• 제목/요약/키워드: AtBI-1

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기계적 합금화법으로 제조된 $Bi_2Te_3$계 열전화합물 분말의 열분석 (Thermal Analysis of $Bi_2Te_3$ Based Thernoelectric Compound Powder Produced by Mechanical Alloying)

  • 김봉서;양준혁;오민욱;박수동;이희웅;박규섭;배동식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.151-152
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    • 2006
  • Bi-Te thermoelectric powder was fabricated by mechanical alloying method for 1 to 10 hours under vacuum in planetary mill. We investigated the properties of mechanically alloyed Bi-Te powder by thermal analysis, X-ray diffractometer and FESEM with EDS Bi-Te raw material was formed to $Bi_2Te_3$ phase at condition over 3.5 hours of mechanical alloying time.

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Microwave Assisted Synthesis of Graphene-Bi2MoO6 Nanocomposite as Sono-Photocatalyst

  • Tang, Jia-Yao;Zhu, Lei;Fan, Jia-Yi;Sun, Chen;Oh, Won-Chun
    • 한국재료학회지
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    • 제32권1호
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    • pp.1-8
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    • 2022
  • In this investigation, Bi2MoO6 deposited graphene nanocomposite (BMG) was synthesized using a simple microwave assisted hydrothermal synthesis method. The synthesized BMG nanocomposite was characterized by X-ray diffraction, transmission electron microscopy, scanning electron microscopy with energy dispersive X-ray analysis, and photocurrent analysis. The study revealed that the catalysts prepared have high crystalline nature, enhanced light responsive property, high catalytic activity, and good stability. XRD results of BMG composite exhibit a koechlinite phase of Bi2MoO6. The surface property is shown by SEM and TEM, which confirmed a homogenous composition in the bulk particles of Bi2MoO6 and nanosheets of graphene. The catalytic behavior was investigated by the decomposition of Rhodamine B as a standard dye. The results exhibit excellent yields of product derivatives at mild conditions under ultrasonic/visible light-medium. Approximately 1.6-times-enhanced sono-photocatalytic activity was observed by introduction of Bi2MoO6 on graphene nanosheet compared with control sample P25 during 50 min test.

Research on Chinese Microblog Sentiment Classification Based on TextCNN-BiLSTM Model

  • Haiqin Tang;Ruirui Zhang
    • Journal of Information Processing Systems
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    • 제19권6호
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    • pp.842-857
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    • 2023
  • Currently, most sentiment classification models on microblogging platforms analyze sentence parts of speech and emoticons without comprehending users' emotional inclinations and grasping moral nuances. This study proposes a hybrid sentiment analysis model. Given the distinct nature of microblog comments, the model employs a combined stop-word list and word2vec for word vectorization. To mitigate local information loss, the TextCNN model, devoid of pooling layers, is employed for local feature extraction, while BiLSTM is utilized for contextual feature extraction in deep learning. Subsequently, microblog comment sentiments are categorized using a classification layer. Given the binary classification task at the output layer and the numerous hidden layers within BiLSTM, the Tanh activation function is adopted in this model. Experimental findings demonstrate that the enhanced TextCNN-BiLSTM model attains a precision of 94.75%. This represents a 1.21%, 1.25%, and 1.25% enhancement in precision, recall, and F1 values, respectively, in comparison to the individual deep learning models TextCNN. Furthermore, it outperforms BiLSTM by 0.78%, 0.9%, and 0.9% in precision, recall, and F1 values.

Photoluminescent and low voltage cathodoluminescent properties of $LaNbO_4$ : X (X = Bi, Eu) phosphors ([ $LaNbO_4$ ] : X (X = Bi, Eu)형광체의 발광 및 저 전압 음극선 발광 특성)

  • 온지원;김유혁
    • 한국결정성장학회지
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    • 제16권1호
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    • pp.32-37
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    • 2006
  • 희토류계 niobates인 $LaNbO_4$(Ln : Y, La, Gd)는 자체 발광형으로 $NbO^{3-}_4$ 이온의 전하 이동에 의한 넓은 띠의 청색 발광 스펙트럼을 410nm에서 나타낸다. 본 연구에서는 새로운 FED용 청색 및 적색 형광체를 개발하기 위하여 $LaNbO_4$ :X (X = Bi, Eu) 형광체를 합성하였으며, $1250^{\circ}C$에서 2시간 소성한 후 $1400^{\circ}C$에서 1시간 소성하였을 때 최대 발광피크를 얻을 수 있었다. 254nm의 여기하에서 $LaNbO_4$ : Bi는 $420\~450nm$ 영역에서 강한 청색 발광 스펙트럼을 나타내며 첨가된 $Bi^{3+}$ 이온 농도가 $1mol\%$일 때 최대 발광세기를 얻었다 $LaNbO_4$ : Eu의 경우는 첨가된 $Eu^{3+}$ 이온 농도가 $10mol\%$일 때 약 610nm에서 최대 적색 발광 스펙트럼을 나타내고 있다. $Eu^{3+}$ 이온 농도가 $10mol\%$ 이하에서는 $415\~460nm$, $530\~560nm$$570\~620nm$ 영역에서 피크가 관측되고 있다. 이들 형광체의 음극선 발광특성은 빛 발광 특성과 유사한 경향을 보였다.

