• Title/Summary/Keyword: Ammonium Nitrate

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Aerosol Size Distribution and Composition at Kosan, Cheju Island : Measurements in April 1998 (제주도 고산에서의 에어로솔 입경분포별 조성: 1998년 4월 측정 연구)

  • 김용표;배귀남;지준호;진현철;문길주
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.5
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    • pp.677-685
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    • 1999
  • Aerosol mass size distributions were measured at Kosan, Cheju Island in April 1998 and their compositions were analyzed. Microorifice Uniform Deposit Impactor(MOUDI) was used to collect aerosols. Sulfate and ammonium ions were predominatly present at fine mode of the aerosols while nitrate, chloride, and metal ions were mostly at coarse mode. Based on the size distribution of nitrate, it is suggested that most nitrate were from gas to particle conversion on coarse particles. Non-sea salt(nss) fraction of sulfate accounted for more than 90% of total sulfate mass concentration. In general, ion concentrations in this study are lower than those measured at the same site from the previous studies. Ion balance and chloride ion levels indicates that there had been anthropogenic chloride emission sources near to the site during the measurements.

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Assessment of Nitrate Leaching from Cultivated Land by LEACHN (LEACHN을 이용한 경작지의 질소 유출 평가)

  • Jung, Young-Wook;Kim, Mee-Jeong;Oh, Dong-Sik;Park, Jae-Woo
    • 한국방재학회:학술대회논문집
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    • 2008.02a
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    • pp.803-806
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    • 2008
  • LEACHN is the computer simulation model which can be used to simulate field-scale N transformations and movement and has three organic pools (plant residue, manure, and soil humus), three inorganic pools (urea, nitrate and ammonium) and plant. Pot experiment operated May to October in 2004. LEACHN simulated the nitrogen movement and transformation in soil using method of PEST and trial and error.

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방사성핵종 오염 토양 특성 분석 및 핵종제거 방법 연구

  • 김계남;원휘준;오원진
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.209-212
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    • 2002
  • Main radionuclides of the soil waste stored in Korea Atomic Energy Research Institute are Co-60 and Cs-137. Moisture content of soil is 12%, pH of soil is 5.8, and content of organic matter is 2.2 %. Radioactive concentrations of the soil particle size of which is less than 0.063mm and soil in the drum surface of which is more than radiation dose rate 0.05mR/hr are higher. Meanwhile, radioactive concentration of soil in the drum surface of which is less than radiation dose rate 0.02 mR/hr are mostly lower. On using the mixing solution of ammonium sulfate and citric acid, 62% Co was removed from soil and 41% Cs was removed. Also, on using the mixing solution of ammonium nitrate and citric acid, 61% Co was removed from soil and 39% Cs was removed, and on using the mixing solution of ammonium potassium oxalate, 36% Co was removed and only 3% Cs was removed. And on using only water, removal efficiency is less than 5%.

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Growth and Amino Acid Contents of Spirulina platensis with Different Nitrogen Sources

  • Park, Aeran;Kim, Song-Gun;Yoon, Byung-Dae;Oh, Hee-Mock
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.6
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    • pp.368-372
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    • 2003
  • The growth and amino acid contents of the cyanobacterium, Spirulina platensis strain NIES 46, were investigated using ammonium, nitrate, nitrite, or urea as the sole nitrogen source in a batch culture. Chlorophyll a concentration was highest at 2,096$\mu\textrm{g}$/L in the nitrate group after 10days of cultivation, while the dry weight of S. platensis was highest at 4.5g/L in the ammonium group after 30days of cultivation. The total amino acid content was highest at 174mg/g dry weight of S. platensis in the urea group at the end of the cultivation period, yet the amino acid patterns for S. platensis were similar for all the experimental groups. Therefore, it seemed that the growth and amino acid composition of S. platensis varied depending on the type of nitrogen sources, while the amino acid patterns were not changed. Also, the most efficient harvesting time for S. platensis seemed to be approximately 10 days after cultivation.

Characteristics of $PM_{2.5}$ Particles Measured in the Background Sites of Korea (우리나라 청정 지역에서 측정한 $PM_{2.5}$ 입자의 특성)

  • 이종훈;김용표;문길주;김희강;정용승;이종범
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.6
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    • pp.439-450
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    • 1997
  • Atmospheric fine particles $(PM_{2.5})$ were collected at the background sites, Kangwha, Taean, and Kosan and characterized to understand their behaviors at the sites. Daily samples of $PM_{2.5}$ mass were measured and ionic species, carbonaceous species, and gaseous species were analyzed. Four-day backward trajectory analysis was also carried out. The mean concentrations of anthropogenic species were highest at Kangwha among three sites, while contributions from sea salts wree highest at Taean during the measurement period due to higher wind speed at Taean. Major chemical components in fine particles were sulfate, organic carbon, nitrate, and ammoniu. Most of the non-sea-salt (nss) sulfates in $PM_{2.5}$ might be present as ammonium sulfates at these sites. Most air parcels arriving at Kangwha and Taean were from northern China. Therefore, both sites were thought to be affected by the same air parcel. At Kosan, during the measurement period, air parcels were from either northern China or sourthern China. The nss sulfate concentration in the air parcels from southern China was higher, while the nss calcium, nitrate, and ammonium concentrations were higher when the air parcels were from northern China.

