• Title/Summary/Keyword: Anode Application

검색결과 205건 처리시간 0.023초

대기압 비평형 플라스마의 발생 및 규소(Si)식각에의 응용 (Generation of Low Temperature Plasma at Atmospheric Pressure and its Application to Si Etching in Open Air)

  • 이봉주
    • 한국세라믹학회지
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    • 제39권4호
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    • pp.409-412
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    • 2002
  • 대기압 하에서 정상적으로 저온 플라스마가 발생 가능한 장치를 개발했다. 개발한 장치는 접지전극을 유전체로 피복한 용량결합형 전극구조로 되어 있다. rf(13.56 M Hz)을 여기 원으로서 사용한 아르곤(Ar) 또는 헬륨(He)은 플라스마 가스로서 사용했다. 발생한 플라스마는 발광분광법, 플로브 진단법에 의해 특성을 검토했다. 그 결과 전자온도>여기온도>가스온도 관계에 있는 비평형 상태의 플라스마였다. 본 장치를 사용하여 발생한 플라스마에 반응가스(CF4)을 첨가해서 대기 개방 계에서 Si(100)식각($1.5{\mu}m$/min)에 적용하여 높은 처리속도를 실현했다.

Application of NiOx Anode for Bottom Emission Organic Light Emitting Diode

  • Kim, Young-Hwan;Kim, Jong-Yeon;Kim, Byoung-Yong;Han, Jeong-Min;Moon, Hyun-Chan;Park, Kwang-Bum;Seo, Dae-Shik
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.448-448
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    • 2007
  • OLED has many advantages of low voltage operation, self radiation, light weight, thin thickness, wide view angle and fast response time to overcome existing liquid crystal display (LCD)'s weakness. Therefore, It draws attention as promising display and has already developed for manufactured goods. Also, OLED is regarded as a only substitute of flexible display with a thin display. However, Indium tin oxide(ITO) thin film for electrode of OLED shows a low electrical properties and is impossible to deposit at high thermal condition because electrical characteristics of ITO is getting worse. One of the ways to realize an improved flexible OLED is to use high internal efficiency electrodes, which have higher work function than those single layer of ITO films of the same thickness. The high internal efficiency electrodes film is developed with structure of nickel oxide for bottom Emission Type of OLED.

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파라메톡시페놀 및 히이드로퀴논 폐수(廢水)의 전기(電氣) 화학적(化學的) 처리(處理)에 관한 연구(硏究) (A Study on the Electrochemical Treatment of p-methoxyphenol and Hydroquinone Wastewater)

  • 김홍수;남기대;정노희;노윤찬
    • 한국응용과학기술학회지
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    • 제8권2호
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    • pp.153-159
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    • 1991
  • The electrochemical oxidation of p-methoxyphenol and hydroquinone for wastewater treatment application was investigated on platinum anode. At the cyclic voltammetry, it was observed that nagative shift of peak potential of p-methoxyphenol and hydroqinone as the pH of electrolytes increases and the peak current showed higher at strong electrolytes than weak electrolytes. In the case of p-methoxyphenol, the optimum electrode potential of controlled potential electrolysis was observed at the potential region of 0.8-1.0 (V vs. SCE) and hydroquinone was showed at the potential of l.0(V vs. SCE). Specially the oxidation rate of p-methoxyphenol and hydroquinone was showed high value in the acid electrolytes.

Li- and Na-ion Storage Performance of Natural Graphite via Simple Flotation Process

  • Laziz, Noureddine Ait;Abou-Rjeily, John;Darwiche, Ali;Toufaily, Joumana;Outzourhit, Abdelkader;Ghamouss, Fouad;Sougrati, Moulay Tahar
    • Journal of Electrochemical Science and Technology
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    • 제9권4호
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    • pp.320-329
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    • 2018
  • Natural graphite is obtained from an abandoned open-cast mine and purified by a simple, eco-friendly and affordable beneficiation process including ball milling and flotation process. Both raw graphite (55 wt %) and its concentrate (85 wt %) were electrochemically tested in order to evaluate these materials as anode materials for Li-ion and Na-ion batteries. It was found that both raw and purified graphites exhibit good electrochemical activities with respect to lithium and sodium ions through completely different reaction mechanisms. The encouraging results demonstrated in this work suggest that both raw and graphite concentrates after flotation could be used respectively for stationary and embedded applications. This strategy would help in developing local electrical storage systems with a significantly low environmental footprint.

