• Title/Summary/Keyword: Atmosphere Gas

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The Microstructural Properties Change Owing to the Sintering Condition of T42 High Speed Steel Produced by Powder Injection Molding Process (분말 사출 성형법으로 제조된 T42 고속도 공구강의 소결 조건에 따른 조직 특성 변화)

  • Do, Kyoung-Rok;Choi, Sung-Hyun;Kwon, Young-Sam;Cho, Kwon-Koo;Ahn, In-Shup
    • Journal of Powder Materials
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    • v.17 no.4
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    • pp.312-318
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    • 2010
  • High speed steels (HSS) were used as cutting tools and wear parts, because of high strength, wear resistance, and hardness together with an appreciable toughness and fatigue resistance. Conventional manufacturing process for production of components with HSS was used by casting. The powder metallurgy techniques were currently developed due to second phase segregation of conventional process. The powder injection molding method (PIM) was received attention owing to shape without additional processes. The experimental specimens were manufactured with T42 HSS powders (59 vol%) and polymer (41 vol%). The metal powders were prealloyed water-atomised T42 HSS. The green parts were solvent debinded in normal n-Hexane at $60^{\circ}C$ for 24 hours and thermal debinded at $N_2-H_2$ mixed gas atmosphere for 14 hours. Specimens were sintered in $N_2$, $H_2$ gas atmosphere and vacuum condition between 1200 and $1320^{\circ}C$. In result, polymer degradation temperatures about optimum conditions were found at $250^{\circ}C$ and $480^{\circ}C$. After sintering at $N_2$ gas atmosphere, maximum hardness of 310Hv was observed at $1280^{\circ}C$. Fine and well dispersed carbide were observed at this condition. But relative density was under 90%. When sintering at $H_2$ gas atmosphere, relative density was observed to 94.5% at $1200^{\circ}C$. However, the low hardness was obtained due to decarbonization by hydrogen. In case of sintering at the vacuum of $10^{-5}$ torr at temperature of $1240^{\circ}C$, full density and 550Hv hardness were obtained without precipitation of MC and $M_6C$ in grain boundary.

A study on the black core formation of artificial lightweight aggregates at various sintering atmospheres (인공경량골재의 소성조건이 블랙코어에 미치는 영향)

  • Kim, Yoo-Taek;Ryu, Yu-Gwang;Jang, Chang-Sub;Lee, Ki-Gang;Kang, Seung-Gu;Kim, Jung-Hwan
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.6
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    • pp.318-323
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    • 2009
  • The lightweight aggregates made of bottom ash (70 wt%) and dredged soil (30 wt%) were prepared to investigate the property differences at various sintering atmospheres. The green aggregates were sintered at $1150^{\circ}C$ and $1200^{\circ}C$ with oxidized, neutralized and reduced atmospheres. The aggregates sintered with oxidized atmosphere showed a clear border between shell and black core area. However, the aggregates sintered with a reduced atmosphere showed only black core area in the entire cross-section of the aggregates. The black core area of the aggregates sintered with a neutralized atmosphere increased with increasing $N_2$ gas flow rates. It was determined that the sintering atmosphere was similar to that of rotary kiln when the CO gas flow was 100 cc/min to make a reduced atmosphere in tube furnace. The water absorption rates of both aggregates from tube furnace with reduced atmosphere and rotary kiln were very similar to each other.

Studies on AlF3-(Mg+Sr+Ba)F2-P2O5 Glasses II. Effect of MgF2 Contents (AlF3-(Mg+Sr+Ba)F2-P2O5계 유리에 관한 연구 제2보 : MgF2의 영향)

  • 김정은;이종근
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.277-281
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    • 1987
  • The various contents of MgF2 from 0 to 12.5wt% are studied in the AlF3-(Mg+Sr+Ba)F2-P2O5 system for the effects of various properties in glasses and the atmosphere of melting was controlled by N2 and Ar gas respectively. Density, refractive index, infrared transmission, thermal conductivity and thermal expansion coefficient of glasses are determined. Density, refractive index and thermal conductivity are decreased, micro-hardness and thermal expansion coefficient are increased according to the increasing of MgF2 contents. Infrared transmittance decreases with increasing the MgF2 contents and it slightly dropped by air than N2 and Ar atmosphere. Other properties are not influenced by atmosphere control.

