• Journal of Environmental Science International
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• v.18 no.4
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• pp.423-434
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• 2009

In recent years, the urban thermal environment has become worse, such as days on which the temperature goes above $30^{\circ}C$, sultry nights and heat stroke increase, due to the changes in terrestrial cover such as concrete and asphalt and increased anthropogenic heat emission accompanied by artificial structure. The land use type is an important determinant to near-surface air temperature. Due to these reasons we need to understand and improve the urban thermal environment. In this study, the fifth-generation Pennsylvania State University-National Center for Atmospheric Research Mesoscale Model(MMS) was applied to the metropolitan of Daegu area in order to investigate the influence of land cover changes and urban modifications increase of Albedo to the surface energy budget on the simulated near-surface air temperature and wind speed. The single urban category in existing 24-category U.S. Geological survey land cover classification used in MM5 was divided into 6 classes to account for heterogeneity of urban land cover. As a result of the numerical simulation intended for the metropolitan of Daegu assumed the increase of Albedo of roofs, buildings, or roads, the increase of Albedo (Cool scenario)can make decrease radiation effect of surface, so that it caused drops in ambient air temperature from 0.2 to 0.3 on the average during the daylight hours and smaller (or near-zero) decrease during the night. The Sensible heat flux and Wind velocity is decreased. Modeling studies suggest that increased surface albedo in urban area can reduce surface and air temperatures near the ground and affect related meteorological parameters such as winds, surface air temperature and sensible heat flux.

• Geomechanics and Engineering
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• v.12 no.3
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• pp.523-539
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• 2017

Clay soils are typical for their swelling properties upon absorption of water during rains and development of cracks during summer time owing to the profile desorption of water through the inter-connected soil pores by water vapour diffusion leading to evaporation. This type of unstable soil phenomenon by and large poses a serious threat to the strength and stability of structures when rest on such type of soils. Even as lime and cement are extensively used for stabilization of clay soils it has become imperative to find relatively cheaper alternative materials to bring out the desired properties within the clay soil domain. In the present era of catastrophic environmental degradation as a side effect to modernized manufacturing processes, industrialization and urbanization the creative idea would be treating the waste products in a beneficial way for reuse and recycling. Bottom ash and ecosand are construed as a waste product from cement industry. An optimal combination of bottom ash-eco sand can be thought of as a viable alternative to stabilize the clay soils by means of an effective dispersion dynamics associated with the inter connected network of pore spaces. A CATIA model was created and imported to ANSYS Fluent to study the dispersion dynamics. Ion migration from the bottom ash-ecosand pile was facilitated through natural formation of cracks in clay soil subjected to atmospheric conditions. Treated samples collected at different curing days from inner and outer zones at different depths were tested for, plasticity index, Unconfined Compressive Strength (UCS), free swell index, water content, Cation Exchange Capacity (CEC), pH and ion concentration to show the effectiveness of the method in improving the clay soil.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.5
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• pp.589-601
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• 2014

Natural gas hydrate (NGH) is emerging as a new eco-friendly source of energy to replace fossil fuels in the 21st century. It is well known that the Natural Gas Hydrate contains large amount of natural gas about 170 times as much as its volume and it is easy to be stored and transported safely at about $-20^{\circ}C$ under atmospheric pressure due to so called "self-preservation effect". The option of gas transport by gas hydrate pellets carrier has been investigated and developed in various industry and academy. The natural gas hydrate pellet carrier is on major link in a potential gas hydrate process chain, starting with the extraction of natural gas from the reservoir, followed by the production of hydrate pellets and the transportation to an onshore terminal for further processing or marketing. In recent years, Korean project team supported by Korean Government has been working on the development of NGH total systems including novel NGH carrier since 2011. In order to increase the knowledge on the NGH pellet carrier developed and to understand the major hazards that could have significant impact on the safety of the vessel, this paper presents and evaluates the pros and cons of cargo holds, loading and unloading systems through the analysis of current patent technology. Based on the proven and well-known technologies as well as potential measures to mitigate sintering and minimize mechanical stress on the hydrate pellet in the self-preservation state, this study presents the conceptual and basic design for NGH carrier.