Numerical model for local corrosion of steel reinforcement in reinforced concrete structure

  • Chen, Xuandong;Zhang, Qing;Chen, Ping;Liang, Qiuqun
    • Computers and Concrete
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    • 제27권4호
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    • pp.385-393
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    • 2021
  • Reinforcement corrosion is the main cause of the durability failure of reinforced concrete (RC) structure. In this paper, a three-dimensional (3D) numerical model of macro-cell corrosion is established to reveal the corrosion mechanisms of steel reinforcement in RC structure. Modified Direct Iteration Method (MDIM) is employed to solve the system of partial differential equations for reinforcement corrosion. Through the sensitivity analysis of electrochemical parameters, it is found that the average corrosion current density is more sensitive to the change of cathodic Tafel slope and anodic equilibrium potential, compared with the other electrochemical parameters. Furthermore, both the anode-to-cathode (A/C) ratio and the anodic length have significant influences on the average corrosion current density, especially when A/C ratio is less than 0.5 and anodic length is less than 35 mm. More importantly, it is demonstrated that the corrosion rate of semi-circumferential corrosion is much larger than that of circumferential corrosion for the same A/C ratio value. The simulation results can give a unique insight into understanding the detailed electrochemical corrosion processes of steel reinforcement in RC structure for application in service life prediction of RC structures in actual civil engineer.

1D와 CFD(Computational fluid dynamic) 시뮬레이션을 통한 PEMFC(Polymer Electrolyte Membrane Fuel Cell) 성능 비교 (Comparison of Polymer Electrolyte Membrane Fuel Cell performance obtained by 1D and CFD simulations)

  • 전원우;안세현;양재완;이지원;조현빈;염은섭
    • 한국가시화정보학회지
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    • 제21권3호
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    • pp.49-56
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    • 2023
  • The Polymer electrolyte membrane fuel cell (PEMFC) operates at ambient temperature as a low-temperature fuel cell. During its operation, voltage losses arise due to factors such as operating conditions and material properties, effecting its performance. Computational simulations of fuel cells can be categorized into 1D simulation and CFD, chosen based on their specific application purposes. In this study, we carried out an analysis validation using 1D geometry and compared its performance with the results from 2D geometry analysis. CFD allows for the representation of pressure, velocity distribution, and fuel mass fraction according to the geometry, enabling the analysis of current density. However, the 1D simulation, simplifying governing equations to reduce time cost, failed to accurately account for fuel distribution and changes in fuel concentration due to fuel cell operations. As a result, it showed unrealistic results in the cell voltage region dominated by concentration loss compared to CFD.

Galvanic Corrosion Between Component Parts of Aluminum Alloys for Heat Exchanger of Automobile

  • Y. R. Yoo;D. H. Kim;G. B. Kim;S. Y. Won;S. H. Choi;Y. S. Kim
    • Corrosion Science and Technology
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    • 제22권5호
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    • pp.322-329
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    • 2023
  • There are a variety of heat exchangers used in automobiles, such as shell and tube heat exchangers, double tube heat exchangers, and plate heat exchangers. Most of them are water-cooled to prevent engine overheating. There have been reports of corrosion damage to these heat exchangers due to continuous wetting caused by external temperature differences, road pollutants, and snow removal. In addition, galvanic corrosion, which occurs when two dissimilar materials come into contact, has been identified as a major cause. In this study, corrosion characteristics and galvanic corrosion behavior of Al alloy (AA3003, AA4045 and AA7072) used in automobile heat exchangers were analyzed. Effective clad materials for heat exchanger tubes and fins were also evaluated. It was found that AA7072 should be applied as the cladding material for fin AA3003 and that AA4045 was suitable as a cladding material for tube AA3003 because this clad materials application was the most effective clad design to delay the occurrence of pinhole in the tube. Main factors influencing galvanic corrosion dissolution were found to be galvanic corrosion potential difference and galvanic corrosion current density.

