• Title/Summary/Keyword: As(V) ion

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Research and Implementation of Using RF wireless Power Transmission System for Wireless Sensor Nodes Battery-Charging Power Harvesting Module (RF 무선전력전송을 이용한 센서노드 배터리 충전용 전력획득모듈 연구 및 구현)

  • Jung, Won-Jae;Park, Jun-Seok
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.48 no.6
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    • pp.34-42
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    • 2011
  • With the progress of USN technology, fields to which wireless sensor node is applicable are increased under a condition that it holds a lot of problems to solve for betterment. One of the problems which acts as an obstacle to USN industry diffusion is the wireless sensor node battery exchange to their individual life cycle. Exchanging the battery of so many sensor nodes one by one requires a great deal of times and costs. Such problem is against the convenience supply -aim by applying USN technology. In this paper, using RF wireless power transmission system that power transmission / harvesting module from a distance of 5 m and the power of 10 dBm with a current of 1 mA or more for Sensor Nodes in lithium-polymer battery charging system tested and verified.

Characterization of an Endoxylanase Produced by an Isolated Strain of Bacillus sp.

  • Lee, Jay-J.;Hahm, Kyoung-Soo;Lee, Ki-Young;Lee, Sung-Taik
    • Journal of Microbiology and Biotechnology
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    • v.7 no.2
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    • pp.114-120
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    • 1997
  • Microorganisms producing xylanase were screened for the enzymatic production of xylo-oligo saccharides from xylan. One of the bacteria isolated from compost produced an endoxylanase extracellularly. The bacterium was identified as Bacillus sp. according to its taxonomic characteristics examined. Xylanase production reached upto 5 U/ml after 22 h of culture in LB medium at $30^{\circ}C$. The xylanase was purified by ammonium sulfate precipitation and gel filtration. The molecular weight of the xylanase was estimated to be 20,400 by SDS-PAGE. Optimal temperature and pH for the xylanase activity was $60^{\circ}C$ and 6.5, respectively. The enzyme was stable at temperatures upto $40^{\circ}C$ and pH values from 4 to 10. The xylanase was completely inhibited by the addition of 2 mM mercury ion. Apparent $K_m$ and $V_max$ values for oat spelt xylan were 9.2 mg/ml and 1954 U/mg protein, respectively. For birchwood xylan, the values were 6.3 mg/ml and 1009 U/mg protein. The predominant products of the xylan hydrolysis were xylobiose, xylotriose and xylotetraose, indicating that the enzyme is an endoxylanase. Upto $85{\%}$ of the initially added enzyme (2 U/ml) was bound to 50 mg/ml of the insoluble fraction of oat spelt xylan after incubation at $30^{\circ}C$ for 30 min.

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Purification and Characterization of Two Thermostable Proteases from the Thermophilic Fungus Chaetomium thermophilum

  • Li, An-Na;Ding, AI-Yun;Chen, Jing;Liu, Shou-An;Zhang, Ming;Li, Duo-Chuan
    • Journal of Microbiology and Biotechnology
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    • v.17 no.4
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    • pp.624-631
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    • 2007
  • Thermostable protease is very effective to improve the industrial processes in many fields. Two thermostable extracellular proteases from the culture supernatant of the thermophilic fungus Chaetomium thermophilum were purified to homogeneity by tractional ammonium sulfate precipitation, ion-exchange chromatography on DEAE-Sepharose, and Phenyl-Sepharose hydrophobic interaction chromatography. By SDS-PAGE, the molecular mass of the two purified enzymes was estimated to be 33 kDa and 63 kDa, respectively. The two proteases were found to be inhibited by PMSF, but not by iodoacetamide and EDTA. The 33 kDa protease (PRO33) exhibited maximal activity at pH 10.0 and the 63kDa protease (PRO63) at pH5.0. The optimum temperature for the two proteases was $65^{\circ}C$. The PRO33 had a $K_m$ value of 6.6mM and a $V_{max}$ value of $10.31{\mu}mol/l/min$, and PRO63 l7.6mM and $9.08{\mu}mol/l/min$, with casein as substrate. They were thermostable at $60^{\circ}C$. The protease activity of PRO33 and PRO63 remained at 67.2% and 17.31%, respectively, after incubation at $70^{\circ}C$ for 1h. The thermal stability of the two enzymes was significantly enhanced by $Ca^{2+}$. The residual activity of PRO33 and PRO63 at $70^{\circ}C$ after 60min was approximately 88.59% and 39.2%, respectively, when kept in the buffer containing $Ca^{2+}$. These properties make them applicable for many biotechnological purposes.

