• 제목/요약/키워드: Atmosphere corrosion

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Effect of Tropical Atmosphere on Corrosion of Different Metals

  • Wijesinghe, Sudesh;Zixi, Tan
    • Corrosion Science and Technology
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    • 제16권6호
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    • pp.273-277
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    • 2017
  • Atmospheric corrosion is clearly the most noticeable of all corrosion processes. A tremendous amount of economic losses are caused by atmospheric corrosion. Thus, it is imperative to know the level of atmosphere's aggressiveness or in other words "corrosivity", before designing or planning any corrosion prevention strategy. In Singapore, corrosivity values were not recorded earlier though the process of measurement and recording was prevalent in other countries. With an aim of filling this gap, three test sites were setup at three locations in Singapore to represent marine, industrial and urban atmospheres or their mixtures. Subsequently, corrosivity readings were measured and recorded according to ISO 9223:2012 for the first time in Singapore. Salient atmospheric constituents or parameters like time of wetness (TOW), $Cl^-$, $SO_2$, $NO_2$, $O_3$, and $HNO_3$ were measured at all sites over a period of time to categorize corrosivity of particular atmosphere. The effect of the atmosphere on corrosion of steel, Cu, Al, and Zn has also been investigated and quantified. "Estimated" and "determined" corrosivities were quantified and compared according to ISO 9223 standard. The study data along with final corrosivity measurements will be presented and discussed in the present work.

고강도 7xxx 알루미늄 합금의 응력부식균열에 미치는 부식환경과 응력속도의 영향 (Effect of Corrosion Atmosphere and Strain Rate on the Stress Corrosion Cracking of High Strength 7xxx Aluminum Alloy)

  • 윤여완;김상호
    • 한국표면공학회지
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    • 제41권3호
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    • pp.121-128
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    • 2008
  • High strength 7xxx aluminum alloys have been applied to automotive bump back beam of the some limited model for light weight vehicle. The aluminum bump back beam is manufactured through extrusion, bending and welding. The residual stress given on these processes combines with the corrosive atmosphere on the road spreaded with corrosive chemicals to melt snow to occur the stress corrosion cracking. The composition of commercial 7xxx aluminum has Zn/Mg ratio about 3 and Cu over 2 wt% for better strength and stress corrosion cracking resistivity. But this composition isn't adequate for appling to the automotive bump back beam with high resistance to extrusion and bad weldability. In this study the composition of 7xxx aluminum alloy was modified to high Zn/Mg ratio and low Cu content for better extrusion and weldability. To estimate the resistivity against stress corrosion cracking of this aluminum alloy by slow strain rate test, the corrosion atmosphere and strain rate separate the stress corrosion cracking from conventional corrosion must be investigated. Using 0.6 Mol NaCl solution on slow strain rate test the stress corrosion cracking induced fracture was not observed. By adding 0.3% $H_2O_2$ and 0.6M $Na_2SO_4$ to 1M NaCl solution, the corrosion potential and current density of polarization curve moved to active potential and larger current density, and on the slow strain rate test the fracture energy in solution was lower than that in pre-exposure. These mean the stress corrosion cracking induced fracture can be estimated in this 1M NaCl + 0.3% $H_2O_2$ + 0.6M $Na_2SO_4$ solution. When the strain rate was below $2{\times}10^{-6}$, the stress corrosion cracking induced fracture start to be observed.

제주도 대기환경의 부식성 평가 (Assessment of Atmospheric Corrosivity at Jeju Island)

  • 김귀식;양경조;허철구;송정화
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.253-259
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    • 2004
  • The Jeju Island in Korea is the clean area which the tradition culture is preserved locally well with the nature environment of Heaven's blessing. An air pollution is becoming recently serious problem as the industrial development is proceeded with the urbanization. This study investigates that the atmosphere environment at Jeju area influences on the metal corrosion. A study of the atmosphere corrosion for carbon steel, copper, zinc ana aluminium exposed on five test sites indoors and outdoors. Corrosion results are treated statistically and adjusted to a model previously proposed for carbon steel, copper, zinc and aluminium based on the influence of environmental parameters and main pollutants($SO_2$ and chlorides) on tire atmosphere corrosion of metals. Through this study, we try to set the standards atmosphere corrosion at Jeju Island.

