• 제목/요약/키워드: Anthracene-isothiouronium salts

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Investigation of Isomerism in Anthracene-Isothiouronium Salts and Application of these Salts for Anion Sensing

  • Nguyen, Quynh Pham Bao;Kim, Jae-Nyoung;Kim, Taek-Hyeon
    • Bulletin of the Korean Chemical Society
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    • 제30권9호
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    • pp.2093-2097
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    • 2009
  • Novel fluorescent anion chemosensors based on anthracene-isothiouronium derivatives were synthesized. Isomerism due to the intramolecular mobility in these isothiouronium salts was detected by $^1H$ NMR spectroscopy. The effect of the substituent, temperature and solvent on the isomerism was also examined. The anthracene-isothiouronium sensor showed significant fluorescent enhancement upon the addition of various anions such as fluoride, acetate, and dihydrogen phosphate, even in the presence of water.