• Title/Summary/Keyword: Analytical Analysis

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Intercomparison and Determination of Trace Elements in Urban Dust by Neutron Activation Analysis (중성자방사화분석법을 이용한 대기분진중의 미량원소 비교분석)

  • Chung, Yong-Sam;Moon, Jong-Hwa;Kim, Sun-Ha;Park, Kwang-Won;Kang, Sang-Hun
    • Analytical Science and Technology
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    • v.13 no.2
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    • pp.179-188
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    • 2000
  • Trace elements in air samples artificially loaded on filters with urban dust and the bulk material of urban dust as an environmental sample were determined non-destructively using instrumental neutron activation analysis. Standard reference material (Urban Dust, SRM 1648) of the National Institute of Standard and Technology was used for the analytical quality control. The relative error for 37 elements was less than 15% and the standard deviation was less than 10%. 29 elements in the urban dust and 21 elements in the loaded filter sample were determined respectively. To evaluate the proficiency and reliability of the measurement, data intercomparison was performed and 39 analytical laboratories participated in the analysis using different analytical methods; neutron activation analysis, particle induced X-ray emission analysis, X-ray fluorescence analysis and atomic absorption spectrometry. Z-scores were calculated using the standard deviation of the laboratorie's mean as target standard deviation, and a good result was obtained that the values fall between -1 and +1 except some elements.

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Analysis and Optimization of the Axial Flux Permanent Magnet Synchronous Generator using an Analytical Method

  • Ikram, Junaid;Khan, Nasrullah;Junaid, Qudsia;Khaliq, Salman;Kwon, Byung-il
    • Journal of Magnetics
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    • v.22 no.2
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    • pp.257-265
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    • 2017
  • This paper presents a 2-D analytical method to calculate the back EMF of the axial flux permanent magnet synchronous generator (AFPMSG) with coreless stator and dual rotor having magnets mounted on both sides of rotor yoke. Furthermore, in order to reduce the no load voltage total harmonics distortion (VTHD), the initial model of the coreless AFPMSG is optimized by using a developed analytical method. Optimization using the 2-D analytical method reduces the optimization time to less than a minute. The back EMF obtained by using the 2-D analytical method is verified by a time stepped 3-D finite element analysis (FEA) for both the initial and optimized model. Finally, the VTHD, output torque and torque ripples of both the initial and optimized models are compared with 3D-FEA. The result shows that the optimized model reduces the VTHD and torque ripples as compared to the initial model. Furthermore, the result also shows that output torque increases as the result of the optimization.

The chemical speciation and analysis of trace elements in sediment with neutron activation analytical method(NAA) and atomic mass spectrometry (중성자 방사화분석법과 원자질량분석법을 이용한 침전물 시료속에 존재하는 미량원소들의 화학종 분류 및 분석)

  • Nam, Sang-Ho;Kim, Jae-Jin;Chung, Yong-Sam;Kim, Sun-Ha
    • Analytical Science and Technology
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    • v.16 no.5
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    • pp.358-367
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    • 2003
  • In this research, first of all, the analytical methods for the determination of major elements in sediment have been developed with ICP-MS (Inductively Coupled Plasma Mass Spectrometry). The analytical results of major elements (Al, Ca, K, Fe, Mg) with Cool ICP-MS were much better than those with normal ICP-MS. The analytical results were compared with those of NAA (Neutron Activation Analysis). NAA were a little superior to ICP-MS for the determination of major elements in sediment as a non-destructive trace analytical method. The analytical methods for the determination of minor elements (Cr, Ce, U, Co, Pb, As, Se) have been also developed with ICP-MS. The analytical results by standard calibration curve with ICP-MS were not accurate due to the matrix interferences. Thus, the internal standard method was applied, then the analytical results for minor elements with ICP-MS were greatly improved. The analytical results obtained by ICP-MS were compared with those obtained by NAA. It showed that the two analytical methods have great capabilities for the determination of minor elements in sediments. Accordingly, the NAA will play an important role in analysis of environment sample with complex matrix. ICP-MS also will play an important role because it has a great capability for the determination of Pb that could not be determined by NAA.

