• Journal of the Korean Applied Science and Technology
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• v.24 no.4
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• pp.399-409
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• 2007

Characteristics of polyaniline anti-corrosive coatings with various primer coating resins(epoxy resin, urethane resin, and others) and top coating resins(epoxy and acrylic urethane resins) were investigated through adhesion, acid resistance, alkaline resistance, water resistance, and anti-corrosion tests. As a result, the anti-corrosive properties of the prepared coatings using polyaniline varied with the types of primer and top coating resins. In this condition, the properties of adhesion, chemical resistance, and water resistance were found to be very satisfactory when using emeraldine base (EB) of polyaniline blended with single-packaged urethane and acrylic urethane resins as the primer coatings, and using acrylic urethane resin as the top coatings. Also, the anti-corrosive function of these anti-corrosive coatings was well preserved for 1000 hr in the salt spray experiment.

• Journal of the Korean Applied Science and Technology
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• v.23 no.3
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• pp.230-237
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• 2006

Anti-corrosive coatings for steel structures with an alternative anti-corrosive pigment, polyaniline was prepared and anti-corrosive characteristics of the prepared coatings were investigated. The structure of the polyaniline was identified by using FT-IR, UV/Vis. and TGA analysis, and the anti-corrosive properties were analyzed from the results of the salt spray experiment. We found that the anti-corrosion properties of the prepared coatings varied in accordance with the types of primer coating resins as well as with the existence and nonexistence of the top coating. In this condition, the properties of adhesion, chemical resistance, and water resistance were found to be very satisfactory when using the single-packaged urethane resin as the primer coating resin and the urethane resin as the top coating resin.

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.201-206
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• 2002

The purpose of this study is to improve the anti-corrosive properties of coated reinforcing bar using polymer cement slurry. Poymer cement slurry are prepared with three types of polymer dispersions and corrosion inhibiting admixture. And tested for corrosion accelerating tests such as immersion in NaCl 10% solution NaCl 10% solution spray, high temperature and pressure steam in condition of 8cycles, carbonation before and after, penetration of NaCl solution. From the test results, it is concluded that the anti-corrosive properties are considerably improved by coating using polymer cement slurry at surface of reinforcing bar. And this trend is marked by adding of corrosion inhibiting admixture. The difference of the anti-corrosive properties is hardly recognized according to types of polymer dispersions. The anti-corrosive properties of coated reinforcing bar using polymer foment slurry are improved to a great extent compared to those of plain reinforcing bar accordiy to increasing content of chloride ion in cement concrete.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2006.11a
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• pp.173-176
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• 2006

There are many kinds of protection methods for marine structures by using and environmental condition. Coating protection method, one of these methods is being widely adopted to both all ground and marine structures. In this study, by adding some additives such as Zn powder(Zn), carbon black(CB) to epoxy anti-corrosive paint, the effect to promote corrosion resistance was investigated with electrochemical method. Corrosion potentials with additives shifted to negative direction than no additive. However passivity current density increased than no additive except for Zn(20)+CB(10), especially, additive of Zn(20)+CB(10) showed the smallest passivity current density. Polarization resistance of Zn(20)+CB(10) by both cyclic voltammogram and impedance measurement was the largest value than other additives. And also surface phenomenon by adding Zn(20)+CB(10) was observed a good add condition not showing bubbling than other additives.

• Corrosion Science and Technology
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• v.8 no.3
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• pp.126-131
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• 2009

The interaction between wear and corrosion can significantly increase total material losses in water chemistry environment. The corrosive wear tests of a PWR steam generator tube material (Alloy 690) against the anti vibration bar material (409 SS) were performed at room temperature. The tests were performed in alkaline water chemistry conditions. NaOH solution was selected for test condition to investigate the corrosive wear effect of steam generator tube material in alkaline pH condition without other factors. The flow induced vibration can caused tube damage and the corrosion can be occurred by water chemistry. The test results showed that, in the alkaline solution at pH 13.9, the corrosion current density was increased about ten times than that in the distilled water. And wear rate at pH 13.9 was increased about ten times from that at neutral condition. However, the wear rate was decreased with time. The decrease would be attributed to the change in roughness of specimen or sub-layer of the worn surface with time. From microstructure observation, severe abrasive shape and several wear debris were found. From those results, it could infer that the oxide film on Alloy 690 changed to easily breakable one in the alkaline water, and then abrasion with corrosion became the main wear mechanism.

