• Title/Summary/Keyword: Association constant

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Effects of changing the oxygen partial pressure in cooling after deposition of PZT thin films by reactive sputtering (Reactive sputtering법에 의한 PZT 박막 증착후 냉각시 산소분압의 영향에 관한 연구)

  • 이희수;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.406-414
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    • 1996
  • We studied the phase formation and the effect of electrical properties of PZT thin films with changing the oxygen partial pressure in cooling after deposition of PZT thin film by reactive sputtering method. The roughness of thin film increased with decreasing the oxygen partial pressure in cooling due to the evaporation on the surface ofthin films and the grain size was not changed very much. The hysteresis property of PZT thin film was improved toward having a good squareness with increasing the cooling oxygen partial pressure. We observed the decrease of remanent polarization, retained polarization and coercive field with decreasing the oxygen partial pressure. Dielectric constant decreased gradually and internal bias field increased in the measurement of dielectric constant-voltage property with decreasing cooling oxygen partial pressure. We observed the increase of nonswitched polarization in the measurement of field accelerated retention and the decrease of nonswitched polarization with increasing the bias time.

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Thermal oxidation and oxidation induced stacking faults of tilted angled (100) silicon substrate (저탈각 (100) Si 기판의 열산화 및 적층 결함)

  • 김준우;최두진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.2
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    • pp.185-193
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    • 1996
  • $2.5^{\circ}\;and\;5^{\circ}$ tilted (100) Si wafer were oxidized in dry oxygen, and the differences in thermal oxidation behavior and oxidation induced stacking faults (OSF) between specimens were investigated. Ellipsometer measurements of the oxide thickness produced by oxidation in dry oxygen from 900 to $1200^{\circ}C$ showed that the oxidation rates of the tilted (100) Si were more rapid than those of the (100) Si and the differences between them decreased as the oxidation temperature increased. The activation energies based on the parabolic rate constant, B for (100) Si, $2.5^{\circ}$ off (100) Si and $5^{\circ}$ off (100) Si were 27.3, 25.9, 27.6 kcal/mol and those on the linear rate constant, B/A were 58.6, 56.6, 57.6 kcal/mol, respectively. Also, considerable decrease in the density of oxidation induced stacking faults for the $5^{\circ}$ off (100) Si was observed through optical microscopy after preferentially etching off the oxide layer, and the angle of stacking faults were changed with tilted angles.

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A study on dielectric characteristic of phosphate glass-ceramic for AC-PDP (AC-PDP용 인산염 결정화 유리의 유전적 특성에 관한 연구)

  • Kim, Joon-Hyung;Yon, Seog-Joo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.3
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    • pp.102-107
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    • 2007
  • Dielectric layer of phosphate glass for plasma display panel (PDP) device made by silk screen printing on soda-lime glass. For regulate thermal expansion coefficient (CTE) of between substrate glass and dielectric layer use addition of $Al_2O_3$ and $TiO_2$. The crystallization process of glass-ceramics for dielectric layer have been examined by DTA, XRD some of optical, electrical properties of the dielectric layer were evaluated by UV-spectrometer, dilatometer, impedance analyser. The principal crystalline phase was identified as zinc metaphosphate [$Zn(PO_3)_2$] and zinc pyrophosphate [$Zn_2P_2O_7$]. Reflectance and dielectric constance increased with the addition of $TiO_2$ filler, dielectric constant lower the out side reflectance unchanging of the adding of $Al_2O_3$ filler. Besides CTE was at about $62{\times}10^{-7}/^{\circ}C$.

