• Title/Summary/Keyword: Atmospheric Effect

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Stabilization of Heavy Metal and CO2 Sequestration in Industrial Solid Waste Incineration Ash by Accelerated Carbonation (산업폐기물의 가속 탄산화법을 이용한 CO2 고용화 및 중금속 안정화 특성 연구)

  • Jung, Seong-Myung;Nam, Seong-Young;Um, Nam-Il;Seo, Joobeom;Yoo, Kwang-Suk;Ohm, Tae-In;Ahn, Ji-Whan
    • Mineral and Industry
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    • v.26
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    • pp.1-12
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    • 2013
  • In this study, an accelerated carbonation process was applied to stabilize hazardous heavy metals of industrial solid waste incineration (ISWI) bottom ash and fly ash, and to reduce $CO_2$ emissions. The most commonly used method to stabilize heavy metals is accelerated carbonation using a high water-to-solid ratio including oxidation and carbonation reactions as well as neutralization of the pH, dissolution, and precipitation and sorption. This process has been recognized as having a significant effect on the leaching of heavy metals in alkaline materials such as ISWI ash. The accelerated carbonation process with $CO_2$ absorption was investigated to confirm the leaching behavior of heavy metals contained in ISWI ash including fly and bottom ash. Only the temperature of the chamber at atmospheric pressure was varied and the $CO_2$ concentration was kept constant at 99% while the water-to-solid ratio (L/S) was set at 0.3 and $3.0dm^3/kg$. In the result, the concentration of leached heavy metals and pH value decreased with increasing carbonation reaction time whereas the bottom ash showed no effect. The mechanism of heavy metal-stabilization is supported by two findings during the carbonation reaction. First, the carbonation reaction is sufficient to decrease the pH and to form an insoluble heavy metal-material that contributes to a reduction of the leaching. Second, the adsorbent compound in the bottom ash controls the leaching of heavy metals; the calcite formed by the carbonation reaction has high affinity of heavy metals. In addition, approximately 5 kg/ton and 27 kg/ton $CO_2$ were sequestrated in ISWI bottom ash and fly ash after the carbonation reaction, respectively.

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Multiple Albedo Variation Caused by the Shadow Effect of Urban Building and Its Impacts on the Urban Surface Heat Budget (도심 건축물 그림자효과에 의한 다중 반사도 변화와 도시지표면 열수지에 미치는 영향)

  • Lee, Soon-Hwan;Ahn, Ji-Suk;Kim, Sang-Woo;Kim, Hae-Dong
    • Journal of the Korean earth science society
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    • v.31 no.7
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    • pp.738-748
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    • 2010
  • In order to clarify the impact of variation of albedo on the atmospheric boundary layer caused by the density of building in urban areas, both satellite data analysis and numerical experiments were carried out. Utilized satellite data were multi-spectral visible data detected by the Korea Multi- Purpose Satellite -2 (KOMSAT-2), and the numerical models for the estimation of surface heat budget are Albedo Calculation Model (ACM) and Oregon State University Planetary Boundary Layer model (OSUPBL). In satellite data analysis, the estimated albedo in densely populated building area is lower than other regions by 17% at the maximum due to the shadow effect of skyscraper buildings. The surface temperature reached $43.5^{\circ}C$ in the highly dense and tall building area and $37.4^{\circ}C$ in the coarse density area of low buildings, respectively. However, the low albedo in densely integrated building area is not directly related to the increase of surface air temperature since the mechanical turbulence induced by the roughness of buildings is more critical in its impact than the decrease of albedo.

Effect of Green Manure Crop and Biochar on Nitrous Oxide Emission from Red Pepper Field (녹비작물과 바이오숯의 고추 재배지 아산화질소 배출량 저감 효과)

  • Seo, Young-Ho;Kim, Se-Won;Choi, Seung-Chul;Kim, In-Jong;Kim, Kyung-Hi;Kim, Gun-Yeob
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.540-543
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    • 2012
  • Atmospheric nitrous oxide ($N_2O$) level has been increasing at a rate of 0.2~0.3% per year. The rise in $N_2O$ concentration in atmosphere was mainly due to an increased application of nitrogen fertilizers. The objective of the study was to assess the effect of green manure crop and biochar on $N_2O$ emissions from upland crop field. The green manure crop used in the study was hairy vetch and the cultivated crop was red pepper (Capsicum annuum L.). Nitrogen was applied at a rate of $190kg\;ha^{-1}$, standard N fertilization rate for red pepper. Emissions of $N_2O$ from the field were reduced from the plots applied with hairy vetch and biochar by 46.5% and 24.6%, respectively, compared with nitrogen fertilizer treated plots with $N_2O$ emission of $1.14kg\;N_2O-N\;ha^{-1}$. The results from the study imply that green manure crop and biochar can be utilized to reduce greenhouse gas emission from the upland crop field.

