• Title/Summary/Keyword: Amphoteric

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Chemical Structural Characteristics of the Amphoteric Imidazoline Surfactants (이미다졸린형 양쪽성계면활성제의 화학구조적 특성)

  • Ro, Y.C.;Nam, K.D.
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.749-755
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    • 1994
  • Imidazoline compounds have been developed in many industrial fields(eg. cosmetic, etc.). These materials can be used in almost all pH ranges and recently its use is successively increased because of nonirritative property. Since the concern of safety has enlarged at industrial application, naturally the use of amphoteric surfactants with new special properties has more. We report general properties of chemical structures of imidazoline surfactants effect.

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Studies on the Packing Characteristics of Coating Colors Based on the Rheological Properties at High Shear Rates (고전단점도 측정에 의한 도공액의 패킹 특성 연구)

  • 이학래;성용주
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.2
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    • pp.7-15
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    • 1997
  • High shear viscosity at several solids levels was measured for a number of pigment slurries and coating colors containing either anionic or amphoteric latex and analyzed according to Mooney and Eiler equations. Maximum packing fraction and intrinsic viscosity were obtained and compared. Eiler equation provides more credible information than Mooney equation on particle packing and intrinsic viscosity. The packing fraction obtained from Eiler equation was slightly greater than that obtained from static FCC measurement indicating the influence of pigment movement under the dynamic condition. Amphoteric latex caused 4-5% increase of maximum packing fraction of a coating color when its pH is lowered from 7 to 6, while anionic latex did not show any significant change in packing characteristics.

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Synthesis of Long Chain Alkyl Urocanate and Solubilization in Organic Solvent (긴사슬 알킬 우로칸에스테르의 합성 및 유기물질에서의 가용성)

  • Ro, Y.C.;Jeong, H.K.;Nam, K.D.;Lee, J.H.
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.1
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    • pp.83-91
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    • 1993
  • The syntheses of urocanic acid esters was optimized, starting from p-toluenesulfonic acid salt of this acid and long chain fatty alcohols in the organic solvent and extracting water from it by means of azeotropic Compound. The salts of these urocanic acid esters showed amphoteric properties, but their micellization enhances their rate of hydrolysis leading to the free amine. Nevertheless the long chain gives to the esters themselves an amphoteric character allowing their solubilization in micellar media and in microemulsions the result, yield could enhanced.

Preparation and Emulsifying characteristics of Diethylene glycol succinate Derivative (에틸렌디글리콜과 숙신산 에스테르의 제조와 유화 특성)

  • Lee, Jae-Duk;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.233-239
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    • 2009
  • A reaction device raising a generation yield by efficiently removing water generated in an esterified reaction between diethylene glycol monoethyl ether and succinic acid with mixture of an azeotropic point was newly developed as a new product in development of more stabilized emulsifier with a semi-solid phase(cream) in an emulsified phase of interfacial activity. The bis-(diethylene glycol monoethyl ether succinate(hereinafter, called as BDGS) with a high yield of more than 95% was obtained. As this has a property containing amphoteric emulsified functions such as W/O type or O/W type, etc., and has a merit that can be used regardless of any emulsified phase, there is no need using other emulsified surfactant. therefore, as this has excellent skin wetability in the cosmetics industry, a product having a wider range in quality compatibility or cost saving, etc. as a humectant has been developed.

Principle Component Analysis on Electrokinetic Measurements for Amphoteric Fibers/Acid Dye System (앰포테릭섬유/산성염료계의 계면동전압 측정치에 대한 PCA)

  • Park, Byeong-Gi
    • Journal of Korean Society for Quality Management
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    • v.13 no.1
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    • pp.26-30
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    • 1985
  • In the light of the properties of colloids, in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Nylon, wool and silk, the typical amphoteric fibers were dyed with Acid dye and various combinations were prepared by combining pH, temperature and dye concentration, in order to generate flowing electric potential which were measured by microviolt meter and specific conductivity meter. The results were transformed to Zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers, and these data were statistically analysed by principle component analysis.

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STUDIES OF DUAL COMPONENT AND MICROPARTICALE RETENTION SYSTEM IN PAPERMAKING ON DYNAMIC DRAINAGE CONDITION

  • Su, Xie-Lai;Yi, Wand-Hai;Shan, Chen-Fu;Quan, Long-Yan
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.11b
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    • pp.125-129
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    • 1999
  • This paper dealt with effect of dual component and micropartical retention system on papermaking. First-pass retention under dynamic drainage condition was studied in neutral and alkaline papermaking system. Cationic starches, amphoteric starches and amphoteric polyacrylamide were added prior to high shear force, then anionic. The system is found to be very useful to inprove filler retention. For mitigating unfavorable effect of interfering sub-stances, anionic trash catcher(ATC) such as p-DADMAC was tested in this study.