Purification and Characterization of Two Novel Fibrinolytic Proteases from Mushroom, Fomitella fraxinea

  • Lee Jong-Suk;Baik Hyung-Suk;Park Sang-Shin
    • Journal of Microbiology and Biotechnology
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    • v.16 no.2
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    • pp.264-271
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    • 2006
  • Two fibrinolytic enzymes were purified from the culture supernatant of Fomitella fraxinea mycelia by ion-exchange and gel filtration chromatographies, and were designated as F. fraxenia proteases 1 and 2 (FFP1 and FFP2). The apparent molecular masses of the enzymes were estimated to be 32 kDa and 42 kDa, respectively, by SDS-PAGE and gel filtration chromatography. Both enzymes had the same optimal temperature ($40^{\circ}C$), but different pH optima (10.0 and 5.0 for FFP1 and FFP2, respectively). FFP1 was relatively stable at pH 7.0-9.0 and temperature below $30^{\circ}C$, whereas FFP2 was very stable in the pH range of 4-11 and temperature below $40^{\circ}C$. FFPI activity was completely inhibited by phenylmethylsulfonyl fluoride (PMSF) and aprotinin, indicating that this enzyme is a serine protease. The activity of FFP2 was enhanced by the addition of $CO^{2+}$ and $Zn^{2+}$ and inhibited by $Cu^{2+},\;Ni^{2+}$, and $Hg^{2+}$. Furthermore, FFP2 activity was strongly inhibited by EDTA and 1,10-phenanthroline, implying that the enzyme is a metalloprotease. Both enzymes readily hydrolyzed fibrinogen, preferentially digesting the $A{\alpha}$- and $B{\beta}$-chains of fibrinogen over ${\gamma}$-chain. FFP1 showed broad substrate specificity for synthetic substrates, but FFP2 did not. $K_{m}$ and $V_{max}$ values of FFP1 for a synthetic substrate, N-succinyl-Ala-Ala-Pro-Phe-pNA, were 0.213 mM and 39.68 units/ml, respectively. The first 15 amino acids of the N-terminal sequences of both enzymes were APXXPXGPWGPQRIS and ARPP(G)VDGQ(R,I)SK(L)ETLPE, respectively.

Operating parameters in electrodialysis membrane processes for removal of arsenic in groundwater (지하수내 비소제거를 위한 전기투석 막여과 운전인자 연구)

  • Choi, Su Young;Park, Keun Young;Lee, Seung Ju;Choi, Dan Bi;Park, Ki Young;Kim, Hee Jun;Kweon, Ji Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.4
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    • pp.449-457
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    • 2016
  • In this study, the effectiveness of electrodialysis in removing inorganic arsenic from groundwater was investigated. To evaluate the feasibility of the electrodialysis, operating parameters such as treatment time, feed concentration, applied voltage and superficial velocity were experimentally investigated on arsenic removal. The higher conductivity removal and arsenic removal efficiency were obtained by increasing applied voltages and operation time. An increase of salinity concentrations in arsenic polluted groundwater exerted no effects on the arsenic separation ratios. Arsenic polluted waters were successfully treated with stack voltages of 1.8 ~ 2.4 V/cell-pair to approximately 93.4% of arsenic removal. Increase flow rate in diluate cell gave positive effect to removal rate. However, increase of superficial velocity in the concentrated cell exerted no effects on either the conductivity reduction or on the separation efficiency. Hopefully, this paper will provide direction in selecting appropriate operating conditions of electrodialysis for arsenic removal.