Corrosion Behavior of Inconel X-750 for Carbon Anode Oxide Reduction Application

  • Jeon, Min Ku;Kim, Sung-Wook;Lee, Sang-Kwon;Choi, Eun-Young
    • 방사성폐기물학회지
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    • 제18권3호
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    • pp.355-362
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    • 2020
  • The corrosion behavior of the Inconel X-750 alloy was investigated for its potential application under a Cl2-O2 mixed gas flow in an Ar atmosphere. The corrosion rate was found to be negligible at temperatures up to 400℃ under a flow rate of 30 mL·min-1 Cl2 + 170 mL·min-1 Ar, whereas an exponential increase was observed in the corrosion rate at temperatures greater than 500℃. The suppression of the corrosion reaction due to the presence of O2 was verified experimentally at flow rates of 30 mL·min-1 Cl2 (4.96 g·m-2·h-1), 20 mL·min-1 Cl2 + 10 mL·min-1 O2 (2.02 g·m-2 ·h-1), and 10 mL·min-1 Cl2 + 20 mL·min-1 O2 (1.34 g·m-2·h-1) under a constant Ar flow rate of 170 mL·min-1 at 600℃ for 8 h. The surface morphology analysis results revealed that porous surfaces with tunnel-type holes were produced under the Cl2-O2 mixed-gas condition. Furthermore, the effects of the Cl2 flow rate on the corrosion rate were investigated, indicating that its impact was negligible within the range of 5-30 mL·min-1 Cl2 at 600℃.

AAO 두께 및 표면 형상에 따른 고체-고체 마찰 대전 기반 에너지 하베스팅 발전 성능에 관한 연구 (A Study on the Output Performance of Solid-solid Triboelectric Energy Harvesting Depending on the Surface Morphology and Thickness of AAO)

  • 이광석;황운봉
    • Composites Research
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    • 제36권3호
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    • pp.224-229
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    • 2023
  • 최근 각종 전자기기의 소형화와 웨어러블 디바이스의 수요가 증가함에 따라 IT 기기들의 나노화가 진행되는 추세이며, 이에 따른 배터리의 크기 및 용량 등의 한계를 극복하기 위하여 에너지 하베스팅 기술인 마찰 대전에 대한 연구가 많은 관심을 받고 있다. 불소계 코팅을 진행한 양극산화 알루미늄은 대전 서열에서 음극 성향이 높은 대전층과 대전된 전하가 전극으로 손실없이 전달되도록 도와주는 절연층 그리고 전극을 모두 포함하고 있는 구조로서 마찰 대전 나노발전기의 적용에 있어 많은 연구가 진행되어 왔다. 본 연구에서는 마찰대전 나노발전기 적용에 유리한 양극산화 알루미늄을 활용하여 마찰대전 나노발전기에 영향을 미치는 표면 형상 및 절연층의 두께를 조절하여 발전량과의 상관관계에 대하여 분석하였다. 이러한 분석을 통하여 추후 마찰대전 나노발전기 제작에 있어 면적 대비 발전량을 증가시킬 수 있는 방향을 제시할 수 있었다.

재순환방식 튜브형 전해모듈시스템을 이용한 안료폐수의 전기화학적 산화 (Electrochemical Oxidation of Pigment Wastewater Using the Tube Type Electrolysis Module System with Recirculation)

  • 정종식
    • 대한환경공학회지
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    • 제38권8호
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    • pp.411-419
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    • 2016
  • 본 연구에서는 안료폐수 중에 포함되어 있는 유기물질과 질소를 처리함으로써 재순환방식을 이용한 튜브형 전해모듈시스템의 적용 가능성을 평가하였다. 튜브형 전해모듈은 내부 봉형 양극과 외부 튜브형 음극으로 이루어져있다. 양극의 재질은 $RuO_2$로 전착된 티타늄이었고 음극의 재질은 스테인리스 스틸이었다. 재순환형 튜브형 전해모듈시스템에서 오염물질의 제거율은 유량이 감소할수록 그리고 전류밀도가 증가할수록 높아졌다. 전해모듈시스템에서 체류시간이 180분일 때 염소산이온의 농도는 382.4~519.6 mg/L로 나타났다. 본 연구에서 사용한 재순환방식을 이용한 튜브형 전해모듈시스템에서 염소산이온의 생성은 전기화학적 산화의 중요한 인자 중의 하나이다. Bench scale의 재순환방식 튜브형 전해모듈시스템에서 전력량을 $4,500C/dm^2$으로 공급하였을 경우 $COD_{Mn}$은 89.6%, $COD_{Cr}$은 67.8%, T-N은 96.8% 그리고 색도는 74.2%가 제거되었으며, 이때 에너지 소모량은 $5.18kWh/m^3$이었다.