자발 성장법으로 성장된 단결정 Bi 단일 나노선의 정상 자기 저항 특성 (Ordinary Magnetoresistance of an Individual Single-crystalline Bi Nanowire)

  • 심우영;김도헌;이경일;전계진;이우영;장준연;한석희;정원용
    • 한국자기학회지
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    • 제17권4호
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    • pp.166-171
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    • 2007
  • 단결정 Bi단일 나노선의 정상 자기 저항(ordinary magnetoresistance) 특성을 $2{\sim}300K$에서 4 단자법으로 측정하였다. I-V 측정을 통해 전기적 오믹 형성을 확인하였고, 2 K과 300 K에서 비저항이 각각 $1.0{\times}10^{-4}$$8.2{\times}10^{-5}{\Omega}{\cdot}cm$으로 측정되었다. 수직(transverse) 및 수평(longitudinal) 자기저항비(MR ratio)가 110 K와 2 K에서 각각 현재까지 보고된 MR 중 가장 큰 2496%와 -38%으로 관찰되었으며, 이 결과는 자발 성장법으로 성장된 Bi 나노선의 결정성이 매우 우수한 단결정임을 증명한다. simple two band(STB) 모델을 통해 Bi 나노선의 수직 및 수평 정상 자기 저항(OMR) 거동이 온도에 따른 페르미 준위(Fermi level)와 밴드 겹침(band overlap)등의 전자 구조 변화 및 운반자 농도 변화로 잘 설명된다.

Effect of Bi4Zr3O12 on the properties of (KxNa1-x)NbO3 based ceramics

  • Mgbemere, Henry. E.;Akano, Theddeus T.;Schneider, Gerold. A.
    • Advances in materials Research
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    • 제5권2호
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    • pp.93-105
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    • 2016
  • KNN-based ceramics modified with small amounts of $Bi_4Zr_3O_{12}$ (BiZ) has been synthesized using high-throughput experimentation (HTE). The results from X-ray diffraction show that for samples with base composition $(K_{0.5}Na_{0.5})NbO_3$ (KNN), the phase present changes from orthorhombic to pseudo-cubic with more than 0.2 mol% BiZ addition; for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.9}Ta_{0.1})O_3$ (KNNLT), the phase present changes from a mixture of orthorhombic and tetragonal symmetry to pseudo-cubic with more than 0.4 mol % while for samples with base composition $(K_{0.48}Na_{0.48}Li_{0.04})(Nb_{0.86}Ta_{0.1}Sb_{0.04})O_3$ (KNNLST), the phase present is tetragonal with <0.3 mol% BiZ addition and transforms to pseudo-cubic with more dopant addition. The microstructures of the samples show that addition of BiZ decreases the average grain size and increases the volume of pores at the grain boundaries. The values of dielectric constant for KNN and KNNLT compositions increase slightly with BiZ addition while that for KNNLST decreases gradually with BiZ addition. The dielectric loss values are between 0.02 and 0.04 for KNNLT and KNNLST compositions while they are ~ 0.05 for KNN samples. The resistivity values increases with BiZ addition and values in the range of $10^{10}{\Omega}cm$ and $10^{12}{\Omega}cm$ are obtained. The piezoelectric charge coefficient ($d{^*}_{33}$) is highest for KNNLST samples and decreases gradually from ~400 pm/V to ~100 pm/V with BiZ addition.

Magnetoresistance of Bi Nanowires Grown by On-Film Formation of Nanowires for In-situ Self-assembled Interconnection

