• Title/Summary/Keyword: Amorphous polymer

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Characteristics of the indium tin oxide film grown on PES and PET substrates by a low-frequency magnetron sputtering method

  • Jung, Sang-Kooun;Lee, Sung-Ho;Kim, Myung-Chan;Lee, Do-Kyung;Cho, Yong;Park, Duck-Kyu;Sohn, Sang-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1560-1563
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    • 2005
  • In this study, we introduce indium tin oxide (ITO) thin films grown by using a low-frequency magnetron sputtering method (LFMSM). Characteristics of the ITO thin films deposited on polyethersulfone (PES) and polyethylene terephthalate (PET) substrates are investigated. Experiments were carried out as a function of deposition time. ITO thin films on polymer substrates revealed amorphous structure. The optical, the electrical and structural properties of the films on PES substrate are better than those on PET substrates.

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Recycling of Wastepaper(IV) -The effect of polyelectrolytes on recycled KOCC stock- (고지재생연구 (제4보) -고분자 전해질이 KOCC 재생지료에 미치는 영향)

  • 김정은;안인숙;류정용;신종호;송봉근;오세균
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.31 no.1
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    • pp.23-30
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    • 1999
  • The effects of polyelectrolytes and enzyme, alone and in combination, were investigated in OCC recycling system. Four types of the polyelectrolytes based on acrylamide, cationic and anionic monomers were applied to the enzyme-treated KOCC stock to improve the strength and drainage properties of testliner. The polyelectrolytes used in this work were designed in terms of molecular weight and charge density. The water conditions used for recycling were also varied. The results showed that the hydrolytic action of enzyme gave reduced surface area and amorphous region of fiber, and as a result, the cationic polymer was lost apparently its flocculating power due to the reduced bonding site of fiber surface. When the hardness and conductivity of water had been controlled to the conditins of OCC paper mill, the application of amphoteric polyelectrolyte to the enzyme-treated recycled stock was the most effective with respect to the strength and drainage properties of testliner.

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A study on the filling imbalances in hot-runner mold for internal gear based on injection molding (내측 기어 성형용 핫러너 금형에서의 충전불균형에 관한 연구)

  • No, Byung-Soo;Jea, Duck-Gun;Jeong, Yeong-Deug
    • Design & Manufacturing
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    • v.2 no.3
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    • pp.1-5
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    • 2008
  • Plastic parts are molded for the purpose of mass production in injection molding. Therefore designer is usually designing molds that has geometrically balanced hot runner lay-out for filling balance at cavities. Although, mold is manufactured with geometrically balanced runner lay-out, there are actually filling imbalances in cavities. These filling imbalances phenomenon are caused by complicated interaction between melt and mold. In this paper, filling imbalances for internal gear based on injection molding in hot-runner mold were investigated by CAE and injection molding experiences.

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Characteristics of Poly-Si TFTs Fabricated on Flexible Substrates using Sputter Deposited a-Si Films

  • Kim, Y.H.;Moon, D.G.;Kim, W.K.;Han, J.I.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.297-300
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    • 2005
  • The characteristics of polycrystalline silicon thin-film transistors (poly-Si TFTs) fabricated using sputter deposited amorphous silicon (a-Si) precursor films are investigated. The a-Si films were deposited on flexible polymer substrates using argon-helium mixture gases to minimize the argon incorporation into the film. The precursor films were then laser annealed by using a XeCl excimer laser and a four-mask-processed poly-Si TFT was fabricated with fully self-aligned top gate structure. The fabricated pMOS TFT showed field-effect mobility of $32.4cm^2/V{\cdot}s$ and on/off ratio of $10^6$.

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Electro-optic Properties of a Guest-Host System Containing a Phenothiazine-based Chromophore: Effect of the Chromophore Density on the Macroscopic Optical Nonlinearity

  • Lee, Sang-Kyu;Cho, Min-Ju;Yoon, Hyuk;Lee, Seung-Hwan;Kim, Jae-Hong;Qing Zhang;Choi, Dong-Hoon
    • Macromolecular Research
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    • v.12 no.5
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    • pp.484-489
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    • 2004
  • We have prepared a phenothiazine-based nonlinear optical (NLO) chromophore that displays a fairly high microscopic nonlinearity through intramolecular charge transfer. The phenothiazine unit plays important roles of contributing its high electron donating ability and connecting the resonance pathway through a conjugative effect in the cyclized ring adjacent to the aromatic ring. Theoretical calculations and an absorption spectroscopic study provided useful information concerning the microscopic nonlinearity of the chromophores. We investigated the electro-optic (EO) properties of the guest-host systems in amorphous polycarbonate containing the synthesized chromophores at different concentrations under different poling temperatures. A real-time pole and probe method provided a much greater amount of information regarding how the EO properties can arise and how they can be optimized.

