• 제목/요약/키워드: Atmosphere corrosion

검색결과 219건 처리시간 0.026초

Improvement of Cooling Technology through Atmosphere Gas Management

  • Renard, Michel;Dosogne, Edgar;Crutzen, Jean-Pierre;Raick, Jean-Marc;Ma, Jia Ji;Lv, Jun;Ma, Bing Zhi
    • Corrosion Science and Technology
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    • 제8권6호
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    • pp.217-222
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    • 2009
  • The production of advanced high strength steels requires the improvement of cooling technology. The use of high cooling rates allows relatively low levels of expensive alloying additions to ensure sufficient hardenability. In classical annealing and hot-dip galvanizing lines a mixing station is used to provide atmosphere gas containing 3-5% hydrogen and 97-95% nitrogen in the various sections of the furnace, including the rapid cooling section. Heat exchange enhancement in this cooling section can be insured by the increased hydrogen concentration. Drever International developed a patented improvement of cooling technology based on the following features: pure hydrogen gas is injected only in the rapid cooling section whereas the different sections of the furnace are supplied with pure nitrogen gas; the control of flows through atmosphere gas management allows to get high hydrogen concentration in cooling section and low hydrogen content in the other furnace zones. This cooling technology development insures higher cooling rates without additional expensive hydrogen gas consumption and without the use of complex sealing equipments between zones. In addition reduction in electrical energy consumption is obtained. This atmosphere control development can be combined with geometrical design improvements in order to get optimised cooling technology providing high cooling rates as well as reduced strip vibration amplitudes. Extensive validation of theoretical research has been conducted on industrial lines. New lines as well as existing lines, with limited modifications, can be equipped with this new development. Up to now this technology has successfully been implemented on 6 existing and 7 new lines in Europe and Asia.

Corrosion Protection Method of Reinforcing Steel in Concrete by Using Corrosion Inhibitors

  • Bae Su-Ho;Chung Young-Soo;Kim Dae-Ho
    • KCI Concrete Journal
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    • 제14권4호
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    • pp.145-150
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    • 2002
  • Reinforced concrete is inherently a durable composite material. When properly designed for the environment to be exposed and carefully constructed, reinforced concrete is capable of giving maintenance-free performance. However, unintentionally using improper materials such as non-washed sea sand having much salt together with poor controlled quality, or the concrete are placed in highly severe environment such as marine atmosphere, the corrosion of reinforcing steel in concrete becomes one of the most significant concerns of concrete. The purpose of this experimental research is to evaluate the performance of corrosion inhibitors for normal strength and high strength concrete, and to propose desirable measures for controlling corrosion of reinforcing steel in concrete. Test specimens in normal strength and high strength concrete were made with and without corrosion inhibitors. The accelerated corrosion test for reinforcing steel in concrete was adopted in accordance with JCI-SC3, which required the periodic 20 cycles for 140 days. One cycle includes 3 days for the wetting condition of $65^{\circ}C$ and $90\%$ RH, and 4 days for the drying condition of $15^{\circ}C\;and\;60\%$ RH. It was observed from the test that corrosion inhibitors in normal strength concrete and high strength concrete showed excellent corrosion resistance for reinforcing steel in concrete, but the silica fume in high strength concrete was found to have a negligible corrosion resistance if not used with corrosion inhibitors, since the chloride corrosion threshold limit in concrete containing silica fume without corrosion inhibitor was found to be considerably smaller than that of the case with corrosion inhibitor.

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시화호 환경 변화에 따른 강재 표면의 부식특성 변화 (Variation of Corrosion Properties on the Steel Surface by Environmental Changes in Shihwa Lake)

  • 박준무;이승효;우상균;추인엽;이명훈
    • 한국표면공학회지
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    • 제51권5호
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    • pp.316-324
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    • 2018
  • Harsh seawater environment is subdivided into marine atmosphere, splash zone, tidal zone, submerged zone and bottom of sea depending on the exposed part. Since corrosion rate depends on the conditions of the exposed parts, proper protection and maintenance for each parts are essential for long-term use of steel structures in seawater environment. For steel structures which were installed in Shiwha Lake, a special maintenance system is required to guarantee its long-term durability and safety. As the tidal power plant has recently been operated, the salinity has risen due to the rapid influx of seawater upstream into Sihwa Lake and the corrosion tendency of the structure is variable according to the water level fluctuation. In this study, corrosion properties of steel structures under water level fluctuation was evaluated by corrosion rate measurement, visual inspection and natural potential measurement and their durability and life management were discussed in view of the effect of variation in of seawater level fluctuations in Shihwa Lake.

은의 표면 부식 및 변색을 방지하기 위해 설치된 Al 희생양극의 전기화학적 특성에 미치는 황산 농도의 영향 (Effect of concentration of H2SO4 on electrochemical properties of equipped Al sacrificial anode to prevent the corrosion and discolor of silver surface)

  • 신병현;정원섭
    • 한국표면공학회지
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    • 제54권1호
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    • pp.12-17
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    • 2021
  • Among the various precious metals, silver is used in various fields because of its low price than other precious metals. However, the surface of silver remains after rain in the atmosphere containing sulfur ions and chlorine ions, causing silver corrosion and discoloration. Existing documents have developed a anode to prevent corrosion but that are concentrated on secondary batteries. This study tried to prevent corrosion and discoloration of silver by using an Al sacrificial anode. Sulfuric acid decreased the potential of silver and increased the current density at active polarization and OCP. The amount of corrosion of silver with the Al sacrificial anode was reduced from 0.5 % to 6.5%. When silver is used for decoration outside, corrosion and discoloration of silver can be suppressed by installing an Al anode.

