• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1277-1279
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• 1997

In this study, the mechanism underlying the corrosion problem have been investigated using X-ray photoelectron spectroscopy(XPS) and scanning electron microscopy(SEM), AES(Auger electron spectroscopy) In regard to the removal of Al-Cu corrsion, the subsequent treatment of the $SF_6$ plasma has also been completed. This work evaluated the effects of grain boundary on the AlCu after dry etching and the role of subsequent $SF_6$ plasma for the removal of AlCu corrosion.

• Journal of Advanced Marine Engineering and Technology
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• 제28권2호
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• pp.300-308
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• 2004

The formation mechanism of anodic oxide films on Mg alloys when anodized in NaOH solution. was investigated by focusing on the effects of anodizing potential. Al content. and anodizing time. Pure Mg and Mg-Al alloys were anodized for 10 min at various potentials in NaOH solutions. $Mg(OH)_2$ was generated by an active dissolution reaction at the surface. and the product was affected by temperature. The intensity ratio of $Mg(OH)_2$ in the XRD analysis decreased with increasing applied potential. while that of MgO increased. The anti-corrosion properties of anodized specimens at each constant potential were better than those of non-anodized specimens. The specimen anodized at an applied potential of 3 V had the best anti-corrosion property. And the intensity ratio of $Mg_{17}Al_{12}$/Mg increased with aluminum content in Mg-Al alloys. During anodizing. the active dissolution reaction occurred preferentially in ${\beta}\;phase(Mg_{17}Al_{12})$ until about 4 mins. and then the current density increased radually until 7 mins. The dissolution reaction progressed in a phase(Mg) which not formed the intermetallic compound. which had a lower Al content. In the anodic polarization test of $0.017\;mol{\cdot}dm^-3$ NaCl and $0.1\;mol{\cdot}dm^-3\;Na_2SO_4$ at 298 K. the current density of Mg-15 mass% Al alloy anodized for 10 mins increased. since the anodic film that forms on the a phase is a non-compacted film. The anodic film on the phase for 30 mins was a compact film as compared with that for 10 mins.

• 열처리공학회지
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• 제8권4호
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• pp.255-265
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• 1995

Stainless steel type 304L has been nitrided in the low pressure (600Pa) and high nitrogen (80% $N_2$+20% $H_2$) environment for 5 hours by the square-wave-pulsed-d.c. plasma as a function of temperature $400{\sim}550^{\circ}C$ and pulsation. At the lower temperature range of $400{\sim}500^{\circ}C$ and at the relatively high ratio of pulse duration to pulse period. "S-phase" has been developed in the form of thin nitrided surface layer which has many cracks, leading to be nearly impossible for the industrial anti-wear and anti-corrosion applications. At the higher temperature up to $550^{\circ}C$ with the increasing ratio of the pulse duration to pulse period up to $50{\mu}s/100{\mu}s$, the nitrided layer, whose growth rate has increased also, has been composed mainly of CrN and $Fe_4N$ phases and has become thick, uniform and nearly crack-free.

• 보존과학회지
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• 제25권4호
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• pp.373-381
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• 2009

야외 전시되는 철제문화재 보존을 위해서 유물 표면을 피복처리 하는 것은 부식방지의 대표적인 방법이다. 근대문화유산 제78호 경의선장단역증기기관차는 보존조치 후 노천에서 전시될 예정이라서 기관차의 재부식 예방에 효과적인 표면 피복재를 내후성 실험을 통해 선별하였다. 실험재료는 기관차 표면 피복에 주로 사용되는 미정질 왁스 2종과 봉밀왁스를 기반으로 제조한 혼합왁스를 선별하였다. 실험방법은 3종의 왁스를 기관차 시편에 각각 피복하고 ISO 4892-1981 기준에 따라 제논아크촉진내후성시험기 속에서 1000시간 내후성 시험을 한 후 그 변화상을 비교 조사하였다. 실험결과 봉밀 왁스는 400시간 이후부터 표면에 백화현상이 발생하면서 노화하였고 미정질 왁스 2종은 800시간 이후부터 변화를 보였다. 시험전과 후 수분접촉각의 변화 역시 봉밀 왁스 보다 미정질 왁스가 적게 나타났다. 따라서 미정질 왁스 중 특히 고온형이 내후성과 수분 차단력이 가장 뛰어난 것으로 확인되어서 이것으로 증기기관차의 표면을 피복하게 되었다.

• 한국건설순환자원학회논문집
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• 제5권3호
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• pp.267-274
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• 2017

본 연구는 상수도 급수과정에 사용되는 대구경 강관이 정수과정에서 사용되는 약품으로 인하여 부식이 발생하게 되고 이를 보수하기 위하여 친환경 소재인 EVA 시트 및 강관과의 부착을 용의하게 할 수 있는 부틸고무를 적용하여 자착식 방수방식 시트를 개발하였다. 이에 자착식 방수방식 시트에 대한 강판과의 부착강도를 확인하고, 강관에 발생될 수 있는 다양한 환경조건에서의 부착강도를 확인하였다. 또한 외부에서 침입하는 유입수의 수압에 의해 강관에 부착된 시트의 탈락여부를 확인하였으며, 마지막으로 강관이 부식된 환경과 유사하게 강판에 녹을 발생시켜 자착식 방수방식 시트와 부착강도를 확인함으로써 대구경강관 보수 시 시공 용의성 외에도 안정적인 부착강도를 확보하여 강관의 부식을 차단함과 동시에 안정적인 성능 유지 방안을 확인하고자 하였다. 그 결과 본 연구에 사용된 자착식 방수방식 시트는 강관에 대한 무처리, 장기 누름, 장기 침수 내화학(염산, 차아염소산, 수산화나트륨), 저온($-20^{\circ}C$) 및 습윤 건조 반복에서의 모든 부착성능은 KS F 4934의 성능기준인 1.5N/mm 이상을 상회하는 부착강도가 나타났으며, 배면 누수압에 따른 시트의 탈락현상을 확인하는 시험에서도 배면 누수압 $3.0N/mm^2$까지 시트의 탈락이 발생되지 않았다. 또한 녹이 발생된 강관에서의 부착성능을 확인하는 과정에서도 12시간동안 녹을 발생시킨 시험편에서 2.1N/mm, 168시간동안 녹을 발생시킨 시험편에서 2.0N/mm 의 성능이 나타남에 따라 녹 발생 강관에 대한 안정성이 확인되었다.

