• Title/Summary/Keyword: Atmospheric Effect

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Strain induced/enhanced ferromagnetism in $Mn_3Ge_2$thinfilms

  • Dung, Dang Duc;Feng, Wuwei;Thiet, Duong Van;Sin, Yu-Ri-Mi;Jo, Seong-Rae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.135-135
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    • 2010
  • In Mn-Ge equilibrium phase diagram, many Mn-Ge intermetallic phases can be formed with difference structures and magnetic properties. The MnGe has the cubic structure and antiferromagnetic(AFM) with Neel temperature of 197 K. The calculation predicted that the $MnGe_2$ with $Al_2Cu$-type is hard to separate between the paramagnetic(PM) states and the AFM states because this compound displays PM and AFM configuration swith similar energy. Mn-doped Ge showed the FM with Currie temperature of 285 K for bulk samples and 116 K for thin films. In addition, the $Mn_5Ge_3$ compound has hexagonal structure and FM with Curie temperature around 296K. The $Mn_{11}Ge_8$ compound has the orthorhombic structure and Tc is low at 274 K and spin flopping transition is near to 140 K. While the bulk $Mn_3Ge_2$ exhibited tetragonal structure ($a=5.745{\AA}$;$c=13.89{\AA}$) with the FM near to 300K and AFM below 150K. However, amorphous $Mn_3Ge_2$ ($a-Mn_3Ge_2$) was reported to show spin glass behavior with spin-glass transition temperature (Tg) of 53 K. In addition, the transition of crystalline $Mn_3Ge_2$ shifts under high pressure. At the atmospheric pressure, $Mn_3Ge_2$ undergoes the magnetic phase transition from AFM to FM at 158 K. The pressure dependence of the phase transition in $Mn_3Ge_2$ has been determined up to 1 GPa. The transition was found to occur at 1 GPa and 155 K with dT/dP=-0.3K/0.1 GPa. Here report that Ferromagnetic $Mn_3Ge_2$ thin films were successfully grown on GaAs(001) and GaSb(001) substrates using molecular beam epitaxy. Our result revealed that the substrate facilitates to modify magnetic and electrical properties due to tensile/compressive strain effect. The spin-flopping transition around 145 K remained for samples grown on GaSb(001) while it completely disappeared for samples grown on GaAs(001). The antiferromagnetism below 145K changed to ferromagnetism and remained upto 327K. The saturation magnetization was found to be 1.32 and $0.23\;{\mu}B/Mn$ at 5 K for samples grown on GaAs(001) and GaSb(001), respectively.

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고강도 및 파괴인성을 갖는 AI-Li-Cu 합금 개발

  • Kim, Song-Hui;Yun, Yeo-Beom;Hwang, Yeong-Hwa;Choe, Chang-U;Hong, Jun-Pyo;Lee, Eung-Jo
    • Korean Journal of Materials Research
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    • v.3 no.3
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    • pp.253-260
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    • 1993
  • High strength and fracture toughness of Al-Li-Cu alloy(2090 Al alloy) have been achieved by the improvement of melting and casting, extrusion and heat treatment techniques. To establish the sucessful process for semi-industrial scale ingot(20Kg) the following areas have been investigated: (1) Improvement of melting and casting techniques for ingot by introducing atmospheric modifications, vacuum and rotary degassing, and deslagging. (2) The effect of heat treatment on mechanical properties (3) Mechanical characterization by tensile test, fracture toughness test and fatigue crack propagation test. High mechanical properties were found to be intimately related with ingot soundness. Tensile strength of final products varied from 534MPa to 566MPa in peak aged condition while elongation/ductility ranged from 9.0% to 11.9%. From the fracture toughness test with using compact tensile specimen, plane strain fracture toughness($K_{Ic}$) appeared to be 39MPa${\surd}$m in peak aged condition and 23MPa${\surd}$ m in underaged condition. When load ratios of 0.1, 0.3 and 0.5 were given ${\Delta}K_{th}$ was 6.0MPa${\surd}$ m, 5.3MPa${\surd}$ m and 4.3MPa${\surd}$ m respectively.