Etching characteristics of gold thin films using inductively coupled Ar/$CF_4/Cl_2$ plasma (Ar/$CF_4/Cl_2$ 유도 결합 플라즈마에 의한 gold 박막의 식각특성)

  • Kim, Nam-Kyu;Chang, Yun-Seong;Kim, Dong-Pyo;Kim, Chang-Il;Chang, Eui-Goo;Lee, Byeong-Ki
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.190-194
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    • 2002
  • In this study, the etching of Au thin films have been performed in an inductively coupled CF4/Cl2/Ar plasma. The etch properties were measured as the CF4 adds from 0 % to 30 % to the Cl2/(Cl2 + Ar) gas mixing ratio of 0.2. Other parameters were fixed at a rf power of 700 W, a dc bias voltage of 150 V, a chamber pressure of 15 mTorr, and a substrate temperature of $30^{\circ}C$. The highest etch rate of the Au thin film was 370 nm/min at a 10 % additive CF4 into Cl2/(Cl2 + Ar) gas mixing ratio of 0.2. The surface reaction of the etched Au thin films was investigated using x-ray photoelectron spectroscopy (XPS) analysis. From x-ray photoelectron spectroscopy (XPS) analysis, the intensities of Au peaks are changed. There is a chemical reaction between Cl and Au. Au-Cl is hard to remove on the surface because of its high melting point and the etching products can be sputtered by Ar ion bombardment. We obtained the cleaned and steep profile.

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Structural and Electrical Properties of Zn-Mn-O System Ceramics for the Application of Temperature Sensors (온도센서로의 응용을 위한 Zn-Mn-O계 세라믹의 구조적, 전기적 특성)

  • Kim, Kyeong-Min;Lee, Sung-Gap;Lee, Dong-Jin;Park, Mi-Ri;Kwon, Min-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.470-475
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    • 2016
  • In this study, $Zn_xMn_{3-x}O_4$ (x=0.95~1.20) specimens were prepared by using a conventional mixed oxide method. All specimens were sintered in air at $1,200^{\circ}C$ for 12 h and cooled at a rate of $2^{\circ}C/min$ to $800^{\circ}C$, subsequently quenching to room temperature. We investigated the structural and electrical properties of $Zn_xMn_{3-x}O_4$ specimens with variation of ZnO amount for the application of NTC thermistors. As results of X-ray diffraction patterns, all specimens showed the formation of a complete solid solution with tetragonal spinel phase. And, the second phase was observed by the solubility limit of Zn ions in $x{\geq}1.10$ composition. The average grain size was increased from $2.72{\mu}m$ to $4.18{\mu}m$ with increasing the compositional ratio of Zn ion from x=0.95 to 1.20, respectively. $Zn_{1.10}Mn_{1.90}O_4$ specimen showed the minimum electrical resistance of $57.5k{\Omega}$ at room temperature and activation energy of 0.392 eV.

