• Title/Summary/Keyword: Analytical-synthetic

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A Study on the Determination for Stochastic Reservoir Capacity (추계학적 저수용량 결정에 관한 연구)

  • Choe, Han-Gyu;Choe, Yong-Park;Kim, Chi-Hong
    • Water for future
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    • v.19 no.2
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    • pp.149-156
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    • 1986
  • The generated sequences of monthly flows were analyzed based on the range concept. With the optimum operation rule of the reservoirs as the one which maximizes the wateruse downstream the waterrelease from the reservoir was determined and with \ulcorner consideration to the mean inflows and the range of monthly flows the required reservoirs capacity was stochastically determind. It is suggested that the result obtained in this study would be applied to approximately estimate, in the stage of preliminary design, the required capacity of a reservoir in question with the limited information such as the mean monthly inflow and the period of reservoir operation. For the determination of a reservoir capacity Rippl's mass-curve method has been long used with the past river flow data assuming the same flow records will be repeated in the future. This study aims to find out a better method for determining the reservoir capacity by employing the analytical theory based on the stochastic process. For the present study the synthetic generation methods of Thomas-Fiering type was used to synthetically generate 50 years of monthly river inflows to three single-purpose reservoirs and three multi-purpose reservoirs.

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X-Ray Fluorescence Analysis of $Ta_2O_5, Nb_2O_5, TiO_2, SnO_2$ and $Zr_O2$ in Tin-Slags (주석-슬랙 중 $Ta_2O_5, Nb_2O_5, TiO_2, SnO_2$, 및 $ZrO_2$의 X-선 형광분석)

  • Young-Sang Kim;Chong Wook Lee
    • Journal of the Korean Chemical Society
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    • v.27 no.4
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    • pp.273-278
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    • 1983
  • With the synthetic standards, valuable metals $(Ta_2O_5, Nb_2O_5, TiO_2, SnO_2$, and $ZrO_2$) in the tin slags have been determined by the x-ray fluorescence spectrometry. The powder sample and the standards are homogeneously mixed with anhydrous $Li_2B_4O_7$ and La_2O_3$ in weight ratio of 15 : 42 : 3 respectively. The mixed material is fused at $1,150^{\circ}C$ for 30 minutes to be changed into the glass bead. The bead is ground to (-) 325 mesh size and pelletized. The analytical results obtained in this work are consistent with the data obtained by other common methods within allowable error range. The standard deviation for $Ta_2O_5$ in PTS-H sample is 0.12 % at level of 3.40 % content.

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Free-Form Surface Reconstruction Method from Second-Derivative Data (형상이차미분을 이용한 자유곡면 형상복원법)

  • Kim, Byoung Chang;Kim, DaeWook;Kim, GeonHee
    • Korean Journal of Optics and Photonics
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    • v.25 no.5
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    • pp.273-278
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    • 2014
  • We present an algorithm for surface reconstruction from the second-derivative data for free-form aspherics, which uses a subaperture scanning system that measures the local surface profile and determines the three second-derivative values at those local sampling points across the free-form surface. The three second-derivative data were integrated to get a map of x- and y-slopes, which went through a second Southwell integration step to reconstruct the surface profile. A synthetic free-form surface 200 mm in diameter was simulated. The simulation results show that the reconstruction error is 19 nm RMS residual difference. Finally, the sensitivity to noise is diagnosed for second-derivative Gaussian random noise with a signal to noise ratio (SNR) of 16, the simulation results proving that the suggested method is robust to noise.

A Novel Acid-Base Catalyzed Sol-Gel Synthesis of Highly Active Mesoporous TiO2 Photocatalysts

  • Khan, Romana;Kim, Sun-Woo;Kim, Tae-Jeong;Lee, Hyo-Sun
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1951-1957
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    • 2007
  • A new synthetic strategy based on the acid-base catalyzed sol-gel method was developed for the preparation of a series of mesoporous TiO2 nanoparticles. A key feature of the method involves a gradual change in pH (0.8- 9) during the sol-gel transition, which guarantees easy introduction of mesoporosity without relying on the well-established sonochemical or template approach. In addition, this method leads to the exclusive formation of the anatase phase stable enough to the calcination temperature up to 600 oC. The physicochemical properties of the particles in the series were characterized by various spectroscopic and analytical techniques such as wide-angle XRD, SAXRD, BET surface area, FE-SEM, TEM, FT-IR, TGA, and XPS. The photocatalytic efficiency of these materials was investigated for the oxidation of toluene under UV-irradiation. All but T-ad in the series exhibited high photocatalytic activity pushing the reaction into completion within 3 h. The reaction followed the first order kinetics, and the rate reaches as high as 3.9 × 10?2/min which exceeds the one with the commercially available Degussa P-25 by a factor of 3.2. When comparison is made among the catalysts, the reactivity increases with increase in the calcination temperature which in turn increases the crystallinity of the anatase phase, thus revealing the following rate orders: T-3 < T-4 < T-5 < T-6.