• Atmosphere
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• v.18 no.4
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• pp.387-395
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• 2008

The impact of horizontal resolution on a regional climate model was investigated by simulating precipitation over the Korean Peninsula. As a regional climate model, the SNURCM(Seoul National University Regional Climate Model) has 21 sigma layers and includes the NCAR CLM(National Center for Atmospheric Research Community Land Model) for land-surface model, the Grell scheme for cumulus convection, the Simple Ice scheme for explicit moisture, and the MRF(Medium-Range Forecast) scheme for PBL(Planetary Boundary Layer) processing. The SNURCM was performed with 20 km resolution for Korea and 60 km resolution for East Asia during a 20-year period (1980-1999). Although the SNURCM systematically underestimated precipitation over the Korean Peninsula, the increase of model resolution simulated more precipitation in the southern region of the Korean Peninsula, and a more accurate distribution of precipitation by reflecting the effect of topography. The increase of precipitation was produced by more detailed terrain data which has a 10 minute terrain in the 20 km resolution model compared to the 30 minute terrain in the 60 km resolution model. The increase in model resolution and more detailed terrain data played an important role in generating more precipitation over the Korean Peninsula. While the high resolution model with the same terrain data resulted in increasing of precipitation over the Korean Peninsula including the adjoining sea, the difference of the terrain data resolution only influenced the precipitation distribution of the mountainous area by increasing the amount of non-convective rain. In conclusion, the regional climate model (SNURCM) with higher resolution simulated more precipitation over the Korean Peninsula by reducing the systematic underestimation of precipitation over the Korean Peninsula.

• Journal of Power System Engineering
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• v.19 no.6
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• pp.47-53
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• 2015

Korea is the geographic location during the summer, the temperature rising to $35^{\circ}C$ and winter temperature is $-15^{\circ}C$ to reduce the air temperature changes, such as relatively large compared to other countries. This increase or decrease of the harmful exhaust gas discharged from automobile substantially inconvenience a significant impact on the active side of the car engine temperature and exhaust gas reducing device receives a large impact on the atmospheric temperature is regulation to be different. However, domestic vehicle emissions test temperature of $20{\sim}30^{\circ}C$ is it does not reflect this situation the actual test temperature to accurately measure the exhaust gas volume of the vehicle is difficult. In this study, domestic automobile exhaust gas test conditions of a test temperature $20{\sim}30^{\circ}C$ various temperatures, including (35, 25, 0, -7, -15, $-25^{\circ}C$) under the two vehicles (2.0L MPI, 2.4 L GDI) as was discussed with respect to the exhaust gas characteristics of the vehicle according to the ambient temperature gas. As a result, domestic emissions test temperature of $25^{\circ}C$ than average conditions were temperature decreases greenhouse gas emissions and increase overall increased by up to 15 times higher. Air temperature and the engine exhaust gas inconvenience a direct effect on the activation temperature required in the reduction unit is determined to be an increase of emissions and greenhouse gases, and also an increase in the variety of lubricants based lubricating and viscosity reduction, such as the engine oil due to the low temperature of these result It is considered that shows the.

• Proceedings of the KSRS Conference
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• 2007.10a
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• pp.556-559
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• 2007

The Urban Environmental Quality (UEQ) indicates a complex and various parameters resulting from both human and natural factors in an urban area. Vegetation, climate, air quality, and the urban infrastructure may interact to produce effects in an urban area. There are relationships among air pollution, vegetation, and degrading environmental the urban heat island (UHI) effect. This study investigates the application of multi-spectral remote sensing data from the Landsat ETM and TM sensors for the mapping of air quality and UHI intensity in Seoul from 2000 to 2006 in fine resolution (30m) using the emissivity-fusion method. The Haze Optimized Transform (HOT) correction approach has been adopted for atmospheric correction on all bands except thermal band. The general UHI values (${\Delta}(T_{urban}-T_{rural})$) are 8.45 (2000), 9.14 (2001), 8.61 (2002), and $8.41^{\circ}C$ (2006), respectively. Although the UHI values are similar during these years, the spatial coverage of "hot" surface temperature (>$24^{\circ}C$) significantly increased from 2000 to 2006 due to the rapid urban development. Furthermore, high correlations between vegetation index and land surface temperature were achieved with a correlation coefficients of 0.85 (2000), 0.81 (2001), 0.84(2002), and 0.89 (2006), respectively. Air quality is shown to be an important factor in the spatial variation of UEQ. Based on the quantifiable fine resolution satellite image parameters, UEQ can promote the understanding of the complex and dynamic factors controlling urban environment.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.11a
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• pp.232-236
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• 2000

Multi-regression statistical analyses were applied for the water quality data of shallow alluvial ground water (n = 47) collected from the Youngdeok area, in order to quantitatively generalize the natural (non-anthropogenic) causes of regional water quality variation. Seven samples having the high contamination index ( $C_{a}$ > 3) reflect the striong effects by anthropogenic activity. Most of the alluvial groundwaters have acquired their quality primarily due to the dissolution of carbonate minerals. The results of multi-regression analysis show that chlorine is mainly derived from seawater effect. Sulfur isotopic compositions of dissolved sulfur and the S $O_4$/Cl ratio also enable us to discriminate the samples (n = 18) which are affected by atmospheric input of marine aerosol (sea-spray) and also by mixing between freshwater and seawater. Hydrogen and oxygen isotope data of the samples collected lie close to the local meteoric water line obtained from nearby Pohang city but has lower slope (5.45) on the $\delta$D-$^{18}$ O plot, indicating that alluvial groundwater was recharged from infiltrated meteoric water which has undergone some degree of kinetic evaporation. The estimated initial isotopic composition of the recharged water ($\delta$D = -74.8$^{0}$ /$_{00}$, $\delta$$^{18}$ O = -10.8$^{[-1000]}$ /$_{[-1000]}$ ) suggests that the alluvial ground water recharge largely occurs during summer storm events.s.s.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.245-245
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• 2012