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Influence of Punch Velocity on Gas Hydrogen Embrittlement Behaviors in SA372 Steel (압력용기용 강의 가스수소 취화 거동에 미치는 펀치속도의 영향)

  • Bae, Kyung-Oh;Shin, Hyung-Seop;Baek, Un-Bong;Nahm, Seung-Hoon;Park, Jong-Seo;Lee, Hae-Moo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.12
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    • pp.1497-1502
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    • 2013
  • When using hydrogen gas as an ecofriendly energy sources, it is necessary to conduct a safety assessment and ensure thereliability of the hydrogen pressure vessel against hydrogen embrittlement expected in the steel materials. In this study, by applying the in-situ SP test method, the gas hydrogen embrittlement behaviors in SA372 steel, which is commonly used as a pressurized hydrogen gas storage container, were evaluated. To investigate the hydrogen embrittlement behavior, SP tests at different punch velocities were conducted for specimens with differently fabricated surfaces at atmospheric pressure and under high-pressure hydrogen gas conditions. As a result, the SA372 steel showed significant hydrogen embrittlement under pressurized hydrogen gas conditions. The effect of punch velocity on the hydrogen embrittlement appeared clearly; the lower punch velocity case indicated significant hydrogen embrittlement resulting in lower SP energy. The fractographic morphologies observed after SP test also revealed the hydrogen embrittlement behavior corresponding to the punch velocity adopted. Under this pressurized gas hydrogen test condition, the influence of specimen surface condition on the extent of hydrogen embrittlement could not be determined clearly.

Effects of packaging gas on the quality characteristics of dried persimmons (포장 기체가 곶감의 품질 특성에 미치는 영향)

  • Choi, Ji-Young;Lee, Hyun-Jae;Jang, Jong-Wook;Kwon, Kwang-Woo;Kim, Ji-Soo;Moon, Kwang-Deog
    • Korean Journal of Food Science and Technology
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    • v.50 no.3
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    • pp.316-323
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    • 2018
  • This study aimed to analyze the effect of packaging gas type on the quality characteristics of dried persimmon during a 60-day storage period. The samples were stored at 10 and $-10^{\circ}C$. Experimental samples were either untreated (CON) or packed with carbon dioxide ($CO_2$), nitrogen ($N_2$), or argon (Ar) gases. In terms of the CIE $a^*$ (redness) and $b^*$ (yellowness) values, the least changes were observed in the Ar package. The color difference observed in the $N_2$ package was found to be the highest at $-10^{\circ}C$. Ar and $CO_2$ packages showed the highest and lowest water content, respectively, at $10^{\circ}C$. Sensory evaluation showed a high score for Ar packages. At $10^{\circ}C$, the score of the Ar package was the highest until day 40 and that of the $CO_2$ package was the highest from day 40 to 60. At $-10^{\circ}C$, the score of the Ar package was the highest. These results show that $N_2$- and Ar-modified packaging is the most desirable, thus suggesting its application in actual market.

Improvement of Small Baseline Subset (SBAS) Algorithm for Measuring Time-series Surface Deformations from Differential SAR Interferograms (차분 간섭도로부터 지표변위의 시계열 관측을 위한 개선된 Small Baseline Subset (SBAS) 알고리즘)

  • Jung, Hyung-Sup;Lee, Chang-Wook;Park, Jung-Won;Kim, Ki-Dong;Won, Joong-Sun
    • Korean Journal of Remote Sensing
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    • v.24 no.2
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    • pp.165-177
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    • 2008
  • Small baseline subset (SBAS) algorithm has been recently developed using an appropriate combination of differential interferograms, which are characterized by a small baseline in order to minimize the spatial decorrelation. This algorithm uses the singular value decomposition (SVD) to measure the time-series surface deformation from the differential interferograms which are not temporally connected. And it mitigates the atmospheric effect in the time-series surface deformation by using spatially low-pass and temporally high-pass filter. Nevertheless, it is not easy to correct the phase unwrapping error of each interferogram and to mitigate the time-varying noise component of the surface deformation from this algorithm due to the assumption of the linear surface deformation in the beginning of the observation. In this paper, we present an improved SBAS technique to complement these problems. Our improved SBAS algorithm uses an iterative approach to minimize the phase unwrapping error of each differential interferogram. This algorithm also uses finite difference method to suppress the time-varying noise component of the surface deformation. We tested our improved SBAS algorithm and evaluated its performance using 26 images of ERS-1/2 data and 21 images of RADARSAT-1 fine beam (F5) data at each different locations. Maximum deformation amount of 40cm in the radar line of sight (LOS) was estimated from ERS-l/2 datasets during about 13 years, whereas 3 cm deformation was estimated from RADARSAT-1 ones during about two years.

