• Journal of the Korean Society for Nondestructive Testing
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• v.34 no.3
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• pp.241-247
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• 2014

This study presents the ultrasonic nonlinearity of AISI316 austenitic stainless steels subjected to longterm isothermal aging. These steels are attractive materials for use in industrial mechanical structures because of their strength at high-temperatures and their chemical stability. The test materials were subjected to accelerated heat-treatment in an electrical furnace for a predetermined aging duration. The variations in the ultrasonic nonlinearity and microstructural damage were carefully evaluated through observation of the microstructure. The ultrasonic nonlinearity stiffly dropped after aging for up to 1000 h and, then, monotonously decreased. The polygonal shape of the initial grain structures changed to circular, especially as the annealing twins in the grains dissolved and disappeared. The delta ferrite on the grain boundaries could not be observed at 1000 h of aging, and these continuously transformed into their sigma phases. Consequently, in the intial aging period, the rapid decrease in the ultrasonic nonlinearity was caused by voids, dislocations, and twin annihilation. The continuous monotonic decrease in the ultrasonic nonlinearity after the first drop resulted from the generation of $Cr_{23}C_6$ precipitates and ${\sigma}$ phases.

• Journal of Korea Foundry Society
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• v.32 no.2
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• pp.104-108
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• 2012

The effect of heat treatment on mechanical properties of 0.4C-2.3Si(wt%) steel with bainitic ferrite matrix were investigated. This steel has been synthesized intergrating concepts from TRIP(Transformation Induced Plasticity) steel & Austempered Ductile Cast Iron(ADI) technology. The low alloy medium carbon (0.4 %C) steel with high silicon (2.3 %Si) was initially annealed for 60 min at $800^{\circ}C$, $820^{\circ}C$ and $840^{\circ}C$ respectively in the intercritical region and then subsequently austempered at various temperatures at $260^{\circ}C$, $320^{\circ}C$ and $380^{\circ}C$ for 30 min in a salt bath. The mechanical properties were measured by using a tensile test. A detailed study of the microstructure of this steel after heat treatment was carried out by means of electron back scattering diffraction (EBSD) technic. In this study, a new low alloy steel with high strength (780~1,050MPa) and exceptionally high ductility (20~40%) was obtained.

• Journal of the Korean Society for Heat Treatment
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• v.28 no.5
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• pp.239-249
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• 2015

Various amount of NbC carbide was intentionally formed in a matrix-type cold-work tool steel by controlled amount of Nb and C addition. And the effect of NbC addition on the mechanical properties was investigated. Four alloys with different Nb and C contents were cast by vacuum induction melting, then hot forging and spheroidizing annealing were conducted. The machinability of the annealed specimens was examined with 3 different cutting tools. And tensile tests at room temperature were conducted. After quenching and tempering, hardness and impact toughness were measured, while wear resistance was evaluated by disk-on-plate type wear test. The increasing amount of NbC addition resulted in degraded machinability with increased strength, whereas the absence of NbC also led to poor machinability due to high toughness. After quenching and tempering, the additional NbC improved wear resistance with increasing hardness, whereas it deteriorated impact toughness. Therefore, it could be found that a moderate addition of NbC was desirable for the balanced combination of mechanical properties.

• Korean Journal of Materials Research
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• v.13 no.12
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• pp.819-824
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• 2003

The Al-7.7Zn-2.0Mg-1.9Cu-0.1Zr-0.1Sc alloy exhibited excellent elongation by the new thermomechanical treatment (TMT) process; solution treatment and furnace cooling\longrightarrowhot and cold rolling and then annealing for short time. Tensile test at high temperature from 430 to $500^{\circ}C$ has been performed with various strain rates using for the Al-7.7Zn-2.0Mg-1.9Cu-0.1Zr-0.1Sc alloy obtained by the TMT process. The elongation of the Al-7.7Zn-2.0Mg-1.9Cu-0.1Zr-0.1Sc was 550% tensile tested at $470^{\circ}C$ temperature and 2.2 $\times$ $10^{-3}$ $s^{-1}$ strain rate. The m value of Al-7.7Zn-2.0Mg-1.9Cu-0.1Zr-0.1Sc alloy deformed 85% increased from 0.33 to 0.46 with increasing total elongation. This new TMT process was very simple and easy to make the sheets in the company.