Syntheses of oxide supported metal catalysts by wet-chemical routes have been well known for their use in heterogeneous catalysis. However, uniform deposition of metal nanoparticles with controlled size and shape on the support with high reproducibility is still a challenge for catalyst preparation. Among various synthesis methods, arc plasma deposition (APD) of metal nanoparticles or thin films on oxide supports has received great interest recently, due to its high reproducibility and large-scale production, and used for their application in catalysis. In this work, Au and Pt nanoparticles with size of 1-2 nm have been deposited on titania powder by APD. The size of metal nanoparticles was controlled by number of shots of metal deposition and APD conditions. These catalytic materials were characterized by x-ray diffraction (XRD), inductively coupled plasma (ICP-AES), CO-chemisorption and transmission electron microscopy (TEM). Catalytic activity of the materials was measured by CO oxidation using oxygen, as a model reaction, in a micro-flow reactor at atmospheric pressure. We found that Au/$TiO_2$ is reactive, showing 100% conversion at $110^{\circ}C$, while Pt/$TiO_2$ shows 100% conversion at $200^{\circ}C$. High activity of metal nanoparticles suggests that APD can be used for large scale synthesis of active nanocatalysts. We will discuss the effect of the structure and metal-oxide interactions of the catalysts on catalytic activity.

• Applied Chemistry for Engineering
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• v.27 no.6
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• pp.555-564
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• 2016

In recent years, methanol has attracted much attention since it can be cleanly manufactured by the combined use of atmospheric $CO_2$ recycling and water splitting via renewable energy. For the concept of "methanol economy", an active methanol synthesis catalyst should be prepared in a sophisticated manner rather than by empirical optimization approach. Even though Cu/ZnO-based catalysts prepared by coprecipitation are well known and have been extensively investigated even for a century, fundamental understanding on the precipitation chemistry and catalyst nanostructure has recently been achieved due to complexity of the necessary preparation steps such as precipitation, ageing, filtering, washing, drying, calcination and reduction. Herein we review the recent reports regarding the effects of various synthesis variables in each step on the physicochemical properties of materials in precursor, calcined and reduced states. The relationship between these characteristics and the catalytic performance will also be discussed because many variables in each step strongly influence the final catalytic activity, called "chemical memory". All discussion focuses on how to prepare a highly active Cu/ZnO-based catalyst for methanol synthesis. Furthermore, the preparation strategy we deliver here would be utilized for designing other coprecipitation-derived supported metal or metal oxide catalysts.

• Journal of The Korean Society of Grassland and Forage Science
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• v.21 no.2
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• pp.59-66
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• 2001

In order to determine the influence of nitrogen on agronomic characters, forage yield and quality, a Kenaf was cultured on the volcanic ash soil at the Experimental Farm of Cheju national University under the seven levels of nitrogen rates(0, 50, 100, 150, 200, 250kg/ha) from April 25 to Dec. 25, 1999. The plant height increased by increase of nitrogen rate, showing longest 250kg/ha with 286.6cm and shortest at no application plot with 255.7cm. The difference on leaf number, leaf withering number, stem diameter and branches number by nitrogen rate showed a similar tendency to the plant height. Increasing N rate from 0 to 250kg/ha fresh forage yield form 55.8 to 99.8MT/ha, dry matter (DM) yield from 8.8 to 15.8MT/ha, crude protein(CP) yield form 1.2 to 3.1MT/ha, total digestible nutrients (TDN) yield from 3.8 to 8.6MT/ha. However, no significant differences in these yields were found between 200 and 250kg N/ha. Nitrogen uptake increased form 192.9 to 496.2 kg/ha but N use efficiency decreased form 95.0 to 66.6 kg DM$^{a}$ /kg N with increasing from 0 to 250 kg/ha. As N rate increased from 0 to 250kg/ha, leaf and stem out of CP, crude fat (CF), nitrogen free extract (NFE), TDN contents increased from 20.1% to 25.8% and from 9.7% to 12.4%, from 5.6% to 8.1% and from 3.3% to 4.4%, from 36.1% to 40.2% and from 21.9% to 32.4%, from 59.3% to 75.0% and from 32.2% to 38.2%, respectively, while leaf and stem out of crude fiber decreased from 18.5% to 16.7% and from 51.5% to 39.3%. Based on the these findings, the optimum N rate for forage production of kenaf seems to be about 200 kg/ha in atmospheric phenomena and volcanic ash soils of jeju island.