A Study on Improvement of Ventilation Efficiency of Multi-Stage Slot Hood (외부식 다단형 슬로트 후드의 효율 향상에 관한 연구)

  • Kim, Hyun Seok;Paik, Nam Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.3 no.2
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    • pp.204-212
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    • 1993
  • This study was conducted to evaluate ventilation efficiency of 4-stage slot hood by variation of slot width, flow rate, hood size and baffle size. The slot velocity, control velocity and plenum velocity were related to slot width and the distance between source of contamination and hood. The results obtained from laboratory experiment for local exhaust ventilation systems were as follows ; 1. When slot widths were constant(equally changed) and the velocity was 6-10 m/s, the slot velocity from 1st slot to 4th slot gradually decreased. As the slot width-to-slot length ratio(WLR) decreased, the slot velocity of each stage increased. But if WLR value was less than 0.04, the slot velocity decreased. 2. When slot velocity exceeded 10 m/s with constant slot widths, the slot velocity of each stage was uniform. 3. When the slot velocity was uniform within 10 m/s and the first slot width was 14-20 mm, the slot width ratio between 1st slot and each of three other slots were 1, 1.25, 1.5 and 3.0, respectively. 4. The slot and plenum velocity were uniform when exhaust flow rate changed from 14 to $19m^3/min$ and there were no hood splitter vanes. 5. When the slot velocity at each stage was uniform, the control velocity at site 30 cm away from hood No.2 increased from 0.15-0.30 to 0.25-0.45 m/s and the control distance from 20 to 30 cm(about 1.5 times).

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Effect of Light and Feed Restriction During Rearing on Production Performance of Egg Strain Layers

  • Ahsan-ul-haq, Ahsan-ul-haq;Ahmad, Nazir;Rasool, Shahid;Shah, T.H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.10 no.6
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    • pp.657-664
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    • 1997
  • 432 Babcock ISA white leghorn pullets reared for 8 weeks on a standard managemental conditions were exposed to feed/nutrient and light restrictions from 9 to 20 weeks of age. Four feeding regimes i. e. 100, 85 or 70 percent of the recommended allowance and low energy (2,500 Kcal/kg) low protein (13% CP) ration were fed each in the three light regimes i. e. (A) Natural day light starting from 13.24 hr/day at 8 weeks of age and ending 10.41 hr/day at the end of 20 weeks; (B) Constant 11 hr/day light and (C) starting with 13 hr/day at 8 weeks and decreasing @ 20 min/week till 20 weeks of age. At the age of 20 weeks all the birds were shifted to separate cages under uniform lighting feeding and management. During the 21st week light was increased to 12 hr a day and thereafter with an increase of 30 min per week, increased to 16 hr a day at the age of 29 weeks. From 20 weeks onward till 72 week age, all the birds were offered commercial layer rations ad libitum, prepared according to climatic conditions. The results of the study revealed that birds reared under natural and constant light had higher weights than decreasing light, yet they could not out perform during production period. The effect of feed and nutrient restriction, on the other hand, was found significant during rearing as well as production period. The birds exposed to higher level of feed and those exposed to nutrient restriction were lighter in weight. The 100% fed birds laid their first egg at an early age. However, those reared on 85% of the recommendation excelled all other groups in terms of produced number of eggs, egg mass, hen housed and hen day production and net returns.

PLASMA ALLANTOIN CONCENTRATION IN RESPONSE TO CHANGES IN NUTRITIONAL STATUS OF CALVES

  • Kagiyama, K.;Funaba, M.;Iriki, T.;Abe, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.9 no.2
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    • pp.165-170
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    • 1996
  • Two experiments were conducted to search factor(s) affecting the plasma allantoin concentration in infant calves. In experiment 1, five male Holstein calves aged 1 week were given only milk replacer free from nucleic acids for 28 days Plasma allantoin concentration varied in a reverse proportion to daily amounts of milk replacer, and the concentration when calves received 750 g/d of milk replacer was significantly lower than that when they received 250 g/d. Contrary to plasma allantoin concentration, glomerular filtration rate(GFR) was directly proportional to daily amounts of milk replacer, leading to a constant filtration of allantoin across the glomeruli. Renal handling of allantion was also unaffected by the amount of milk replacer, resulting in the constant urinary excretion of allantoin. These results suggested that GFR, which was affected by the nutritional status, could affect plasma allantoin concentration. In experiment 2, the effect of age-related changes in nutritional status after weaning on GFR was examined in eight calves weaned at 5 weeks of age. The GFR expressed as body weight basis was lower immediately after weaning, but linearly increased up to the 19th week post-weaning. The present results suggested that the changes in GFR in response to nutritional status would be one of the possible causes of atypical plasma allantoin concentration immediately after weaning. We conclude that plasma allantoin concentration would not be a proper estimator of intestinal flow of microbial protein in cattle.

