• Title/Summary/Keyword: Antistatic Property

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Preparation of Durable Softeners for Nylon Fiber Using Fatty Polyamide and Alkyl Imidazoline (지방산 폴리아미드 및 알킬이미다졸린을 이용한 나일론 섬유용 내구성 유연제의 제조)

  • Jung, Choong-Ho;Kim, Sung-Rae;Park, Hyong-Jin;Hahm, Hyun-Sik;Kim, Tae-Ok;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.4
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    • pp.291-296
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    • 2002
  • Fatty polyamide that gives softness, lubrication and bulky property and alkyl imidazoline that gives durable softness and antistatic property were synthesized. then, an O/W-type durable softener (DSN) was prepared by the emulsion of the synthesized fatty polyamide and alkyl imidazoline. Emulsion stability of the DSN was good, and the mixed HLB value was 11.2. From the measurement of softness, lubrication, antistatic property, bending resistance, and color fastness, it was proved that the prepared DSN was a good durable softener for nylon.

Preparation and Characterization of Polyamide/MEPDM Alloy to Improve a Low Temperature Impact Strength and Antistatic Property (저온 충격강도 및 대전방지성 향상을 위한 개질 EPDM을 함유한 polyamide alloy의 제조 및 물성)

  • Lee, Soo;Jin, Seok-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.3
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    • pp.299-305
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    • 2011
  • Alloys of nylon(PA6) and ethylene-propylene-diene polymer, modified with maleic anhydride(MEPDM) were prepared using a melt kneading process. This study focuses on the effects of the content of MEPDM in PA6 blend on the mechanical and thermal properties of such blends where MEPDM is the dispersed phase. Mechanical properties were examined by stress-strain measurements and impact strength test. Both impact strength of PA6/MEPDM at room temperature and at $-20^{\circ}C$ were improved up to 400-550% with the amounts of MEPDM. However, PA6/MEPDM containing 3-5 wt% of MEPDM showed the about $700kg_f/m^2$ of the maximum tensile strength but 8.5 % of the lowest elongation. For certain compositions of PA6 with rubbery MEPDM, the interesting reduction of elongation is caused by the reaction of the polyamide amine end groups with maleic anhydride portion in MEPDM, that provided a reinforcement in the PA6 matrix. In addition, the introduction of antistatic agent on the surface of alloys causes significant reduction of their surface electrostatic resistance.

Preparation of Waterborne Polyurethane Coating Solutions with Antistatic Property from Alkali Metal Salts (알카리 금속염으로부터 대전방지용 수분산 폴리우레탄 코팅용액 제조)

  • Hong, Min Gi;Kim, Byung Suk;Lee, Yong Woon;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.50 no.3
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    • pp.427-434
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    • 2012
  • Waterborne polyurethane dispersions (PUD) were synthesized from poly (carbonate diol), isophrone diisocyanate and dimethylol propionic acid at different NCO/OH molar ratios. Subsequently, the PUD was mixed with different types of alkali metal salts ($LiClO_4$, $NaClO_4$, and $KClO_4$) to prepare antistatic waterborne polyurethane coating solutions. Effects of the types and amounts of alkali metal salts were investigated on the surface resistances of the resulting coating films. The surface resistances of coating films were decreased with increasing the amounts of alkali metal salts added in the PUD. The coating films prepared with the same amount of alkali metal salts showed increased ionic conductivity with the order of $LiClO_4$ > $NaClO_4$ > $KClO_4$. Also, the surface resistances of coating films were increased with increasing the molar ratios of NCO/OH in the PUD.

A study on the Manufacture and Application of UV-Cured Anti-stain Coating Compounds for PVC Tile (PVC 바닥상재용 광경화형 내오염 코팅액의 제조 및 응용에 관한 연구)

  • Yoon, Hyun-Jung;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1741-1746
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    • 2010
  • This study is on development of UV-cured anti-stain coating compounds which have more improved anti-stain function to prevent a surface of PVC tile from stain. To make an anti-stain coating composition, water soluble antistatic agent made from ammonium(IV) salt, antistatic agents for acrylic and polyurethane were used. Their contents varied from 5 to 20wt% against quantities of resin in coating composition. After coating PVC tiles using bar-coating method that can adjust a thickness, we estimated surface properties of coated layer such as anti-stain, electric resistance, adhesive power, thickness of coating, and so on. Results showed that a coating composition added 15wt% of water soluble antistatic agent and coated with No.12 bar-coater had the optimum surface property in electric resistance($3.24{\times}10^9{\Omega}/cm^2$), anti-stain(ink Test, Dust Test) and adhesive power. We could also find electric resistance and anti-stain effect were improved as antistatic agent content increased. However, excessive addition of antistatic agents(over 20wt%) caused the migration.

The Effect of Number of Twists of Lyocell Yarns on Compression Property and Abrasion Resistance Blanket Fabrics (라이오셀방적사의 꼬임수에 따른 담요직물의 압축특성과 마모강도)

  • Song, Min-Kyu
    • The Korean Fashion and Textile Research Journal
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    • v.8 no.3
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    • pp.363-369
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    • 2006
  • In this the study, Lyocell fabrics for blanket were developed to get high value added goods for elder and Infant. Therefore, the purpose of the study was determine the effect of twist per inch on the physical properties of developed fabrics, including compression property and abrasion resistance on the process for making Lyocell combined yarns. For comparison, commonly used cotton blanket was used. The results were as the follows: 1) Dimensional changes of Lyocell fabrics was in -3% which value was pretty stable, and antistatic property was very good with 10V of electric propensity voltage which means there was no static electricity at all. Pilling property of Lyocell fabrics showed 3 grade which was good and air permeability and moisture vapor transmission rate of Lyocell fabrics were higher than those of cotton fabric and keeping warmth rate of Lyocell fabrics was about 50% which means it very warms. 2) Twist per inch of Lyocell combined yarns increased with tensile strength and elongation of Lyocell fabrics. 3) Twist per inch of Lyocell combined yarns increased with decreasing thickness reduction rate and therefore, compression property of those was pretty good. Specially, compression property of Lyocell fabrics made with yarns of 3.9TPI was better than those of cotton fabric. 4) Twist per inch of Lyocell combined yarns increased with abrasion resistance of Lyocell fabrics.

