• Title/Summary/Keyword: Anoxic phase

Search Result 29, Processing Time 0.031 seconds

A Study on Denitrification Efficiency with External Carbon Sources in Pilot-scale Modified SBR (Pilot-scale modified SBR 공정에서 외부탄소원의 종류에 따른 탈질효율 비교 연구)

  • 서인석;김병군;홍성택;정위득
    • Journal of environmental and Sanitary engineering
    • /
    • v.17 no.3
    • /
    • pp.52-59
    • /
    • 2002
  • Pilot-scale PSSBR(Phase Separated Sequencing Batch Reactor) was operated to evaluate requirement of external carbon sources(${\Delta}gCOD/{\Delta}gNO_3^{-}-N$) in denitrification. Methanol and fermented food waste were used as external carbon sources. Methanol and fermented food waste were fed to the anoxic state of first reactor and concentration were 50 and 40 mgCOD/L on the basis of concentration in reactor, respectively. In case that external carbon source was not used, average $NO_3^{-}-N$ concentration in effluent was 22.49 mg/L. When methanol and fermented food waste were fed, average $NO_3^{-}-N$ concentration in effluent were 10.13 mg/L and 6.3 mg/L, respectively and requirement of external carbon sources were 4.04 and 2.5 ${\Delta}gCOD/{\Delta}gNO_3^{-}-N$, respectively. Fermented food waste was better than methanol in denitrification efficiency. Therefore fermented food waste could be one of the excellent external carbon sources for nitrogen removal in biological nutrient removal process.

Isolation and Characterization of Denitrification Bacteria (탈질 세균의 분리 및 특성)

  • 차월석;최형일;이동병;차진명
    • KSBB Journal
    • /
    • v.18 no.6
    • /
    • pp.461-465
    • /
    • 2003
  • Five denitrifying bacteria, which were identified as Pseudomonas sp., were isolated by the enrichment culture technique. The most effective denitrifying bacterium was named as Pseudomonas DWS, which was cultivated at anoxic condition. The optimal growth temperature and pH were 30$^{\circ}C$ and 7-8, respectively. Cell growth almost revealed a stationary phase at 18 hours after cultivation and nitrate was degrade 99.9% during this period. Therefore, it is suggested that Pseudomonas DWS could be effectively used for the biological treatment of wastewater containing nitrogen compounds.

Factors affecting nitrite build-up in an intermittently decanted extended aeration process for wastewater treatment (하수처리를 위한 간헐 방류식 장기폭기 공정에서 아질산염의 축적에 영향을 미치는 인자)

  • Ahn, Kyu-Hong;Park, Ki-Young;Lee, Hyung-Jib
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.13 no.1
    • /
    • pp.51-60
    • /
    • 1999
  • An intermittently-aerated, intermittently-decanted single-reactor process (KIDEA process : KIST intermittently decanted extended aeration process) was applied for nitrogen removal from wastewater. Synthetic wastewater with chemical oxygen demand (COD): nitrogen (N) ratio of approximately 5.25: 1 was used. The average COD removal efficiency reached above 95%, and under optimal conditions nitrogen removal efficiency also reached above 90%. This process consisted of 72 minute aeration, 48 minute settling and 24 minute effluent decanting with continuous feeding of influent wastewater from the bottom of the reactor, and did not require a separate anoxic mixing-phase. In this process, nitritation ($1^{st}$ step of nitrification) was induced but nitratation($2^{nd}$ step of nitrification) was suppressed. Main factors responsible for the accumulation of nitrite ion in the experimental condition were free ammonium and dissolved oxygen. This condition of nitrite build-up accelerated by continuous feed flow in the bottom of the KIDEA reactor because of high concentration of ammonia nitrogen in the influent. This research provides one of answers to control nitrate build-up.

  • PDF

Removal of nitrogen and sulfur odorous compounds and their precursors using an electrolytic oxidation process (산화전리수를 이용한 질소와 황 계열 악취 및 악취전구물질의 제거)

  • Shin, Seung-Kyu;An, Hea-Yung;Kim, Han-Seung;Song, Ji-Hyeon
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.25 no.2
    • /
    • pp.223-230
    • /
    • 2011
  • An electrolytic oxidation process was applied to remove odorous compounds from non-point odor sources including wastewater pipelines and manholes. In this study, a distance between the anode and the cathode of the electrolytic process was varied as a system operating parameters, and its effects on odor removal efficiencies and reaction characteristics were investigated. Odor precursors such as sediment organic matters and reduced sulfur/nitrogen compounds were effectively oxidized in the electrolytic process, and a change in oxidation-reduction potential (ORP) indicated that an stringent anaerobic condition shifted to a mild anoxic condition rapidly. At an electrode distance of 1 cm and an applied voltage of 30 V, a system current was maintained at 1 A, and the current density was 23.1 $mA/cm^{2}$. Under the condition, the removal efficiency of hydrogen sulfide in gas phase was found to be 100%, and 93% of ammonium ion was removed from the liquid phase during the 120 minute operating period. Moreover, the sulfate ion (${SO_4}^{2-}$) concentration increased about three times from its initial value due to the active oxidation. As the specific power consumption (i.e., the energy input normalized by the effective volume) increased, the oxidation progressed rapidly, however, the oxidation rate was varied depending on target compounds. Consequently, a threshold power consumption for each odorous compound needs to be experimentally determined for an effective application of the electrolytic oxidation.

