• Title/Summary/Keyword: As(V)

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Effect of the Physicochemical Properties of Soil on the Arsenic Bioaccessibility (비소용출에 대한 토양의 물리화학적 특성 영향)

  • Yang, Jae-Kyu;Chang, Yoon-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.7
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    • pp.731-737
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    • 2006
  • Four well-characterized soils collected from A- and B-horizon in the Department of Energy Oak Ridge Reservation in USA, mainly distributed with Inceptisol(Inc) and Ultisol(Ult) soils, were used in this work. The bioaccessibility of arsenic as well as oxidation phenomena of As(III) was investigated with soils spiked with As(III) and As(V) using a physiologically based extraction test(PBET) at pH 1.5 and 1:100 soil to solution ratio. Also effect of aging time on the bioaccessibility of arsenic was investigated over the 6 months. After 48 hours(fresh) contacting As(V) solution with soils, all soils rapidly and strongly sequestrated As(V), especially Ult-B. However, little sequestration was observed after 3-months. When As(III) was spiked on the same soils, a great portion of As(III) was oxidized to As(V) after 48 hrs, especially Inc-A and Ult-A soils, which is strongly related with Mn content in soils. By using As(III)-spiked soils, much reduced bioaccessibility as total arsenic was observed from Inc-B and Ult-B soils over the 6 months aging time compared to that from Inc-A and Ult-A soils. This result can be explained by the continuous sequestration of As(V), produced from oxidation of As(III), onto Inc-B and Ult-B soils having much amount of iron. The trend of As(III) sequestration over six months aging time was quite similar with that of As(V) sequestration.

A study on the features of English as a lingua franca in Asian contexts: Rhythmic features (아시아 상황의 영어 공통어 자질 연구: 리듬 특성)

  • Chung, Hyunsong;Lee, Sang-Ki;Kim, Yoon-Kyu
    • Phonetics and Speech Sciences
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    • v.8 no.2
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    • pp.1-9
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    • 2016
  • This paper investigated the rhythmic features of speakers of English as a lingua franca in Asian contexts. A speech corpus of 150 conversations between speakers of English in Asia with different L1 backgrounds was collected and %V, ${\Delta}V$, VarcoV, and nPVI-V of each speaker were analyzed. It was found that L1 difference of the speakers and the speakers' daily use of English influenced %V, while the speakers' daily use of English influenced ${\Delta}V$. The gender difference of the speakers also affected the rhythm of the utterances in VarcoV. A weak correlation between the two speakers' rhythm in each conversation was also found in %V and ${\Delta}V$. No significant effects were found in nPVI-V. The results revealed that the speakers tended to accommodate the rhythm of their utterance to that of the interlocutors'. Further study on the speaking rate of the speakers is required to overcome some inconsistencies found in the results of the rhythmic metrics used in this study.

Catalytic Performance of V-KIT-6 for the Oxidation of Styrene (스티렌 산화반응에 대한 V-KIT-6의 촉매특성 고찰)

  • Kim, Sang-Yun;Jermy, Balasamy R.;Bineesh, Kanattukara V.;Lim, Dong-Ok;Kim, Kyung-Hoon;Park, Dae-Won
    • Korean Chemical Engineering Research
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    • v.47 no.3
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    • pp.275-280
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    • 2009
  • The direct incorporation of vanadium into the three-dimensional(3-D) cubic Ia3d mesostructure designated as V-KIT-6 was carried out hydrothermally using a Pluronic P123 and n-butanol as the structure-directing mixture, tetraethylorthosilicate(TEOS) as the silica source and $NH_4VO_3$ as the vanadium source. The obtained V-KIT-6 showed a very high specific surface area ${\sim}1,000m^2/g$ with tunable pore diameters in narrow distribution of sizes ~6.0 nm. The coordination and nature of V sites in V-KIT-6 are characterized by $^{51}V$-spin-echo NMR analysis. The calcined V-KIT-6 materials showed excellent catalytic activity in the direct oxidation of styrene using tert-butyl hydroperoxide(TBHP) as an oxidant.