• 공업화학
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• 제18권3호
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• pp.296-302
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• 2007

6가 크롬의 크로메이트 코팅제의 대체를 위한 3가 크롬의 크로메이트 코팅용액의 제조에 관한 것이다. 본 연구에서 제안된 코팅제는 3가 크롬원으로서 $KCr(SO_4)_2$를 35~45 g/L, 인산계 화합물로서 $NaH_2PO_4$를 20~30 g/L을 주성분으로 하고 여기에 금속계 황산화물로서 $CoSO_4$ 10~20 g/L, $ZnSO_4$ 10~20 g/L의 조성으로 구성된 것이다. 이 제안된 3가 크롬 코팅용액을 사용하여 pH 2.0~2.2, 상온에서 담지시간 20~25 s의 조건하에 시안아연도금체에 코팅된 피막은 염수분무시험결과 5% 백청발생까지 120 h 이상 견디는 우수한 내식성을 발현하였다.

• 한국재료학회지
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• 제16권7호
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• pp.430-434
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• 2006

Au/Ni coatings are widely used in the electrical interconnect system, such as connectors, sockets and wire crimps. But due to repeated mechanical contacts, fretting corrosion occurs and causes a rapid increase in resistance. As an attempt to resolve these problem, application of Ni-P-PTFE to replace Ni undercoats was proposed, for which basic materials properties of Ni-P-PTFE coatings for preventing fretting corrosion was examined in this study. The Ni-P-PTFE coatings were formed by electroless Ni plating and PTFE coating followed by the heat-treatment. PTFE particles were found to be uniformly distributed in the Ni-P matrix. The Ni-P-PTFE coatings showed the excellent anti-adherent property with the contact angle of $104.3^{\circ}$, microhardness of 144.3 Hv comparable to that of Ni-P, and electric conductivity equivalent to that of Ni-P.

• Corrosion Science and Technology
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• 제21권1호
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• pp.68-76
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• 2022

Several technologies are employed to protect substrates from corrosion and erosion damage. In particular, arc thermal spray coating technology is widely used as anti-corrosive technology for steel and concrete structures and is applied to offshore plants and petrochemical and drilling facilities. In this investigation, solid particle impingement erosion experiments were performed on an arc thermal spraying-coated specimen using 85% Al-14% Zn-1% Zr wire rod in KR-RA steel. This study investigated the effect of fluorosilicone sealing on the erosion resistance characteristics of the thermal spray coating layer. The erosion rates of the thermal spray-coated and sealed specimens were 4.1×10^-4 and 8.5×10^-4, respectively. At the beginning of the experiment, the fluorosilicone sealant was almost destroyed by the impact of the solid particles. The destruction time for the coating layer was 10 minutes for the thermal spray-coated specimen and 13 minutes for the sealed specimens, indicating that the sealed specimens had better erosion resistance characteristics to solid particle impingement.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1996년도 추계학술대회 논문집
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• pp.1093-1097
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• 1996

The Substitution development of 7075-T6 Al alloy to 7050-T74 Al alloy in small arms to improve anti-stress corrosion cracking was processed along with mass productivity consideration. To meet 7050 Al alloy material characteristics Indirect extrusion type was adopted and local heating above recrystalization temperature in forging process had to be avoided. The T74 aging treatment was 12$0^{\circ}C$ -6hrs and 175$^{\circ}C$ -12hrs and was appropriate for both machanical and anti-cohesion properties. In accessment of field application test 7050Al alloy made parts of small arms showed equivalent or better performance than 7075 Al alloy.

• 열처리공학회지
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• 제15권5호
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• pp.213-218
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• 2002

In order to develop the economic and environmental water-soluble black coloring agent, some adequate chemical mixtures were mixed and this solution was applied to coat quenched and tempered 51B20 steel bolt. Some basic properties of the solution and characteristics of the coated film in addition to the corrosion resistance were investigated. The developed 100 kg of water-soluble black coloring agent solution was a chemical mixture consisted of 10 kg of aqueous coloring agent, 40 kg of surface active agent, 0.3 kg of anti-foam agent and $50{\ell}$ of water. The coated film of the bolt was composed of hard layer of about $2{\mu}m$ and the disbondable soft layer of about $4{\mu}m$ above the hard layer. Many surface active agents peaks and a few hydrophilic peaks were observed in the coated film. Surface roughness value of the coated bolt was lower than that of the non-coated bolt. Corrosion resistance of the coated bolt considerably improved and also relatively showed a good polarization resistance at test condition of $40^{\circ}C$ colorizing temperature and 5% the solution concentration in 3% NaCl anodic polarization test. Initial appearance time of the surface rust was greatly retarded owing to the coated film in salt spray test.