• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
• /
• pp.822-823
• /
• 2006

The compaction and sintering behavior of zirconium titanate $(ZrTiO_4)$ was investigated by means of the measurement of sintering density and shrinkage, and the observation of microstructure. With increasing the content of $Al_2O_3$ additive, $Al_2O_3$-modified zirconium titanate samples fired at $1300^{\circ}C$ showed the anisotropic shrinkage behavior that the upper region of sintered body has higher sintering shrinkage than the low region. This difference of sintering shrinkage decreased with increasing firing temperature from 1300 to $1400^{\circ}C$. The SEM micrographs of powder compation show that the anisotropic shrinkage behavior is related with non-uniform density in a uniaxial compaction.

• 정보저장시스템학회:학술대회논문집
• /
• 정보저장시스템학회 2005년도 추계학술대회 논문집
• /
• pp.134-138
• /
• 2005

The crosstalk noise of thick holographic photopolymer is studied. Three different experiments, (1) reading area dependency (2) post-exposure effect (3) effect of later recorded holograms on earlier recorded holograms, have been accomplished and a tendency of crosstalk noises has been found for each case. The larger reading area, the higher crosstalk noises fur the later recorded holograms. Before the post-exposure the crosstalk noises are higher in the earlier recorded holograms, but after the post-exposure the crosstalk noises we higher in the later recorded holograms. The crosstalk noises of the earlier recorded holograms become higher as more holograms are recorded by multiplexing. To explain the tendency of crosstalk noises of these experiments, we suggest a model considering the anisotropic shrinkage of the photopolymer According to the model. the shrinkage is more dominant at the center of the recorded region than the edge of that. After the post-exposure, however, the amount of shrinkage becomes the same far the whole recorded region. The results of all three experiments are well explained by this model.

• Restorative Dentistry and Endodontics
• /
• 제28권6호
• /
• pp.457-466
• /
• 2003

The aim of study was to investigate the effect of flow, specimen geometry and adhesion on the measurement of linear polymerization shrinkage of light cured composite resins using linear shrinkage measuring device. Four commercially available composites - an anterior posterior hybrid composite Z100, a posterior packable composite P60 and two flowable composites, Filtek flow and Tetric flow-were studied. The linear polymerization shrinkage of composites was determined using 'bonded disc method' and 'non-bond-ed' free shrinkage method at varying C-factor in the range of 1∼8 by changing specimen geometry. These measured linear shrinkage values were compared with free volumetric shrinkage values. The viscosity and flow of composites were determined and compared by measuring the dropping speed of metal rod under constant load. In non-bonded method, the linear shrinkage approximated one third of true volumetric shrink-age by isotropic contraction. However, in bonded disc method, as the bonded surface increased the linear shrinkage increased up to volumetric shrinkage value by anisotropic contraction. The linear shrinkage value increased with increasing C-factor and approximated true volumetric shrinkage and reached plateau at about C-factor 5∼6. The more flow the composite was, reduced linear shrinkage was measured by compensation radial flow.

• 한국소성가공학회:학술대회논문집
• /
• 한국소성가공학회 2008년도 춘계학술대회 논문집
• /
• pp.507-511
• /
• 2008

LTCC (Low Temperature Co-fired Ceramic) has been successfully applied to ceramic substrates for circuits and micro-fluidic systems and has proven its superior performance in a variety of applications. The prediction of shrinkage in LTCC process is an important for dimensional control of micro LTCC products which has influences on electronic characteristics. For avoiding the unpredictable shrinkage of LTCC during the sintering which makes accurate placement of the circuit devices difficult, pre-processes such as WIP (Warm Isostatic Pressing) and lamination must be modified. The objective of the present investigation is to establish a proper WIP conditions for near net shape fabrication of LTCC products. This paper discusses the influence of WIP conditions on the dimensional change of LTCC sheet. In the investigation, it is shown that the shrinkage values of sheets depend on WIP conditions and sheet directions. This work is a quantitative evaluation of the effect of WIP pressure on shrinkage of LTCC sheet. Additionally, the results show anisotropic shrinkage behaviour of sheet during LTCC process.

• Elastomers and Composites
• /
• 제48권4호
• /
• pp.300-305
• /
• 2013

사출성형에서 성형수축은 피할 수 없는 현상이다. 따라서 성형수축을 줄이기 위한 연구가 필요할 뿐만 아니라 성형수축의 특성을 명확히 파악하는 것이 필요하다. 본 연구에서는 유리섬유로 보강된 폴리카보네이트를 이용하여 2.5차원형상인 환상형상의 시편에서 보이는 성형수축 현상을 조사하였다. 환상시편은 외경의 크기와 두께를 달리하여 설계하였다. 성형조건은 수지온도, 보압시간 및 보압크기를 변수로 설정하였다. 여러 성형조건으로 성형된 시편에서 내경과 외경의 크기가 변하는 양상에 대해서 분석하였다. 성형된 시편의 외경과 내경의 치수는 금형의 치수보다 작게 나타났다. 시편의 외경이 클수록, 그리고 시편의 두께가 두꺼울수록 수출율은 작게 나타났다. 또한 게이트의 위치에 따라 수축의 크기가 방향성을 보였다. 따라서 성형된 시편은 원형이 아니라 타원형으로 나타났고 게이트 방향으로 내경과 외경이 가장 큰 수축을 보였다. 수축된 제품의 형상조절을 위해서는 게이트 설계와 같은 금형설계가 중요하다고 판단된다.