Effects of $K^+$ Channel Modulators on Extracellular $K^+$ Accumulation during Ischemia in the Rat Hippocampal Slice (해마절편의 허혈성 $K^+$ 축적에 대한 $K^+$채널 조절 약물의 작용)

  • Choi, Jin-Kyu;Chun, Boe-Gwun;Ryu, Pan-Dong
    • The Korean Journal of Physiology and Pharmacology
    • /
    • v.1 no.6
    • /
    • pp.681-690
    • /
    • 1997
  • Loss of synaptic transmission and accumulation of extracellular $K^+([K^+]_O)$ are the key features in ischemic brain damage. Here, we examined the effects of several $K^+$channel modulators on the early ischemic changes in population spike (PS) and $[K^+]_o$ in the CA1 pyramidal layer of the rat hippocampal slice using electrophysiological techniques. After onset of anoxic aglycemia (AA), orthodromic field potentials decreased and disappeared in $3.3{\pm}0.22\;min$ $(mean{\pm}SEM,\;n=40)$. The hypoxic injury potential (HIP), a transient recovery of PS appeared at $6.0{\pm}0.25\;min$ (n=40) in most slices during AA and lasted for $3.3{\pm}0.43\;min$. $[K^+]_o$ increased initially at a rate of 0.43 mM/min (Phase 1) and later at a much faster rate (12.45 mM/min, Phase 2). The beginning of Phase 2 was invariably coincided with the disappearance of HIP. Among $K^+$ channel modulators tested such as 4-aminopyridine (0.03, 0.3 mM), tetraethylammonium (0.1 mM), NS1619 $(0.3{\sim}10\;{\mu}M)$, niflumic acid (0.1 mM), glibenclamide $(40\;{\mu}M)$, tolbutamide $(300\;{\mu}M)$ and pinacidil $(100\;{\mu}M)$, only 4-aminopyridine (0.3 mM) induced slight increase of $[K^+]_o$ during Phase 1. However, none of the above agents modulated the pattern of Phase 2 in $[K^+]_o$ in response to AA. Taken together, the experimental data suggest that 4-aminopyridine-sensitive $K^+$channels, large conductance $Ca^{2+}-activated$ $K^+$ channels and ATP-sensitive $K^+$ channels may not be the major contributors to the sudden increase of $[K^+]_o$ during the early stage of brain ischemia, suggesting the presence of other routes of $K^+$ efflux during brain ischemia.

  • PDF

Life Cycle Assessment of the Carbon Emissions of MLE process and Denitrification Process Using Granular Sulfur (MLE공법과 황이용 탈질 프로세스의 전과정 탄소 배출량 평가)

  • Moon, Jin-young;Hwang, Yong-woo
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.26 no.5
    • /
    • pp.619-627
    • /
    • 2012
  • In order to determine reduction of greenhouse gas emissions (GHGs) when the submerged membrane bioreactor with granular sulfur (MBR-GS) is used in wastewater treatment plant (WTP), the amount of GHGs was compared and analyzed in the advanced treatment process of P wastewater treatment plant (WTP). The amount of GHGs was estimated by classifying as construction and operation phase in WTP. The amount of GHGs in construction phase was evaluated from multiplying raw materials by using carbon emission factors. Also the amount of GHGs in operating phase was calculated by using total electricity consumption and carbon emission factor. The construction of anoxic tank and secondary settling tank is unnecessary, because the MBR-GS conducts simultaneously the nitrification and denitrification in aeration tank and filtration by hollow fiber membrane. The amount of $CO_2$, $CH_4$, and $N_2O$ emitted by constructing the MBR-GS was 6.44E+06 kg, 8.16E+03 kg and 1.38E+01 kg, respectively. The result shows that the GHGs was reduced about 47 % as compared with the construction in the MLE process. In operating the MBR-GS, the electricity is not required in the biological reactor and secondary setting tank. Thus, the amount of $CO_2$, $CH_4$, and $N_2O$ emitted by operating in the MBR-GS was 7.39E+05 kg/yr, 5.80E+02 kg/yr and 2.44E+00 kg/yr, respectively. The result shows that the GHGs were reduced about 37 % as compared with the operation in the MLE process. Also, $LCCO_2$(Life Cycle $CO_2$) was compared and analyzed between MLE process and MBR-GS. The amount of $LCCO_2 $emitted from the MLE process and MBR-GS was 3.56E+04 ton $CO_2$ and 2.12E+04 ton $CO_2$, respectively. The result shows that the GHGs in MBR-GS were reduced to about 40 % as compared in the MLE process during life cycle. As a result, sulfur-utilizing autotrophic denitrification process (SADP) is expected to be utilized as the cost-effective advanced treatment process, owing to not only high nitrogen removal efficiency but also the GHGs reduction in construction and operation stage.