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AISI304L 스테인리스강의 저온 플라즈마 침탄처리 후 질화처리 시 Ar 가스가 표면 경화층에 미치는 영향 (The Influence of Ar Gas in the Nitriding of Low Temperature Plasma Carburized AISI304L Stainless Steel.)

  • 정광호;이인섭
    • 대한금속재료학회지
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    • 제46권3호
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    • pp.125-130
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    • 2008
  • Conventional plasma carburizing or nitriding for austenitic stainless steels results in a degradation of corrosion resistance. However, a low temperature plasma surface treatment can improve surface hardness without deteriorating the corrosion resistance. The 2-step low temperature plasma processes (the combined carburizing and post nitriding) offers the increase of both surface hardness and thickness of hardened layer and corrosion resistance than the individually processed low temperature nitriding and low temperature carburizing techniques. In the present paper, attempts have been made to investigate the influence of the introduction of Ar gas (0~20%) in nitriding atmosphere during low temperature plasma nitriding at $370^{\circ}C$ after low temperature plasma carburizing at $470^{\circ}C$. All treated specimens exhibited the increase of the surface hardness with increasing Ar level in the atmosphere and the surface hardness value reached up to 1050 HV0.1, greater than 750 $HV_{0.1}$ in the carburized state. The expanded austenite phase (${\gamma}_N$) was observed on the most of the treated surfaces. The thickness of the ${\gamma}_N$ layer reached about $7{\mu}m$ for the specimen treated in the nitriding atmosphere containing 20% Ar. In case of 10% Ar containing atmosphere, the corrosion resistance was significantly enhanced than untreated austenitic stainless steels, whilst 20% Ar level in the atmosphere caused to form CrN in the N-enriched layer (${\gamma}_N$), which led to the degradation of corrosion resistance compared with untreated austenitic stainless steels.

산성환경 중에서 구상흑연주철재의 마멸-부식거동에 관한 연구 (The Study on the Wear-Corrosion Behavior of Ductile Cast Iron in the Acidic Environment)

  • 임우조;박동기;윤병두
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 제35회 춘계학술대회
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    • pp.96-102
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    • 2002
  • This paper was studied on the wear-corrosion behavior of ductile cast iron in the acidic environment. In the dry atmosphere and variety of pH solution, wear-corrosion characteristics and friction coefficient of GCD 60 with various sliding speed and distance were investigated. And electrochemical polarization test of GCD 60 was examined in the environment of various pH value. The main results are as following : In the dry atmosphere, boundary friction appears below nearly 5 $kg_{f}$ of contact load, and it is considered that solid friction occurs over nearly 5 $kg_{f}$ of contact load. As pH value becomes low, wear-corrosion loss in the aqueous solution increases. As the corrosion environment is acidified, corrosion potential of GCD 60 becomes noble, polarization resistance becomes low, and corrosion current density increases.

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강심알루미늄연선의 부식특성 (Corrosion Characteristics of Aluminum Conductors Steel Rainforced wires)

  • 김용기;장세기;이덕희
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2002년도 추계학술대회 논문집(II)
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    • pp.981-986
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    • 2002
  • ACSR of the catenary wires is corrosion degradation progressed by the effect of atmospheric pollution. ACSR which consists of galvanized steel stranded aluminum. The inside of Steel Reinforced is hot-dipped zinc coating steel wire and it takes charge of tension. If ACSR is exposed in atmosphere, the galvanic corrosion is occurred because it is contacted with aluminum. It is occurred the chemical reaction rapidly so that the local a defect is also occurred. If the catenary wires are exposed in atmosphere of pollution conditions, it may cause to reduce the mechanical strength by corrosion degradation and may cause to damage the wires by micro cracks. Accordingly, this study presents the effects of mechanical properties through the corrosion of ACSR.

