A simple two stage aerosol filter sampler which allows simultaneous and fractional collection of two different-size particles, coarse and fine, was constructed and applied to the collection of Seoul atmospheric particulate for inorganic analysis. The sampler consist of two 47-mm diameter filter holder, a pneumatic pump, and a flowmeter. Filtering rate normally runs around 20$\ell$/min for 8 hrs. Using the sampler, a series of seasonal aerosol samples were collected from June 1986 to March 1988 at Yonsei University campus, Seoul and subsequently analysed for ten environmentally important metals using an atomic absorption spectrometer and an inductively coupled plasma emission spectrometer. The analysed metals are Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, V, and Zn. The analytical results showed the following order of metal abundance; Al > Fe > Zn > Pb > Mn > Cu > V > Ni > Cr > Cd. Based upon their size distribution pattern, the analyzed matals could be clasified into two groups, those present primarily in coarse particle and those in fine particle. Fe, Al, Mn, V, and Cr belong to the former group while the rest to the latter. Most metal concentration were highest in spring or winter, and lowest in autumn. Statistical analysis showed strong correlations between Al and Fe, Pb and Zn, and Cu and Mn.

• Journal of the Korean Vacuum Society
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• v.7 no.3
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• pp.267-267
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• 1998

The fluorine doped silicon oxide (SiOF) intermetal dielectric (IMD) films have been of interest due to their lower dielectric constant and compatibility with existing process tools. However instability issues related to bond and increasing dielectric constant to water absorption when the SiOF films was exposured to atmospheric ambient. Therefore, the purpose of this research is to study the effect of post oxygen plasma treatment on the resistance of moisture absorption and reliability of SiOF film. Improvement of moisture absorption resistance of SiOF film is due to the forming of thin SiO₂layer at the SiOF film surface. It is thought that the main effect of the improvement of moisture absorption resistance was densification of the top layer and reduction in the number of Si-F bonds that tend to associate with OH bonds. However, the dielectric constant was increased when plasma treatment time is above 5 min. In this study, therefore, it is thought that the proper plasma treatment time is 3 min when plasma treatment condition is 700 W of microwave power, 3 mTorr of process pressure and 300℃ of substrate temperature.

• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.213-217
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• 2007

Decomposition of benzene and selectivity of byproducts were investigated by using Dielectric Barrier Discharge (DBD) at atmospheric pressure. In order to increase the decomposition rate and selectivity of byproducts, two types of catalysts, H-ZSM-5 and Na-Y, were optionally employed inside the reactor of the process. The decomposition efficiency of benzene was investigated on the DBD and DBD/catalyst systems at various processing parameters including discharge voltage, residence time, and concentration of benzene. The results showed that, compared with the DBD only, the catalyst-assisted DBD process as a hybrid discharge type had an improved decomposition efficiency at the same process conditions of discharge voltage and residence time

• Korean Journal of Materials Research
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• v.14 no.3
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• pp.218-223
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• 2004

P-type $\beta$-FeSi$_2$ with a nominal composition of $Fe_{0.92}Mn_{0.08}Si_2$ powders has been produced by mechanical alloying process. As-milled powders were spray dried and consolidated by atmospheric plasma thermal spraying as a rapid sintering process. As-milled powders were of metastable state and fully transformed to $\beta$-$FeSi_2$ phase by subsequent isothermal annealing. However, as-thermal sprayed $Fe_{0.92}Mn_{0.08}Si_2$ consisted of untransformed mixture of $\alpha$-$Fe_2Si_{5}$ and $\varepsilon$-FeSi phases. Isothermal annealing has been carried out to induce transformation to the thermoelectric semiconducting $\beta$-$FeSi_2$ phase. Isothermal annealing at $845^{\circ}C$ in vacuum gradually led to the thermoelectric semiconducting $\beta$-$FeSi_2$ phase transformation, but some residual metallic $\alpha$ and $\varepsilon$ phases were unavoidable even after prolonged annealing. Thermoelectric properties of $\beta$-$FeSi_2$ materials before and after isothermal annealing were evaluated. Seebeck coefficient increased and electric conductivity decreased with increasing annealing time due to the phase transition from metallic phases to semiconducting phases. Thermoelectric properties showed gradual increment, but overall properties appeared to be inferior to those of vacuum hot pressed specimens.

• The Bulletin of The Korean Astronomical Society
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• v.43 no.1
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• pp.53.1-53.1
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• 2018

During a major solar eruption, the erupting plasma is possibly out of the equilibrium ionization state because of its rapid heating or cooling. The non-equilibrium ionization process is important in a rapidly evolving system where the thermodynamical time scale is shorter than the ionization or recombination time scales. We investigate the effects of non-equilibrium ionization on EUV and X-ray observations by the Atmospheric Imaging Assembly (AIA) on board Solar Dynamic Observatory and X-ray Telescope (XRT) on board Hinode. For the investigation, first, we find the emissivities for all the lines of ions of elements using CHIANTI 8.07, and then we find the temperature responses multiplying the emissivities by the effective area for each AIA and XRT passband. Second, we obtain the ion fractions using a time-dependent ionization model (Shen et al. 2015), which uses an eigenvalue method, for all the lines of ion, as a function of temperature, and a characteristic time scale, $n_et$, where $n_e$ and t are density and time, respectively. Lastly, the ion fractions are multiplied to the temperature response for each passband, which results in a 2D grid for each combination of temperature and the characteristic time scale. This is the set of passband responses for plasma that is rapidly ionized in a current sheet or a shock. We investigate an observed event which has a relatively large uncertainty in an analysis using a differential emission measure method assuming equilibrium ionization state. We verify whether the observed coronal plasmas are in non-equilibrium or equilibrium ionization state using the passband responses.