Automatic Estimation of Threshold Values for Change Detection of Multi-temporal Remote Sensing Images (다중시기 원격탐사 화상의 변화탐지를 위한 임계치 자동 추정)

  • 박노욱;지광훈;이광재;권병두
    • Korean Journal of Remote Sensing
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    • v.19 no.6
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    • pp.465-478
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    • 2003
  • This paper presents two methods for automatic estimation of threshold values in unsupervised change detection of multi-temporal remote sensing images. The proposed methods consist of two analytical steps. The first step is to compute the parameters of a 3-component Gaussian mixture model from difference or ratio images. The second step is to determine a threshold value using Bayesian rule for minimum error. The first method which is an extended version of Bruzzone and Prieto' method (2000) is to apply an Expectation-Maximization algorithm for estimation of the parameters of the Gaussian mixture model. The second method is based on an iterative thresholding algorithm that successively employs thresholding and estimation of the model parameters. The effectiveness and applicability of the methods proposed here were illustrated by two experiments and one case study including the synthetic data sets and KOMPSAT-1 EOC images. The experiments demonstrate that the proposed methods can effectively estimate the model parameters and the threshold value determined shows the minimum overall error.

A review on status of organic micropollutants from sewage effluent and their management strategies (하수 유래 미량오염물질 현황과 관리 방안 고찰)

  • Choi, Sangki;Lee, Woongbae;Kim, Young-Mo;Hong, Seok-Won;Son, Heejong;Lee, Yunho
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.3
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    • pp.205-225
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    • 2021
  • Due to the large-scale production and use of synthetic chemicals in industralized countries, various chemicals are found in the aquatic environment, which are often termed as micropollutants. Effluents of municipal wastewater treatment plants (WWTPs) have been identified as one of the major sources of these micropollutants. In this article, the current status of occurrence and removal of micropollutants in WWTPs and their management policies and options in domestic and foregin countries were critically reviewed. A large number of pharmaceuticals, personal care products, and industrial chemicals are found in WWTPs' influent, and are only partially removed by current biological wastewater treatment processes. As a result, some micropollutants are present in WWTPs' effluents, which can negatively affect receiving water quality or drinking water source. To better understand and assess the potential risk of micropollutants, a systematic monitoring framework including advanced analytical tools such as high resolution mass spectrometry and bioanalytical methods is needed. Some Western European countries are taking proactive approach to controlling the micropollutants by upgrading WWTP with enahnced effluent treatment processes. While this enahnced WWTP effluent treatment appears to be a viable option for controlling micropollutant, its implementation requires careful consideration of the technical, economical, political, and cultural issues of all stakeholders.

Closed-form Expressions of Vector Magnetic and Magnetic Gradient Tensor due to a Line Segment (선형 이상체에 의한 벡터 자력 및 자력 변화율 텐서 반응식)

  • Rim, Hyoungrea
    • Geophysics and Geophysical Exploration
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    • v.25 no.2
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    • pp.85-92
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    • 2022
  • An elongated object in one direction can be approximated as a line segment. Here, the closed-form expressions of a line segment's vector magnetic and magnetic gradient tensor are required to interpret responses by a line segment. Therefore, the analytical expressions of the vector magnetic and magnetic gradient tensor are derived. The vector magnetic is converted from the existing gravity gradient tensor using Poisson's relation where the gravity gradient tensor caused by a line segment can be transformed into a vector magnetic. Then, the magnetic gradient tensor is derived by differentiating the vector magnetic with respect to each axis in the Cartesian coordinate system. The synthetic total magnetic data simulated by an iron pile on boreholes are inverted by a nonlinear inversion process so that the physical parameters of the iron pile, including the beginning point, the length, orientation, and magnetization vector are successfully estimated.

Finite Element Analysis Study of CJS Composite Structural System with CFT Columns and Composite Beams (CFT기둥과 합성보로 구성된 CJS합성구조시스템의 유한요소해석 연구)

  • Moon, A Hae;Shin, Jiuk;Lim, Chang Gue;Lee, Kihak
    • Journal of the Earthquake Engineering Society of Korea
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    • v.26 no.2
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    • pp.71-82
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    • 2022
  • This paper presents the effect on the inelastic behavior and structural performance of concrete and filled steel pipe through a numerical method for reliable judgment under various load conditions of the CJS composite structural system. Variable values optimized for the CJS synthetic structural system and the effects of multiple variables used for finite element analysis to present analytical modeling were compared and analyzed with experimental results. The Winfrith concrete model was used as a concrete material model that describes the confinement effect well, and the concrete structure was modeled with solid elements. Through geometric analysis of shell and solid elements, rectangular steel pipe columns and steel elements were modeled as shell elements. In addition, the slip behavior of the joint between the concrete column and the rectangular steel pipe was described using the Surface-to-Surface function. After finite element analysis modeling, simulation was performed for cyclic loading after assuming that the lower part of the foundation was a pin in the same way as in the experiment. The analysis model was verified by comparing the calculated analysis results with the experimental results, focusing on initial stiffness, maximum strength, and energy dissipation capability.