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Preparation of Porous $Al_2O_3$-AIN-Mullite and $Al_2O_3$-AIN-SiC

  • Kim, Byung-Hoon;Na, Yong-Han
    • The Korean Journal of Ceramics
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    • v.1 no.3
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    • pp.147-151
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    • 1995
  • Porous composite of $Al_2O_3$ and AIN based mullite and SiC can be prepared by alumium reaction synthesis and atmosphere controllied sintering in order to improve the durability of a gas filter body. The porous $Al_2O_3$-AIN-mullite, which has a strength of 168 kg/$\textrm{cm}^2$ and porosity of 51.59%, could be obtained by stmospheric firing at $1600^{\circ}C$ and the porous $Al_2O_3$-AIN-SiC with a porosity of 33% and strength of 977 kg/$\textrm{cm}^2$, could also be prepared. The average pore size has been changed from 0.2$\mu\textrm{m}$ in a reduction atmosphere and to 2$\mu\textrm{m}$ in an air atmosphere, respectively.

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Study of atmosphere parameters of the IVV-2M reactor hall

  • M.E. Vasyanovich;M.V. Zhukovsky;E.I. Nazarov;I.M. Russkikh
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.3935-3939
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    • 2023
  • The paper presents the results of a study of radioactive noble gases and from decay products in the atmosphere of the reactor hall of the research nuclear reactor IVV-2M. The distribution of short-lived 88Rb and 138Cs activity by sizes of aerosol particles was measured in the range of 0.5-1000 nm. It is shown that radioactive aerosols are characterized by three main modes with AMTD 2-3 nm, 7-15 nm and 400 nm. About 70% of aerosol activity is due to 88Rb. The equilibrium factor between 88Kr and 88Rb is 0.2 ± 0.1. The total concentration of aerosols particles was measured using an aerosol diffusion spectrometer. The value of unattached fraction of radioactive aerosols in the atmosphere of reactor hall IVV2M was f = 0.15-0.25 at the average total aerosol particles concentration from 20,000 cm3 to 53,000 cm3.

Measurements and Calculation of Injection Mass Rate of LFG for Intake Injection in Spark Ignition Engines (불꽃점화 엔진의 흡기관 분사를 위한 매립지가스 분사량의 측정 및 계산)

  • Kim, Kyoungsu;Choi, Kyungho;Jeon, Wonil;Kim, Bada;Lee, Daeyup
    • Journal of the Korean Institute of Gas
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    • v.25 no.4
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    • pp.36-42
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    • 2021
  • When the landfill gas generated at the landfill site is released into the atmosphere, methane gas with a high global warming potential is emitted, which adversely affects climate change. When methane contained in landfill gas is used as fuel for internal combustion engines and burned to generate electricity, it is emitted into the atmosphere in the form of carbon dioxide, which can contribute to lowering the global warming potential. Therefore, in order to use the landfill gas as fuel for power generation using an internal combustion engine, it is important to increase the thermal efficiency of the engine. Thus, it is necessary to use a fuel supply system in which gas is injected using an electronically controlled injector at an intake port for each cylinder rather than a fuel supply technology using the conventional mixer technology. In order to use the electronically controlled gas injection method, it is important to accurately measure the mass flow rate according to the conditions of using landfill gas. For this, a study was conducted to measure the injection amount and calculate them in order for the intake port gas injection of landfill gas.