Formation and Behavior of Sedimentary Inorganic Sulfides in Banweol Intertidal Flat, Kyoung-gi Bay, West Coast of Korea (황해 경기만 반월조간대 퇴적물 내의 황화물 형성과 행동에 관한 연구)

  • 김범수;이창복
    • 한국해양학회지
    • /
    • v.28 no.3
    • /
    • pp.229-240
    • /
    • 1993
  • This study investigated the behaviour of sulfur species after the early diegenetic reduction of sulfate from pore solution in an anoxic intertidal flat deposit in the Banweol area of Kyeong-gi Bay, west coast of Korea. A total of seven sediment cores were collected during 1990∼1992 and were analyzed for their solid-phase sulfur species (acid-volatile sulfur, element sulfur, pyrite sulfur) as well as for chemical components in the pore solution, such as sulfate, ammonium, hydrogen sulfide, phosphate and Fe ion. The pore water sulfate oncentration was found to decrease rapidly downward from the sediment surface, while that of hydrogen sulfide, ammonium and phosphate showed and increase. The dissolved iron concentration in pore water, on the other hand, was found high in the surface layer of sediment, but fell sharply below this layer. these characteristic profiles of pore water sulfide and iron concentrations suggest that some reaction occurs between dissolved iron and sulfide ions, leading to the formation of various sulfide minerals in the sedimentary phase. The amount of inorganic sulfur species in the sediment increased downward, and showed a maximum of up to 7.9 mg/g. among the three species analyzed, acid-volatile sulfur (AVS) was dominant comprising more than 50% of the total. The amount of pyrite sulfur was greater than that of element sulfur. This implies that the formation of pyrite was restricted in this environment. the limited amount of element sulfur in this deposit may have discouraged the active formation of pyrite.

  • PDF

Behavior of trace metals in Masan Bay, Korea during oxygen deficient period (하계 마산만 혐기성 환경에서의 미량금속의 거동)

  • Jin Y.H.;Kim K.T.;Chung C.S.;Kim S.H.;Yang D.B.;Hong G.H.;Lee K.W.
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.3 no.4
    • /
    • pp.56-64
    • /
    • 2000
  • Behavior of trace metals in Masan Bay, Korea was studied in August 1998 when the oxygen deficient condition occurred. Dissolved Cd and Zn concentration in the surface waters decreased with increasing distance from Masan Harbor. Dissolved concentrations of Cd, Cu Pb and Zn in the surface waters were higher than bottom waters. Particulate(acid-teachable fraction) concentrations of Cu, Cd and Pb in the surface waters of Masan Bay decreased with increasing distance from Masan Harbor. Bottom waters contained higher concentrations of particulate Cd, Cu, Pb and Zn than surface waters. Distribution coefficients between dissolved and particulate phase (K/sub d/) of Cu and Cd decreased with the increasing distance from the Harbor, possibly due to reaction of these elements with sewage-derived particulate matter Al, Zn, Cu, Cd, and Pb in the surface sediment showed relatively high concentration in the inner Masan Bay.

  • PDF

Control of $NH_4-N$ in Wastewater Treatment Effluent According to Simplified ASM No. 1 (간략화된 활성슬러지 모델(ASM No. 1)을 이용한 유출수 중 암모니아성 질소의 제어에 관한 연구)

  • Kim, Shin-Geol;Choi, In-Su;Koo, Ja-Yong
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.29 no.5
    • /
    • pp.548-555
    • /
    • 2007
  • The control of wastewater treatment has two merits; one is to regulate water quality of effluent and the other is to reduce the cost of wastewater treatment. The purpose of this study was to control the ammonium nitrogen in effluent that is known to cause eutrophication. The control was based on simplified ASM No. 1 which had 3 component materials and 8 coefficients, and the control method was as following. Firstly the ammonium concentration of inflow was measured and the optimal aeration time in effluent was determined according to simplified ASM No. 1 to be 1.0 mg/L. If ammonium concentration of effluent was not equal to 1.0 mg/L, the influent ammonium was corrected by adaptive control. These processes above were repeatedly performed. The SBR running aerobic-anoxic phase had been controlled for 1 month with this method. As a result, the ammonium concentration of the effluent showed in the range of $0.22\sim3.1$ mg/L with an average concentration of 1.1 mg/L. The adaptive control method used in this study was found very useful to control and predict the effluent concentration of ammonium.