• 제목/요약/키워드: Anchoring energy

검색결과 74건 처리시간 0.025초

반사형 TN 액정 셀의 In-Plane스위칭 (In-Plane Switiching of a Twisted-Nematic Reflective LC Cell)

  • 정미준;곽진석;이기동;김재창;윤태훈
    • 한국광학회:학술대회논문집
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    • 한국광학회 2004년도 제15회 정기총회 및 동계학술발표회
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    • pp.138-139
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    • 2004
  • In this paper, we propose a reflective In-Plane Switching twisted nematic mode with negative liquid crystal and weak surface anchoring energy (10$^{-6}$ J/m) in order to enhance reflectance and cellgap margin.

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Improving support performances of cone bolts by a new grout additive and energy absorber

  • Komurlu, Eren
    • Advances in materials Research
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    • 제11권3호
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    • pp.237-250
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    • 2022
  • The cone bolts with expanded front ends supply improved anchoring performances and increase energy absorbing capacities due to ploughing in the grouted drills. Within this study, use of a novel energy absorber for the cone bolt heads were investigated to assess its design in terms of supplying high support performances. Additionally, different grout material designs were tested to investigate whether the energy absorption capacities of the rock bolts can be improved using a silicone based thermoset polymer (STP) additive. To determine load bearing and energy absorption capacities, a series of deformation controlled pull-out tests were carried out by using bolt samples grouted in rock blocks. According to the results obtained from this study, maximum load bearing capacities of cone bolts are similar and mostly depend on the steel material strength, whereas the energy absorption capacity was determined to significantly vary in accordance with the displacement limits of the shanks. As a result of using STP additive and new polyamide absorber rings, displacement limits without the steel failure increase. The STP additive was found to improve the energy absorption capacities of grouted cone bolts. The absorber rings designed within this study were also assessed to be highly effective and able to double up the energy absorption capacities of the cone bolts.

트리페닐아민을 이용한 염료감응형 태양전지 고효율 염료합성 (Highly Efficient and Stable Organic Photo-Sensitizers based on Triphenylamine with Multi-anchoring Chromophore for Dye-sensitized Solar Cells)

  • 양현식;정대영;정미란;김재홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2010년도 춘계학술대회 초록집
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    • pp.88.1-88.1
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    • 2010
  • Organic dyes, because of their many advantages, such as high molar extinction coefficients, convenience of customized molecular design for desired photophysical and photochemical properties, inexpensiveness with no transition metals contained, and environment-friendliness, are suitable as photosensitizers for the Dye-sensitized Solar Cell (DSSC). The efficiency of DSSC based on metal-free organic dyes is known to be much lower than that of Ru dyes generally, but a high solar energy-to-electricity conversion efficiency of up to 8% in full sunlight has been achieved by Ito et al. using an indoline dye. This result suggests that smartly designed and synthesized metal-free organic dyes are also highly competitive candidates for photosensitizers of DSSCs with their advantages mentioned above. Recently, the performance of DSSC based on metal-free organic dyes has been remarkably improved by several groups. We had reported the novel organic dye with double electron acceptor chromophore, which was a new strategy to design an efficient photosensitizer for DSSC. To verify the strategy, we synthesized organic dyes whose geometries, electronic structures and optical properties were derived from preceding density functional theory (DFT) and time-dependent density functional theory (TD-DFT) calculations. In this paper, we successfully synthesized the chromophore containing multi-acceptor push-pull system from triphenylamine with thiophene moieties as a bridge unit. Organic dyes with a single electron acceptor and double acceptor system were also synthesized for comparison purposes. The photovoltaic performances of these dyes were compared, and the recombination dark current curves and the incident photon-to-current (IPCE) efficiencies were also measured in order to characterize the effects of the multi-anchoring groups on the open-circuit voltage and the short-circuit current. In order to match specifications required for practical applications to be implemented outdoors, light soaking and thermal stability tests of these DSSCs, performed under $100mWcm^{-2}$ and $60^{\circ}C$ for 1000h.

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Asperities on the Surface of Plate-like Alumina and their Effect on Nacre-inspired Alumina-PMMA Composites

  • Kim, Bo-Yeon;Lee, Yoonjoo;Kim, Soo-Ryong;Shin, Dong-Geun;Kwon, Woo-Teck;Choi, Duck-Kyun;Kim, Younghee
    • 한국세라믹학회지
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    • 제52권4호
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    • pp.248-252
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    • 2015
  • Natural materials often have unique mechanical properties, such as the hierarchical structure of nacre formed through mineral bridges or asperities created between an inorganic particle and a natural-layer surface. As these asperities produce an exceptional shear resistance, in this study, we aimed to emulate the natural structure of nacre by synthesizing inorganic asperities and mineral bridges with different temperatures in the range of $1100-1300^{\circ}C$ and clay contents from 10 - 50 wt%. Following the infiltration of methyl methacrylate, we measured the mechanical properties to assess whether they were improved by the asperities. It was confirmed that the asperities improved the bending strength by 10%, and the anchoring effect was observed on the fracture surface.