• 한국의류학회지
• /
• 제21권1호
• /
• pp.170-181
• /
• 1997

The purpose of this study was to determine the effect of knit structure and knit density (machine tightness factor) on the dimensional properties and K1-4 values of weft-knitted fabrics followed over eleven cycles of mechanical relaxation to provide the basic data for constructing weft-knitted fabrics for outwear with excellent dimensional stability The eighteenth weft-knitted fabrics were produced with different knit structure (1$\times$1 rib, half-cardigan rib, half-milano rib, interlock, single pique, crossmiss interlock) and machine tightness factor (loose, medium, tight) for this study. Dimensional properties such as width, lengh, area shrinkage and dimensional parameter (K) of eighteenth knitted fabrics including thickness and bulk property were measured. The results were as follows; 1. The dimensional behavior of the Ix1 rib and interlock in relaxation cycles was anisotropic, i.e., length shrinkage was usually associated with a width expansion, whereas the other weft-kntted fabrics which have tuck or miss loops in the knit structure behaved isotropically, i.e., length and width shrinkages were usually found. It was proposed that the difference in dimensional behavior between these structures was due to the dissimilar nonrelaxed geometrical shapes of the individual structural units forming these weft-knitted structures. The mechanical relaxation shrinkage of weft-knitted cotton fabrics was dependent on the tightness of construction. For a range of fabrics knitted on this study, an increase in fabric tightness caused a decrease in the length shrinkage of the fabric accompanied by an increase in its width shrinkage.

• 한국세라믹학회지
• /
• 제56권2호
• /
• pp.130-145
• /
• 2019

Widespread commercialization of solid oxide fuel cells (SOFCs) is expected to be realized in various application fields with the advent of cost-effective fabrication of cells and stacks in high volumes. Cost-reduction efforts have focused on production yield, power density, operation temperature, and continuous manufacturing. In this article, we examine several issues associated with processing for SOFCs from the standpoint of the bimodal packing model, considering the external constraints imposed by rigid substrates. Optimum compositions of composite cathode materials with high volume fractions of the second phase (particles dispersed in matrix) have been analyzed using the bimodal packing model. Constrained sintering of thin electrolyte layers is also discussed in terms of bimodal packing, with emphasis on the clustering of dispersed particles during anisotropic shrinkage. Finally, the structural transition of dispersed particle clusters during constrained sintering has been correlated with the structural stability of thin-film electrolyte layers deposited on porous solid substrates.

• 방사성폐기물학회지
• /
• 제18권1호
• /
• pp.31-41
• /
• 2020

본 연구에서는 우라늄 폐촉매 처리 공정에서 발생하는 우라늄 함유 폐기물 대상으로 유리-세라믹 매질 구조의 대형 디스크 소결체 형태로 제작 시, 최종 제작된 소결체의 비등방향 수축 특성 및 변형율 변화를 연구하였다. 본 연구에서는 최대 직경 40 cm를 갖는 다양한 크기 원형 디스크 형태와 원형 디스크의 1/4 크기의 부채꼴 형 소결체를 제작하여 이들의 비등방성 수축 특성을 평가하였다. 60 MPa 압력하에서 만들어지는 성형체는 소결 시 성형체의 크기 및 형태에 관계없이 높은 등방성 수축하였다. 제조된 전체 소결체에 대한 비등방성율은 평균 1.6%이었고 이때 평균 부피 감용율은 37.4% 이었다. 이러한 결과로부터 국내에서 발생한 우라늄 폐촉매를 처리하기 위한 공정에서 발생하는 우라늄 함유 폐기물은 대형 디스크 형태의 유리-세라믹 매질 형태로 고형화함으로써 높은 안정성과 부피감용 효과를 가지며 200 L 드럼에 포장될 수 있음이 확인되었다.

• 폴리머
• /
• 제30권5호
• /
• pp.407-411
• /
• 2006

액상의 고분자 전구체 polyvinylsilazane (PVS) 혹은 allylhydridopolycarbosilane(AHPCS)를 실리콘 기판 위에 스핀 코팅한 다음, DVD 마스터로부터 제조된 polydimethylsiloxane(PDMS) 몰드를 이용한 자외선 나노임프린트법으로 나노 크기의 고분자 패턴을 제조하였다. 나아가 질소 분위기하에서 $800^{\circ}C$ 열처리함으로써 각각 SiCN, SiC 세라믹 패턴도 제조하였다. 가교된 고분자와 세라믹 패턴의 폭과 넓이를 원자힘현미경(AFM)과 주사전자현미경(SEM)으로 관측한 결과 PVS와 AHPCS의 패턴 높이는 각각 38.5%와 24.1%, 패턴 폭은 18.8%와 16.7%의 수축률을 나타내었다. 즉 전구체의 세라믹 수율이 높을수록 세라믹 패턴 수축률은 낮아졌고, 패턴과 기판과의 접착에 의한 수축억제로 이방성 수축현상도 관찰되었다. 본 연구결과는 새로운 세라믹 MEMS 소자제작공정으로서 나노임프린트법의 가능성과 수축률 제어 연구가 필요함을 제시하고 있다.

• 대한기계학회논문집A
• /
• 제21권1호
• /
• pp.154-163
• /
• 1997

Thermally-induced deformation in SMC(Sheet Molding Compound) products is analyzed using three dimensional finite element method. Planar fiber orientation, which causes the anisotropic material properties, is calculated through the flow analysis during the compression stage of the mold. Also curing process is analyzed to predict temperature profile which has significant effects on warpage of SMC products. Through the developed procedure, effects of various process conditions such as charge location, mold temperature, fiber contents, and fiber orientations on deformation of final products are studied. and processing strategies are proposed to reduce the warpage and the shrinkage.