EFFECT OF CARBONATE ON THE SOLUBILITY OF NEPTUNIUM IN NATURAL GRANITIC GROUNDWATER

  • Kim, B.Y.;Oh, J.Y.;Baik, M.H.;Yun, J.I.
    • Nuclear Engineering and Technology
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    • v.42 no.5
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    • pp.552-561
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    • 2010
  • This study investigates the solubility of neptunium (Np) in the deep natural groundwater of the Korea Atomic Energy Research Institute Underground Research Tunnel (KURT). According to a Pourbaix diagram (pH-$E_h$ diagram) that was calculated using the geochemical modeling program PHREEQC 2.0, the redox potential and the carbonate ion concentration both control the solubility of neptunium. The carbonate effect becomes pronounced when the total carbonate concentration is higher than $1.5\;{\times}\;10^{-2}$ M at $E_h$ = -200 mV and the pH value is 10. Given the assumption that the solubility-limiting stable solid phase is $Np(OH)_4(am)$ under the reducing condition relevant to KURT, the soluble neptunium concentrations were in the range of $1\;{\times}\;10^{-9}$ M to $3\;{\times}\;10^{-9}$ M under natural groundwater conditions. However, the solubility of neptunium, which was calculated with the formation constants of neptunium complexes selected in an OECD-NEA TDB review, strongly deviates from the value measured in natural groundwater. Thus, it is highly recommended that a prediction of neptunium solubility is based on the formation constants of ternary Np(IV) hydroxo-carbonato complexes, even though the presence of those complexes is deficient in terms of the characterization of neptunium species. Based on a comparison of the measurements and calculations of geochemical modeling, the formation constants for the "upper limit" of the Np(IV) hydroxo-carbonato complexes, namely $Np(OH)_y(CO_3)_z^{4-y-2z}$, were appraised as follows: log $K^{\circ}_{122}\;=\;-3.0{\pm}0.5$ for $Np(OH)_2(CO_3)_2^{2-}$, log $K^{\circ}_{131}\;=\;-5.0{\pm}0.5$ for $Np(OH)_3(CO_3)^-$, and log $K^{\circ}_{141}\;=\;-6.0{\pm}0.5$ for $Np(OH)_4(CO_3)^{2-}$.

White Electroluminescent Device by ZnS: Mn, Cu, Cl Phosphors

  • Kim, Jong-Su;Park, Je-Hong;Lee, Sung-Hun;Kim, Gwang-Chul;Kwon, Ae-Kyung;Park, Hong-Lee
    • Journal of the Semiconductor & Display Technology
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    • v.5 no.3 s.16
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    • pp.1-4
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    • 2006
  • White-light-emitting ZnS:Mn, Cu, Cl phosphors with spherical shape and the size of $20\;{\mu}m$ are successfully synthesized. They have the double phases of cubic and hexagonal structures. They are applied to electroluminescent (EL) devices by silk screen method with the following structure: $electrode/BaTiO_3$ insulator layer ($50{\sim}60\;{\mu}m$)/ ZnS:Mn, Cu, Cl phosphor layer ($30{\sim}50\;{\mu}m$)/ITO glass. The EL devices are driven with the voltage of 100 V and the frequency of 400 Hz. The EL devices show the three emission peaks. The blue and green emission bands are originated from $CICu^{2+}$ transition and $ClCu^+$ transition, respectively. The yellow emission band results from $^4T^6A$ transition of $Mn^{2+}$ ion. As an increase of Cu concentrations, the blue and green emission intensities decrease whereas the yellow emission intensity increases; the quality becomes warm white. It is due to the energy transfer from the blue and green bands to the yellow band.

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Preparation of $Ce_{0.8}Sm_{0.2}O_{x}$ Electrolyte Thin Film for Solid Oxide Fuel Cells by Electrophoretic Deposition (전기영동법을 이용한 고체산화물 연료전지용 $Ce_{0.8}Sm_{0.2}O_{x}$ 전해질 박막 제조)

  • Kim, Dong-Gyu;Song, Min-Wu;Lee, Kyeong-Seop;Kim, Yoen-Su;Kim, Young-Soon;Shin, Hyung-Shik
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.781-785
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    • 2011
  • In this work, a nano-sized samaria-doped ceria(SDC) was prepared by a urea-based hydrothermal method and characterized by XRD, FESEM and TEM. It was observed that the increase in synthesis time and temperature gave rise to crystallity and particles size. Moreover, the synthesised powders had a excellent ion-conductivity(0.1 S/cm at 600~$800^{\circ}C$) which is suitable for electrolyte of intermediate temperature-solid oxide fuel cell(IT-SOFC). Subsequently for use as electrolyte for anode-supported IT-SOFC, we tried to deposit the SDC powder on a porous NiO-SDC substrate by electrophoretic deposition(EPD) method. From the FESEM observation, a compact