IPS-LCD에서의 표면액정배향효과가 시야각 특성과 응답속도에 미치는 영향 (Improvement of the response time and embodiment of the viewing angle in IPS mode)

  • 최재학;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1998년도 추계학술대회 논문집
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    • pp.65-68
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    • 1998
  • The mechanism of response time and viewing angle in in-plane switching ( IPS ) liquid crystal display ( LCD ) were investigated. The response time of photo-aligned IPS-LCD is fast compared with rubbing-aligned IPS-LCD on polyimide ( PI ) surface. The decay time $\tau$$\_$d/ is decreased with increasing the azimuthal anchoring energy A $\psi$ due to the steric interaction between the LC molecules and side chain of polymer. The viewing angle of IPS-LCD is increased by using photo-depolymerizatin method ; about ${\pm}$70$^{\circ}$at all direction.

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Structure and Dynamics in Surfaces of Polymers and Organic Electronic Materials

  • Yoon, Do-Y.;Lee, Sang-Hun;Jung, Young-Suk;Jo, Jung-Ho;Jeong, Won-Hee;Chang, Jae-Eon;Luning, Jan
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.112-112
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    • 2006
  • Detailed surface characteristics of polymer films have been investigated by atomistic molecular dynamics simulations and NEXAFS spectroscopy experiments. The geometric confinement of the surfaces and the necessity to minimize the surface energy lead to the significant molecular organization and orientation in polymer surfaces, with their properties strongly depending upon the atomistic monomer structures. As compared with polymers, oligomeric electronic materials are much more readily aligned by employing various surface anchoring forces, rendering them highly attractive as polarized-light emitting materials and active semiconducting materials in thin film transistors.

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Surface sliding effect of nematic liquid crystals on soft- polymer

  • Lee, Chang-Hoon;Gwag, Jin-Seog;Lee, You-Jin;Jin, Min-Young;Kim, Jae-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.310-313
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    • 2008
  • Recently, study on the weak interaction energy between the soft polymer surface and liquid crystals has been a primary topic for new LC device applications. In this paper, to understand the switching property of nematic liquid crystals (LCs) at the interface with a weak anchoring boundary, we investigate experimentally the rotation property of surface nematic director by electric field on non-treated Poly-Methylmethacrylate (PMMA, $T_g=110^{\circ}C$, Sigma Aldrich) film observed under various temperatures including the glass transition temperature ($T_g$) of the polymer layer.

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Periodic Boundary Effect on Multi-Domain Formation in Liquid Crystal Devices

  • Yu, Chang-Jae;Park, Jae-Hong;Kim, Jin-Yool;Jung, Min-Sik;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.478-481
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    • 2003
  • We studied a periodic boundary effect in liquid crystal (LC) devices with multi-domains consisting of homeotropic and hybrid alignments. In this configuration, the surface anchoring energy was determined using the LC director-distorted length near the domain boundary, in a linear approximation of the director profile based on the continuum theory. The distorted length was measured in the LC binary diffraction grating.

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Flexible bistable chiral splay nematic display mode using reactive mesogens

  • Bae, Kwang-Soo;Lee, You-Jin;You, Chang-Jae;Kim, Jae-Hoon
    • Journal of Information Display
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    • 제12권4호
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    • pp.195-198
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    • 2011
  • Proposed herein is a flexible bistable chiral splay nematic display mode with an enhanced memory retention time under external distortion. By adopting the polymerized reactive-mesogen structure mixed in a liquid crystal layer, local anchoring energy is generated on the boundary between the polymer structures, and the relaxation from the ${\pi}$-twisted state to the initial splay state could be interrupted. As a result, the memory retention time becomes significantly longer, and the stability against the external distortion is enhanced.

Director gliding on photoaligning surfaces

  • Reznikov, Yuri;Buluy, Olexander;Kurioz, Yuriy;lljin, Andery;Ouskova, Elena;Antonova, K.;Nobili, Maurizio
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.764-767
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    • 2005
  • Photoaligning polymers usually possess "sofe" surface, containing flexible groups and provide relatively small anchoring energy($W<10^{-2}$ erg $cm^{-2}$). In this case field-induced reorientation of director on the aligning surface is essential. We have shown that surface director reorientation can modify the aligning surface and result in gliding of the axis of easy orientation of LC. this phenomena together with adsorption/desorption of ions in electric field cause strong sticking effect in LCDs photoaligning materials. We proposed a method of decreasing of the sticking effect based on irradiation of the photoaligning surface by an unpolarized light.

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