Characterization of PVOH Nonwoven Mats Prepared from Surfactant-Polymer System via Electrospinning

  • Jung, Yoon-Ho;Kim, Hak-Yong;Lee, Douk-Rae;Park, Sun-Young;Khil, Myung-Seob
    • Macromolecular Research
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    • v.13 no.5
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    • pp.385-390
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    • 2005
  • The electrospinning process is a fascinating method to fabricate small nanosized fibers of diameter several hundred nanometers. Surfactant-polymer solutions were prepared by adding poly(vinyl alcohol) (PVOH) to distilled water with cationic, anionic, amphoteric, and non-ionic surfactants. Average diameter of the electrospun PVOH fibers prepared from PVOH solution was over 300 nm, and was decreased to 150 nm for the mixture of PVOH/amphoteric surfactant. To explain the formation of ultra fine fiber, the characteristic properties in a mixture of PVOH/surfactant such as surface tension, viscosity, and conductivity were determined. In this paper, the effect of interactions between polymers with different classes of surfactants on the morphological and mechanical properties of electrospun PVOH nonwoven mats was broadly investigated.

A study on ionic character of antibiotics (항생물질(抗生物質)의 이온성상(性狀)에 관(關)한 연구(硏究))

  • Yu, Tae-Jong;Kim, Won-Kyung
    • Applied Biological Chemistry
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    • v.7
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    • pp.59-65
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    • 1966
  • The ionic character of antibiotics and suitable pH values for their extraction can simultaneously be determined by pH-chromatography. The authors utilized the analytical procedure in determining the ionic character of several antibiotics, followed by microbiological Rf determination. The folowing conclusions were made: (1) Antibiotics analyzed can be devided into four groups according to their ionic chracter, that is acidic, basic, neutral, and amphoteric compounds. (2) Penicillin and aureomycin are proved to be acidic, streptomycin to be basic, polymyxin-B to be neutral, and finally both chloromycetin and erythromycin to be amphoteric. The results on their ionic character with regard to their molecular structure were briefly discussed.

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Recycling of Wastepaper(XIV) -The Effect of Amphoteric PAM and Fines on the Dry Strength Properties of Condebelt Press Dried Linerboards- (고지재생연구(제14조) -고온압착건조처리 골판지 원지의 강도에 미치는 양성 PAM과 미세분의 영향-)

  • 최병수;윤혜정;류정용;신종호;송봉근
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.2
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    • pp.24-31
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    • 2001
  • As a novel method to improve strength properties of recycled test liner, Condebelt press drying system was introduced and adopted into Korea. New press drying treatment could enhance the surface and strength properties in accordance with the increase of sheet density. However, Condebelt drying can not increase the density of repeatedly recycled test liner as much as that of virgin UKP and at the same density condition, the strength of Condebelt press dried UKP is greater than that of press dried test liner. In order to increase the strength of test liner, two attempts were tried in this study. First, addition of polyelectrolytes, dry strength agent was investigated with a view to promote the fiber bonding potential of reclaimed corrugated container pulp. Second, blending effect of fines were analyzed in an aims of increasing density and strength of test liner. The results were as follows; Even in the case of test liner densified by Condebelt press dryer, addition of amphoteric PAM as a dry strength agent was effective in increasing strength properties and so the effect of dry strength agent on improving bonding potential of recycled OCC fiber could be confirmed. As an appropriate addition level of amphoteric PAM, below 1% based on dry pulp weight was suggested. Different from virgin UKP, density of recycled test liner can be increased by the blending of OCC fines and strength properties also can be improved. However, excessive blending of OCC fines could result in decreasing of density and serious weakening of test liner. The best blending ration of fines in test liner can be determined as about 30%. Taking into account the fines content in general OCC pulp as 50%, excessive 20% of fines were supposed to be fractionated and removed in order to achieve the best strength of Condebelt press dried test liner.

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Synetheses and Surface Active Properties of Amphoteric Surfactant Derivatives(7);Detergency Performance of Amphoteric Surfactants Derived from Imidazoline (양쪽성계면활성제의 유도체합성 및 계면성에 관한 연구(제 7보);이미다졸린으로부터 유도된 양쪽성계면활성제의 세정성)

  • Ro, Y.C.;Kim, T.Y.;Nam, K.D.
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.47-54
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    • 1995
  • Water pollution, which is caused by surfactants, is increased by insolubility and excessive uses of detergents. The detergency properties of nine kinds of amphoteric surfactants derived from imidazoline were investigated and compared with sodium lauryl sulfats(SLS) of petrochemical surfactant by using detergent formulations. Several physico-chemical properties were measured to investigate the effective factors on detergency. From the comparision of these compounds with SLS, it was found that 1-(2-hydroxyethyl)-1- (3-sulfonatedpropyl)-2-undecyl-2-imidazolinum [IV] has the most outstnading characteristics of detergency and various fundamental properties. Therefore, this result is expected to do its environmental stability as a nonpolluting detergent. Detergency process of surfactants were discussed in relation to physico-chemical treatments. Performance improvement on detergency is made work of adhesion to soil as small as possible. Therefore these results show that contamination is easily removed and industrial applications may be respected.