4개 모델에 따른 항공기의 대기 부식성 모의 결과 비교 (A Comparison of Four Atmospheric Corrosivity Modeling Results for Aircraft)

  • 우무성;이재원;이지혜;우경진;박종철
    • 한국항공운항학회지
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    • 제31권3호
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    • pp.79-92
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    • 2023
  • Aluminum alloys are important materials in modern aircraft. Aircraft failures due to corrosion are fatal and costly. Thus, information about the atmospheric corrosion of aluminum is helpful for aviation safety. This study employed four corrosion models and 12 environmental variables to improve knowledge of aluminum atmospheric corrosivity: PACER LIME, ICP, ISO CORRAG, and a modified model of CORRAG. This study applied each model on 47 aircraft operating bases in Korea and compared the results. In the results, The risk of corrosion was different for each model. The cause was the difference in environmental variables according to the model. Especially, the effect of ozone, which has recently been increasing, was shown in the results of PACER LIME. These findings suggest that caution is needed when assessing atmospheric corrosion risk as a single model. Furthermore, it means that the application and integration of various models are needed to improve atmospheric corrosion risk assessment.

주조용 Al합금의 내식성에 관한 전기화학적 평가 (An Electrochemical Evaluation on the Corrosion Resistance of a Al Alloy)

  • 윤대현;이명훈;김기준;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • 제29권5호
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    • pp.495-501
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    • 2005
  • Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

Effect of Aluminum and Silicon on Atmospheric Corrosion of Low-alloying Steel under Containing NaHSO3 Wet/dry Environment

  • Chen Xinhua;Dong Junhua;Han Enhou;Ke Wei
    • Corrosion Science and Technology
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    • 제7권6호
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    • pp.315-318
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    • 2008
  • The atmospheric corrosion performance of Al-alloying, Si-alloying and Al-Si-alloying steel were studied by wet/dry cyclic corrosion tests (CCT) at $30^{\circ}C$ and 60% relative humidity (RH). The corrosion electrolyte used for CCT was 0.052 wt% $NaHSO_{3}$ (pH~4) solution. The result of gravimetry demonstrated that Al-Si-bearing steels showed lower corrosion resistance than other rusted steels. But the rusted 0.7%Si-alloying steel showed a better corrosion resistance than rusted mild steel. Polarization curves demonstrated that Al-/Si-alloying and Al-Si-alloying improved the rest potential of steel at the initial stage; and accelerated the cathodic reduction and anodic dissolution after a rust layer formed on the surfaces of steels. XRD results showed that Al-Si-alloying decreased the volume fraction of $Fe_{3}O_{4}$ and $\alpha-FeOOH$. The recycle of acid accelerated the corrosion of steel at the initial stage. After the rust layer formed on the steel, the leak of rust destabilized the rust layer due to the dissolution of compound containing Al (such as $FeAl_{2}O_{4}$, $(Fe,\;Si)_{2}(Fe,\;Al)O_{4}$). Al-Si-alloying is hence not suitable for improving the anti-corrosion resistance of steel in industrial atmosphere.

가선재의 피로수명 예측 (Fatigue Life Prediction for Electric Railway Catenary wires)

  • 김용기;장세기
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2003년도 추계학술대회 논문집(III)
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    • pp.558-567
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    • 2003
  • The catenary wires are damaged by periodic running of train as well as repeated stress. The wires are also degraded by atmosphere corrosion at fields. Corrosion of wires increased surface roughness and deteriorated mechanical properties by providing fatigue crack initiation sited resulting in a bad effect on service life of the wires. Fatigue test of catenary wires performed to estimate service lifetime. Also, simulation to analyze stress on catenary wires was conducted through modelling the finite elements for dynamic behaviors of wires. Fatigue life of catenary wires was estimated with fatigue and simulation tests.

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ACSR 슬리브 개소에서의 송전선 재료특성 검토 (Material characteristic of ACSR due to eccentricity at sleeve point)

  • 강지원;홍동석;장태인;윤형희;이동일;최한열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 A
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    • pp.309-310
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    • 2006
  • The considerations for remaining life of ACSR (Aluminum Stranded Conductors Steel Reinforced) in transmission lines has become gradually important to hold reliability and stability of power supply. The remaining life of ACSR exposed to the atmosphere for a long period may rely on deterioration caused by environmental indices such as atmospheric corrosion, galvanic corrosion, crevice corrosion and fatigue corrosion. This paper deals with material characteristic of ACSR due to eccentricity at sleeve point. Test samples are ACSR 240[$mm^2$] conductors, which are real transmission lines. As a result, it is obvious that ACSR due to eccentricity may lead to mechanical deterioration.

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해안지역 ACSR 가공지선의 기계적 특성 (Tensile Characteristics of ACSR Overhead Lines located in seaside)

  • 장태인;강지원;이동일;장인출
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 하계학술대회 논문집 C
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    • pp.1709-1711
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    • 2001
  • The remaining life of ACSR(Aluminum Conductor Steel Reinforced) wires exposed to the atmosphere for a long period relies on the extent of deterioration caused by environmental factors such as atmospheric corrosion, galvanic corrosion, crevice corrosion and fatigue corrosion. We investigated the tensile characteristics of ACSR wires in a coastal area through several mechanical tests, and analyzed the constituents of them using SEM(scanning electron microscope). Test samples are parts of ACSR 97[$mm^2$] overhead transmission lines in that area. The result shows that ACSR wires exposed to salt may lead to rapid mechanical deterioration.

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