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대기온도에 따른 적외선 열화상 처리기법을 이용한 철근의 부식률 측정 기법 (Non-Destructive Corrosion Measurement Technique of Reinforcing Bars Using Infrared Thermography according to Atmosphere Temperature)

  • 윤주영;백인관;조승호;정란
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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    • pp.233-236
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    • 2006
  • This study presents a technique to quantitatively measure the corrosion level of a reinforcing bar using the infrared thermography system. The temperature-distribution of the concrete surface is monitored and the temperature change of the reinforcing bar is analysed in terms of corrosion level and concrete cover depth. The experimental results indicate that temperature increase of the reinforcing bar is significant when the corrosion level is high, which implies that the quantity of heat is strongly dependent on corrosion level. Also, as the concrete cover depth of the specimen and the atmosphere temperature increase, the temperature variation becomes small.

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The Capacity of Applying Electrical Resistance Probe in Natural Corrosion Tests of Vietnam

  • Pham, Thy San;Le, Thi Hong Lien;Le, Quoc Hung
    • Corrosion Science and Technology
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    • 제2권2호
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    • pp.98-101
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    • 2003
  • The Electrical Resistance Probe of carbon steel and weight loss coupons were exposed in atmosphere and in the lake water of Hanoi. The comparison of data received by two methods after one year exposure was presented. The correspondence of the data of these methods on the exposure time in both environments showed a capacity of using Electrical Resistance Probe in Vietnamese natural corrosion testing of Carbon steel.

해양 및 일반대기환경의 폭로실험에 의한 철근콘크리트구조물 보수재료.공법의 성능평가 및 철근의 부식특성에 관한 연구 (A Study on the Corrosion Properties of Reinforcing bar and Performance Evaluation of Repair Material and Method for Reinforced Concrete Structure by Exposure Experiment under the Coastal and Normal Atmosphere Environment)

  • 남정수;노경민;신승봉;김영선;김규용;김무한
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2006년도 춘계학술논문 발표대회 제6권1호
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    • pp.167-171
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    • 2006
  • In this study, for the establishment of the performance evaluation methods of repair material and method for reinforced concrete structure and the quality control standards of durability recovery method, the quantitative exposure data by exposure experiment under the coastal and normal atmosphere environment is accumulated and analyzed. Investigating and evaluating the result of exposure experiment during 30 months of exposure age under the coastal and normal atmosphere environment, carbonation depth and chlorideion penetration depth very little penetrated than cover depth. It seems reasonable to conclude that main cause of corrosion of reinforcing bar are inner chloride-ion and macro cell from the result of corrosion area and corrosion velocity. Accordingly, it is considered that fundamental data on the performance evaluation and quality control standards of repair material and method could be presented through continuous exposure test in the future.

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Domain Switching and Crack Propagation of $BaTiO_3$ Single Crystal in Different Environments

  • Gao, Kewei;Zhao, Xianwu;Wang, Ruimin;Qiao, Lijie;Chu, Wuyang
    • Corrosion Science and Technology
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    • 제7권6호
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    • pp.307-314
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    • 2008
  • The influence of a moist atmosphere on $90^{\circ}$ domain switching under a sustained electric field, stress corrosion cracking of an indentation crack in water and an aggressive solution, and the relation between penetrating crack propagation and domain switching were studied using $BaTiO_3$ single crystal. The results indicate that enlarging the domain switching zone and crack propagation could be facilitated by a moist atmosphere or an aggressive solution due to the indentation residual stress. A moist atmosphere exerts remarkable influence upon the polarization of $BaTiO_3$ single crystal under a sustained electric field, and the surface energy of the c domain was much lower than that of the a domain. Domain switching ahead of a penetrating indentation crack tip was an essential requirement for crack propagation under constant stress.