Establishment of Analytical Method for Dichlorprop Residues, a Plant Growth Regulator in Agricultural Commodities Using GC/ECD (GC/ECD를 이용한 농산물 중 생장조정제 dichlorprop 잔류 분석법 확립)

  • Lee, Sang-Mok;Kim, Jae-Young;Kim, Tae-Hoon;Lee, Han-Jin;Chang, Moon-Ik;Kim, Hee-Jeong;Cho, Yoon-Jae;Choi, Si-Won;Kim, Myung-Ae;Kim, MeeKyung;Rhee, Gyu-Seek;Lee, Sang-Jae
    • Korean Journal of Environmental Agriculture
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    • v.32 no.3
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    • pp.214-223
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    • 2013
  • BACKGROUND: This study focused on the development of an analytical method about dichlorprop (DCPP; 2-(2,4-dichlorophenoxy)propionic acid) which is a plant growth regulator, a synthetic auxin for agricultural commodities. DCPP prevents falling of fruits during their growth periods. However, the overdose of DCPP caused the unwanted maturing time and reduce the safe storage period. If we take fruits with exceeding maximum residue limits, it could be harmful. Therefore, this study presented the analytical method of DCPP in agricultural commodities for the nation-wide pesticide residues monitoring program of the Ministry of Food and Drug Safety. METHODS AND RESULTS: We adopted the analytical method for DCPP in agricultural commodities by gas chromatograph in cooperated with Electron Capture Detector(ECD). Sample extraction and purification by ion-associated partition method were applied, then quantitation was done by GC/ECD with DB-17, a moderate polarity column under the temperature-rising condition with nitrogen as a carrier gas and split-less mode. Standard calibration curve presented linearity with the correlation coefficient ($r^2$) > 0.9998, analysed from 0.1 to 2.0 mg/L concentration. Limit of quantitation in agricultural commodities represents 0.05 mg/kg, and average recoveries ranged from 78.8 to 102.2%. The repeatability of measurements expressed as coefficient of variation (CV %) was less than 9.5% in 0.05, 0.10, and 0.50 mg/kg. CONCLUSION(S): Our newly improved analytical method for DCPP residues in agricultural commodities was applicable to the nation-wide pesticide residues monitoring program with the acceptable level of sensitivity, repeatability and reproducibility.

Analysis of Optimal Locations for Resource-Development Plants in the Arctic Permafrost Considering Surface Displacement: A Case Study of Oil Sands Plants in the Athabasca Region, Canada (지표변위를 고려한 북극 동토 지역의 자원개발 플랜트 건설 최적 입지 분석: 캐나다 Athabasca 지역의 오일샌드 플랜트 사례 연구)

  • Taewook Kim;YoungSeok Kim;Sewon Kim;Hyangsun Han
    • The Journal of Engineering Geology
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    • v.33 no.2
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    • pp.275-291
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    • 2023
  • Global warming has made the polar regions more accessible, leading to increased demand for the construction of new resource-development plants in oil-rich permafrost regions. The selection of locations of resource-development plants in permafrost regions should consider the surface displacement resulting from thawing and freezing of the active layer of permafrost. However, few studies have considered surface displacement in the selection of optimal locations of resource-development plants in permafrost region. In this study, Analytic Hierarchy Process (AHP) analysis using a range of geospatial information variables was performed to select optimal locations for the construction of oil-sands development plants in the permafrost region of southern Athabasca, Alberta, Canada, including consideration of surface displacement. The surface displacement velocity was estimated by applying the Small BAseline Subset Interferometric Synthetic Aperture Radar technique to time-series Advanced Land Observing Satellite Phased Array L-band Synthetic Aperture Radar images acquired from February 2007 to March 2011. ERA5 reanalysis data were used to generate geospatial data for air temperature, surface temperature, and soil temperature averaged for the period 2000~2010. Geospatial data for roads and railways provided by Statistics Canada and land cover maps distributed by the North American Commission for Environmental Cooperation were also used in the AHP analysis. The suitability of sites analyzed using land cover, surface displacement, and road accessibility as the three most important geospatial factors was validated using the locations of oil-sand plants built since 2010. The sensitivity of surface displacement to the determination of location suitability was found to be very high. We confirm that surface displacement should be considered in the selection of optimal locations for the construction of new resource-development plants in permafrost regions.