• Journal of the Korea institute for structural maintenance and inspection
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• v.17 no.6
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• pp.95-103
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• 2013

Half Cell Potential (HPC) technique has been widely adopted for its quantitative evaluation of corrosion possibility. In this study, RC specimens with three different cover depths (10mm, 30mm, and 60mm) and w/c ratios (0.35, 0.55, and 0.70) are prepared and accelerated salt spray test (SST) is performed for 45 days. Steel corrosion occurs in the specimens with 0.55 of w/c and 10mm of cover depth. In the case of 0.70 of w/c and 30mm of cover depth, steel corrosion is also monitored. Considering the effect of cover depth and w/c ratio, HCP evaluation equation is proposed and the condition which can control steel corrosion is obtained. Furthermore, anti-corrosive conditions containing w/c ratio and cover depth are analyzed through Life 365 program and the conditions are compared with the results from this study.

• Proceedings of the Korea Concrete Institute Conference
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• 1995.04a
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• pp.402-406
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• 1995

The purpose of this paper is to decrease shotcrete rebound losses and to produce economic effectiveness at the same time in construction. The mechanical properties and quick acceleration of various shoterete mixes were analyzed, which were intuenced by several accelerators and their amouts used. And the application and construction in the felds were evaluated. The shotcrete rebounds relied on the condition of construction rather than on the quality of materials, but it is found that the decreasing of the cost and time in shotcreting under the same condition was based on the rebounds which were affected by the accelerating capability of the accelerators. The application of the accelerator was limited by the condition of tunnel construction ; such as ground water, anti-corrosive, or anti-chemistry. It is important to choose a proper accelerator. Therefore, it is necessary that better accelerators which satisfly mechanical characteristics and economy are developed. Optimal working conditions should be announced to the workers and workers' skill be improved in the shotcrete construction feld as well.

• Journal of Ocean Engineering and Technology
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• v.12 no.1
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• pp.23-31
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• 1998

Kind 1 propeller shaft in ships is the shaft which is provided with effective measures against corrosion by sea water, or the shaft which is made of approved corrosion resistance materials. The propeller shaft other than specified above is Kind 2. Thus, this study is mainly concerned with the resistance to fatigue damage in sea water against stress concentrations due to the notches. The results obtained can be summarized as follows; (1) The stress increases with curing time, however, when the curing time reaches at 96 hours the stress becomes a constant value. The elongation decreases with curing time, however, when the curing time reaches at 48 hours the elongation becomes a constant value. Thus, in case of FRP coating on propeller shaft, it is necessary to cure for 48 hours at least. (2) The relation of $\sigma$$_n$-K$_t$ is to be classified into two parts, which is a part where fracture nominal stress, $\sigma$$_n$, decreases with increasing $K_t$, and a part where $\sigma$$_n$ is nearly constant independent of $K_t$. (3) According to a linear notch mechanics, the measure of severity controlling the fracture in notched FRP body is the notch root radius, $\rho$. The notched static strength of an arbitrary specimen will be estimated from $\sigma$$_{max}$ -1/$\rho$ curve. (4) Through the observation of cross section after fatigue test, the part of interface was kept good condition irrespective of loading conditions.

• Journal of the Korean Society for Heat Treatment
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• v.31 no.3
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• pp.120-125
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• 2018

The PMMA composited material mixed with alumina studied to find the optimal condition, the adequate ratio of mixing, for the associated mechanical properties such as anti-corrosive, weatherproof performance. The 80% of hardness and 52% of scratch coefficient improved according to increasing ratio of alumina, which is mostly 3 times higher than that of pure PMMA, on other hand 16% of tensile strength and 35% of flexural strength has lost while alumina was adding in. The most proper ratio, having the best availability in substantial production, of composite between pure PMMA and alumina is determined as 93 wt. % vs 7 wt. %. Results of related five properties had estimated by using of a pentagram.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2007.04a
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• pp.153-154
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• 2007

Mg thin films were prepared by PVD method on electroplated Zn steel substrate. And the influence of gas pressure on their morphology and crystal orientation of the deposited films were investigated by scannig electron microscopy(SEM) and X-ray diffraction(XRD), respectively. In addition, the effect of corrosion resistance of these films as a funtion of morphology and crystal orientation was evaluated by anodic polarization test. From the measured results, it is investigated that the film of granular structure which deposited in condition of high gas pressure had the highest corrosion resistance.