Torque Analysis of Magnetic Spur Gear with Radial Magnetized Permanent Magnets based on Analytical Method (해석적 방법을 이용한 반경방향 영구자석을 갖는 자기 스퍼 기어의 토크특성해석)

  • Min, Kyoung-Chul;Choi, Jang-Young;Sung, So-Young;Park, Jong-Won
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.64 no.4
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    • pp.545-551
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    • 2015
  • This paper deals with torque analysis of magnetic spur gear with radial magnetized permanent magnets based on analytical method. The analysis is implemented in three parts: First, on the basis of magnetic vector potential and a two-dimensional (2D) polar-coordinate system, the magnetic field solution due to permanent magnet of source gear are obtained. And by using derived magnetic field solutions, the analytical solutions for external magnetic field distribution which affects load gear are obtained. Second, by using coordinate conversion, external magnetic field which is on the primary coordinate system is converted to the secondary coordinate system. Finally, the load gear is reduced to equivalent current densities, and the torque is computed on these currents in the external field of the source magnet. These analytical results are validated by comparing with the 2-D finite element analysis (FEA).

Semi-analytical Numerical Analysis of the Core-size and Electric-field Intensity Dependency of the Light Emission Wavelength of CdSe/ZnS Quantum Dots

  • Lee, Honyeon
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.3
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    • pp.11-17
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    • 2021
  • I performed a semi-analytical numerical analysis of the effects of core size and electric field intensity on the light emission wavelength of CdSe/ZnS quantum dots (QDs). The analysis used a quantum mechanical approach; I solved the Schrödinger equation describing the electron-hole pairs of QDs. The numerical solutions are described using a basis set composed of the eigenstates of the Schrödinger equation; they are thus equivalent to analytical solutions. This semi-analytical numerical method made it simple and reliable to evaluate the dependency of QD characteristics on the QD core size and electric field intensity. As the QD core diameter changed from 9.9 to 2.5 nm, the light emission wavelength of CdSe core-only QDs varied from 262.9 to 643.8 nm, and that of CdSe/ZnS core/shell QDs from 279.9 to 697.2 nm. On application of an electric field of 8 × 105 V/cm, the emission wavelengths of green-emitting CdSe and CdSe/ZnS QDs increased by 7.7 and 3.8 nm, respectively. This semi-analytical numerical analysis will aid the choice of QD size and material, and promote the development of improved QD light-emitting devices.

Strengthening of prestressed girder-deck system with partially debonding strand by the use of CFRP or steel plates: Analytical investigation

  • Haoran Ni;Riliang Li;Riyad S. Aboutaha
    • Computers and Concrete
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    • v.31 no.4
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    • pp.349-358
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    • 2023
  • This paper describes an in-depth analysis on flexural strength of a girder-deck system experiencing a strand debonding damage with various strengthening systems, based on finite element software ABAQUS. A detailed finite element analysis (FEA) model was developed and verified against the relevant experimental data performed by other researchers. The proposed analytical model showed a good agreement with experimental data. Based on the verified FE model, over a hundred girder-deck systems were investigated with the consideration of following variables: 1) debonding level, 2) span-to-depth ratio (L/d), 3) strengthening type, 4) strengthening material thickness. Based on the data above, a new detailed analytical model was developed and proposed for estimating residual flexural strength of the strand-debonding damaged girder-deck system with strengthening systems. It was demonstrated that both finite element model and analysis model could be used to predict flexural behaviors for debonding damaged prestressed girder-deck systems. Since the strands are debonding from surrounding concrete over a certain zone over the length of the beam, the increase of strain in strands can be linked with a ratio ψ, which is Lp/c. The analytical model was proposed and developed regarding the ratio ψ. By conducting procedure of calculating ψ, the ψ value varies from 9.3 to 70.1. Multiple nonlinear regression analysis was performed in Software IBM SPSS Statistics 27.0.1 to derive equation of ψ. ψ equation was curved to be an exponential function, and the independent variable (X) is a linear function in terms of three variables of debonding level (λ), span length (L), and amount of strengthening material (As). The coefficient of determinate (R2) for curve fitting in nonlinear regression analysis is 0.8768. The developed analytical model was compared to the ultimate capacities computed by FEA model.