  • Ham, Jin-Hee;Kang, Joo-Hoon;Noh, Jin-Seo;Lee, Woo-Young
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2010년도 임시총회 및 하계학술연구발표회
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    • pp.79-79
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    • 2010
  • Semimetallic bismuth (Bi) has been extensively investigated over the last decade since it exhibits very intriguing transport properties due to their highly anisotropic Fermi surface, low carrier concentration, long carrier mean free path l, and small effective carrier mass $m^*$. In particular, the great interest in Bi nanowires lies in the development of nanowire fabrication methods and the opportunity for exploring novel low-dimensional phenomena as well as practical application such as thermoelectricity[1]. In this work, we introduce a self-assembled interconnection of nanostructures produced by an on-film formation of nanowires (OFF-ON) method in order to form a highly ohmic Bi nanobridge. A Bi thin film was first deposited on a thermally oxidized Si (100) substrate at a rate of $40\;{\AA}/s$ by radio frequency (RF) sputtering at 300 K. The sputter system was kept in an ultra high vacuum (UHV) of $10^{-6}$ Torr before deposition, and sputtering was performed under an Ar gas pressure of 2m Torr for 180s. For the lateral growth of Bi nanowires, we sputtered a thin Cr (or $SiO_2$) layer on top of the Bi film. The Bi thin films were subsequently put into a custom-made vacuum furnace for thermal annealing to grow Bi nanowires by the OFF-ON method. After thermal annealing, the Bi nanowires cannot be pushed out from the topside of the Bi films due to the Cr (or $SiO_2$) layer. Instead, Bi nanowires grow laterally as a mean s of releasing the compressive stress. We fabricated a self-assembled Bi nanobridge (d=192 nm) device in-situ using OFF-ON through annealing at $250^{\circ}C$ for 10hours. From I-V measurements taken on the Bi nanobridge device, contacts to the nanobridge were found highly ohmic. The quality of the Bi nanobridge was also proved by the high MR of 123% obtained from transverse MR measurements. These results manifest the possibility of self-assembled nanowire interconnection between various nanostructures for a variety of applications and provide a simple device fabrication method to investigate transport properties on nanowires without complex patterning and etching processes.

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볼-밀 시간에 따른 SBN-BTN 세라믹의 강유전 특성 (Ferroelectric properties of SBN-BTN ceramics with variation of the ball-milling time)

  • 이원섭;이성갑;배선기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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    • pp.549-552
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    • 2002
  • $(SrBi_2Nb_2O_9)_{0.5}-(Bi_3TiNbO_9)_{0.5}$ ceramics were fabricated by the mixed-oxide method, and the structural and electrical properties with variation of ball-milling time were investigated. All SBN-BTN specimens showed the typical polycrystalline X-ray diffraction patterns without the presence of the second phase. The SBN-BTN specimen sintered at $1200^{\circ}C$ and ball-milled for 168h showed the average grain size of $16{\mu}m$. The dielectric constant and dielectric loss of the SBN-BTN specimen sintered at $1150^{\circ}C$ and ball-mill for 72h were 225, 0.4% at 1KHz, respectively.

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Bi계 고온초전도 전류 리드의 특성 (Characteristics of Bi-based High $T_c$ Superconducting Current Lead)

  • 백승명;이병성;김영석;곽민환;김상현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.73-76
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    • 1999
  • We have fabricated and tested a Bi-based high temperature superconducting current lead system. Ag sheathed Bi-2223 mono-filament tapes of $I_c=8.4$ A at 77 K under self-field condition were fabricated using powder-in-tube(P1T) method. Multi-layer current leads can be made by stacking of Ag sheathed Bi-2223 mono-filament wires. The critical current of this 10-layer current lead is about 68 A. The contact resistance across the copper-current lead interface has been studied using current-voltage characteristics. At temperature below critical temperature the resistive contribution of the interface to the total contact resistance dominates. We have measured AC transport losses in a current lead at 77 K, 60 Hz by a transport method.

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Characteristics of HTS Tube Depending on Chemical Compositions

  • Jung, Seung-Ho;Jang, Guneik
    • 한국초전도ㆍ저온공학회논문지
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    • 제5권1호
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    • pp.27-30
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    • 2003
  • The Bi2212 based HTS tubes with 4 different compositions, Bi:Sr:Ca:Cu = 2.0:2.0:1.0:2.0, 2.1:2.0:1.0:2.0,2.2:1.8:1.0:2.0 and 2.2:1.8.1.0.2:2 with 10% of SrSO$_4$ were studied. For tube fabrication the optimum range of melt temperatures and preheating temperature and time for mold were 105$0^{\circ}C$~110$0^{\circ}C$ and 55$0^{\circ}C$ for 30min respectively. The mold rotating speed was 1000rpm. Typical tube dimension was 30/24mm in outside/inside diameter and 60mm in length. A tube was annealed at 84$0^{\circ}C$ for 40 hours in oxygen atmosphere. The plate like grains more than 20${\mu}{\textrm}{m}$ were well developed along the rotating direction of mold regardless of initial chemical compositions. The specimen with Bi2212 composition exhibited $T_c$ of 83K while the specimen with other compositions are lower than 60K. The measured $I_c and J_c$ at 77K(B = 0T) in Bi2212 composition were about 80A and 266A/$\textrm{cm}^2$.