Characteristics of Low Dielectric Constant SiOF Thin Films with Post Plasma Treatment Time (플라즈마 후처리 시간에 따른 저유전율 SiOF 박막의 특성)

  • Lee, Seok Hyeong;Park, Jong Wan
    • Journal of the Korean Vacuum Society
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    • v.7 no.3
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    • pp.267-267
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    • 1998
  • The fluorine doped silicon oxide (SiOF) intermetal dielectric (IMD) films have been of interest due to their lower dielectric constant and compatibility with existing process tools. However instability issues related to bond and increasing dielectric constant to water absorption when the SiOF films was exposured to atmospheric ambient. Therefore, the purpose of this research is to study the effect of post oxygen plasma treatment on the resistance of moisture absorption and reliability of SiOF film. Improvement of moisture absorption resistance of SiOF film is due to the forming of thin SiO₂layer at the SiOF film surface. It is thought that the main effect of the improvement of moisture absorption resistance was densification of the top layer and reduction in the number of Si-F bonds that tend to associate with OH bonds. However, the dielectric constant was increased when plasma treatment time is above 5 min. In this study, therefore, it is thought that the proper plasma treatment time is 3 min when plasma treatment condition is 700 W of microwave power, 3 mTorr of process pressure and 300℃ of substrate temperature.

Study on the improvement of prediction model for the railway environmental noise using ISO 9613-2 (ISO 9613-2를 이용한 철도 환경소음 예측 모델 개선에 관한 연구)

  • Jang, Seungho;Koh, Hyo-In;Hong, Jiyoung
    • Journal of Environmental Impact Assessment
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    • v.26 no.1
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    • pp.11-26
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    • 2017
  • Approximate empirical equations obtained by measuring overall noise levels at different distances have been used to evaluate environmental influence of the railway noise though the accurate prediction of noise levels is important. In this paper, a noise prediction model considering the frequency characteristics of noise sources and propagation was suggested to improve the accuracy of noise prediction. The railway noise source was assorted into track, wheel, traction and aerodynamic components and they were characterized with the source strength and speed coefficient at each octave-band frequency. Correction terms for the acoustic roughness and the track/bridge condition were introduced. The sound attenuation from a source to a receiver was calculated taking account of the geometrical divergence, atmospheric absorption, ground effect, diffraction at obstacles and directivity of source by applying ISO 9613-2. For obtaining the source strength and speed coefficients, the results of rolling noise model, numerical analysis and measurements of pass-by noise were analyzed. We compared the predicted and measured noise levels in various vehicles and tracks, and verified the accuracy of the present model. It is found that the present model gives less error than the conventional one, so that it can be applied to make the accurate prediction of railway noise effect and establish its countermeasures efficiently.

Studies on Physical Properties of Pork Frozen by Various High Pressure Freezing Process (초고압 동결 처리 방법에 따른 돈육의 물리적 특성에 관한 연구)

  • Ko, Se-Hee;Hong, Geun-Pyo;Park, Sung-Hee;Choi, Mi-Jung;Min, Sang-Gi
    • Food Science of Animal Resources
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    • v.26 no.4
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    • pp.464-470
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    • 2006
  • This study was carried out to investigate the effect of various high pressure freezing treatments on the physical properties of pork To compare the effect of freezing on meat quality, atmospheric freezing (AF), pressure and freezing (PF), pressure shift freezing (USF) and pressure assisted freezing (PAF) were conducted at pressure of 100 MPa. Water binding properties, shear force and colour were measured as physical properties of pork PAF showed shorter phase transition time than PSF. Although significant increase (p<0.05) in water binding properties was found only at PAF, meat frozen under hydrostatic pressure environment showed improved water binding properties. However, all high pressure freezing treatment caused significantly increased shear force (p<0.05), especially at PF treatment. In color, all high pressure freezing treatments showed significantly higher color parameters (p<0.05) than AF, whilst no significant differences among high pressure freezing treatments were found (p>0.05). Therefore the result indicated that applied hydrostatic pressure improved functional properties of pork with increasing freezing rate and PAF had more potential benefit than PSF at mild pressure range.

Effects of low NaNO2 and NaCl concentrations on Listeria monocytogenes growth in emulsion-type sausage

  • Lee, Jeeyeon;Gwak, Eunji;Lee, Heeyoung;Ha, Jimyeong;Lee, Soomin;Kim, Sejeong;Oh, Mi-Hwa;Park, Beom-Young;Choi, Kyoung-Hee;Yoon, Yohan
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.3
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    • pp.432-438
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    • 2017
  • Objective: The objective of this study was to evaluate the effect of combinations of $NaNO_2$ and NaCl concentrations on Listeria monocytogenes (L. monocytogenes) growth in emulsion-type sausage. Methods: Emulsion-type sausages formulated with different combinations of $NaNO_2$ (0 and 10 ppm) and NaCl (1.00%, 1.25%, and 1.50%) were inoculated with a five-strain L. monocytogenes mixture, and stored at $4^{\circ}C$, $10^{\circ}C$, and $15^{\circ}C$, under aerobic or vacuum conditions. L. monocytogenes cell counts were measured at appropriate intervals, and kinetic parameters such as growth rate and lag phase duration (LPD) were calculated using the modified Gompertz model. Results: Growth rates increased (0.004 to 0.079 Log colony-forming unit [CFU]/g/h) as storage temperature increased, but LPD decreased (445.11 to 8.35 h) as storage temperature and NaCl concentration increased. The effect of combinations of NaCl and low-$NaNO_2$ on L. monocytogenes growth was not observed at $4^{\circ}C$ and $10^{\circ}C$, but it was observed at $15^{\circ}C$, regardless of atmospheric conditions. Conclusion: These results indicate that low concentrations of $NaNO_2$ and NaCl in emulsion-type sausage may not be sufficient to prevent L. monocytogenes growth, regardless of whether they are vacuum-packaged and stored at low temperatures. Therefore, additional techniques are necessary for L. monocytogenes control in the product.