Nonlinear Analysis for the Prediction of Lateral Behavior of Single Piles in Non-homogeneous Sandy Soil (비균질 사질토 지반에서 단일말뚝의 수평거동 예측을 위한 비선형 해석기법)

  • 김영수;김병탁;허노영
    • Journal of the Korean Geotechnical Society
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    • v.16 no.4
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    • pp.5-16
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    • 2000
  • THe purpose of this paper is to suggest the analytical method which can predict lateral nonlinear behavior in non-homogeneous soil using the coefficient of soil resistance and ultimate soil resistance. Those parameters are obtained through back analysis on the base of the results of a series of model tests.Analytical method of Chang is more or less difficult to predict nonlinear behavior in non-homogeneous sol. So, in this study, for the prediction of nonlinear behavior the compositive analytical method which apply the p - y curve to Chang model is suggested. Also, the program is developed to predict nonlinear behavior using the compositive analytical method and it can be used to calculated the deflection, bending moment and soil reaction with DFM in non-homogeneous soil. To establish applicability of the suggested analytical method, the results of model tests and field tests and Pentagon2D finite element program are compared with those of the compositive analytical method. In the analysis values of the coefficient of soil reaction and ultimate soil resistance are also applied to the case of non-homogeneous soil. Lateral defection calculated using the compositive analytical method has been found to be in good agreement with values measured in field and model load tests.

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Quality Control on Neutron Activation Analysis for Urban Dust by the Proficiency Test (비교숙련도 시험을 통한 도시대기분진에 대한 중성자방사화분석법의 품질관리)

  • Moon, Jong-Hwa;Kim, Sun-Ha;Chung, Yong-Sam
    • Analytical Science and Technology
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    • v.15 no.5
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    • pp.433-438
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    • 2002
  • Trace elements in two air filters (V-50, P-50) artificially loaded with urban dust provided from IAEA were determined non-destructively using instrumental neutron activation analysis. Standard reference material (Urban Particulate Matter, SRM 1648) of National Institute of Standard and Technology was used for analytical quality control. About 20 elements in both of loaded filter samples were determined. To evaluate inter-laboratory comparison and proficiency test, analytical data were statistically treated with the results which collected from 49 laboratories, 40 countries participated in this study using neutron activation analysis, particle induced X-ray emission, inductively coupled plasma mass spectroscopy, etc,. From the results of statistical treatment, Z-scores are within ${\pm}2$. Furthermore, accuracy and precision of obtained analytical values are passed according to the criteria of the proficiency test. Consequently, it was proved that analytical quality for air dust samples being performed has been controlled properly.

Eddy Current Loss Analysis of Slotless Double-sided Cored Type Permanent Magnet Generator by using Analytical Method (해석적 방법을 이용한 슬롯리스 양측식 코어드 타입 영구자석 발전기의 와전류 손실 해석)

  • Jang, Gang-Hyeon;Jung, Kyoung-Hun;Hong, Keyyong;Kim, Kyong-Hwan;Choi, Jang-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.10
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    • pp.1639-1647
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    • 2016
  • This paper deals with eddy current loss analysis of Slotless Double sided Cored type permanent magnet linear generator by using analytical method, space harmonic method. In order to calculate eddy current, this paper derives analytical solution by the Maxwell equation, magnetic vector potential, Faraday's law and a two-dimensional(2-D) cartesian coordinate system. First, we derived the armature reaction field distribution produced by armature wingding current. Second, by using derived armature reaction field solution, the analytical solution for eddy current density distribution are also obtained. Finally, the analytical solution for eddy current loss induced in permanent magnets(PMs) are derived by using equivalent, electrical resistance calculated from PMs volume and eddy current density distribution solution. The analytical result from space harmonic method are validated extensively by comparing with finite element method(FEM).

Simplified analytical solution of tunnel cross section under oblique incident SH wave in layered ground

  • Huifang Li;Mi Zhao;Jingqi Huang;Weizhang Liao;Chao Ma
    • Earthquakes and Structures
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    • v.24 no.1
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    • pp.65-79
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    • 2023
  • A simplified analytical solution for seismic response of tunnel cross section in horizontally layered ground subjected to oblique incidence of SH wave is deduced in this paper. The proposed analytical solution consists of two main steps: free-field response in layered field and tunnel response. The free field responses of the layered ground are obtained by one-dimensional finite element method in time domain. The tunnel lining is treated as a thick-wall cylinder to calculate the tunnel response, which subject to free field stress. The analytical solutions are verified by comparing with the dynamic numerical results of two-dimensional ground-lining interaction analysis under earthquake in some common situations, which have a good agreement. Then, the appropriate range of the proposed analytical solution is analyzed, considering the height of the layered ground, the wavelength and incident angle of SH wave. Finally, by using the analytical solutions, the effects of the ground material, burial depth of the tunnel, and lining thickness and the slippage effect at the ground-lining interface on the seismic response of tunnels are investigated. The proposed solution could serve as a useful tool for seismic analysis and design of tunnels in layered ground.