• Molecular & Cellular Toxicology
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• v.1 no.4
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• pp.230-236
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• 2005

Formaldehyde is a common environmental contaminant found in tobacco smoke, paint, garments, diesel and exhaust, and medical and industrial products. Formaldehyde has been considered to be potentially carcinogenic, making it a subject of major environmental concern. However, only a little information on the mechanism of immunological sensitization and asthma by this compound has been known. So, we performed with Jurkat cell line, a human T lymphocyte, to assess the induction of DNA damage and to identify the DEGs related to immune response or toxicity by formaldehyde. In this study, we investigated the induction of DNA single strand breaks by formaldehyde using single cell gel electrophoresis assay (comet assay). And we compared gene expression between control and formaldehyde treatment to identify genes that are specifically or predominantly expressed by employing annealing control primer (ACP)-based $GeneFishing^{TM}$ method. The cytotoxicity ($IC_{30}$) of formaldehyde was determined above the 0.65 mM in Jurkat cell in 48 h treatment. Based on the $IC_{30}$ value from cytotoxicity test, we performed the comet assay in this concentration. From these results, 0.65 mM of formaldehyde was not revealed significant DNA damages in the absence of S-9 metabolic activation system. And the one differentially expressed gene (DEG) of formaldehyde was identified to zinc finger protein 292 using $GeneFishing^{TM}$ method. Through further investigation, we will identify more meaningful and useful DEGs on formaldehyde, and then can get the information on the associated mechanism and pathway with immune response or other toxicity by formaldehyde exposure.

• Journal of the Korean Magnetics Society
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• v.16 no.1
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• pp.75-78
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• 2006

In case of contacts between semiconductor and metal in semiconductor circuits, they become unstable because of thermal budget. To prevent these problems, we use diffusion barrier that has a good thermal stability between metal and semiconductor. So we consider the diffusion barrier to prevent the increase of contact resistance between the interfaces of metals and semiconductors, and the increase of resistance and the reaction between the interfaces. In this paper we deposited tungsten boron carbon nitride (W-B-C-N) thin film on silicon substrate. The impurities of the $1000\;{\AA}-thick$ W-B-C-N thin films provide stuffing effect for preventing the inter-diffusion between metal thin films $(Cu-2000\;{\AA})$ and silicon during the high temperature $(700\~1000^{\circ}C)$ annealing process.

• Journal of the Mineralogical Society of Korea
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• v.17 no.4
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• pp.327-338
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• 2004

XRD studies on annealed Na-feldspar (Amelia albite) at $1100^{\circ}C$ showed rapid structural changes due to Si-Al disordering, which resulted in phase transformations from low albite to high albite by 4-days annealing test. TEM SAED analyses on the annealed samples revealed a trend of structural changes, but estimation of the structural state was difficult due to a large deviation of the SAED data. Optimum conditions of CBED analyses on albite was established by employing a cooling specimen holder, 120 kV of acceleration voltage, 37 Jim of condenser aperture size and 25 nm of spot size. A proper orientation showing distinct changes of HOLZ lines corresponding to the structure changes of albite turned out to be close to the [418] direction with $-1.2^{\circ}$ tilting, where the width of two HOLZ lines in low albite was opposite to those in high albite.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.169-170
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• 2006

In this study, ultra thin films of ferroelectric vinylidene fluoride-trifluoroethylene (VF2-TrFE) copolymer were fabricated on degenerated Si (n+, $0.002\;{\Omega}{\cdot}cm$) using by spin coating method. A 1~5 wt% diluted solution of purified vinylidene fluoride-trifluoroethylene (VF2:TrFE=70:30) in a dimethylformamide (DMF) solvent were prepared and deposited on silicon wafers at a spin rate of 2000~5000rpm for 30 seconds. After annealing in a vacuum ambient at $200^{\circ}C$ for 60 min, upper gold electrodes were deposited by vacuum evaporation for electrical measurement. X-ray diffraction results showed that the VF2-TrFE films on Si substrates had $\beta$-phase of copolymer structures. The capacitance on $n^+$-Si(100) wafer showed hysteresis behavior like a butterfly shape and this result indicates clearly that the dielectric films have ferroelectric properties. The typical measured remnant polarization (2Pr) and coercive filed (EC) values measured using a computer controlled a RT-66A standardized ferroelectric test system (Radiant Technologies) were about $0.54\;C/cm^2$ and 172 kV/cm, respectively, in an applied electric field of ${\pm}0.75\;MV/cm$.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.464-464
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• 2012