Studies on the Durable Softners (II) -Applications of Alkyl Imidazoline Derivatives as the Durable Softners- (내구성유연제에 관한 연구 (II) -알킬이미다졸린 유도체의 내구성유연제로서의 응용-)

  • Kim, Young-Geun;Park, Hong-Soo;Song, Kab Jun
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.168-175
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    • 1990
  • Softners-BHICS, BBICS, and BTICS were prepared from 1, 2-disubstituted imidazoline compounds, such as 1-behenoylaminoethyl-1-glycidyl-2-heneicosylimidazolinium chloride(BHIC), 1-behenoylbis(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride (BBIC), and 1-behenoyltris(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride(BTIC), and treated to acrylic fiber. The measurements of softness, lubricating and antistatic properties showed that they have not only good softness and lubricating property but also a little antistatic property. Furthermore, the initial bending resistance for BBICS and BTICS was 5 grade, and remained 3~4 grade after 5 times washing. As results of these tests, they showed good softner effects having durability. The prepared softners were proved to be durable softner through a series of experimental results for washable properties of feeling by varying treating temperature and pH change.

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Preparation of Antistatic Nylon 6/PVA Blend Films by Vapor-phase Polymerization of Thiophene (Thiophene의 기상중합에 의한 제전성 Nylon 6/PVA 블렌드 필름의 제조)

  • 박연흠;호요승
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.63-68
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    • 1989
  • It has been attempted to improve the anti-static property of Nylon 6 by means of Vapor-phase polymerization of thiophene in Nylon 6/PVA blend films impregnated with aluminium chloride as an oxident. After Polymerization of thiophene for two hours in Nylon 6/PVA blend films the conductivity increased from $10^{-12}-10^{-13}S/cm\;to\;10^{-5}-10^{-7}$S/cm, and the conductivity of composite films increased with increasing the concentration of aluminium chloride, the content of PVA annd polymerization time of thiophene. Polythiophene introduced in Nylon 6/PVA blend films has been confirmed by FT-IR spectra and scanning electron micrographs.

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Preparation and Characterization of Durable Softeners for Acrylic Fiber (아크릴 섬유용 내구성 유연제의 제조 및 유연특성)

  • Hahm, Hyun-Sik;Kim, Young-Kook;Chung, Dong-Jin;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.20 no.1
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    • pp.1-7
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    • 2003
  • In order to prepare a softener, alkyl imidazoline salt, fatty carbamide salt, and fatty polyamide salt were synthesized first, and then the synthesized salts were blended. The prepared softeners were applied to acrylic fibers, and then several properties were tested. As a result, the prepared softeners show good softening and lubricating properties, and they also show a little antistatic property. Through bending resistance tests and measurements of feeling change of acrylic fibers treated with the softeners, it was proved that the prepared softeners are durable softeners.

Preparation and Properties of Fatty Alkylate Type Durable Softner for Nylon Fiber (알킬지방산 에스테르계 나일론 섬유용 내구성 유연제의 제조와 물성)

  • Kim, Seung-Jin;Park, Hong-Soo;Kang, Doo-Whan
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.87-92
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    • 1995
  • To prepare a O/W type durable softner(OESA), octadecamidoethylaminoethyl dodecate and tetra (2-dodecamidoethyl) urea synthesized as the main components of softner, were blended with polyoxyethylene(20) oleyl ether, sorbitan sesquioleate, and polyoxyethylene(7) stearyl ether in various compositions. Emulsion stability of OESA was good, and mixed HLB value was 9.7, OESA was found was to be good durable softner for nylon through the examination of softness, lubriation, antistatic property, bending resistance, and color fastness.

A Study on Bathochromic Finish of Poly(ethylene Terephthalate) Fabrics by Low Temperature Plasma$(O_2)$ Treatment (산소 저온 Plasma 처리에 의한 Poly(ethylene Terephthalate) 직물의 심색화에 관한 연구)

  • Cho, Hwan;Chang, Byong-Ryul;Chang, Du-Sang;Huh, Man-Woo;Cho, In-Suol;Lee, Kwang-Woo
    • Textile Coloration and Finishing
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    • v.4 no.1
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    • pp.1-9
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    • 1992
  • In order to study on the surface modification of the poly(ethylene Terephthalate)(PET) fabrics, low temperature plasma$(O_2)$ has been irradiated on the PET fabrics in various conditions. Experiments were carried out at pressure ranging from 0.5 tort to 3 tort. The properties of PET fabrics treated with low temperature plasma($(O_2)$, such as bathochromic, wettability, antistatic property were measured. Etching ratio was increased as the pressure and the output of discharge increased. When its were put on the cathode, the most efficient effect of etching according to the position of sample between anode and cathode was obtained. The bathochromic effect has more or less improved as pressure was getting higth in case of dyed fabrics treated with only low temperature plasma$(O_2)$ . And when it was treated with the low refractive index resin, the bathochromic of dyed fabrics treated with low temperature plasma$(O_2)$ was better than that of the dyed fabrics untreated.

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