Antimuscarine-like Action of Licorice Alkaloidal Fraction on Intestinal Smooth Muscle -Studies of Alkaloid of Glycyrrhiza glabra L. III- (감초(甘草) Alkaloidal Fraction 의 평활근(平滑筋)에 대(對)한 Acetylcholine 길항작용(拮抗作用) -감초 알카로이드에 관한 연구 (제 3 보)-)

  • Kim, Myung-Suk;Oh, Jin-Sup;Hong, Sa-Ack
    • The Korean Journal of Pharmacology
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    • v.5 no.2
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    • pp.121-127
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    • 1969
  • Antimuscarinic agent like antispasmodic actions of licorice alkaloidal fraction, obtained from the Glycyrrhiza glabra L., was compared with that of atropine quantitatively. For this purpose, the author calculated the kinetic constants and $ED_{50}$ for acetylcholine antagonism by these drugs on rat ileum and guinea-fig ileum longitudinal muscle according to Paton's theoretical equations describing the combination of an antagonist drug with its receptors. The results are as follows. 1. On rat ileum. a) Licorice alkaloidal fraction $K_1$ (association rate constant)=$4.078{\times}10^2\;(s^{-1}\;gm^{-1}\;ml)$ $K_2$ (dissociation rate constant)=$6.986{\times}10^{-4}\;(s^{-1})$ $ED_{50}(K_2/K_1)=1.772{\times}10^{-6}(gm/ml)$ b) Atropine $K_1=5.136{\times}10^6$, $K_2=7.714{\times}10^{-4}$, $ED_{50}=1.408{\times}10^{-10}$ 2. On guinea-pig ileum longitudinal muscle a) Licorice alkaloidal fraction $K_1=1.30{\times}10^2$, $K_2=1.25{\times}10^{-3}$ $ED_{50}=9.58{\times}10^{-6}$ b) Atropine $K_1=5.75{\times}10^6$, $K_2=1.54{\times}10^{-3}$ $ED_{50}=2.68{\times}10^{-10}$ Above results present that 1 r of licorice alkaloidal fraction has equal fotency of acetylcholine antagonism with $8.5{\times}10^{-5}r$ of atropine on rat ileum, $2.8{\times}10^{-5}r$ on guinea-pig ileum longitudinal muscle. This facts suggest that the site and numbers of licorice alkaloid receptors of guinea-pig ileum are different from that of rat ileum. Besides, it also gives a suggestion that licorice alkaloidal fraction may be a partial antagonist on guinea-pig ileum in this experimental conditions.

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Diurnal Variation of Atomospheric Pollutant Concentrations Affected by Development of Windstorms along the Lee Side of Coastal Mountain Area

  • Choi, Hyo
    • International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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    • v.24 no.1
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    • pp.29-45
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    • 1996
  • Before (March 26, 1994) or after the occurrence of a downslope windstorm (March 29), the NO, $NO_2$, and $SO_2$ at the ground level of Kangnung city were monitored with high concentrations in the afternoon, due to a large amount of gases emitted from combustion of motor vehicle and heating apparatus, especially near 1600-1800 LST and 2000-2100 LST, but at night, they had low concentrations, resulting from small consumptions of vehicle and heating fuels. When both moderate westerly synoptic-scale winds flow over Mt. Taegwallyang and easterly meso-scale sea breeze during the day, atmospheric pollutants should be trapped by two different wind systems, resulting in higher concentration at Kangnung city in the afternoon. At night, the association of westerly synoptic wind and land breeze can produce relatively strong winds and the dissipation by the winds cause these low concentrations to lower and lower, as nightime goes on. From March 27 through 28, an enforced localized windstorm could be produced along the lee side of the mountain near Kangnung, generating westerly internal gravity waves with hydraulic jump motions. Sea breeze toward inland appartantly confines to the bottom of the eastern side of the mountain, due to the interruption of eastward violent internal gravity waves. As the windstorm moves down toward the ground, an encountering point of two opposite winds approaches Kangnung, and a great amount of NO and $NO_2$ were removed by the strong surface winds. Thus, their maximum concentrations are found to be near 18 and 20 LST, 17 and 21 LST. In the nighttime, the more developed storm should produce very strong surface winds and the NO and $NO_2$ could be easily dissipated into other place. The $SO_2$ concentration had no maximum value, that is, almost constant one all day long, due to its removal by the strong surface winds. Especially, the CO concentrations were slightly lower during the strom period than both before or after the strom, but they were nearly constant without much changes during the during the daytime and nighttime.