수문분야에 있어서 빈도해석의 목적은 특정 재현기간에 대한 발생 가능한 수문량의 규모를 파악하는데 있으며, 빈도해석의 정확도는 적합한 확률분포모형의 선택과 매개변수 추정방법에 의존하게 된다. 일반적으로 각 확률분포모형의 특성을 대표하는 매개변수를 추정하기 위해서는 모멘트 방법, 확률가중 모멘트 방법, 최대우도법 등을 이용하게 된다. 모멘트 방법에 의한 매개변수 추정은 해를 구하기 위한 과정이 단순한 반면, 비대칭형의 왜곡된 분포를 갖는 자료들에 대해서는 부정확한 결과를 나타내게 된다. 확률가중 모멘트 방법은 표본의 크기가 작거나 왜곡된 자료일 경우에도 비교적 안정적인 결과를 제공하는 반면, 확률 가중치가 정수로만 제한되는 단점을 갖고 있다. 그리고 대수 우도함수를 이용하여 매개변수를 추정하게 되는 최우도법은 가장 효율적인 매개변수 추정치를 얻을 수 있는 것으로 알려져 있으나, 비선형 연립방정식으로 표현되는 해를 구하기 위해서는 Newton-Raphson 방법을 사용하는 등 절차가 복잡하며, 때로는 수렴이 되지 않아 해룰 구하지 못하는 경우가 발생되게 된다. 이에 반해, 최근의 Genetic Algorithm, Ant Colony Optimization 및 Simulated Annealing과 같은 Meta-Heuristic Algorithm들은 복잡합 공학적 최적화 문제 있어서 효율적인 대안으로 주목받고 있으며, Hassanzadeh et al.(2011)에 의해 수문학적 빈도해석을 위한 매개변수 추정에 있어서도 그 적용성이 검증된바 있다. 본 연구의 목적은 연 최대강수 자료의 빈도해석에 적용되는 확률분포모형들의 매개변수 추정을 위해 Meta-Heuristic Algorithm을 적용하고자 함에 있다. 따라서 본 연구에서는 매개변수 추정을 위한 방법으로 Genetic Algorithm 및 Harmony Search를 적용하였고, 그 결과를 최우도법에 의한 결과와 비교하였다. GEV 분포를 이용하여 Simulation Test를 수행한 결과 Genetic Algorithm을 이용하여 추정된 매개변수들은 최우도법에 의한 결과들과 비교적 유사한 분포를 나타내었으나 과도한 계산시간이 요구되는 것으로 나타났다. 하지만 Harmony Search를 이용하여 추정된 매개변수들은 최우도법에 의한 결과들과 유사한 분포를 나타내었을 뿐만 아니라 계산시간 또한 매우 짧은 것으로 나타났다. 또한 국내 74개소의 강우관측소 자료와 Gamma, Log-normal, GEV 및 Gumbel 분포를 이용한 실증연구에 있어서도 Harmony Search를 이용한 매개변수 추정은 효율적인 매개 변수 추정치를 제공하는 것으로 나타났다.

• Korean Journal of Metals and Materials
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• v.48 no.8
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• pp.691-698
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• 2010

A study has been carried out to evaluate the interaction behavior between a lanthanide element and clad material in order to analyze the effect of the lanthanide element on the fuel cladding chemical interaction (FCCI). A diffusion couple test between Misch metal (70Ce-30La) and ferritic-martensitic steel (Gr.92) was performed at $660^{\circ}C$, followed by a microstructural analysis of the coupled sample. The results showed that Ce in the Misch metal, rather than La, reacted with the ferritic-martensitic steel (FMS) to form an interaction layer that penetrated the clad thickness. Fe diffused outside the clad interface to form an $Fe_2Ce$ compound, leaving a depletion of Fe caused by excess diffusion as well as by the formation of Cr-rich precipitation inside the interaction layer. The rate of growth followed the cubic rate law, which indicated that Fe depletion was caused by the diffusion of Fe and that the associated Cr-rich phase formation controlled the whole diffusion process.