A Study on the Enhancement of DEM Resolution by Radar Interferometry (레이더 간섭기법을 이용한 수치고도모델 해상도 향상에 관한 연구)

  • Kim Chang-Oh;Kim Sang-Wan;Lee Dong-Cheon;Lee Yong-Wook;Kim Jeong Woo
    • Korean Journal of Remote Sensing
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    • v.21 no.4
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    • pp.287-302
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    • 2005
  • Digital Elevation Models (DEMs) were generated by ERS-l/2 and JERS-1 SAR interferometry in Daejon area, Korea. The quality of the DEM's was evaluated by the Ground Control Points (GCPs) in city area where GCPs were determined by GPS surveys, while in the mountain area with no GCPs, a 1:25,000 digital map was used. In order to minimize errors due to the inaccurate satellite orbit information and the phase unwrapping procedure, a Differential InSAR (DInSAR) was implemented in addition to the traditional InSAR analysis for DEM generation. In addition, DEMs from GTOPO30, SRTM-3, and 1:25,000 digital map were used for assessment the resolution of the DEM generated from DInSAR. 5-6 meters of elevation errors were found in the flat area regardless of the usage and the resolution of DEM, as a result of InSAR analyzing with a pair of ERS tandem and 6 pairs of JERS-1 interferograms. In the mountain area, however, DInSAR with DEMs from SRTM-3 and the digital map was found to be very effective to reduce errors due to phase unwrapping procedure. Also errors due to low signal-to-noise ratio of radar images and atmospheric effect were attenuated in the DEMs generated from the stacking of 6 pairs of JERS-1. SAR interferometry with multiple pairs of SAR interferogram with low resolution DEM can be effectively used to enhance the resolution of DEM in terms of data processing time and cost.

Effects of Urban Greenspace on Microclimate Amelioration, $CO_2$ Sequestration and Eire Obstruction (도시녹지의 미기후개선, $CO_2$흡수 및 화재방지의 효과)

  • ;Yoshiteru Nojima
    • Korean Journal of Plant Resources
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    • v.13 no.3
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    • pp.162-170
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    • 2000
  • This study quantified the effects of urban greenspace on microclimate amelioration and atmospheric $CO_2$ reduction for several residential districts selected in Korea and Japan. The study also explored fire obstruction by urban trees to develop systematic planting guidelines. Transpiration by a Zelkova serrata tree (diameter at breast height: 15 cm) in a day of August equaled cooling effect of about 3 air conditioners running for 12 hours. Average air temperature for the growing season was 0.5$^{\circ}C$ and 1.2$^{\circ}C$ cooler, respectively, in districts with 12% and 22% cover of woody plants than in a district with no vegetation. Annual $CO_2$ uptake and $O_2$ production by woody plants were 3 times greater in a district which was 2 times higher in their cover. Woody plants played, in a district with their 22% cover, an important role through offsetting total $CO_2$ emission from the district by about 3% annually, and through producing 10% of annual $O_2$ requirement by all residents within the district. Appropriate planning strategies of residential greenspace, including species selection, planting layout, greenspace enlargement, and maintenance were suggested to improve microclimate amelioration, air purification, and fire obstruction.

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Mild and Efficient Synthesis of Sodium Dodecanoyl-4-oxybenzenesulfonate using Water and Polar Aprotic Solvent Mixed System and Its Application as a Bleach Activator (물과 극성 비양자성 용매 혼합 계를 이용한 4-도데카노일옥시벤젠술폰산 나트륨의 효율적인 합성 및 표백활성화제로의 응용)