Structural dependences of the extinction in an 1.55 $1.55{\mu}m$ InGaAsP/InGaAsP multiple-quantum-well electro-absorption modulator (1.55 $1.55{\mu}m$ InGaAsP/InGaAsP MQW 광흡수 변조기에서 구조변수가 소광특성에 미치는 영향)

  • 민영선;심종인;어영선
    • Korean Journal of Optics and Photonics
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    • v.12 no.1
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    • pp.40-47
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    • 2001
  • The structural dependence of the performance of an 1.55 $1.55{\mu}m$ InGaAsPIInGaAsP MQW electro-absorption modulator for highspeed digital fiber communication was systematically investigated. The effects of n-doped SCH region length $t_n$ as well as the general structure parameters including quantum well number $N_w$, well-thickness $t_w$, detuning wavelength $\Delta\lambda$, and device length L were thoroughly analyzed. Thereby, a high-pelfoIDlance electro-absorption modulator with device length L of $100{\mu}m$ was successfully designed. The designed structure showed excellent characteristics that have residual loss less than -1.5 dB, operational voltage from 0 V to -2V, and extinction ratios of -2.92 dB at $V_{\alpha}$=-1 V and -10 dB at $V_{\alpha}$=-2V.X>=-2V.

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Adsorption Characteristics of Arsenic using the Recycled Aluminium Oxide (재생 알루미늄 산화물을 이용한 비소 흡착 특성)

  • Min, Kyung-Chul;Kim, Won-Gee;Lee, Seung-Mok;Kim, Keun-Han;Lee, Hee-Yong;Yang, Jae-Kyu;Park, Youn-Jong
    • Journal of Korean Society on Water Environment
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    • v.27 no.4
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    • pp.486-490
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    • 2011
  • As(V) adsorption on aluminum oxide powder which was recycled from industrial wastes containing aluminum hydroxide was evaluated. Aluminum oxide powder in this study was prepared by calcinating aluminum hydroxide wastes at$550^{\circ}C$. Spectroscopic analysis indicated that the aluminum hydroxide wastes were changed to aluminum oxide by calcination. Arsenic adsorption isotherm was conducted with variation of ionic strength and multiple-ion systems using Ca(II) and Cu(II). As(V) removal showed typical anionic adsorption characteristics that the removal efficiency decreased with increasing pH in single As(V) system as well as in binary and ternary system. More than 80% of As(V) at an initial concentration of $5{\times}10^{-5}$ M was removed from aluminum oxide powder in As(V) single system. The effect of ionic strength on As(V) adsorption was negligible, which indicated the strong bonding between aluminum oxide powder and As(V). The removal efficiency of As(V) was higher in a binary system with Cu(II) than in a binary system with Ca(II).

A Study on the Channeling Effect of Ultra Low Energy B, P and As Ion Implant to Form Ultra-Shallow Junction of Semiconductor Device (초미세 접합형성을 위한 극 저 에너지 B, P 및 As 이온주입시 채널링 현상에 관한연구)

  • 강정원;황호정
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.36D no.3
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    • pp.27-33
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    • 1999
  • We have investigated the ultra-low energy B, P, and As ion implantation using upgraded MDRANGE code to study formation of nanometer junction depths. Even at the ultra-low energies simulated in this paper, it was revealed that ion channeling should be carefully considered. It was estimated that ion channelings have much effect on dopant profiles when B ion implant energies were more than 500 eV, P more than 2 keV and As approximately more than 4 keV. When we compared 2-dimensional dopant profiles of 1 keV B with that of tilted one, 2 keV P with tilt, and 5 keV As with tilt, we could find that most channeling cases occurred not lateral directions but depth directions.

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FPGA Implementation and Verification of RISC-V Processor (RISC-V 프로세서의 FPGA 구현 및 검증)

  • Jongbok Lee
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.23 no.5
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    • pp.115-121
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    • 2023
  • RISC-V is an open-source instruction set architecture, and anyone can freely design and implement a RISC-V microprocessor. This paper designes and simulates the RISC-V architecture, synthesizing it in FPGA and verifying it using logic analyzer (ILA). RISC-V core is written in SystemVerilog, which has efficient design and high reusability, and can be used in various application fields. The RISC-V core is implemented as hardware by synthesizing it on the Ultra96-V2 FPGA board using Vivado, and the accuracy and operation of the design are verified through Integrated Logic Analyzer(ILA). As a result of the experiment, it is confirmed that the designed RISC-V core performs the expected operation, and these results can contribute to the design and verification of RISC-V based systems.

