• Resources Recycling
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• v.27 no.2
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• pp.63-67
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• 2018

Gibbs free energy is a measure of relative stability among substances. Since the nature of the ions in aqueous solution is diverse, their thermodynamic data at extensive experimental conditions is scarce. In this work, the calculation procedure was introduced to obtain the absolute and conventional standard molar enthalpies and entropies of hydration of ions from the standard enthalpies and entropies of formation of hydrated ions. The application of correspondence principle to estimate thermodynamic data at high temperature was explained.

• Advances in environmental research
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• v.5 no.4
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• pp.225-235
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• 2016

Synthesized hydroxyapatite (Hyd) and Fe-hydroxyapatite (Fe-Hyd) composite were used for the removal of Methylene Blue (MB) from aqueous solutions in this study. The effect of adsorbent amount, pH and initial MB concentration were carried out to investigate in the aqueous solution. The kinetic study shows that the MB adsorption process with Hyd or Fe-Hyd follow pseudo-second order kinetic model. Experimental results are well fitted to the Langmuir isotherm model. The maximum adsorption capacities of Hyd and Fe-Hyd were obtained as 2.90 mg/g and 5.64 mg/g for MB according to Langmuir Isotherm models, respectively. Fe-Hyd composite increased the adsorption capacity of Hyd by 1.95 times that Hyd. It is concluded that Fe-Hyd composite is promising and economical adsorbent for MB removal in the aqueous solution.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.9
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• pp.1267-1276
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• 1998

Falling-film evaporation experiments with aqueous lithium bromide (LiBr) solution were performed to investigate the heat transfer characteristics of enhanced copper tubes. Enhanced tubes (a knurled tube, a spirally grooved tube, and a tube coated with $20{\mu}m$ aluminum particles) and a bare tube were selected as test specimens. Averaged evaporation fluxes of water were obtained from horizontal tubes with various film Reynolds numbers, system pressures, LiBr concentrations and degrees of wall superheat. The enhanced performance of steam generation was compared between tubes with varying parameters. The knurled tube geometry showed the most excellent performance among the tubes tested. The specified enhanced tubes were more useful for generating steam on a low grade heat source such as waste heat.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2002.10a
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• pp.58-63
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• 2002

This study has performed rotary bending fatigue testing that smooth specimen using SM45C materials and notched specimen whose radii were R6, R4 and R2, were processed in 3% NaCl aqueous solutions or in the air. The results are as followed; 1. In the air fatigue limit at 10$^{7}$ cycles remarkably reduced as notch radius goes small. 2. In 3% NaCl aqueous solution fatigue strength at 10$^{6}$ cycles also had large range of reduction as notch radius goes small. 3. Comparing fatigue strength in the air, fatigue strength at 10$^{6}$ cycles in 3% NaCl aqueous solution reduced by 46.2% at smooth specimen, 55.3% at R6 notch radius, 45.8% at R4 and 39.7% at R2 respectively. 4. The reason that fatigue strength reduced in the reduction of notch radius sire was because the surface of notch exposed in corrosion was small and consequently it was less corroded.

• Archives of Pharmacal Research
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• v.20 no.3
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• pp.269-274
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• 1997

Solubilities of oleanolic acid and ursolic acid in aqueous surfactant solutions, liquid polyethylene glycols (PEG), and solvents of various polarity were measured. The results showed that the solutes were slightly or moderately solubilized in the surfactant solutions and the liquid PEGS. It was also revealed that the solutes were slightly soluble in the solvent of either extreme polarity or nonpolarity, but moderately soluble in solvents of intermediate polarity of which solubility parameters are around 10. The solubility parameters of these solutes were calculated from the group contribution to be 10.2 for both of them. Of the solvents tested, tetramethylurea was exceptionally effective in solubilizing the solutes. The solutes were also moderately soluble in the aqueous cosolvents containing tetramethylurea. This suggests that the mixed systems of tetramethylurea could be employed for the solubilization in the formulation of these compounds as an aqueous system.