Experimental and Numerical Study on the Viscoelastic Property of Polycarbonate near Glass Transition Temperature for Micro Thermal Imprint Process (열방식 마이크로 임프린트 공정을 위한 고분자 재료의 수치적 모델링)

  • Lan, Shuhuai;Lee, Hey-Jin;Lee, Hyoung-Wook;Song, Jung-Han;Lee, Soo-Hun;Ni, Jun;Lee, Moon-G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.70-73
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    • 2009
  • The aim of this research is to obtain a numerical material model for an amorphous glassy polymer, polycarbonate (PC), which can be used in finite element analysis (FEA) of the micro thermal imprint process near the glass transition temperature. An understanding of the deformation behavior of the PC specimens was acquired by performing tensile stress relaxation tests. The viscoelastic material model based on generalized Maxwell model was introduced for the material near Tg to establish the FE model based on the commercial FEA code ABAQUS/Standard with a suitable set of parameters obtained for this material model from the test data. Further validation of the model and parameters was performed by comparing the analysis of FE model results to the experimental data.

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PvT measruement method of polymer using capillary rheometer (캐필러리 레오미터를 이용한 고분자의 PvT 측정 방법)

  • Kim, Sun-Kyoung;Park, Jae-Un
    • Design & Manufacturing
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    • v.14 no.3
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    • pp.31-36
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    • 2020
  • In injection molding processes, the property of molten resin should be characterized accurately. Among several properties, the PvT state is the most important one, since it affects the shrinkage, warpage, molded weight, and the part density. Thus, the PvT data is crucial to the simulation of the injection molding process. This work shows how such a measurement can be performed for a semi-crystalline and amorphous polymers. The PvT measurement has been conducted using a capillary rheometer using a suitable accessory that blocks the capillary. The results have shown that the PvT data can be obtained using such a rheometer and then the PvT coefficients of the Tait equation can be reached.

Dissolution Enhancement of Fenticonazole Nitrate from Hydrophilic Polymer Solid Dispersions (친수성 고분자와의 고체분산체로부터 질산펜티코나졸의 용출 증가)

  • Kim, Young-Il;Kim, Seung-In;Choi, Jae-Yoon
    • Journal of Pharmaceutical Investigation
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    • v.19 no.2
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    • pp.109-116
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    • 1989
  • Solid dispersion of fenticonazole nitrate (FN) with poloxamer 407, polyethylene glycol 6000, povidone (K-90) were prepared by the solvent method. To characterize the state of the drug in solid dispersions, the x-ray diffractometry and differential scanning calorimetry were carried out. The identification of these systems suggested that FN in the poloxamer 407 system remained in crystalline state, and the drug in the PVP system was amorphous. A marked increase in the dissolution rate of FN was attained by dispersing the drug in the hydrophilic polymers used, and the dispersion with poloxamer 407 was superior to the other two carriers in releasing the drug into solution.

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Dispersions of partially reduced graphene oxide in various organic solvents and polymers

  • Kim, Hye Min;Kim, Seo Gyun;Lee, Heon Sang
    • Carbon letters
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    • v.23
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    • pp.55-62
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    • 2017
  • We report on the dispersion state of partially reduced graphene oxide (PRGO) in organic solvents, namely methyl ethyl ketone, ethyl acetate, methylene chloride, toluene, and xylene, by controlling the carbon to oxygen (C/O) atomic ratio of the PRGOs. A two-phase solvent exchange method is also proposed to transfer PRGO from water to an aprotic solvent, such as methyl ethyl ketone. We achieve relatively good dispersion in aprotic and non-polar solvents by controlling the C/O atomic ratio of the PRGOs and applying the two-phase solvent exchange method. There is an increase in the glass transition temperatures with the dispersion of PRGOs into amorphous polymers, in particular a $4.4^{\circ}C$ increase for poly(methyl methacrylate) and $3.0^{\circ}C$ increase for polycarbonate. Good dispersion of PRGO in a nonpolar polymer, such as linear low density polyethylene, is also obtained.

Corrosion Properties of Carbon-Coated Metallic Bipolar Plate for PEMFC (고분자 전해질 연료전지 금속 분리판 적용을 위한 탄소 박막의 증착과 내식성 평가)

  • Jang, Dong-Su;Lee, Jung-Joong
    • Journal of the Korean institute of surface engineering
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    • v.48 no.3
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    • pp.87-92
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    • 2015
  • Carbon thin films were deposited on STS 316L sheets by inductively coupled plasma enhanced magnetron sputtering with or without substrate bias voltage. Typical Raman spectrum for amorphous diamond-like carbon (DLC) was obtained, and the interfacial contact resistance (ICR) was measured to show its conductive nature. The electrochemical impedance spectroscopy (EIS) was used to investigate the corrosion mechanism of the carbon coating under the polymer electrolyte membrane fuel cell (PEMFC) condition. According to the pore-corrosion mechanism, the electrolyte penetrates the carbon coating through the pores and reacts with the substrate. As the substrate corrosion proceeds, the pore enlargement occurs and the surface area of the substrate exposed to the electrolyte. Applicability of the carbon coating for the PEMFC bipolar plate was evaluated by potentiodynamic polarization experiments. Finally, an adhesion problem was briefly considered.