• Journal of the Korean Vacuum Society
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• v.17 no.3
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• pp.189-194
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• 2008

Measurements with a Langmuir probe, which are the most often used procedures of plasma diagnostics, can disturb plasma flows and change its characteristics quite a little because the probe should be inserted into thermal flowing plasmas. In this study, we calculated the characteristics of thermal plasmas with and without the probe into an atmospheric argon free-burning arc numerically, and investigated aerodynamic and thermal disturbances with temperature and axial velocity distributions. For the modelling of thermal plasmas, we have made two governing equations, which are on the thermal-flow and electromagnetic fields, coupled together with a commercial CFD package and user-coded subroutines. It was found that thermal disturbances happened to both sides of the probe, before and behind, seriously. Due to the aerodynamic disturbance, we could find that there were the stagnation point in front of the probe and the wake behind it. Therefore, aerodynamic and thermal disturbances caused by the probe insertion should be considered to increase the reliability of the probe diagnostics.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.1
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• pp.74.1-74.1
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• 2014

We have investigated a supra-arcade structure associated with an M1.6 flare, which occurred on the south-east limb in the 4th of November 2010. It is ob- served in extreme ultraviolet (EUV) with the Atmospheric Imaging Assembly (AIA) onboard the Solar Dynamics Observatory (SDO), microwaves at 17 and 34 GHz with the Nobeyama Radioheliograph (NoRH), and soft X-rays of 8-20 keV with the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI). Interestingly, we found exceptional properties of the supra-arcade thermal plasma from the AIA 131 A and the NoRH: 1) plasma upflows along large coronal loops and 2) enhancing microwave emission. RHESSI detected two soft X-ray sources, a broad one in the middle of supra-arcade structure and a bright one just above the flare-arcade. We estimated the number density and thermal energy for these two source regions during the decay phase of the flare. In the supra-arcade source, we found that there were increases of the thermal energy and the density at the early and the last stages, respectively. On the contrary, the density and thermal energy of the source on the top of the flare-arcade decreases throughout. The observed upflows imply that there is continuous energy supply into the supra- arcade structure from below during the decay phase of the flare. It is hard to be explained by the standard flare model in which the energy release site is located high in corona. Thus, we suggest that the potential candidate as the energy source for the hot supra-arcade structure is the flare-arcade which has exhibited a predominant emission throughout.

• Bulletin of the Korean Space Science Society
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• 2010.04a
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• pp.40.4-41
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• 2010

Using magnetic field and plasma moment data obtained by THEMIS satellites(A, D, and E), we selected 203 fast flow events accompanied by dipolarization in the near-Earth region( X(GSM) = -7 ~ -12 RE) and statistically examined their properties. It was found that most of the fast flows show the maximum velocity between 1 minute before dipolarization onset and 2 minutes after onset and proceed earthward and duskward. We also found that only the flows with low velocity of less than 400 km/s are observed at X > -8 RE, while the high velocity flows(as well as low velocity flows) are observed at the further tailward region(X < -8 RE). And most of the tailward flows are slow regardless of distance at X(GSM) = -7 ~ -12 RE. On the other hand, if we consider the fast flow as a bubble (Pontius and Wolf, 1990), the entropy parameter, PV5/3 is an important factor to describe the plasma sheet dynamics. Thus we investigated the relationship between the flow velocity and the amount of change in PV5/3 before and after dipolarization onset and found out that the dipolarizations with more depleted entropy parameter tend to show higher flow velocity. Also we examined how the magnetic field at geosynchronous orbit responds to the fast flow accompanied by dipolarization in the near-earth plasma sheet, using the measurements from GOES 11 and 12 statellites. We found that most of the fast flows do not reach geosynchronous orbit as suggested by Ohtani et al. (2006).

• Applied Chemistry for Engineering
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• v.25 no.5
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• pp.455-462
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• 2014

This work investigated the hydrophobic coating of silicate yellow phosphor powder in the form of divalent europium-activated strontium orthosilicate ($Sr_2SiO_4:Eu^{2+}$) by using an atmospheric pressure dielectric barrier discharge (DBD) plasma with argon as a carrier and hexamethyldisiloxane (HMDSO), toluene and n-hexane as precursors. After the plasma treatment of the phosphor powder, the lattice structure of orthosilicate was not altered, as confirmed by an X-ray diffractometer. The coated phosphor powder was characterized by scanning electron microscopy, fluorescence spectrophotometry and contact angle analysis (CAA). The CAA of the phosphor powder coated with the HMDSO precursor revealed that the water contact angle increased from $21.3^{\circ}$ to $139.5^{\circ}$ (max. $148.7^{\circ}$) and the glycerol contact angle from $55^{\circ}$ to $143.5^{\circ}$ (max. $145.3^{\circ}$) as a result of the hydrophobic coating, which indicated that hydrophobic layers were successfully formed on the phosphor powder surfaces. Further surface characterizations were performed by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometry, which also evidenced the formation of hydrophobic coating layers. The phosphor coated with HMDSO exhibited a photoluminescence (PL) enhancement, but the use of toluene or n-hexane somewhat decreased the PL intensity. The results of this work suggest that the DBD plasma may be a viable method for the preparation of hydrophobic coating layer on phosphor powder.