• Proceedings of the SCSK Conference
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• 2003.09b
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• pp.280-285
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• 2003

The cosmetic industry associated L-ascorbic acid (LAA) or not with its salts and esters, to be employed for fighting the cutaneous aging process. In large part, in the segment of cosmetics, the salts and esters of the LAA alone are employed more frequently than the pure LAA, since the former are chemically more stable, but result in less effective products. The present work refers to a process for stabilizing LAA in an aqueous medium, which includes the step of placed the LAA in contact with Polyvinylalcohol (PVA) through weak force like Van der Waals interaction. The PVA provides stability for LAA aqueous solution, which is stable for 106 days with a LAA content decrease only of 10% w/v.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.13 no.12
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• pp.1275-1281
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• 2001

Aqueous polymer solutions are known to have small pressure reduction. Paraffin slurries are known to have high thermal capacity. Paraffin particles are mixed into an aqueous polymer solution to make a new heat transfer fluid having high thermal capacity but low pressure reduction. The heat transfer characteristics of the new slurry was tested in a circular tube having a constant heat transfer boundary condition. The new slurry was found to have high Nusselt numbers as well as high thermal capacity and low pressure reduction in the laminar flow. The trends of the Nusselt numbers along the heating test section were studied for various heating conditions.

• Plant Resources
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• v.8 no.2
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• pp.116-121
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• 2005

Compositae plants are known to contain biologically active substances that are allelopathic to agricultural crops as well as weed species. Aqueous or methanol extracts and plant residues from leaves of Xanthium occidentale were assayed against alfalfa (Medicago sativa) to determine its allelopathic effects, and the results showed that the extracts applied onto filter paper significantly inhibited seed germination as well as root growth of alfalfa. Aqueous leaf extracts of $40g\;L^{-1}$ were completely inhibitory on root growth of alfalfa, while root growths of barley (Hordeum vulgare L.) and soybean (Glycine max L.) were less sensitive. Leaf residue incorporation at $100g\;kg^{-1}$ into soil on seedling growth of barnyard grass (Echinochloa crus-galli Beauv. var. oryzicola Ohwi) inhibited both shoot and root fresh weights of barnyard grass by 94 and $96\%$, respectively. Methanol extracts from BuOn and EtOAc fractions of X. occidentale reduced alfalfa root growth more than did those from hexane and water fractions. The results based on bioassay of extracts and residues show that X. occidentale had potent an allelopathic activity against other plant species.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06b
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• pp.129-153
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• 1996

In aqueous slurry processing of silicon nitride, the interaction of dispersant and binder on the surface of particles was studied to identify the effect of these additives on ceramic powder processing. Polymethacrylic acid (PMAA) and polyvinyl alcohol (PVA) were used as dispersant and binder, respectively. the adsorption isotherms of PMAA and PVA for the silicon nitride suspension were determined, while the adsorption of PMAA was differentiated in the mixed additive system by ultraviolet spectroscopy. These experiments were done in order to investigate the effect of these organic additives on the physicochemical properties of silicon nitride suspensions. The electrokinetic behavior of silicon nitride was subsequently measured by electrokinetic sonic amplitude (ESA). As PMAA adsorbed onto silicon nitride, the isoelectric point (pHicp) shifted from pH=6.7 to acidic pH, depending on the surface coverage of PMAA. However, adsorption of PVA did not change the pHicp of suspensions, but did decrease the surface potential of silicon nitride moderately. The rheological behavior of silicon nitride suspensions was measured to assess the stability of particles in aqueous media, and was correlated with the electrokinetic behavior and adsorption isotherm data for silicon nitride.

• Bulletin of the Korean Chemical Society
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• v.30 no.1
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• pp.53-56
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• 2009

At room-temperature, a facile, seedless, and environmentally benign green route for the synthesis of star like PbS nanoclusters at 7 min in aqueous solution of 1-ethyl-3-methylimidazolium ethyl sulfate, [EMIM] [$EtSO_{4}$], room-temperature ionic liquid (RTIL), via ultrasonic irradiation is proposed. The X-ray diffraction studies display that the products are excellently crystallized in the form of cubic structure. An energy dispersive X-ray spectroscopy (EDX) investigation reveals the products are extremely pure. The absorption spectra of the product exhibit band gap energy of about 4.27 eV which shows an enormous blue shift of 3.86 eV that can be attributed to very small size of PbS nanoparticles produced and quantum confinement effect. A possible formation mechanism of the PbS nanoparticles using ultrasonic irradiation in aqueous solution of the RTIL is presented.