Mapping of Work Function in Self-Assembled V2O5 Nanonet Structures

  • Park, Jeong Woo;Kim, Taekyeong
    • Journal of the Korean Chemical Society
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    • v.61 no.1
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    • pp.12-15
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    • 2017
  • We presented a mapping the work function of the vanadium pentoxide ($V_2O_5$) nanonet structures by scanning Kelvin probe microscopy (SKPM). In this measurement, the $V_2O_5$ nanonet was self-assembled via dropping the solution of $V_2O_5$ nanowires (NWs) onto the $SiO_2$ substrate and drying the solvent, resulting in the networks of $V_2O_5$ NWs. We found that the SKPM signal as a surface potential of $V_2O_5$ nanonet is attributed to the contact potential difference (CPD) between the work functions of the metal tip and the $V_2O_5$ nanonet. We generated the histograms of the CPD signals obtained from the SKPM mapping of the $V_2O_5$ nanonet as well as the highly ordered pyrolytic graphite (HOPG) which is used as a reference for the calibration of the SKPM tip. By using the histogram peaks of the CPD signals, we successfully estimated the work function of ~5.1 eV for the $V_2O_5$ nanonet structures. This work provides a possibility of a nanometer-scale imaging of the work function of the various nanostructures and helps to understand the electrical characteristics of the future electronic devices.

Removal of Arsenic(V) from Aqueous Solutions by Using Natural Minerals

  • Mohapatra Debasish;Mishra Debaraj;Chaudhury G. Roy;Das R.P.;Park, Kyung-Ho
    • Resources Recycling
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    • v.15 no.5 s.73
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    • pp.38-46
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    • 2006
  • The removal of arsenic(V) using four different natural minerals were evaluated. Parameters like contact time, pH, adsorbent dosages, and As(V) concentration were optimized. The kinetics of adsorption was observed to be fast and reached equilibrium within 2h. As(V) adsorption on studied minerals was dependent on pH and followed a pseudo-second-order reaction model. For kaolin, maximum adsorption was found at pH 5.0. Whereas, in case of other three minerals, a pH range of 6.0-7.0 was found to be the best for As(V) adsorption. The maximum adsorption capacity (Q) was calculated by fitting Langmuir equation to the adsorption isotherms obtained under a specified condition. From the slope of best fit, the Q values were calculated to be 2.07, 2.15, 1.95 and 0.86 mg As(V)/g of bauxite, wad, iron ore and kaolin, respectively. Desorption of As(V) from loaded materials was dependent on the type of leaching reagents used. Based on the results, it was found that among the studied natural minerals, wad was the best As(V) adsorbent.

SARS-CoV-2 Infection of Airway Epithelial Cells

  • Gwanghui Ryu;Hyun-Woo Shin
    • IMMUNE NETWORK
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    • v.21 no.1
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    • pp.3.1-3.16
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    • 2021
  • Coronavirus disease 2019 caused by severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has been spreading worldwide since its outbreak in December 2019, and World Health Organization declared it as a pandemic on March 11, 2020. SARS-CoV-2 is highly contagious and is transmitted through airway epithelial cells as the first gateway. SARS-CoV-2 is detected by nasopharyngeal or oropharyngeal swab samples, and the viral load is significantly high in the upper respiratory tract. The host cellular receptors in airway epithelial cells, including angiotensin-converting enzyme 2 and transmembrane serine protease 2, have been identified by single-cell RNA sequencing or immunostaining. The expression levels of these molecules vary by type, function, and location of airway epithelial cells, such as ciliated cells, secretory cells, olfactory epithelial cells, and alveolar epithelial cells, as well as differ from host to host depending on age, sex, or comorbid diseases. Infected airway epithelial cells by SARS-CoV-2 in ex vivo experiments produce chemokines and cytokines to recruit inflammatory cells to target organs. Same as other viral infections, IFN signaling is a critical pathway for host defense. Various studies are underway to confirm the pathophysiological mechanisms of SARS-CoV-2 infection. Herein, we review cellular entry, host-viral interactions, immune responses to SARS-CoV-2 in airway epithelial cells. We also discuss therapeutic options related to epithelial immune reactions to SARS-CoV-2.