Inter-Annual Variability of Ice Cap in Himalaya (히말라야산맥의 만년설 경년변화 연구)

  • Lee, Chang-Suk;Han, Kyung-Soo;Yeom, Jong-Min;Lee, Ga-Lam;Song, Bong-Guen
    • Journal of the Korean Association of Geographic Information Studies
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    • v.11 no.4
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    • pp.32-40
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    • 2008
  • In this study, we monitor ice cap using calculated NDSI from September to December in 2001, 2003, 2006, 2007 and snow cover area in 2007 decrease by compare with 2001. Global warming is one of the most important issue in this world. Because global-warming is the reason of various meteorological disasters and extreme weather events in these days and snow and glaciers showed that global warming effect most easily. Snow and glaciers play an important role in Earth cooling system because of their high reflectance. The present study has been carried out monitoring ice cap in Himalayas, using MODIS(Moderate Resolution Imaging Spectroradiometer)data. Indicator to monitoring ice cap, NDSI(Normalized Differenced Snow Index) was used in this study. The NDSI is a spectral band ratio that takes advantage of the spectral differences of snow in visible and short-wave infrared domain to detect snow cover area versus non-snow cover area in a scene. This study is quantitative evaluation about effect of global warming for icecap.

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Hydrophobic Coating on Fish Feed Using Dielectric Barrier Discharge Plasma Polymerization (유전체장벽방전 플라즈마 중합을 이용한 양어 사료의 소수성 코팅)

  • Lee, Sang Baek;Hung, Trinhquang;Jo, Jin Oh;Jung, Jun Bum;Im, Tae Heon;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.174-180
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    • 2014
  • A plasma hydrophobic coating on commercial fish feed was conducted to prolong the floating time of feed, thereby enhancing the feed consumption rate and reducing the contamination of water in fish farms. The hydrophobic coating on the fish feed was prepared using an atmospheric-pressure dielectric barrier discharge (DBD) plasma with hexamethyldisiloxane (HMDSO), toluene and n-hexane as the precursors. The effect of the parameters such as input power, precursor type and coating time on the coating performance were examined. The physicochemical properties of the coating layer were analyzed using a Fourier transform infrared (FTIR) spectrometer and a contact angle (CA) analyzer. The water CA increased after the coating preparation, indicating that the surface changed from hydrophilic to hydrophobic. The FTIR characterization revealed that the hydrophobic layer was comprised of functional groups such as $CH_3$, Si-O-Si and Si-C. As a result of the hydrophobic coating, the floating time of the fish feed increased from several seconds to 3 minutes, which suggested that the plasma coating method could be a viable means for practical applications. Compared to the water CA measured as soon as the coating layer was prepared, the 6-day aged sample exhibited a substantial CA increase, confirming the aging effect on the improvement of the hydrophobicity.

Enhancement of Ionospheric Correction Method Based on Multiple Aperture Interferometry (멀티간섭기법에 기반한 이온왜곡 보정기법의 보완)

  • Lee, Won-Jin;Jung, Hyung-Sup;Chae, Sung-Ho;Baek, Wonkyung
    • Korean Journal of Remote Sensing
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    • v.31 no.2
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    • pp.101-110
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    • 2015
  • Synthetic Aperture Radar Interferometry (InSAR) is affected by various noise source such as atmospheric artifact, orbital error, processing noise etc.. Especially, one of the dominant noise source for long-wave SAR system, such as ALOS PALSAR (L-band SAR satellite) is the ionosphere effect because phase delays on radar pulse through the ionosphere are proportional to the radar wavelength. To avoid misinterpret of phase signal in the interferogram, it is necessary to detect and correct ionospheric errors. Recently, a MAI (Multipler Aperture SAR Interferometry) based ionospheric correction method has been proposed and considered one of the effective method to reduce phase errors by ionospheric effect. In this paper, we introduce the MAI-based method for ionospheric correction. Moreover we propose an efficient method that apply the method over non-coherent area using directional filter. Finally, we apply the proposed method to the ALOS PALSAR pairs, which include the west sea coast region in Korea. A polynomial fitting method, which is frequently adopted in InSAR processing, has been applied for the mitigation of phase distortion by the orbital error. However, the interferogram still has low frequency of Sin pattern along the azimuth direction. In contrast, after we applied the proposed method for ionospheric correction, the low frequency pattern is mitigated and the profile results has stable phase variation values within ${\pm}1rad$. Our results show that this method provides a promising way to correct orbital and ionospheric artifact and would be important technique to improve the accuracy and the availability for L-band or P-band systems.