  • Kwak, Sang-Woon;Cha, Kyung-on;Jeong, Kook-In;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.32 no.5
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    • pp.532-540
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    • 2021
  • Sodium dodecanoyl-4-oxybenzenesulfonate (DOBS) salt is a substance that exhibits effective bleaching and antimicrobial abilities at low temperatures. A mild and efficient synthesis method of DOBS starting from dodecanoyl chloride and sodium 4-hydroxybenzene sulfonate was investigated under alkaline conditions using a water (W)-polar aprotic solvent system. First, the reaction was carried out using only water as a solvent system with the variables of temperature and time. The yield was found to be as low as about 5% in most cases under the reaction conditions of more than 30 ℃ and 1 h. In order to develop an efficient solvent system, the effect on the yield of DOBS was evaluated in various solvent systems which were prepared by changing the type of polar aprotic solvents while mixing them with the water. A solvent system in which acetone (AC) and water were mixed showed the best yield and about 82 % under mild reaction conditions (30 ℃, 1 h and atmospheric pressure) was obtained. The prepared DOBS showed good bleaching and antimicrobial activities indicating that it could be used an excellent bleach activator.

A proposal for the classification of Korean taste terms (한국어의 '맛 어휘' 분류 체계)

  • Kim, Hyeong Min
    • 기호학연구
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    • no.56
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    • pp.7-44
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    • 2018
  • The objective of this paper is to propose a classification of Korean taste terms, especially Korean taste adjectives, from the perspective of cognitive science. The classification of Korean taste terms is here grounded in the definition of 'taste sense', 'flavor' and 'taste' which is usually employed in disciplines of cognitive science. There have been a large number of domestic researches in field of taste terms. Accordingly, a lot of research findings on the classification of taste terms have steadily been released showing the differences among researchers. These different classifications are largely based on the fact that researchers have applied their subjective criteria rather than their objective in order to categorize taste terms. According to previous studies, it is well-known that, in everyday usage, the term 'taste' covers a much wider range of qualities than those perceived through the taste receptor cells alone. In addition, we take it for granted that as much as 80~90% of taste comes from olfactory modality. It is also important to note that the texture and temperature of food, the color of food, the sounds of food, and atmospheric cues have an essential effect on taste perception. Many scientists have already pointed out that taste evaluations are influenced by a number of individual and sociocultural factors. Eating and tasting are important parts of our everyday life, so that linguistic approaches to taste perception seem to be of great significance. We can assume that a classification of taste terms from the perspective of cognitive sciences may shed light on the perceptive mechanism through which we perceive taste. It should be noted that this paper is an advanced work prepared for the follow-up study which will try to make a geometric model of word field 'taste terms' existing or probably existing in the mental lexicon of human beings.

Impacts of Local Meteorology caused by Tidal Change in the West Sea on Ozone Distributions in the Seoul Metropolitan Area (서해 조석현상에 따른 국지기상 변화가 수도권 오존농도에 미치는 영향)

  • Kim, Sung Min;Kim, Yoo-Keun;An, Hye Yeon;Kang, Yoon-Hee;Jeong, Ju-Hee
    • Journal of Environmental Science International
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    • v.28 no.3
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    • pp.341-356
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    • 2019
  • In this study, the impacts of local meteorology caused by tidal changes in the West Sea on ozone distributions in the Seoul Metropolitan Area (SMA) were analyzed using a meteorological model (WRF) and an air quality (CMAQ) model. This study was carried out during the day (1200-1800 LST) between August 3 and 9, 2016. The total area of tidal flats along with the tidal changes was calculated to be approximately $912km^2$, based on data provided by the Environmental Geographic Information Service (EGIS) and the Ministry of Oceans and Fisheries (MOF). Modeling was carried out based on three experiments, and the land cover of the tidal flats for each experiment was designed using the coastal wetlands, water bodies (i.e., high tide), and the barren or sparsely vegetated areas (i.e., low tide). The land cover parameters of the coastal wetlands used in this study were improved in the herbaceous wetland of the WRF using updated albedo, roughness length, and soil heat capacity. The results showed that the land cover variation during high tide caused a decrease in temperature (maximum $4.5^{\circ}C$) and planetary boundary layer (PBL) height (maximum 1200 m), and an increase in humidity (maximum 25%) and wind speed (maximum $1.5ms^{-1}$). These meteorological changes increased the ozone concentration (about 5.0 ppb) in the coastal areas including the tidal flats. The increase in the ozone concentration during high tide may be caused by a weak diffusion to the upper layer due to a decrease in the PBL height. The changes in the meteorological variables and ozone concentration during low tide were lesser than those occurring during high tide. This study suggests that the meteorological variations caused by tidal changes have a meaningful effect on the ozone concentration in the SMA.