• Title/Summary/Keyword: Aniline decomposition

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Preparation and Photocatalytic Characteristics of $TiO_2$ by Anodic Oxidation Process (양극산화법에 의한 광촉매용 $TiO_2$제조 및 특성)

  • Jang, Jae-Myeong;Kim, Seong-Gap;O, Han-Jun;Lee, Jong-Ho;Ji, Chung-Su
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.61-66
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    • 2001
  • $TiO_2$films for photocatalytic reaction were synthesized by anodizing process. The photocatalytic efficiencies of anodized $TiO_2$were evaluated by the rate of decomposition of aniline blue. The properties of photocatalysis on anodic $TiO_2$films have been observed, but the efficiencies of photocatalytic reaction depended on the conditions of films formation. The microstructure of the anodic film formed in $H_2SO_4$ solution differed from that of $TiO_2$films formed in $H_2SO_4+H_3PO_4$ solution. It has been shown that the appropriate applied-voltage for anodizing of titanium for photocatalysis was 180V in both aqueous solutions.

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Characterization of Biodegradable Conductive Composite Films with Polyaniline(2) (폴리아닐린을 함유한 도전성 복합필름의 제조 및 특성 연구(2))

  • Lee, Soo;Seong, Eun-Suk
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.85-92
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    • 2015
  • The 50 mole% HCl doped polyaniline(PAni) was synthesized by polymerization of aniline in the presence of hydrochloric acid and ammonium persulfate(APS) as dopant and oxidant, respectively. Then, conducting biodegradable cellulose acetate composite films were also prepared with PAni in acetone to find their applicability to antistatic packaging materials. The tensile strength of PCA05 film with 5 wt% of PAni was decreased by 27% from $377.1kg_f/cm^2$ for CA film itself to $275.2kg_f/cm^2$. Elongation was also decreased from 7.65% to 4.35%. Surface registance of $7.0{\times}10^9{\Omega}/sq$ could be achieved for the PCA containing 5 wt% of PAni. Therefore, this PCA05 film can be applied to antistatic package film for electronic board. In addition, decomposition temperature of these PCA films obtained by thermogravimetric analysis(TGA) was decreased with the amount of PAni in PCA films, and the final weight of char was directly proportional to PAni contents. From this thermal result we can calculate the content of PAni in unknown PCA films.