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Analysis of Explosion Energy related to the Cause of Tianjin Explosion Accident in China (중국 텐진항 폭발사고 원인과 관련된 폭발 에너지 분석)

  • Kwon, Sangki;Kim, Ha Yung
    • Explosives and Blasting
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    • v.34 no.1
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    • pp.1-10
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    • 2016
  • On August 12, 2015, two huge explosions were accidently happened in Tianjin port, China. The explosion energies of the two explosions were similar to those of TNT 3 tons and TNT 21 tons. Until now, the cause of the explosions was not clearly announced but some guesses of the cause were released. One of the possible cause of the explosion is the generation of explosive acetylene gas from the chemical reaction between $CaC_2$ and spraying water to extinguish fire happened at the storage site of different chemical compounds. The explosion of acetylene gas might ignite the explosion of 800 tons of ammonium nitrate. In this study, the explosion due to the scenario was analyzed in order to check that such a chemical reaction can produce the huge explosion observed at the Tianjin accident.

Analysis of Soil Total Nitrogen and Inorganic Nitrogen Content for Evaluating Nitrogen Dynamics

  • Lee, Seul-Bi;Sung, Jwa-Kyung;Lee, Ye-Jin;Lim, Jung-Eun;Song, Yo-Sung;Lee, Deog-Bae;Hong, Suk-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.2
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    • pp.100-105
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    • 2017
  • Various methods for assessing soil total nitrogen (TN) and inorganic N content have been developed to manage nutrient and to understand N cycle in soil. This paper address the technical procedures in arable soil samples to conduct soil sampling, sample preparation, and measuring total N and inorganic N. Among various methods for measuring soil total nitrogen contents, Kjeldahl distillation and Indophenol blue method have widely used due to reliability and economic advances. Also, two methods can analyze more samples at the same time compared with other nitrogen measuring methods. For evaluating inorganic N content, mainly in forms of nitrate-N ($NO_3{^-}-N$) and ammonium-N ($NH_4{^+}-N$), extraction with a single reagent such as 2M KCl has been employed, followed by Kjeldahl distillation or indophenol blue methods.

Apparent Dominance of Regenerated Primary Production in the Yellow Sea

  • Park, Myung-G.;Yang, Sung-R.;Shim, Jae-H.;Hong, Gi-H.;Chung, Chang-S.;Yang, Dong-B.;Cho, Byung-C.
    • Journal of the korean society of oceanography
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    • v.39 no.1
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    • pp.20-25
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    • 2004
  • The Yellow Sea is known to be a very productive region in terms of fisheries. However, its trophic status seems to be highly variable, ranging from oligotrophic to eutrophic, based on new production (NP) values. The NP and regenerated production (RP) values estimated from $^{15}N$-labelled nitrate and ammonium uptake in spring (April 1996) and winter (February 1997) during this study ranged from 0.05 to 19.8 mg $N m^{-2} d^{-1}$ and from 0.1 to 22.8 mg $N m^{-2}d^{-1}$, respectively. Our measurements and earlier observations suggested that NP in the Yellow Sea varied over the four orders of magnitude (range 0.05-180.9 mg $N m^{-2} d^{-1}$) temporally and spatially, and that RP (range 0.1-507.5 mg $N m^{-2}d^{-l}$) based on ammonium predominated during most period of the year, except in winter when both productions were low. The significant nitrogen uptake by phytoplankton below the euphotic zone and episodic entrainment of phytoplankton from below the euphotic zone into the euphotic zone, and nitrite excretion and dissolved organic nitrogen release during nitrate uptake might explain the apparent dominance of RP in the Yellow Sea.

Development of Capillary Columns for Ion Chromatography (이온 크로마토그래피용 모세관 컬럼의 개발)

  • Kim, Ho-Hyun;Pyo, Dong-Jin
    • Analytical Science and Technology
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    • v.12 no.6
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    • pp.521-527
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    • 1999
  • In this study, capillary columns for ion chromatography were developed to analyze trace amount of ions in samples. When small I.D. capillary columns are used in ion chromatography, the typical flow rate of the mobile phase is $5{\sim}15{\mu}L/min$ and the typical column length is 50~150 mm. The capillary columns were made using RSL-300 fused silica capillary(I.D.: 0.53 mm, O.D.: 0.67 mm) and AG14 column resin(support : polystyrene-divinylbenzene, functional group : alkyl quaternary ammonium). The new conductivity cell and suppressor were also developed and made for capillary column ion chromatography. When several anions (fluoride, nitrite, nitrate, chlorate) were analyzed using these capillary columns, reproducible and good chromatograms were obtained.

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Etchant for Dissolving Thin Layer of Ag-Cu-Au Alloy

  • Utaka, Kojun;Komatsu, Toshio;Nagano, Hiroo
    • Corrosion Science and Technology
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    • v.6 no.6
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    • pp.304-307
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    • 2007
  • As to the reflection electrode of LCD (liquid crystal displays), silver-copper-gold alloy (hereafter, it is called as ACA (Ag98%, Cu1%, Au1%)) is an effective material of which weathering resistance can be improved more compared with pure silver. However, there is a problem that gold remains on the substrate as residues when ACA is etched in cerium ammonium nitrate solution or phosphoric acid. Gold can not be etched in these etchants as readily as the other two alloying elements. Gold residue has actually been removed physically by brushing etc. This procedure causes damage to the display elements. Another etchant of iodine/potassium iodide generally known as one of the gold etchants can not give precise etch pattern because of remarkable difference in etching rates among silver, copper and gold. The purpose of this research is to obtain a practical etchant for ACA alloy. The results are as follows. The cyanogen complex salt of gold generates when cyanide is used as the etchant, in which gold dissolves considerably. Oxygen reduction is important as the cathodic reaction in the dissolution of gold. A new etchant of sodium cyanide / potassium ferricyanide whose cathodic reduction is stronger than oxygen, can give precise etch patterns in ACA alloy swiftly at room temperature.