Development of a Gas Mixing System for Controlled Atmosphere(CA) Chambers

  • Yun, Hong-Sun;Lee, Hyun-Dong;Lee, Won-Ock;Chung, Hun;Cho, Kwang-Hwan
    • Agricultural and Biosystems Engineering
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    • v.2 no.1
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    • pp.31-36
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    • 2001
  • Based on the viscous flow characteristics of gas through capillary tube, a simple and cheap gas mixing system was developed for controlling gas compositions in CA chambers. The gas flow rate through capillary tube had a linear relationship with pressure, (length)$^{-1}$ and (radius)$^4$ of capillary tube, which agreed well with Hagen-Poiseuille’s law. The relationship between flow rate and combined parameters was described as Q=0.000209724($\pi$ r$^4$P/$\mu$L) and the coefficient of determination was 0.9984. The developed system could control gas concentrations in CA chambers within $\pm$0.3% deviation compared to the preset concentrations. It was possible to predict the required time and required gas flow rate for exchanging the gs in CA chamber to a certain concentration of gas by using the mathematical model developed in this study.

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Electrical Behaviors of SnO2 Thin Films in Hydrogen Atmosphere (수소가스분위기하에서의 SnO2 박막의 전기적 거동)

  • 김광호;박희찬
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.341-348
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    • 1988
  • Thin films of tin-oxide were prepared by chemical vapor deposition technique using the direct of SnCl4. Resistivity and carrier concentration of deposited SnO2 thin film were measured by 4-point probe method and Hall effect measurement. The results showed the remarkable dependence of electrical properties on the deposition temperature. As the deposition temperature increased, resistivity of deposited film initially decreased to a minimum value of ~10-3$\Omega$cm at 50$0^{\circ}C$, and then rapidly increased to ~10$\Omega$cm at $700^{\circ}C$. Electrical conductance of these films was measured in exposure to H2 gas. It was found that gas sensitivity was affected combination of film thickness and intrinsic resistivity of deposited film. Gas sensitivity increased with decrease of film thickness. Fairly high sensitivity to H2 gas was obtained for the film deposited at $700^{\circ}C$. Optimum operation temperature of sensing was 30$0^{\circ}C$ for H2 gas.

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CO Gas Sensing Characterstics and Electrical Properties of $SnO_2-TiO_2$ Composite Ceramics ($SnO_2-TiO_2$ 세라믹 복합체의 일산화탄소 감응특성 및 전기적 성질)

  • 갬태원;최우성;정승우
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.6
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    • pp.453-457
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    • 1998
  • In order to improve CO gas sensitivity, $TiO_2$added $SnO_2$ composite ceramics were prepared. Using XRD and SEM, the phases and micro structures of these ceramics were investigated. The resistances as a function of gas atmosphere were measured by High Voltage Measure/Source Unit. The maximum 100 ppm CO gas sensitivities of $SnO_2-TiO_2$composites were 2.5 times larger than that of pure $SnO_2$ composite and showed the obvious temperature dependence of sensitivities in 500, 100 ppm CO gas atmospheres.

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A properties and the fabrication of ZnO-Si system CO gas sensor with low power consumption (절전형 ZnO-Si계 CO 가스 센서 제작과 그 특성)

  • Yi, S.H.;Hung, H.K.;Kim, J.K.;Chang, B.H.;Sung, Y.K.
    • Proceedings of the KIEE Conference
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    • 1997.11a
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    • pp.324-326
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    • 1997
  • Low power ZnO-Si gas sensor below 500 mW at operating temperature has been fabricated by using micromachining technique. I-V measurement shows the power consumption of 260 mW at $400^{\circ}C$ The sensitivity of the sensor was 45 percent at operating temperature of $350^{\circ}C$(230 mW) with 1,000 ppm CO gas atmosphere. The response and the recovery time found out to be 94 sec and 180 sec, respectively, when CO gas was used. In order to measure the exact temperature of the gas sensing layer, Pt/Cr bilayer-RTD was used in this experiment.

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