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Interaction of Antihistaminics with Muscarinic Receptor(I) -Action on the cardiac muscarinic receptor- (항(抗) Histamine제(劑)와 Muscarinic Receptor와의 상호작용(相互作用)(I) -심장(心臟) muscarinic receptor에 대한 작용(作用)-)

  • Lee, Shin-Woong;Park, Yeung-Joo;Lee, Jeung-Soo;Ha, Kwang-Won;Jin, Kap-Duck
    • YAKHAK HOEJI
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    • v.32 no.2
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    • pp.101-111
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    • 1988
  • $[^3H]$ Quinuclidinyl benzilate(QNB) binding assays were performed in the dog ventricular sarcolemma fraction enriched approx. 32-fold in sarcolemma compared to the starting homogenate to elucidate the effect of antihistaminics on cardiac muscarinic receptor. Chlorpheniramine(CHP) inhibited specific binding of $[^3H]$QNB and delayed the equilibrium binding. The rate constants at $37^{\circ}C$ for formation and dissociation of the QNB receptor complex were $0.38{\times}10^9\;M^{-1}$ and $1.6{\times}10^{-2}\;min^{-1}$, respectively. The mean value for the dissociation constant from the pairs of the rate constants was 43. 2 pM and this value was similar to the value(44.8pM) determined from Scatchard analysis. CHP decreased association rate constant, indicating increase in $K_D$ value. Decrease in affinity without affecting the binding site concentration$(B_{max})$ for $[^3H]$QNB binding by CHP was also demonstrated by Scatchard analysis. $K_i$ values for $H_i$-blockers that inhibited specific $[^3H]$QNB binding were $0.02{\sim}4.8{\mu}M$. Cimetidine with $K_i$ value of $230{\mu}M$, however, was ineffective in displacing $[^3H]$QNB binding at concentration of $50{\mu}M$. The Hill coefficient for $H_1$-blockers were about one. The results indicate that $H_1$-antihistaminics inhibit $[^3H]$ QNB binding by interaction with myocardiac muscarinic cholinergic receptor and anticholinergic side effects of these drugs are mainly due to this receptor blocking mechanism.

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Preparation of 0.9PMN-0.1PT ceramics by sol-gel process (졸-겔법에 의한 0.9PMN-0.1PT 소결체의 제조)

  • 연석주;김종흠;고태석
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.1
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    • pp.1-6
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    • 2002
  • The preparation of 0.9PMN-0.1PT ceramics by the metal alkoxide method and the effect of excess $Mg(OC_2H_5)_2$, $Pb(CH_3COO)_2{\cdot}3H_2O$ are reported. The excess$ Mg(OC_2H5)_2$ addition signficantly affects the rate of perovskite phase formation in 0.9PMN-0.1PT ceramics. The sample by addition of 5 wt% excess $Mg(OC_2H5)_2$ sintered at $1150^{\circ}C$ for 1 hr obtained perovskite single phase and showed 98% of the theoretical density. The dielectric constant of the pellets sintered at $1150^{\circ}C$ was increased by the addition of 5 wt% excess $Mg(OC_2H_5)_2$ and had a maximum value of 15000 at 1 kHz.